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Article

Properties of Conglomerates from the Middle Ordovician Dongchong Formation and Its Response to the Yunan Orogeny in the Yunkai Area, South China

1
Hubei Key Laboratory of Paleontology and Geological Environment Evolution, Wuhan 430205, China
2
Wuhan Center, China Geological Survey (Geosciences Innovation Center of Central South China), Wuhan 430205, China
3
Guangdong Marine Geological Survey Institute, Guangzhou 510080, China
4
Jiangxi Institute of Applied Science and Technology, Nanchang 330100, China
5
Guangdong Geologic Survey Institute, Guangzhou 510080, China
*
Author to whom correspondence should be addressed.
Minerals 2023, 13(8), 998; https://doi.org/10.3390/min13080998
Submission received: 7 June 2023 / Revised: 11 July 2023 / Accepted: 26 July 2023 / Published: 28 July 2023

Abstract

:
The strata in the Shita Mountain, Yunkai region, are predominantly composed of clastic rocks with intercalated limestones. However, the precise stratigraphic age remains uncertain due to the scarcity of fossils. Previously, conglomerate layers in this region were considered indicative of the Yunan Orogeny during the Cambrian–Ordovician transition. However, through the identification of 12 lithofacies types and 5 lithofacies combinations in the conglomerate layers of the Shita Mountain section, it has been confirmed that these layers represent a fan delta depositional environment characterized by debris flow, traction flow, torrent, and rock flow. Based on the presence of brachiopod fossils dating to the Early–Middle Ordovician, we propose a novel two-episode model for the Yunan Orogeny. The first episode corresponds to submarine fan deposition, while the second episode involves tectonic uplift and a short-term sedimentary hiatus. Further analysis of the detrital zircon provenance reveals a strong affinity among the Yunkai area, India, Antarctica, the Lhasa, the Himalayas, Southern Qiangtang, and Western Australia during the Early–Middle Ordovician transition under the Gondwana assemblage background.

1. Introduction

The South China Block (SCB) consists of the Yangtze and Cathaysia Blocks (Figure 1A), which amalgamated along the Jiangnan Orogen during the Neoproterozoic period [1,2,3,4]. In recent years, numerous studies on litho-geochemistry and detrital zircon provenance have provided compelling evidence for the connectivity or adjacency of the Yangtze, Cathaysia, and Gondwana blocks during the late Neoproterozoic to early Paleozoic periods [1,5,6,7,8,9,10,11]
The Ordovician period played a significant role in the early Paleozoic Orogeny in South China, as it witnessed notable variations in sedimentary formations and paleontological fauna [12]. Mo [13] suggested that there was a parallel unconformity between the Lower Ordovician Suoweiling Group and the Cambrian Bacun Group, which represented the first episode of the early Paleozoic orogeny and was named the Yunan Orogeny. Since then, the Yunan Orogeny has been widely quoted and elaborated [9,11,14,15,16]. The derivation of detritus suggests that South China was located at the nexus between India, Antarctica, and Australia, along the northern margin of East Gondwana during the Cambrian–Ordovician transition [9,10]. The orogeny during the Cambrian–Ordovician transition, which is widely distributed along the northern margin of Gondwana, may represent the Kuunga collision belt between the Australian and Indian–East Antarctic plates for the consolidation of Gondwana. The collision zone runs northward from Prydz Bay of Antarctica to the northeastern margin of the Himalayas and the western margin of Australia and extends to the southern margin of South China. In addition, the Yunan Orogeny may be a specific manifestation of this great orogenic event in South China [9].
The Yunan–Deqing in the Yunkai area, after which the Yunan Orogeny was named, represents a key locality for studying the evolution of early Paleozoic orogeny in South China (Figure 1B). Despite extensive discussions on the geological record and manifestation characteristics of the Yunan Orogeny, there has been ongoing controversy due to poor outcrop exposures and stratigraphic dating constraints. In our recent years of investigation in the region, we discovered previously unknown fossil preservation sites, which have provided us with a different understanding of the stratigraphic age. Additionally, we observed conglomerate layers near the fossil-bearing horizons. These findings have led us to reevaluate the geological evolutionary history of this area and have offered new insights into the processes of the Yunan Orogeny. The aim of this study is to investigate the conglomerate layers in the Yunan region and propose novel perspectives on the Yunan Orogeny and its implications from a stratigraphic and sedimentological standpoint.
Figure 1. (A) Simplified geological map of South China Block (modified from [4]) and (B) simplified geological map of Yunan–Deqing area showing the location of the section presented in Figure 2. (SMF: Song-Ma Fault, HHF: Honghe Fault, XSHF: Xianshuihe Fault, LMSF: Longmenshan Fault, HYSF: Huayingshan Fault, QYSF: Qiyueshan Fault, CBF: Cili–Baojing Fault; ALF: Anhua–Luocheng Fault; ZLF: Ziyun–Luodian Fault; YJF: Youjiang Fault; XGF: Xiangfan–Fuangxi Fault; TLF: Tan–Lu Fault; ZDF: Zhenghe–Dapu Fault; CNF: Changle–Nanao Fault).
Figure 1. (A) Simplified geological map of South China Block (modified from [4]) and (B) simplified geological map of Yunan–Deqing area showing the location of the section presented in Figure 2. (SMF: Song-Ma Fault, HHF: Honghe Fault, XSHF: Xianshuihe Fault, LMSF: Longmenshan Fault, HYSF: Huayingshan Fault, QYSF: Qiyueshan Fault, CBF: Cili–Baojing Fault; ALF: Anhua–Luocheng Fault; ZLF: Ziyun–Luodian Fault; YJF: Youjiang Fault; XGF: Xiangfan–Fuangxi Fault; TLF: Tan–Lu Fault; ZDF: Zhenghe–Dapu Fault; CNF: Changle–Nanao Fault).
Minerals 13 00998 g001
Figure 2. (A) Image from Google Earth showing the measured section’s location at Shita Mountain and (B) the geological cross-section of the Ordovician strata (the two fossil localities are respectively referred to this study and Wang et al. 2019 [17]).
Figure 2. (A) Image from Google Earth showing the measured section’s location at Shita Mountain and (B) the geological cross-section of the Ordovician strata (the two fossil localities are respectively referred to this study and Wang et al. 2019 [17]).
Minerals 13 00998 g002

2. Geological Background

The SCB, an important continental plate in eastern Asia, underwent extensive tectono-magmatic activities during the early Paleozoic Wuyi–Yunkai orogeny. This orogeny is named after the Wuyi and Yunkai areas in South China, which exhibit a high concentration of early Paleozoic magmatic rocks. The Yunkai area in the early Paleozoic period exhibited a relatively complete exposure of sedimentary formations, which were predominantly composed of clastic rocks interbedded with minor amounts of carbonate rocks. However, due to subsequent strong tectonic-magmatic activities and complex metamorphic deformation, particularly with limited research on biota, the lack of a high-precision chronostratigraphic framework, and unclear correlation markers in clastic rock assemblages, a profound understanding of this area has been impeded.
A sequence of early to mid-Neoproterozoic accretionary arc complexes helped to construct and accrete the Archean and Paleoproterozoic basement units that make up the Cathaysia Block at the northern edge of Gondwana [18,19]. The Neoproterozoic succession is overlain by lower Paleozoic strata, displaying significant facies variations across the Cathaysia Block. The Cambrian and Ordovician strata are predominantly composed of siliciclastic sediments with minor interbedded carbonate deposits [20]. These strata exhibit a variety of sedimentary structures, including rhythmic bedding, cross-bedding, and wavy scour marks, suggesting deposition in a littoral-neritic environment [21]. In general, Silurian sequences are not widely preserved within the Cathaysia Block, except for the Qinzhou–Fangchenggang area in the south. Within the Yunkai area of the Cathaysia Block, there is a limited occurrence of unconformity surfaces within the early Paleozoic succession, notably including the presence of a disconformity between the Cambrian and Ordovician strata [11]. Within these sedimentary records, remarkably well-preserved sedimentary features are retained, enabling geologists to reconstruct paleocurrent directions during that period. Paleocurrent analysis, which is closely associated with provenance, plays a pivotal role in deciphering the orientation of the current system responsible for the dispersion and deposition of sedimentary rock units. This analysis can be conducted by examining scalar properties of the sediment or by evaluating vectoral directional elements within it. The predominant paleocurrent orientations inferred from the early Paleozoic successions in the western Cathaysia region indicate a northwestern direction [21,22]. Consequently, it can be deduced that the prevailing paleocurrent direction in most regions of the Cathaysia Block was predominantly northwestward.Systematic research on the Ordovician in the Yunkai area commenced in 1962 with the publication of the Geological Map of the Luoding Region (1:200,000). This initial mapping effort classified the Ordovician strata into the Huilong Group, Suoweiling Group, and Sanjian Group. Subsequently, in 1977, during the compilation of the 1:500,000 Geological Map of Guangdong Province, new fossil evidence led to the revision of the Huilong Group’s age as Late Cambrian. As a result, the Ordovician strata were reclassified into the Early Ordovician Shuweiling Group and the Middle–Late Ordovician Sanjian Group. Further advancements came from the Deqing–Yuecheng geological survey (1:50,000) conducted in 1992 by the Guangdong Regional Geological Survey Team. They proposed a revised classification for the Ordovician strata, including the Luohong, Luodong, Dongchong, and Lanweng Formations, which are still used today. The Luodong Formation represents a partially exposed limestone unit within the region.
Recent fossil collections have significantly enhanced the understanding of the lithostratigraphic and biostratigraphic sequences of the Ordovician period in the studied area [12,17,23,24]. The Ordovician in the Deqing area is mainly composed of flyschoidal clastics with locally intercalated limestone, multi-layered conglomerate, gravel-bearing sandstone, and medium-fine-grained quartz sandstone interposed between medium-thin layers of silt. Several layers of conglomerate rock have been observed in the basal part of the Ordovician units [23]. In this study, the Ordovician strata section was measured near Huilong town, Deqing County (Figure 2A). The discovery of several Middle Ordovician brachiopod fossils within the strata of the Dongchong Formation has provided valuable insights into the dynamics of the Yunan Orogeny in South China, particularly in the Cathaysia.

3. Materials and Methods

A total of 12 outcrops were observed and one section was logged using sedimentary facies analysis. As a result, a novel lithostratigraphic framework for the Ordovician section was established, as depicted in Figure 2B.
This study specifically investigates the lower part of the Dongchong Formation. Through a comprehensive analysis of lithological variations, a total of 12 distinct lithofacies and 5 lithofacies associations were identified. The fieldwork encompassed meticulous mapping of the section, enabling the establishment of a detailed lithological log that summarizes the characteristics observed within the studied area (Figure 3). The identification of the sedimentary lithofacies was performed as described by Miall [25,26]. Facies identifications and interpretations were based on a detailed examination of color, texture, composition, sedimentary structures, and bedding characteristics.
In the process of fossil excavation, two fossil sites were found. One was at the lower part of the Dongchong Formation (Figure 2B, this study) and the other was at the upper Ordovician of the Lanweng Formation (reported by [17]). Three brachiopod fossils from the Dongchong Formation were identified. All figured specimens are kept in the Wuhan Center, China Geological Survey.
One surrounding sandstone rock sample of the conglomerate analyzed in this study was collected from the basal Dongchong Formation for U–Pb dating of detrital zircons. A total of 80 analyses were made on 80 individual zircon grains yielding 79 concordant ages. Zircons were separated by conventional heavy liquid and magnetic techniques. A random selection of grains was mounted in epoxy resin, sectioned approximately in half, and polished. Zircon U–Pb dating was conducted using LA-ICPMS in Nanjing Hongchuang Exploration Technology Service Co., Ltd. The Resolution SE model laser ablation system (Applied Spectra, Carlsbad, CA, USA) was equipped with an ATL (ATLEX 300) excimer laser and a Two Volume S155 ablation cell. The laser ablation system was coupled to an Agilent 7900 ICPMS (Agilent, Santa Clara, CA, USA). Detailed tuning parameters can be seen in Thompson et al. [27]. LA-ICPMS tuning was performed using a 50-micron-diameter line scan at 3 μm/s on an NIST 612 at ~3.5 J/cm2 with a repetition rate of 10 Hz. The gas flow was adjusted to obtain the highest sensitivity (238U~6 × 105 cps) and the lowest oxide ratio (ThO/Th < 0.2%). P/A calibration was conducted on the NIST 610 using a 100-micron-diameter line scan. Other laser parameters were the same as that of tuning. Pre-ablation was conducted for each spot analysis using 5 laser shots (~0.3 μm in depth) to remove potential surface contamination. The analysis was performed using a 30 μm diameter spot at 5 Hz with a fluence of 2.5 J/cm2. The Iolite software package was used for data reduction [28]. The Zircon 91500 and GJ-1 were used as primary and secondary reference materials, respectively. Triplets of 91500 and GJ-1 were bracketed between multiple groups of 10 to 12 sample unknowns. Typically, 35–40 s of the sample signals was acquired after 20 s gas background measurement. The exponential function was used to calibrate the downhole fractionation [28]. NIST 610 and 91Zr were used to calibrate the trace element concentrations as the external reference material and internal standard element, respectively. Measured ages of 91500 (1061.5 ± 3.2 Ma, 2σ) and GJ-1 (604 ± 6 Ma, 2σ) were well within 1% of the accepted age.

4. Result

The measured section (GPS:23°11′34” N, 111°40′09” E) is located on Shita Mountain about 12 km northwest of Deqing County. The sedimentary characteristics of the section are shown in Figure 3, and Beds 8–10 are the key horizons in this study.

4.1. Characteristics of Conglomerates in the Lower Part of Dongchong Formation

The lithology of the Dongchong Formation primarily consists of yellow-brown to brownish-yellow medium-bedded (locally thick-bedded) quartz sandstone, feldspar quartz sandstones, and quartzose sandstones interbedded with gray-green, brownish-yellow, and purple-red thin- to medium-bedded silty sandstones, siltstones, and mudstones. In general, the Dongchong Formation is characterized by the development of cyclic sequences composed of quartz sandstones, siltstones, and mudstones. The lower part of the coarse clastic rocks exhibits distinct normal grading, while upward, rhythmic bedding, ripple bedding, and parallel bedding sedimentary structures are observed. Overall, there is a fining of grain size and an increase in the proportion of muddy components from the bottom to the top.
The basal part is typically marked by the occurrence of limestone lenses or thick-bedded conglomerates and sandstones, and it is in unconformable contact with the underlying strata. A well-defined, normal-graded bedding is commonly developed in the coarse clastic rocks at the base. From the bottom to the top, there is a general fining upward trend with an increase in mud content, exhibiting distinct characteristics of a retrograding sequence. The sedimentary succession of the studied conglomerate layer is 27 m thick and is well exposed along the mountain ridge. Below are the detailed descriptions.
Bed 8, with a thickness of 6 m, comprises reddish-purple medium-layered cobbles, interspersed with a bedding of pebbles in the middle. The cobbles exhibit particle size ranging from approximately 4~8 cm, while the pebbles have an average particle size of 2~3 cm. The predominantly grain-supported conglomerate exhibits a relatively simple composition, consisting of rounded to subrounded gravels with moderate sorting. The reddish-purple argillaceous siltstones play a significant role as cementing agents. A distinct erosional surface is evident at the base of this layer, indicating a sedimentary hiatus and separating it from the underlying Luohong Formation.
The thickness of Bed 9 is 12 m. The lower part of this layer is composed of reddish pebbles, displaying particle sizes ranging from 2.5~5 cm and exhibiting a graded bedding. It comprises gravels from the underlying Luohong Formation that are subrounded to rounded, have a matrix-supported structure, and contain sand and muddy sediments between them. The upper part of Bed 9 comprises purplish-red massive mixed cobbles, featuring larger particle size of up to 25 cm, which are commonly around 12~15 cm. The middle part of this layer exhibits coarse-tailed graded bedding, while its bottom is characterized by erosion structures.
A layer nine-meters-thick covers Bed 10, which is mostly composed of reddish medium-bedded granules and gravel-bearing sandstones with few intercalated, thin-bedded gravelly sandstones. The particle size of moderately sorted gravels is mainly around 3~4 mm. These gravels in general exhibit a subrounded shape, although a few of them are subangular. The composition of the gravels primarily consists of argillaceous siltstones and sandstones, with a small amount of quartz gravels. Erosion-related structures are at the bottom of this layer. Compared to Beds 8 and 9, the gravels of Bed 10 are not only small in volume but also dominated by single-component gravels.

4.2. Lithofacies Types and Facies Associations

Based on our investigations, in the conglomerate layer of Beds 8–10 at the top of Shita Mountain, 12 types of lithofacies could be identified (Table 1), which could be classified into 5 types of lithofacies associations (Figure 4), as described in detail below.

4.2.1. Lithofacies Association A

This lithofacies association is recognized in Bed 8 with a thickness of 6 m. The lower 8A layer is composed of grain-supported conglomerate facies (Gc) and the upper 8B layer is composed of sandy-matrix-supported conglomerate facies (Gms) to form complete channel deposits. These channel deposits exhibit lenticular bodies or thick tabular sheets with intricate bedding geometries and erosive bases.

4.2.2. Lithofacies Association B

Within association B, three lithofacies types are distinguished: (1) massive, clast-supported gravel facies (Gcm); (2) grain-supported conglomerate facies (Gc); and (3) massive-bedded clast-supported gravel facies (Gm). This lithofacies association is 5.8 thick, is seen in Bed 9 (A–C), and represents debris-flow and flood-flow deposits in an alluvial fan. The sedimentary structure observed corresponds to a poorly stratified clast-supported conglomerate. It consists of alternating centimeter-thick horizons characterized by pebbles to small clast-supported cobbles, as well as gravely to pebbly sandy layers. These units exhibit a lateral extent and can be observed with either horizontal bedding or large-scale slightly dipping sigmoidal foresets.

4.2.3. Lithofacies Association C

Lithofacies association C occurs in Bed 9 (D–E) of the studied section and includes (1) gravel-supported float conglomerate facies (Gmg), (2) imbricated conglomerate facies (Gi), and (3) parallel sandstone-bedding facies.
The lower part of Bed 9D belongs to Gmg facies, which is composed of purplish-red massive cobble/pebble stones and gravel-bearing sandstones. The conglomerate within the pebbly sandstones is clast-supported and exhibits subangular to subrounded shapes with moderate sorting, with gravels ranging in particle size from 2~6 cm (median of 4 cm). In terms of matrix content, it is about 20~25%, while the gravel content is about 75~80% with a thickness of 0.4 m.
The upper part of Bed 9D belongs to well-sorted pebbles, moderately sorted gravel (Gi) facies, and flat-shaped gravels, particle size ranging from 4~6 cm and dipping northeastward at 28~30°. Either matrix-supported or grain-supported structures are visible. Purple-reddish sandstones constitute the gravel composition. It makes up about 15~20% of the matrix content, while the gravel content is about 80~85% with a thickness of 0.4 m.
Bed 9E, which is 0.2 m thick, shows horizontally bedded, medium-to-coarse sandstone (Sh) facies and is composed of yellow-green, medium-fine grained sandstones to fine sandstones with lens-like distributions and parallel bedding. Fine gravels can be found at the bottom of this layer. Sandstones and siltstones are the main components of the gravels, which show an oval or round shape and are moderately sorted.
Association C represents a well-defined sedimentary sequence exhibiting a clear transition from debris-flow deposits to braided-river facies, culminating in the formation of a central bar. The depositional environments within association C are arranged in a distinct bottom-to-top sequence, indicating a progressive shift in sedimentary processes and hydrodynamic conditions over time.

4.2.4. Lithofacies Association D

Lithofacies association D is recognized in Bed 9 (F–G) and is made up of thin pebble layers (Gc), granule-to-massive gravels (Gg), and medium-to-large-scale trough cross-bedded gravel (Gt) facies. Bed 9F is about 1 m thick and is composed of purple-red massive coarse and medium-grained conglomerate. It is well observed that the gravel particle size is uneven, whose cloud varies from 8 cm to as large as 22 cm. A positive sequence is noted in the gravels, accompanied by abundant sandstones and few quartz gravels, and there is a scour structure at the bottom. The sedimentary characteristics indicate the presence of debris flow during the flood stage.

4.2.5. Lithofacies Association E

This lithofacies association is distributed in Bed 10 with a graded conglomerate (Gg), planar cross-bedding conglomerate (Gp), parallel layered sandstones (Sh), and fine-laminated siltstone (Fl) facies. The sedimentary structures include positive-grained progressive bedding and erosion surfaces. The lower part of the sedimentary succession is dominated by gravels, which are subrounded and well sorted. The sequences show thinning and fining trends vertically upward on an outcrop scale. These sediments are characterized by the presence of small-scale ripple marks with low relief, which are formed by the action of tidal currents or waves.

4.3. Detrital Zircon U-Pb Ages of Dongchong Formation

Detrital zircon U-Pb ages were determined using 80 grains from the sandstone sample STS-3 (show in Figure 4) of Dongchong Formation, of which 79 detrital zircons display a 90% or greater concordance and range in ages from 2433 Ma to 521 Ma. Two major age groups are recognized at 1.2 to 0.9 Ga and 0.6 to 0.5 Ga, with distinct age peaks at 992 ± 8 Ma (MSWD = 5.2) and 526 ± 2 Ma (MSWD = 1.8) (Figure 5).
The LA-ICP-MS U-Pb data of the analyzed sample of this study are reported in Table 2. The interpreted ages are based on 206Pb/238U ages for <1000 Ma grains and 206Pb/207Pb ages for >1000 Ma grains [29].

5. Discussion

5.1. Sedimentary Facies Units

Through field observation and identification of rock types and sedimentary structures of the conglomerates that are horizons in the lowest part of the Dongchong Formation in the Shita Mountain section, 12 lithofacies and 5 lithofacies associations were established. The obtained results were compared with the alluvial fan depositional types [30,31,32,33], suggesting that the conglomerates in this area are closely related to the shelf-type fan delta, which mainly occurs in debris flow, tractive flow, flood flow, and rock flow.
This study proposes the classification of the conglomerates developed in Shita Mountain as the fan root subfacies of the fan delta. The sedimentary microfacies units can be divided into debris-flow deposits, braided channels, sieve deposits, and sheet-flow deposits. The conglomerate at the bottom of the Dongchong Formation is 18 m thick, which shows a three-part characteristic. The lower unit primarily consists of debris channels and channels, with a thickness of 6 m. The middle unit, which is 8.1 m thick, is composed of braided channels and inter-channel lenticular sandstones, interbedded with sieve deposits and occasionally containing sheet-flow deposits. The upper unit is predominantly deposited by debris flow and has a thickness of 3.9 m. On the whole, these units form an upwardly coarsening progradational sedimentary sequence. It is over-covered by about 9 m thick nearshore facies-retained gravels. The bottom boundary of the conglomerate of the Dongchong Formation is in a minor-angle unconformity contact with the purple-reddish medium-thin fine sandstones of the underlying Luohong Formation. This suggests that the conglomerate formation was primarily influenced by tectonic uplift processes.

5.2. Age of the Conglomerates

In the Shita Mountain section, while no fossils have been discovered within the conglomerate layer, fossils have been documented in the overlying upper layer. In the 1:200,000 Geological Survey Report of Luoding, faunal assemblages were documented in gray-white, fine-grained quartz sandstones interbedded with siltstones above the purplish-red conglomerate layer of Suweiling (now Shita Mountain). This pioneer work revealed the presence of trilobites, including Illaenus sinenis, I. sp. and Synhomalonatus birmanica, along with brachiopods (Orthis carausis, O. calligramma intercalave, O. calligramma hupehensis, Metorthis delicata, and Martella cf. ichangensis) and gastropod fauna. According to the report, these fossils are commonly found in the Middle Ordovician Aijiashanian Stage of Hubei and Southern Shaanxi along the Yangtze River. The genus and species of the fossils were subsequently referenced by the Central-South China Regional Stratigraphic Time Scale Compilation Group [34] and the Bureau of Geology and Mineral Resources of Guangdong Province [20].
In 2019, our research team conducted a fossil collection campaign in the Shita Mountain area, targeting the medium-coarse-grained sandstone layer located directly above the conglomerate layer at the mountain’s summit. Despite the fossils’ unsatisfactory state of preservation, they still possess a significant identification value. The fossils were identified as Syntrophinella sp. and Orthambonites sp., indicative of an early Middle Ordovician age (Figure 6).
When examining the appearance of the conglomerates at the boundary between the Luohong Formation and the Dongchong Formation, the lithological characteristics change obviously and have a certain spatial distribution, which is beneficial for field work. Wang et al. [17] described a fossil group dominated by trilobites in the Lanweng Formation, which corresponds to the upper part of the section. This fossil group includes species such as Nankinolithus wanyuanensis, N. nankinensis, N. sp., Dionide sp., Ampyx abnormis, A. sp., Nileus sp., Cyclopyge sp. 1, C. sp. 2, Lisogorites sp., Birmanites? sp., Ovalocephalus sp., and Asaphidae (gen. et sp. indet.). In addition to these trilobites, brachiopods, echinoderms, and machaeridians are also present, indicating a Late Ordovician age. Based on our findings, we suggest that the deposition of the conglomerate unit predates the fossil-bearing layers, indicating an age slightly earlier than the fossil assemblages. It is hypothesized that the conglomerate unit likely represents a transitional age during the Early–Middle Ordovician period.

5.3. Reconsideration of the Yunan Orogeny

5.3.1. The Conglomerate Difference between Luohong and Dongchong Formations

The type section of the Luohong Formation is located in Luohong Village, Deqing County. The basal conglomerate of the Luohong Formation has been widely recognized as a characteristic feature associated with the Yunan Orogeny, indicating its affiliation with the Lower Ordovician period [11,13,14,23,35,36].
The Luohong Formation’s type section exhibits a predominantly coarse clastic rock sequence, characterized by grayish-white and yellowish-white conglomerates, glutenites, pebble-bearing feldspathic quartz sandstones, and pebble-bearing phyllites. The conglomerate layer is primarily concentrated in the lower part of the formation, with sporadic occurrences of gravels observed in the upper sections. The composition of gravels is mostly metamorphic quartz sandstones, with a small number of argillaceous siltstones and siliceous rocks. The particle size of gravels ranges from 1.5 cm to 20 cm, with an average size of 6~7 cm. In particular, the largest flat faces of all pebbles are nearly parallel to the bedding surface. The conglomerate layer is characterized by moderate sorting and rounded to subrounded gravels, representing the primary constituent of the conglomerate.
The conglomerate layer of the Lower Ordovician Luohong Formation is generally considered to have the characteristics of basal conglomerate with significant tectonic movements; however, some scholars have proposed that it is a turbidite fan [37] or a submarine alluvial fan deposit [38].
By conducting a field survey of the type section of the Luohong Formation again, we observed significant weathering, although some gravels remain visible. These gravels have a subrounded to rounded shape and could be divided into matrix-rich conglomerate facies and matrix-poor conglomerate facies from the bottom to the top, showing typical debris-flow characteristics rather than a turbidity flow with positive grading. The sedimentary features resemble those of a main channel within a submarine fan system. Therefore, our findings align with the perspective presented by the Guangdong Geological Survey Institute [38].
In addition, multiple conglomerate layers have been identified in Tongmen town, Deqing County. Through a field geological survey, we observed that the gravels in these layers are well rounded, and the composition is mainly sandstones, which have a well-sorted and certain orientation. The sedimentary characteristics of these conglomerates suggest a depositional environment associated with submarine fan deposits, previously assigned to the Middle Ordovician Dongchong Formation [23]. However, after isotope dating, the granitic pebbles found within the sandstones yielded an age range of 430–420 Ma, indicating a Silurian age for the deposits (unpublished data).
In general, the gravel characteristics of the Early Ordovician Luohong Formation’s type section in Luohong Village, Deqing, differ from the Middle Ordovician Dongchong Formation on the Shita Mountain. Previously, these two conglomerate layers were regarded as the stratigraphic horizon markers of the Yunan Orogeny at the transition period from Cambrian to Ordovician. However, the current evidence shows that the difference between them is not only in age, but also in geological and scientific significance.

5.3.2. Two Episodes of Yunan Orogeny

The Yunan Orogeny is a tectonic movement that occurred between the Pan-African collisional orogeny and the breakup of the Gondwana continent. It was equivalent to a small number of metamorphic events between 520 and 470 Ma [36,39] and synchronized with the widespread orogenic event in the northern margin of East Gondwana. Nevertheless, South China occupied a position toward the terminal region of the collision zone, resulting in minimal influence and limited occurrences of coeval magmatism and metamorphism [16]. The Yunan orogeny has been attributed to the far-field stress induced by the collision between South China and Indian Gondwana [40]. In South China, the effects of this tectonic event are relatively mild and are represented by a local disconformity at the base of the Ordovician succession, but elsewhere in north Gondwana, they are marked by an angular unconformity with a metamorphism of older units and relatively widespread magmatic activity [11]. According to the records of Guangdong Lithostratigraphy [41], the thickness of the conglomerate-concentrated layer in the type section of the Luohong Formation is about 35 m. The discovery of important Early Ordovician graptolite fossils, such as Anisograptus and Bryograptus, in the shale above the conglomerate layer further confirms the geological age of the conglomerate layer [42].
The distinct sedimentary successions observed in the concentrated layers of the Luohong and Dongchong Formations reflect two different episodes of the Yunan Orogeny, which were possibly driven by tectonic activities. The first episode of the Yunan Orogeny refers to the tectonic movement corresponding to the conglomerate layer at the base of the Luohong Formation in the Early Ordovician. There are two types of Ordovician sediments in Guangdong Province: one is graptolite shale and clastic facies, represented by Liuchen in Guangxi, Taishan and Shaoguan in Guangdong, and the other is flysch neritic clastic facies represented by the Yunkai area [20]. The former has a conformable contact between the Cambrian and Ordovician secession, such as the Shenjing section in Taishan, the Laoshuzhai section in Qujiang, and the Yangmeidong section in Nanxiong, showing the differences in lithology caused by a change in sea level. The latter is represented by the type section of the Luohong Formation in Deqing. The study conducted by Nan and Zhou [41] initially suggested an unconformity between the Luohong Formation and the underlying Cambrian strata. However, our findings indicate that the gravel layer in the study area was actually a result of submarine fan deposits rather than uplift and exposure. This deposition could be attributed to the steepening of the paleotopography of the seafloor. In other words, the first episode of the Yunan Orogeny in the Yunkai area was characterized by changes in seafloor topography, without evident exposure or fold deformation.
During the Early–Middle Ordovician transition, the conglomerate layer found at the base of the Dongchong Formation represents the second episode of the Yunan Orogeny. The sedimentary microfacies units of the Shita Mountain fan-toe subfacies can be divided into debris-flow deposits, braided channels, sieved sediment, debris channels, and a small amount of sheet-flow deposits. In the lower part of the Dongchong Formation, debris channels and inter-channel deposits dominate, while the middle part is characterized by braided channels with lens-shaped sandstones intercalated with sieved sediments, occasionally accompanied by a very small amount of sheet-flow deposits. The upper part is predominantly composed of debris-flow deposits, forming an upward coarsening progradational sedimentary sequence. Overlying these deposits is a nearshore facies with a lag gravel layer, which we speculate to be the result of local tectonic uplift acting as a base-level change. This sedimentary response is characterized by the presence of purple-reddish polymictic conglomerates, which can be correlated with Beds 8–10 in the Shita Mountain section. The notable similarities in lithological attributes, sedimentary facies, and stratigraphic positioning substantiate their correlation and reinforce the inference that these conglomerates represent exposed sedimentary units. These conglomerates document the transition from an exposed surface to an alluvial fan and coastal facies, indicating a gradual deepening of seawater. Furthermore, a distinct parallel unconformity is observed between the Dongchong Formation and the underlying Luohong Formation. There exists a temporal gap between the first episode and the second episode of the Yunan Orogeny, representing a relatively continuous process. However, the second episode exhibits more prominent characteristics compared to the first episode.

5.3.3. Regional Comparison of the Yunan Orogeny

Cawood et al. [5] inferred that the location of the SCB was at the nexus between Western Australia and northern India because of their high similarity in stratigraphic sequence and detrital-zircon age spectra. Xu et al. [9] suggested that the SCB constituted part of the lithosphere of greater India and was separated from Australia by the Kuunga Ocean. Due to the collision between the SCB and Western Australia, an unconformity surface between the Cambrian and Ordovician secession that was widely distributed in the northern margin of East Gondwana was formed, and it was displayed as the Yunan Orogeny in the Cathysian and the south-west tectonic structure at the southern margin of the SCB. Most of the previous studies focused on the first episode of the Yunan Orogeny at the transition of the Cambrian–Ordovician boundary. Qin et al. [43] showed that the lower Ordovician Liuchen Formation and the underlying Cambrian Huangdongkou Formation were in a parallel unconformity contact in Malu, Cenxi City, on the west margin of Yunkai, with conglomerates, gravel-bearing sandstones, and local 1–3 cm iron shells at the bottom. The sedimentary response of the Yunan Orogeny in the Sanya area of Hainan Island might be a parallel unconformity contact between the Middle Cambrian Damao Group and the Upper Cambrian Dakui Group [44]. Zhang et al. [36] suggested that the 490 Ma magmatism in the Wuping area might be correlated with the Yunan Orogeny (our first episode), representing a rapid tectonic uplifting event. However, according to the evidence we have so far, at least in western Guangdong, this tectonic activity was not so strong, and it only manifested as changes in seabed paleotopography and a differentiation of sedimentary facies, forming a sedimentary record of submarine fans.
The second episode of the Yunan Orogeny (ca., 470 Ma) is related to the continuous effects of the plate–margin collision at the turn of the Cambrian–Ordovician and the intracontinental orogeny widely distributed in the northern margin of Gondwana, and it is the continuation of the first episode, with a short interval between them. Conglomerates from the basal Dongchong Formation were found nearby in Lanzhai, Nanjiangkou [23]. Nevertheless, pebble-bearing, medium-coarse sandstones above the limestone layer of the Luodong Formation in Yuecheng were also found in Gaoyao, Guangdong, which belongs to the Dongchong Formation as well [41]. The conglomerate layer at the top of Shita Mountain was not well discovered via lateral tracing, because Ordovician (actually the entire pre-Devonian succession) fossils in the Yunkai area were scarce in the past. It is very difficult to obtain evidence that can determine the age of strata in clastic rocks. The previous understanding that the conglomerates in Tongmen belonged to the Dongchong Formation had been challenged by subsequent zircon dating of granitic gravels, which does not support this interpretation. The Qianzhong uplift within the Yangtze block is regarded as one of the manifestations of the Yunan Orogeny [45]. The second episode of this orogenic event might have continued to uplift on the basis of the first episode, resulting in a sedimentary discontinuity between the Lower and Middle Ordovician [46]. The northwestern Shaowu–Taining area in Fujian lacks Middle Ordovician sediments, which might possess the same structural characteristics as those in the Middle Ordovician area [47].
As previously discussed, it is postulated that the Yunan Orogeny was likely primarily driven by the collision between the SCB and Western Australia during the Cambrian–Ordovician period. This collision is believed to have exerted a significant influence, undergoing at least two distinct tectonic events of varying intensity during the Late Cambrian and Early–Middle Ordovician. Importantly, the timing of the second tectonic event aligned with the recognized Bhimphedian Orogeny in the northern Indian region [6], further supporting the hypothesis.

5.3.4. Probable Provenance based on Detrital Zircon U-Pb Ages

The Shita Mountain is located on the western side of the Cathaysia Block, and therefore its sediments are believed to have primarily originated from the Ross–Delamerian Orogen, Wilkes–Albany–Fraser Belt, and Western Australia [48]. The detrital zircon LA-ICP-MS U-Pb ages obtained from the Dongchong Formation indicate the influence of multiple tectonothermal events on the source area, supporting the findings of previous investigations in the adjacent regions. The detrital zircon grains exhibit a broad distribution of U-Pb ages, characterized by prominent age clusters at 522~628 Ma, 930~1103 Ma, and 1421~1750 Ma (Table 2). The U-Pb ages obtained from dating detrital zircons within the sediments of Shita Mountain were compared with previously reported zircon U-Pb ages from diverse sources reported by different researchers to infer the provenance of the studied sediments (Figure 7).
The age distributions observed in this study for detrital zircons have also been documented in sediments from the northern margin of Gondwana [4,49,50,51,52,53,54,55,56]. The obtained results indicate that a wide-ranging source area contributed a significant quantity of detrital materials to this area. Therefore, in the Yunkai area, the detrital-zircon age spectra from the Ordovician samples show a strong similarity with India, Antarctica, the Lhasa, the Himalayas, Southern Qiangtang, and Western Australia (Figure 8).
In this study, a prominent age peak at 520~530 Ma is found in the Early–Middle Ordovician of western Guangdong. However, this result has only previously been described in the Cambrian of Northern Guangdong [57] and Southern Hunan [58], and the Ordovician of Eastern Guangxi [59] in the adjacent area. There is a soaring number of detrital zircons of 525–520 Ma in the lower Cambrian in western SCB, which has been interpreted as showing a magmatic arc of similar ages [60]. One potential origin for the 520~530 Ma detrital zircons found in the Shita Mountain samples is the local recycling of Cambrian strata within western SCB, followed by transportation during the Early Ordovician period. In contrast to the reported Cambrian samples, the Shita Mountain samples do not exhibit a prominent peak in the 750~850 Ma range. These results provide further support for the hypothesis, suggesting global plate re-organization at, ca., 520~530 Ma during the Gondwana assembly [61].
Figure 7. Density probability diagrams of detrital zircons with age histograms representative for (a) this study, (b) India, (c) Antarctica, (d) the Lhasa, (e) the Himalayas, (f) Southern Qiangtang, (g) Northern Qiangtang, and (h) Western Australia. The age data were compiled from Turner et al. [62], Bickford et al. [63], Malone et al. [64], and Collins et al. [65] for India; Goodge et al. [66] for Antarctica; Gehrels et al. [67], Leier et al. [68], Li et al. [52], Li et al. [69], Pullen et al. [70], and Zhu et al. [56] for the Lhasa; Myrow et al. [54,71], McKenzie et al. [72], and Hughes et al. [73] for the Himalayas; Xu et al. [74] for Southern Qiangtang; Zhang et al. [75] for the Northern Qiangtang; and Cawood and Nemchin [49] and Veevers et al. [76] for Western Australia.
Figure 7. Density probability diagrams of detrital zircons with age histograms representative for (a) this study, (b) India, (c) Antarctica, (d) the Lhasa, (e) the Himalayas, (f) Southern Qiangtang, (g) Northern Qiangtang, and (h) Western Australia. The age data were compiled from Turner et al. [62], Bickford et al. [63], Malone et al. [64], and Collins et al. [65] for India; Goodge et al. [66] for Antarctica; Gehrels et al. [67], Leier et al. [68], Li et al. [52], Li et al. [69], Pullen et al. [70], and Zhu et al. [56] for the Lhasa; Myrow et al. [54,71], McKenzie et al. [72], and Hughes et al. [73] for the Himalayas; Xu et al. [74] for Southern Qiangtang; Zhang et al. [75] for the Northern Qiangtang; and Cawood and Nemchin [49] and Veevers et al. [76] for Western Australia.
Minerals 13 00998 g007
Figure 8. Simplified paleogeographic reconstruction of eastern Gondwana during the Early–Middle Ordovician period (modified after [61,77]). The canal blue arrows indicate possible detritus transport pathways (SQ = Southern Qiangtang). The yellow pentagram represents the study area.
Figure 8. Simplified paleogeographic reconstruction of eastern Gondwana during the Early–Middle Ordovician period (modified after [61,77]). The canal blue arrows indicate possible detritus transport pathways (SQ = Southern Qiangtang). The yellow pentagram represents the study area.
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6. Conclusions

Investigation of the Yunkai area in the Early Paleozoic period provides evidence of a two-episode Yunan orogenic event occurring near the Cambrian–Ordovician and Early–Middle Ordovician boundaries, respectively. Twelve lithofacies and five lithological associations were identified based on the conglomerate sequence at the bottom of the Dongchong Formation in the Shita Mountain section, with the age constraints of brachiopod fossils, which support the above viewpoint. The first episode of the Yunan Orogeny resulted in changes in the paleotopography of the seafloor in the Yunkai area, leading to the deposition of a submarine fan conglomerate layer. The second episode was more intense, causing a brief period of exposure and the formation of a sedimentary gap. The dynamic mechanism of the Yunan Orogeny is mainly controlled by the amalgamation of Gondwana. The first episode of the orogeny was synchronous with the widespread orogenic events along the northern margin of East Gondwana. The second episode corresponded to the concluding phase of the North Indian orogeny. The Yunkai area had its provenance from India, Antarctica, the Lhasa, the Himalayas, Southern Qiangtang, and Western Australia. This interpretation sheds new light on the Yunan Orogeny, but further sedimentological investigations of coeval sequences in adjacent regions are necessary to validate this hypothesis on a larger scale and to reconstruct the paleogeography of the Cathaysia Block at the onset of the Phanerozoic era.

Author Contributions

Z.W., Z.L. and Z.N. contributed to the conception and design of the study. Z.W. and Z.L. wrote the first draft of the manuscript. C.L., H.C., X.L. and K.H. participated in the field investigation and sample collection. H.Y. contributed to the data discussion. All authors have read and agreed to the published version of the manuscript.

Funding

This study was supported by the National Natural Science Foundation of China (Nos. 41802018 and 41772019); Key Laboratory of Stratigraphy and Palaeontology, Ministry of Natural Resources (KLSP2105); Hubei Key Laboratory of Paleontology and Geological Environment Evolution (PEL-202006); and Wuhan Center, China Geological Survey (QL2022-07).

Data Availability Statement

The raw data supporting the conclusion of this article will be made available by the authors, without undue reservation.

Acknowledgments

The authors want to express their gratitude to Qingluan Zeng (Wuhan) and Yuchen Zhang (Nanjing) for their invaluable assistance with the identification of brachiopod fossils in this study. Special thanks to Song Fang, Yang Wenqiang, and He Yaoyan (Wuhan) for their support during field work. The first author also acknowledges China Scholarship Council (Grant No. 202108575015) for supporting his research in the University of Münster. We thank four anonymous reviewers, and editors for their comments that led to significant improvements in the manuscript.

Conflicts of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

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Figure 3. Outcrops of basal part of the Dongchong Formation at Shita Mountain, Deqing, western Guangdong: (A) conglomerates in lower part of Bed 8; (B) conglomerates in upper part of Bed 8; (C,D) conglomerates interbedded with sandstones in Bed 9; (E) conglomerates in lower part of Bed 10; (F) coarse sandstone in upper part of Bed 10 (geological hammer = ca., 30 cm).
Figure 3. Outcrops of basal part of the Dongchong Formation at Shita Mountain, Deqing, western Guangdong: (A) conglomerates in lower part of Bed 8; (B) conglomerates in upper part of Bed 8; (C,D) conglomerates interbedded with sandstones in Bed 9; (E) conglomerates in lower part of Bed 10; (F) coarse sandstone in upper part of Bed 10 (geological hammer = ca., 30 cm).
Minerals 13 00998 g003
Figure 4. The lithology and lithofacies association of the Ordovician upper Luohong Formation and lower Dongchong Formation in Shita Maintain, Deqing, Guangdong. The length of the white bar is 10 cm, and the hammer is 30 cm. The photos (ag) showcase characteristic lithofacies features observed in various field outcrops.
Figure 4. The lithology and lithofacies association of the Ordovician upper Luohong Formation and lower Dongchong Formation in Shita Maintain, Deqing, Guangdong. The length of the white bar is 10 cm, and the hammer is 30 cm. The photos (ag) showcase characteristic lithofacies features observed in various field outcrops.
Minerals 13 00998 g004
Figure 5. LA-ICP-MS zircon U-Pb concordia age plots and age histograms of zircons of STS-3 from the basal Dongchong Formation.
Figure 5. LA-ICP-MS zircon U-Pb concordia age plots and age histograms of zircons of STS-3 from the basal Dongchong Formation.
Minerals 13 00998 g005
Figure 6. Brachiopod fossils preserved in sandstones at Shita Mountain: (ad) Orthambonites sp. and (e) Syntrophinella sp. The scale bar represents 0.5 cm. All fossils are kept in the Wuhan Center, China Geological Survey.
Figure 6. Brachiopod fossils preserved in sandstones at Shita Mountain: (ad) Orthambonites sp. and (e) Syntrophinella sp. The scale bar represents 0.5 cm. All fossils are kept in the Wuhan Center, China Geological Survey.
Minerals 13 00998 g006
Table 1. Description and interpretation of the lithofacies of Beds 8–10 for the studied section.
Table 1. Description and interpretation of the lithofacies of Beds 8–10 for the studied section.
Facies Code *LithofaciesSedimentary StructuresInterpretation
Gcboth well- and poorly sorted grainsmassive or horizontal stratificationlongitudinal bars in the braided river channel
GmsMatrix-supported gravelnonedebris flow deposits
Gcmclast-supported massive gravelcross-stratified, matrix-supported conglomeratetraction by a unidirectional current
Gmmassive or crudely bedded gravel,
clast-supported gravel
horizontal bedding, imbricationsieve deposits, channel-lag deposits
GmgMatrix-supported gravelinverse to normal gradingpseudoplastic debris flow (low strength, viscous)
Giconglomerate with well-sorted and rounded clasts.imbricationlongitudinal bars
Shparallel layered sandstoneshorizontal or flat beddinglower flow regime plane bed
Gggranule to massive gravelchaotic deposits, poorly sorted.longitudinal bedforms
Gtgravel, stratifiedtrough cross-bed imbricationminor channel fills
Gpgravel, stratifiedplanar cross-bedslinguoid bars or deltaic growths from older bar remnants
Flsand, silt, mud, interbeddedRipple-laminated or
undulatory bedding
waning flow
Fmclay, siltmassivedrape deposits
* Lithofacies codes of Miall [25,26].
Table 2. U-Pb data for detrital zircons from the Early–Middle Ordovician transition in the Shita Mountain, Western Guangdong.
Table 2. U-Pb data for detrital zircons from the Early–Middle Ordovician transition in the Shita Mountain, Western Guangdong.
Analysis207Pb/206Pb207Pb/235U207Pb/238U207Pb/206Pb207Pb/235U206Pb/238UThUTh/UConcordance
RatioRatioRatioAgeAgeAgeppmppm
SRM 6100.925710.02747 28.302050.853280.22076 0.00366 //3430301286195485421.019%
91500std0.075640.001721.87626 0.046060.179000.00213 10874610731610621232850.3798%
91500std0.074120.001681.824140.038860.17934 0.002171056 51 10541410631232850.3799%
GJ-6000.060750.001360.814560.018380.09723 0.00111 63248 605105987161930.0898%
GJ-6000.060540.001250.812700.016960.09727 0.00100 63372 604105986161900.0899%
Ple-3370.066870.002240.499850.019910.05302 0.00058 835 70 412143334777070.1178%
STS-3–010.09384 0.00129 2.717520.04223 0.20910 0.00202 150626133312122411802140.3791%
STS-3-020.06030 0.00174 0.69626 0.01925 0.08441 0.00101 613635371252262161131.9297%
STS-3-030.05882 0.00210 0.68587 0.01752 0.08433 0.00096 561785301152263061721.7898%
STS-3-040.12705 0.00140 6.56211 0.08561 0.37306 0.00338 2058192054122044161012130.4799%
STS-3-050.07804 0.00095 1.89155 0.03666 0.17418 0.00222 114824107813103512517920.0695%
STS-3-060.12032 0.00192 5.39622 0.09371 0.32418 0.00337 196129188415181016801200.6695%
STS-3-070.07328 0.00130 1.66175 0.03245 0.16390 0.00171 10223599412978101001480.6798%
STS-3-080.08068 0.00126 2.30906 0.04384 0.20716 0.00273 121430121514121415761690.4599%
Ple-3370.05379 0.00104 0.40473 0.008840.05442 0.00066 36144.4 345 63424 435000.0998%
91500std0.07302 0.00166 1.799530.04194 0.17893 0.002101015 46 1045 15 10611231850.3798%
91500std0.07674 0.00168 1.90087 0.04327 0.179410.001961115 481081 15 1064 1131830.3798%
GJ-6000.05988 0.00126 0.813400.01839 0.09829 0.00111 598 44 604 10 6047 161900.0899%
STS-3-090.08485 0.00209 1.59216 0.04109 0.13582 0.00149 1322479671682181401001.4083%
STS-3-100.06258 0.00080 0.93272 0.01367 0.10800 0.00117 69527669766173448840.3998%
STS-3-110.10653 0.00134 4.61784 0.08385 0.31346 0.00444 1743241753151758221031770.5899%
STS-3-120.07036 0.00100 1.53051 0.02371 0.15741 0.00139 939309431094281262320.5499%
STS-3-130.06057 0.00080 0.85680 0.01417 0.10229 0.00115 6333062886287465610.0899%
STS-3-140.05908 0.00151 0.69088 0.01917 0.08456 0.00103 569565331252361301181.1098%
STS-3-150.07462 0.00129 1.71112 0.03447 0.16576 0.00179 105730101313989101461650.8897%
STS-3-160.07424 0.00097 1.71385 0.02980 0.16695 0.00213 10482610141199512116080.0298%
SRM 6100.91932 0.01130 28.37179 0.393210.223220.00195 //3432141299105485421.019%
91500std0.07388 0.00162 1.83199 0.04384 0.17962 0.00215 1039 4410571610651231840.3799%
91500std0.07588 0.001671.86841 0.04334 0.17872 0.00212 1092 4910701510601232850.3799%
GJ-6000.06123 0.00126 0.82277 0.01708 0.097630.00102656 44610106006161910.0898%
STS-3-170.10100 0.00164 3.79664 0.07099 0.27203 0.00286 164330159215155115441010.4497%
STS-3-180.07151 0.00157 1.57421 0.03565 0.16008 0.00174 972449601495710571190.4899%
STS-3-190.13115 0.00134 7.03470 0.09457 0.38821 0.00386 2113182116122115181834520.4099%
STS-3-200.07424 0.00130 1.71619 0.03268 0.16759 0.00165 1048351015129999491220.4098%
STS-3-210.15787 0.00153 10.22251 0.14048 0.46871 0.00493 2433162455132478224023001.3499%
STS-3-220.10121 0.00132 4.07940 0.06205 0.29214 0.00284 1647241650131652141351550.8799%
STS-3-230.07177 0.00101 1.64309 0.02607 0.16591 0.00146 98930987109908512740.1999%
STS-3-240.06918 0.00144 1.49848 0.03288 0.15750 0.00176 90643930139431058900.6498%
Ple-3370.052470.000920.394110.00780 0.054460.000593064133763424707060.1098%
91500std0.07618 0.00159 1.88543 0.04583 0.17940 0.00222 11004310761610641232870.3798%
91500std0.07358 0.00152 1.81497 0.04126 0.17894 0.00186 10314310511510611032850.3799%
GJ-6000.05837 0.00121 0.78541 0.01737 0.09780 0.0011154344589106027161910.0897%
STS-3-250.07048 0.00129 1.59739 0.03078 0.16479 0.00168 943429691298392101841.1498%
STS-3-260.08799 0.00119 2.92341 0.04616 0.24115 0.00258 1383211388121393132151991.0899%
STS-3-270.07490 0.00101 1.95565 0.03236 0.18895 0.00195 1066281100111116112072800.7498%
STS-3-280.15537 0.00195 9.09972 0.13621 0.42411 0.00427 24062123481422791959640.9397%
STS-3-290.09859 0.00124 3.75855 0.05404 0.27582 0.00249 159822158412157013601310.4599%
STS-3-300.07520 0.00088 1.86156 0.02606 0.17907 0.00182 107424106891062102074720.4499%
STS-3-310.10627 0.00143 4.60994 0.07645 0.31349 0.00355 1736191751141758171392350.5999%
STS-3-320.07831 0.00128 2.09801 0.03822 0.19344 0.00190 1155331148131140101491890.7999%
SRM 6100.915170.01149 28.600760.36546 0.22599 0.00204 //3440131313115485421.0110%
91500std0.074110.00169 1.82053 0.04195 0.178130.00197 10565110531510571131830.3799%
91500std0.07565 0.00157 1.87987 0.03870 0.18021 0.00208 10874210741410681130810.3799%
GJ-6000.06227 0.00124 0.83730 0.017100.09740 0.001066834361895996161920.0896%
STS-3-330.07478 0.00131 1.86179 0.03546 0.18003 0.00196 1063351068131067111881641.1599%
STS-3-340.05745 0.00104 0.67946 0.01349 0.08544 0.00087 5093652685295812470.3399%
STS-3-350.07629 0.00092 1.89719 0.02492 0.17967 0.00136 1103241080910658993910.2598%
STS-3-360.07248 0.00104 1.59182 0.02387 0.15893 0.00137 100029967995181304920.2698%
STS-3-370.07073 0.00091 1.61987 0.02387 0.16574 0.00159 95026978998993034040.7598%
STS-3-380.09543 0.00131 3.46423 0.05106 0.26287 0.00219 153726151912150511871350.6499%
STS-3-390.10706 0.00142 4.64561 0.07386 0.31435 0.00350 1750251758131762171103020.3699%
STS-3-400.10696 0.00146 4.66704 0.06959 0.31622 0.00284 1750251761131771141041880.5699%
Ple-3370.05273 0.00113 0.391260.008870.05380 0.00054 3171633563383455200.0999%
91500std0.07609 0.001761.887900.04659 0.18001 0.00200 10984610771610671129780.3799%
91500std0.07367 0.001811.812500.048210.17833 0.00196 10314910501710581130800.3799%
GJ-6000.057930.001240.78697 0.01804 0.09869 0.00113 52846589106077161960.0897%
STS-3-410.08508 0.00134 2.84293 0.05640 0.24304 0.00373 131830136715140319971820.5397%
STS-3-420.05800 0.00113 0.68196 0.01437 0.08526 0.00092 52843528952864813131.5499%
STS-3-430.07073 0.00128 1.51117 0.02811 0.15523 0.00151 950329351193081071770.6198%
STS-3-440.06888 0.00093 1.36548 0.02007 0.14351 0.00124 8942387498657265070.0598%
STS-3-450.10551 0.00125 4.60495 0.06599 0.31610 0.00317 172422175012177116382140.1898%
STS-3-460.10823 0.00127 4.69456 0.06341 0.31412 0.00302 177021176611176115881970.4599%
STS-3-470.09808 0.00194 3.79443 0.07295 0.28158 0.00312 15883715921615991688481.8399%
STS-3-480.07580 0.00117 1.85915 0.03091 0.17761 0.00170 11003110671110549942290.4198%
STS-3-810.06171 0.00118 0.84341 0.01874 0.09883 0.00131 66536621106088772420.3297%
SRM 6100.921770.01042 28.73780 0.36374 0.22576 0.00221 //3445131312125485421.0110%
91500std0.07515 0.00148 1.85642 0.03891 0.17926 0.00217 10724510661410631230790.3799%
91500std0.074610.00148 1.84398 0.039000.17908 0.00204 10574010611410621130800.3799%
GJ-6000.06019 0.00116 0.81706 0.017500.09839 0.0012160941606106057161920.0899%
STS-3-490.05793 0.00119 0.67822 0.01478 0.08492 0.00094 52846526952563822631.4599%
STS-3-500.16373 0.00196 9.84665 0.13007 0.43519 0.00402 249519242112232918741090.6896%
STS-3-510.08084 0.00087 2.26460 0.02803 0.20249 0.00172 12182112019118991844990.3798%
STS-3-520.07217 0.00087 1.66344 0.02546 0.16678 0.00201 9912699510994113374720.7199%
STS-3-530.07240 0.00109 1.59051 0.02571 0.15895 0.00149 99831967109518272390.1198%
STS-3-540.06103 0.00122 0.84344 0.01632 0.10051 0.00108 63943621961761251620.7799%
STS-3-550.05851 0.00087 0.68909 0.01118 0.08520 0.00088 55036532752753265460.6099%
STS-3-560.07155 0.00108 1.58576 0.02562 0.16032 0.00157 973309651095991163150.3799%
Ple-3370.055330.00117 0.409800.009100.05358 0.00056 43348 34973363384310.0996%
91500std0.07304 0.001811.806850.045880.17943 0.00210 1017 501048171064 11 28780.3798%
91500std0.076720.00182 1.893550.04740 0.17891 0.00235 1114 48 1079 171061 1326710.3698%
GJ-6000.06148 0.001300.827100.01878 0.09726 0.00109 657 46612 10598 6161920.0897%
STS-3-570.07610 0.00108 1.89206 0.02961 0.17976 0.00180 1098-41078101066101594640.3498%
STS-3-580.13613 0.00164 7.72937 0.11945 0.40994 0.00453 218921220014221521563130.1899%
STS-3-590.07106 0.00105 1.535770.02618 0.156210.00163 95932945119369593020.299%
STS-3-600.11554 0.00155 5.37681 0.08066 0.33647 0.00316 1888291881131870151331181.1399%
STS-3-610.09935 0.00176 3.78490 0.06998 0.27589 0.00295 16133315901515711557590.9698%
STS-3-620.07390 0.00096 1.69859 0.02752 0.16603 0.00185 10392610081099010455010.0998%
STS-3-630.08980 0.00110 3.07350 0.04263 0.24775 0.00249 1421291426111427131905040.3899%
STS-3-640.05975 0.00153 0.77524 0.02061 0.09402 0.00101 59556583125796421180.3599%
SRM 6100.92462 0.01208 28.39805 0.40686 0.22214 0.00206 //3433141293115485421.019%
91500std0.07480 0.00178 1.84791 0.04625 0.17920 0.00221 10654810631710631226720.3699%
91500std0.074960.00169 1.85249 0.04512 0.17914 0.00237 11335010641610621329790.3799%
GJ-6000.06139 0.00128 0.83010 0.01830 0.09790 0.00105 65444614106026161910.0898%
STS-3-650.07632 0.00117 2.05412 0.03641 0.19458 0.00204 110336113412114611922240.4198%
STS-3-660.05753 0.00156 0.68101 0.01506 0.08500 0.00086 52261527952653952241.7699%
STS-3-670.06363 0.00093 1.03389 0.01789 0.11760 0.00135 72932721971781783970.4599%
STS-3-680.12658 0.00143 6.48720 0.08550 0.37103 0.00362 2051202044122034171122700.4299%
STS-3-690.07342 0.00097 1.77024 0.02654 0.17436 0.00156 102628103510103691993530.5799%
STS-3-700.09867 0.00122 3.39063 0.04741 0.24851 0.00212 1599231502111431111363630.3895%
STS-3-710.083220.00118 2.12369 0.04494 0.18348 0.00250 127623115715108614973550.2793%
STS-3-720.07678 0.00135 1.94578 0.03415 0.18403 0.00180 111735109712108910561130.5099%
Ple-3370.054370.00095 0.40739 0.00836 0.05423 0.00068 38744347634041048160.1398%
91500std0.074930.00177 1.86008 0.047070.17979 0.00211 11335210671710661230810.3799%
91500std0.07483 0.001651.84032 0.042000.17855 0.00200 10654410601510591130810.3799%
GJ-6000.06163 0.00127 0.83416 0.018060.09814 0.00107 66144616106036161910.0897%
STS-3-730.05828 0.001480.68407 0.017360.085240.00088 539565291052751931381.4099%
STS-3-740.07818 0.001272.08670 0.037570.193230.002061152311144121139111251970.6499%
STS-3-750.07357 0.00101 1.69236 0.02649 0.16638 0.00162 10292310061099292033420.5998%
STS-3-760.06327 0.00097 0.97519 0.01632 0.11156 0.00106 71733691868261213680.3398%
STS-3-770.06761 0.00136 1.25360 0.02488 0.13492 0.00153 85742825118169941070.8898%
STS-3-780.07316 0.00108 1.62807 0.02791 0.16073 0.00160 1018319811196191442990.4897%
STS-3-790.10025 0.00143 4.03175 0.06710 0.29070 0.00299 1629271641141645151141350.8499%
STS-3-800.05835 0.00164 0.74682 0.02007 0.09314 0.00095 54366566125746461020.4698%
SRM 6100.93316 0.01209 28.89784 0.38974 0.224050.00200 //3450131303115485421.019%
91500std0.07348 0.00172 1.81299 0.04310 0.17893 0.00204 10284210501610611125690.3698%
91500std0.076280.00172 1.88741 0.044770.179410.00212 11024410771610641225700.3698%
GJ-6000.05983 0.00126 0.80980 0.01706 0.098200.00099 59846602106046161900.0899%
Ple-3370.05576 0.00102 0.41598 0.00808 0.05394 0.00054 443835363393576370.0995%
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MDPI and ACS Style

Wang, Z.; Li, Z.; Niu, Z.; Li, C.; Chen, H.; Lin, X.; Hu, K.; Yao, H. Properties of Conglomerates from the Middle Ordovician Dongchong Formation and Its Response to the Yunan Orogeny in the Yunkai Area, South China. Minerals 2023, 13, 998. https://doi.org/10.3390/min13080998

AMA Style

Wang Z, Li Z, Niu Z, Li C, Chen H, Lin X, Hu K, Yao H. Properties of Conglomerates from the Middle Ordovician Dongchong Formation and Its Response to the Yunan Orogeny in the Yunkai Area, South China. Minerals. 2023; 13(8):998. https://doi.org/10.3390/min13080998

Chicago/Turabian Style

Wang, Zhihong, Zhihong Li, Zhijun Niu, Chu’an Li, Hao Chen, Xiaoming Lin, Kun Hu, and Huazhou Yao. 2023. "Properties of Conglomerates from the Middle Ordovician Dongchong Formation and Its Response to the Yunan Orogeny in the Yunkai Area, South China" Minerals 13, no. 8: 998. https://doi.org/10.3390/min13080998

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