A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials and Instrumentation
2.2. Synthesis of [Cd(L)(frda)(H2O)]·0.5L·H2O (1)
2.3. Crystal Structure Determination
3. Results and Discussion
3.1. Structural of [Cd(L)(frda)(H2O)]·0.5L·H2O (1)
3.2. Thermal Analysis and Powder X-Ray Diffraction Analysis
3.3. Diffuse Reflectance Spectra
3.4. Photoluminescent Property
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Empirical Formula | C45H39N15O14Cd2 |
---|---|
Formula weight | 1238.73 |
Temperature/K | 293(2) |
Crystal system | Triclinic |
Space group | P-1 |
a/Å | 10.0552(2) |
b/Å | 10.1437(2) |
c/Å | 14.1937(2) |
α/° | 75.690(10) |
β/° | 69.664(2) |
γ/° | 62.167(2) |
Volume/Å3 | 1194.13(4) |
Z | 1 |
ρcalcmg/mm3 | 1.723 |
μ/mm−1 | 0.976 |
F(000) | 622 |
Index ranges | −12 ≤ h ≤ 13, −12 ≤ k ≤ 12, −13 ≤ l ≤ 18 |
Reflections collected | 14832 |
Independent reflections | 4980 |
Data/restraints/parameters | 5560/0/396 |
Goodness-of-fit on F2 | 1.030 |
Final R indexes [I ≥ 2σ(I)] | R1 = 0.0310, wR2 = 0.0709 |
Final R indexes [all data] | R1 = 0.0361, wR2 = 0.0742 |
Largest diff. peak/hole / e Å−3 | 0.470/−0.460 |
Bond | d | Bond | d |
---|---|---|---|
Cd(1)-N(1) | 2.288(2) | Cd(1)-N(3) i | 2.281(2) |
Cd(1)-O(6) | 2.346(2) | Cd(1)-O(2) | 2.3470(16) |
Cd(1)-O(4) ii | 2.3871(19) | Cd(1)-O(3) ii | 2.5427(18) |
Cd(1)-O(1) | 2.5866(18) | ||
Angle | ω | Angle | ω |
N(3) i-Cd(1)-N(1) | 175.41(7) | N(3) i-Cd(1)-O(6) | 90.86(8) |
N(1)-Cd(1)-O(6) | 84.94(8) | N(3) i-Cd(1)-O(2) | 93.45(6) |
N(1)-Cd(1)-O(2) | 90.84(7) | O(6)-Cd(1)-O(2) | 135.86(7) |
N(3) i-Cd(1)-O(4) ii | 99.08(7) | N(1)-Cd(1)-O(4) ii | 82.57(7) |
O(6)-Cd(1)-O(4) ii | 133.33(7) | O(2)-Cd(1)-O(4) ii | 89.19(6) |
N(3) i-Cd(1)-O(3) ii | 83.11(7) | N(1)-Cd(1)-O(3) ii | 94.58(7) |
O(6)-Cd(1)-O(3) ii | 83.62(7) | O(2)-Cd(1)-O(3) ii | 140.50(6) |
O(4) ii-Cd(1)-O(3) ii | 53.03(6) | N(3) i-Cd(1)-O(1) | 87.07(7) |
N(1)-Cd(1)-O(1) | 94.26(7) | O(6)-Cd(1)-O(1) | 83.57(7) |
O(2)-Cd(1)-O(1) | 52.90(6) | O(4) ii-Cd(1)-O(1) | 142.01(6) |
O(3) ii-Cd(1)-O(1) | 163.71(6) |
D–H···A | d(D–H) | d(H···A) | d(D···A) | ∠DHA |
---|---|---|---|---|
O(6)–H(6A)···O(5) a | 0.70(4) | 2.18(4) | 2.872(4) | 167(5) |
C(6)–H(6B)···O(6) b | 0.79(4) | 1.96(4) | 2.738(3) | 169(5) |
C(2)–H(2)···O(2) c | 0.9300 | 2.3200 | 3.142(3) | 148.00 |
C(4) –H(4)···N(4) | 0.9300 | 2.5100 | 2.826(4) | 100.00 |
C(9)–H(9)···O(4) a | 0.9300 | 2.5400 | 3.086(3) | 118.00 |
C(10)–H(10)···O(2) c | 0.9300 | 2.2300 | 3.101(4) | 155.00 |
C(11)–H(11)···O(6) d | 0.9300 | 2.5700 | 3.410(4) | 151.00 |
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Han, S.-S.; He, Z.-W.; Li, L.; Chen, S.-S. A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties. Crystals 2019, 9, 625. https://doi.org/10.3390/cryst9120625
Han S-S, He Z-W, Li L, Chen S-S. A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties. Crystals. 2019; 9(12):625. https://doi.org/10.3390/cryst9120625
Chicago/Turabian StyleHan, Shuai-Shuai, Zi-Wei He, Lei Li, and Shui-Sheng Chen. 2019. "A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties" Crystals 9, no. 12: 625. https://doi.org/10.3390/cryst9120625