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Volume 14
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10.3390/cryst14100860
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This is an early access version, the complete PDF, HTML, and XML versions will be available soon.
Article

Crystallographic Studies on Non-Covalent Interactions in Aryl-Substituted Antimony Organometallics

by
Ana Torvisco
*,†,
Melanie Wolf
†,
Roland C. Fischer
and
Frank Uhlig
Institute of Inorganic Chemistry, Graz University of Technology, Stremayrgasse 9/V, 8010 Graz, Austria
*
Author to whom correspondence should be addressed.
†
These authors contributed equally to this work.
Crystals 2024, 14(10), 860; https://doi.org/10.3390/cryst14100860 (registering DOI)
Submission received: 13 September 2024 / Revised: 26 September 2024 / Accepted: 28 September 2024 / Published: 29 September 2024
(This article belongs to the Section Crystal Engineering)
Versions Notes

Abstract

A series of novel and previously published organoantimony compounds (RnSbX3-n, X = Cl, Br; R = o-tolyl, 2,6-xylyl, 1-naphthyl, and 9-anthracenyl), were synthesized and characterized. In addition, single-crystal X-ray diffraction was employed to elucidate the molecular structures of all solid species. These compounds display non-covalent intermolecular interactions in the form of edge-to-face, π···π stacking, and CH3···π interactions, and the effects of the substituent type and substituent bulk on the nature of these interactions present will be highlighted and discussed.
Keywords: organoantimony; solid-state structures; intermolecular interactions organoantimony; solid-state structures; intermolecular interactions

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MDPI and ACS Style

Torvisco, A.; Wolf, M.; Fischer, R.C.; Uhlig, F. Crystallographic Studies on Non-Covalent Interactions in Aryl-Substituted Antimony Organometallics. Crystals 2024, 14, 860. https://doi.org/10.3390/cryst14100860

AMA Style

Torvisco A, Wolf M, Fischer RC, Uhlig F. Crystallographic Studies on Non-Covalent Interactions in Aryl-Substituted Antimony Organometallics. Crystals. 2024; 14(10):860. https://doi.org/10.3390/cryst14100860

Chicago/Turabian Style

Torvisco, Ana, Melanie Wolf, Roland C. Fischer, and Frank Uhlig. 2024. "Crystallographic Studies on Non-Covalent Interactions in Aryl-Substituted Antimony Organometallics" Crystals 14, no. 10: 860. https://doi.org/10.3390/cryst14100860

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

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