Electrochemical Detection of Sarcosine and Supercapacitor Based on a New Ni–Metal Organic Framework Electrode Material
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials and Methods
2.2. Synthesis of Ni-1
2.3. Single-Crystal Structure Determination
2.4. Fabrication of Working Electrode
2.5. Electrochemical Measurements
3. Results and Discussion
3.1. Structure Description
3.2. Purity and Thermal Stability
3.3. Investigation of Electrochemical Properties
3.4. Selectivity and Stability of the Sensor
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | Ni-1 |
---|---|
Chemical Formula | C60H54N6Ni3O18 |
Formula weight | 1323.16 |
Crystal system | Monoclinic |
Space group | C2 |
a (Å) | 22.501(2) |
b (Å) | 11.2879(12) |
c (Å) | 13.4015(12) |
α (°) | 90 |
β (°) | 126.099(10) |
γ (°) | 90 |
V (Å3) | 2750.3(5) |
Z | 2 |
Dc (g/cm3) | 1.598 |
μ (mm−1) | 1.101 |
T (K) | 293(2) |
Wavelength (Å) | 0.71073 |
F(000) | 1368.0 |
Crystal size (mm) | 0.20 × 0.19 × 0.12 |
θ range(°) | 7.22 to 59.298 |
Index ranges | −28 ≤ h ≤ 31 |
−15 ≤ k ≤ 15 | |
−18 ≤ l ≤ 16 | |
Reflections collected | 11,900 |
Independent reflections | 11,900 [Rint = 0.0759, Rsigma = 0.1150] |
Parameters | 396 |
Goodness-of-fit on F2 | 1.056 |
R1 indices [I > 2σ(I)] | 0.0769 |
wR2 indices [I > 2σ(I)] | 0.1609 |
R1 indices [all data] | 0.1005 |
wR2 indices [all data] | 0.1772 |
Peak and hole (e Å-3) | 1.37/−0.95 |
Ni1- O1 = 2.029(7) | Ni2- O3 = 2.078(8) |
Ni1- O7 = 2.048(6) | Ni2- O3 2 = 2.078(8) |
Ni1- N2 = 2.090(12) | Ni2- N3 = 2.098(15) |
Ni1- O5 1 = 2.091(6) | Ni2- O2 2 = 2.118(7) |
Ni1- N1 = 2.113(12) | Ni2- O2 = 2.118(7) |
Ni1- O5 = 2.120(6) | Ni2- N4 = 2.127(15) |
O1-Ni1-O7 98.1(3) | O3-Ni2-O3 2 176.6(5) |
O1-Ni1-N2 84.6(3) | O3-Ni2-N3 88.3(3 |
O7-Ni1-N2 87.3(4) | O3 2-Ni2-N3 88.3(3) |
O1-Ni1-O5 1 93.2(3) | O3-Ni2-O2 2 99.7(3) |
O7-Ni1-O5 1 168.4(3 | O3 2-Ni2-O2 2 80.4(3) |
N2-Ni1-O5 1 91.2(4) | N3-Ni2-O2 2 91.0(2) |
O1-Ni1-N1 92.0(4) | O3-Ni2-O2 80.4(3) |
O7-Ni1-N1 90.8(4) | O3 2-Ni2-O2 99.7(3) |
N2-Ni1-N1 175.9(3) | N3-Ni2-O2 91.0(2) |
O5 1-Ni1-N1 91.3(4) | O2 2-Ni2-O2 178.0(5) |
O1-Ni1-O5 168.3(3) | O3-Ni2-N4 91.7(3) |
O7-Ni1-O5 92.6(3) | O3 2-Ni2-N4 91.7(3) |
N2-Ni1-O5 91.1(4) | N3-Ni2-N4 180.0 |
O5 1-Ni1-O5 76.0(3) | O2 2-Ni2-N4 89.0(2) |
N1-Ni1-O5 92.6(4) | O2-Ni2-N4 89.0(2) |
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Lin, S.; Wang, Y.; Zhang, C.; Wu, Y.; Zhang, B.; Zhou, C.; Yang, H. Electrochemical Detection of Sarcosine and Supercapacitor Based on a New Ni–Metal Organic Framework Electrode Material. Crystals 2021, 11, 1036. https://doi.org/10.3390/cryst11091036
Lin S, Wang Y, Zhang C, Wu Y, Zhang B, Zhou C, Yang H. Electrochemical Detection of Sarcosine and Supercapacitor Based on a New Ni–Metal Organic Framework Electrode Material. Crystals. 2021; 11(9):1036. https://doi.org/10.3390/cryst11091036
Chicago/Turabian StyleLin, Shaomin, Yi Wang, Chenyang Zhang, Yunying Wu, Bodong Zhang, Chunjuan Zhou, and Huan Yang. 2021. "Electrochemical Detection of Sarcosine and Supercapacitor Based on a New Ni–Metal Organic Framework Electrode Material" Crystals 11, no. 9: 1036. https://doi.org/10.3390/cryst11091036