Effects of Magmatic-Hydrothermal Activities on Characteristic of Source Rocks from Beipiao Formation in the Jinyang Basin, NE China
Abstract
:1. Introduction
2. Geological Settings
3. Samples and Methods
4. Results
4.1. Total Organic Carbon and Rock-Eval Pyrolysis
4.2. Rare Earth Elements
4.3. Biomarkers
5. Discussion
5.1. Evidence of Magmatic-Hydrothermal Activities
5.2. Influence of Magmatism on Organic Matter Abundance
5.3. Influence of Magmatism on Hydrocarbon Evolution Stage of Source Rocks
5.4. Influence of Magmatic-Hydrothermal Activities on the Sedimentary Environment and Organic Matter Input
6. Conclusions
- (1)
- The hydrothermal indicator discrimination diagram (Zn-Ni-Co triangular plot) and rare earth element anomalies (δEu and δCe) indicate hydrothermal activity occurred during the deposition of the WL samples, but not for the DK samples.
- (2)
- The TOC values indicate that the organic matter abundance of the WL samples was higher than that of the DK samples.
- (3)
- The WL samples were influenced by the magmatic intrusion with higher maturity, demonstrating the magmatic-hydrothermal activities promoted a hydrocarbon generation process.
- (4)
- The magmatic-hydrothermal activities brought abundant nutrients to the lake basin, increased the salinity of water and promoted the formation of a water reducing environment, resulting in the formation of organic-rich source rocks.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample No. | Fm. | Lithology | Distance (m) | TOC (%) | S1 (mg/g) | S2 (mg/g) | Tmax (°C) | HI (mg/g) | OI (mg/g) | Ro (%) |
---|---|---|---|---|---|---|---|---|---|---|
WL-1 | J1b | Shale | 29.00 | 2.18 | 0.09 | 0.19 | 573.00 | 8.72 | 216.06 | 1.45 |
WL-2 | J1b | Shale | 46.00 | 3.20 | 0.05 | 0.12 | 558.00 | 3.75 | 184.38 | 1.51 |
WL-3 | J1b | Shale | 94.00 | 2.90 | 0.03 | 0.08 | 531.00 | 2.76 | 160.34 | 1.43 |
WL-4 | J1b | Shale | 114.00 | 2.57 | 0.06 | 0.15 | 447.00 | 5.84 | 163.04 | 0.97 |
WL-5 | J1b | Shale | 150.00 | 1.29 | 0.11 | 0.19 | 471.00 | 14.73 | 430.23 | 1.13 |
WL-6 | J1b | Shale | 250.00 | 1.63 | 0.03 | 0.04 | 427.00 | 2.45 | 142.94 | 0.84 |
WL-7 | J1b | Shale | 300.00 | 1.68 | 0.04 | 0.10 | 430.00 | 5.95 | 110.71 | 0.86 |
WL-8 | J1b | Shale | 335.00 | 0.61 | 0.02 | 0.03 | 472.00 | 4.96 | 345.45 | 1.14 |
WL-9 | J1b | Shale | 380.00 | - | - | - | - | - | - | - |
WL-10 | J1b | Shale | 396.00 | - | - | - | - | - | - | - |
DK-1 | J1b | Shale | 280.00 | 0.87 | 0.13 | 0.61 | 444.00 | 70.36 | 144.18 | 1.11 |
DK-2 | J1b | Shale | 310.00 | 0.65 | 0.06 | 0.28 | 444.00 | 43.28 | 194.74 | 1.14 |
DK-3 | J1b | Shale | 340.00 | 0.95 | 0.25 | 1.08 | 447.00 | 114.04 | 180.57 | 1.14 |
DK-4 | J1b | Shale | 370.00 | 1.66 | 0.20 | 1.16 | 450.00 | 69.88 | 80.12 | 1.09 |
DK-5 | J1b | Shale | 390.00 | 1.44 | 0.04 | 0.19 | 470.00 | 13.19 | 106.25 | 1.08 |
DK-6 | J1b | Shale | 450.00 | 2.39 | 0.16 | 1.22 | 446.00 | 51.05 | 66.95 | 1.02 |
DK-7 | J1b | Shale | 520.00 | 1.39 | 0.12 | 0.35 | 444.00 | 25.18 | 87.05 | 0.97 |
DK-8 | J1b | Shale | 570.00 | 1.56 | 0.09 | 0.97 | 447.00 | 62.18 | 123.08 | 0.86 |
DK-9 | J1b | Shale | 620.00 | 3.27 | 0.30 | 2.69 | 448.00 | 82.26 | 47.09 | 0.86 |
DK-10 | J1b | Shale | 740.00 | 2.17 | 0.14 | 1.23 | 446.00 | 56.68 | 86.18 | 0.82 |
Sample No. | Distance (m) | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | ∑REE | LREE/HREE | δEu | δCe |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
WL-1 | 29 | 60.11 | 117.66 | 14.36 | 54.89 | 10.72 | 2.33 | 7.99 | 1.13 | 6.38 | 1.20 | 3.35 | 0.49 | 3.02 | 0.42 | 284.03 | 10.85 | 1.19 | 0.92 |
WL-2 | 46 | 55.41 | 110.59 | 13.34 | 51.55 | 9.97 | 2.18 | 7.08 | 0.98 | 5.50 | 1.01 | 2.70 | 0.38 | 2.55 | 0.36 | 263.59 | 11.82 | 1.22 | 0.94 |
WL-3 | 94 | 57.09 | 113.47 | 13.88 | 54.39 | 10.57 | 2.23 | 8.46 | 1.12 | 6.52 | 1.17 | 3.25 | 0.46 | 2.82 | 0.44 | 275.85 | 10.38 | 1.11 | 0.93 |
WL-4 | 114 | 67.59 | 129.06 | 15.90 | 62.36 | 12.13 | 2.57 | 9.96 | 1.37 | 7.81 | 1.52 | 4.30 | 0.62 | 4.01 | 0.59 | 319.79 | 9.60 | 1.10 | 0.91 |
WL-5 | 150 | 59.23 | 124.87 | 14.07 | 54.21 | 10.45 | 2.21 | 7.94 | 1.15 | 6.92 | 1.34 | 3.66 | 0.56 | 3.61 | 0.49 | 290.70 | 10.32 | 1.14 | 1.00 |
WL-6 | 250 | 57.72 | 123.64 | 14.59 | 56.39 | 11.08 | 2.08 | 7.71 | 1.03 | 5.92 | 1.10 | 2.96 | 0.44 | 2.86 | 0.40 | 287.92 | 11.84 | 1.06 | 0.98 |
WL-7 | 300 | 52.07 | 97.74 | 11.94 | 45.00 | 8.12 | 1.84 | 6.28 | 0.86 | 5.11 | 0.93 | 2.59 | 0.38 | 2.58 | 0.35 | 235.80 | 11.35 | 1.21 | 0.90 |
WL-8 | 335 | 46.68 | 92.84 | 11.25 | 43.44 | 8.26 | 2.04 | 6.90 | 0.99 | 5.97 | 1.17 | 3.24 | 0.46 | 3.13 | 0.46 | 226.83 | 9.16 | 1.27 | 0.93 |
WL-9 | 380 | 70.25 | 148.08 | 17.41 | 65.30 | 11.22 | 2.11 | 7.13 | 0.94 | 5.44 | 0.94 | 2.63 | 0.37 | 2.59 | 0.33 | 334.73 | 15.43 | 1.11 | 0.98 |
WL-10 | 396 | 36.07 | 56.87 | 6.19 | 19.38 | 3.24 | 0.70 | 2.63 | 0.51 | 3.20 | 0.63 | 1.77 | 0.28 | 1.73 | 0.22 | 133.40 | 11.18 | 1.13 | 0.88 |
DK-1 | 280 | 34.21 | 68.99 | 4.23 | 33.09 | 9.93 | 1.92 | 10.83 | 0.53 | 9.45 | 1.60 | 7.81 | 0.29 | 9.62 | 0.13 | 192.64 | 3.78 | 0.87 | 1.32 |
DK-2 | 310 | 30.61 | 85.54 | 6.96 | 36.01 | 6.97 | 1.73 | 6.87 | 0.51 | 4.22 | 0.39 | 1.80 | 0.24 | 1.83 | 0.20 | 183.87 | 10.46 | 1.17 | 1.35 |
DK-3 | 340 | 27.03 | 54.34 | 5.92 | 31.08 | 6.33 | 1.02 | 6.35 | 0.43 | 4.39 | 0.48 | 2.31 | 0.10 | 2.47 | 0.12 | 142.38 | 7.55 | 0.76 | 0.99 |
DK-4 | 370 | 43.87 | 118.08 | 9.53 | 49.21 | 9.68 | 2.05 | 9.74 | 0.76 | 6.31 | 0.70 | 2.99 | 0.34 | 3.19 | 0.31 | 256.76 | 9.55 | 0.99 | 1.33 |
DK-5 | 390 | 20.13 | 61.92 | 3.86 | 33.70 | 10.95 | 1.77 | 12.19 | 0.66 | 10.46 | 1.74 | 8.37 | 0.23 | 10.14 | 0.19 | 176.32 | 3.01 | 0.72 | 1.62 |
DK-6 | 450 | 18.01 | 58.88 | 3.44 | 30.43 | 10.19 | 1.84 | 11.34 | 0.61 | 9.78 | 1.65 | 7.94 | 0.26 | 9.62 | 0.15 | 164.13 | 2.97 | 0.80 | 1.73 |
DK-7 | 520 | 38.08 | 104.58 | 8.02 | 42.91 | 9.69 | 1.58 | 10.62 | 0.81 | 7.52 | 0.97 | 4.46 | 0.37 | 5.43 | 0.44 | 235.47 | 6.69 | 0.73 | 1.38 |
DK-8 | 570 | 29.45 | 67.52 | 6.49 | 32.69 | 6.24 | 1.30 | 6.07 | 0.43 | 3.80 | 0.36 | 1.70 | 0.16 | 1.85 | 0.13 | 158.17 | 9.92 | 0.99 | 1.13 |
DK-9 | 620 | 32.80 | 64.19 | 6.86 | 35.85 | 7.37 | 1.27 | 7.35 | 0.52 | 5.06 | 0.56 | 2.63 | 0.18 | 2.99 | 0.19 | 167.81 | 7.62 | 0.81 | 0.99 |
DK-10 | 740 | 39.39 | 106.43 | 9.10 | 51.75 | 12.19 | 2.81 | 13.23 | 1.05 | 8.12 | 0.89 | 3.47 | 0.34 | 3.35 | 0.29 | 252.41 | 7.21 | 1.04 | 1.30 |
Sampleno. | Fm. | Lithology | Distance (m) | Pr/Ph | 20S | αββ | 22S | Ts | M/H | C27 (%) | C28 (%) | C29 (%) | C19+20 TT(%) | C21TT (%) | C23TT (%) | C19/C23 | C27/C29 | S/H | GI | 4MSI |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
WL-1 | J1b | Shale | 29.00 | - | 0.49 | 0.43 | 0.65 | 0.54 | 0.13 | 35.64 | 30.55 | 33.81 | 16.40 | 30.39 | 53.21 | 0.08 | 1.05 | 0.81 | 0.43 | 0.23 |
WL-2 | J1b | Shale | 46.00 | - | 0.45 | 0.40 | 0.65 | 0.52 | 0.14 | 41.89 | 27.74 | 30.37 | 11.82 | 34.21 | 53.97 | 0.05 | 1.38 | 0.89 | 0.42 | 0.26 |
WL-3 | J1b | Shale | 94.00 | 0.81 | 0.43 | 0.36 | 0.68 | 0.55 | 0.15 | 38.16 | 26.58 | 35.26 | 28.18 | 28.51 | 43.31 | 0.22 | 1.08 | 0.90 | 0.36 | 0.28 |
WL-4 | J1b | Shale | 114.00 | 0.62 | 0.47 | 0.43 | 0.66 | 0.54 | 0.13 | 45.26 | 26.34 | 28.41 | 16.35 | 28.61 | 55.03 | 0.09 | 1.59 | 1.18 | 0.48 | 0.23 |
WL-5 | J1b | Shale | 150.00 | 0.71 | 0.46 | 0.42 | 0.59 | 0.52 | 0.13 | 37.82 | 29.60 | 32.58 | 17.15 | 28.38 | 54.47 | 0.07 | 1.16 | 0.91 | 0.50 | 0.22 |
WL-6 | J1b | Shale | 250.00 | 0.79 | 0.48 | 0.42 | 0.65 | 0.54 | 0.13 | 35.55 | 31.60 | 32.85 | 19.42 | 32.69 | 47.89 | 0.12 | 1.08 | 0.80 | 0.38 | 0.29 |
WL-7 | J1b | Shale | 300.00 | 0.92 | 0.50 | 0.43 | 0.60 | 0.51 | 0.13 | 38.89 | 30.38 | 30.74 | 21.29 | 28.38 | 50.33 | 0.10 | 1.27 | 0.73 | 0.46 | 0.26 |
WL-8 | J1b | Shale | 335.00 | 0.87 | 0.45 | 0.40 | 0.68 | 0.51 | 0.13 | 39.83 | 28.71 | 31.46 | 17.00 | 30.62 | 52.38 | 0.16 | 1.27 | 0.92 | 0.38 | 0.26 |
WL-9 | J1b | Shale | 380.00 | 0.70 | 0.48 | 0.41 | 0.71 | 0.53 | 0.12 | 39.04 | 30.79 | 30.17 | 20.50 | 30.53 | 48.96 | 0.09 | 1.29 | 1.18 | 0.36 | 0.25 |
WL-10 | J1b | Shale | 396.00 | 0.63 | 0.48 | 0.40 | 0.66 | 0.53 | 0.14 | 33.83 | 32.58 | 33.59 | 14.69 | 33.34 | 51.97 | 0.07 | 1.01 | 0.80 | 0.74 | 0.16 |
DK-4 | J1b | Shale | 370.00 | 2.95 | 0.50 | 0.52 | 0.59 | 0.69 | 0.12 | 26.55 | 27.30 | 46.15 | 56.13 | 20.55 | 23.32 | 0.95 | 0.73 | 0.49 | 0.16 | 0.05 |
DK-5 | J1b | Shale | 390.00 | 2.57 | 0.48 | 0.43 | 0.60 | 0.40 | 0.13 | 26.91 | 22.27 | 50.82 | 63.59 | 17.62 | 18.79 | 1.65 | 0.89 | 0.16 | 0.08 | 0.04 |
DK-9 | J1b | Shale | 620.00 | 3.93 | 0.45 | 0.38 | 0.59 | 0.26 | 0.13 | 25.48 | 20.11 | 54.41 | 68.66 | 16.48 | 14.87 | 2.31 | 0.66 | 0.12 | 0.05 | 0.04 |
DK-10 | J1b | Shale | 740.00 | 1.93 | 0.52 | 0.49 | 0.61 | 0.89 | 0.09 | 32.29 | 25.12 | 42.59 | 63.04 | 16.97 | 19.98 | 1.02 | 1.01 | 0.70 | 0.46 | 0.04 |
Sample No. | Fm. | Lithology | Co | Ni | Zn |
---|---|---|---|---|---|
WL-1 | J1b | Shale | 21.96 | 150.22 | 118.74 |
WL-2 | J1b | Shale | 20.99 | 145.05 | 115.84 |
WL-3 | J1b | Shale | 26.81 | 171.63 | 99.55 |
WL-4 | J1b | Shale | 21.40 | 160.33 | 112.85 |
WL-5 | J1b | Shale | 24.39 | 115.97 | 105.27 |
WL-6 | J1b | Shale | 27.88 | 145.31 | 96.17 |
WL-7 | J1b | Shale | 10.05 | 100.50 | 79.33 |
WL-8 | J1b | Shale | 9.92 | 105.82 | 58.54 |
WL-9 | J1b | Shale | 9.44 | 96.46 | 67.21 |
WL-10 | J1b | Shale | 4.16 | 35.34 | 40.03 |
DK-1 | J1b | Shale | 24.85 | 70.87 | 165.80 |
DK-2 | J1b | Shale | 31.27 | 53.41 | 116.73 |
DK-3 | J1b | Shale | 18.74 | 69.26 | 127.86 |
DK-4 | J1b | Shale | 25.41 | 110.08 | 200.36 |
DK-5 | J1b | Shale | 26.71 | 141.51 | 133.05 |
DK-6 | J1b | Shale | 37.37 | 197.21 | 163.98 |
DK-7 | J1b | Shale | 35.41 | 58.50 | 302.34 |
DK-8 | J1b | Shale | 21.82 | 74.29 | 135.88 |
DK-9 | J1b | Shale | 24.53 | 104.40 | 156.69 |
DK-10 | J1b | Shale | 33.02 | 110.92 | 185.75 |
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Deng, S.; Li, S.; Sun, S.; Hao, Z.; Qin, M.; Li, Y. Effects of Magmatic-Hydrothermal Activities on Characteristic of Source Rocks from Beipiao Formation in the Jinyang Basin, NE China. Minerals 2022, 12, 947. https://doi.org/10.3390/min12080947
Deng S, Li S, Sun S, Hao Z, Qin M, Li Y. Effects of Magmatic-Hydrothermal Activities on Characteristic of Source Rocks from Beipiao Formation in the Jinyang Basin, NE China. Minerals. 2022; 12(8):947. https://doi.org/10.3390/min12080947
Chicago/Turabian StyleDeng, Shuo, Sumei Li, Shouliang Sun, Ziyan Hao, Menghua Qin, and Yongfei Li. 2022. "Effects of Magmatic-Hydrothermal Activities on Characteristic of Source Rocks from Beipiao Formation in the Jinyang Basin, NE China" Minerals 12, no. 8: 947. https://doi.org/10.3390/min12080947