Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye
Abstract
:1. Introduction
- (1)
- Metasomatism, occurring during volcanic exhalations and the diagenesis of basement volcanic and volcanic sedimentary material in proximal metamorphic facies,
- (2)
- As a result of hydrothermal SiO2 autometasomatism of volcanogenic rocks, and
- (3)
- Contact of hornfels-type metamorphic rocks and tufogenic units with postvolcanic metasomatism.
Geology
2. Materials and Methods
3. Results
3.1. Field Investigation
3.2. Mineralogical–Petrographic Investigation
Polarizing Microscope (Thin Section) Investigation
3.3. XRD (X-Ray Diffraction) Investigation
3.4. Geochemistry Investigation
WDXRF (Wavelength Dispersive X-Ray Fluorescence) Investigation
3.5. ICP-MS (Inductively Coupled Plasma-Mass Spectrometry) Investigation
3.6. Gemstone Studies
4. Discussion and Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
- Kaydu Akbudak, İ.; Başıbüyük, Z.; Gürbüz, M. Silicified woods consist with malachite, azurite, and hematite in the Middle Eocene Çekerek Formation, Tokat—Turkey. Lithol. Miner. Resour. 2021, 56, 548–558. [Google Scholar] [CrossRef]
- Başıbüyük, Z.; Akbudak, I.K.; Gürbüz, M. Mineralogical, geochemical and gemological investigation of Artova Ch-chalcedonies, Tokat–Turkey. Gospod. Surowcami Miner. 2020, 36, 77–92. [Google Scholar]
- Candan, E.Ö.; Akbudak, İ.K.; Başıbüyük, Z.; Ekincioğlu, G. Mineralogical-Petrographical and Gemological Investigation of Tokat Nebiköy Chalcedony. Turk. Geol. Bull. 2022, 65, 287–296. [Google Scholar]
- Başibüyük, Z.; Gürbüz, M.; Kaydu Akbudak, İ. Surprise eggs, the miracle of nature: Almus agates (Tokat–Turkïye). Gospod. Surowcami Miner. 2023, 39, 5–22. [Google Scholar]
- Yüzbaşıoğlu, T.Y. Mineralogical-Petrographic Investigation and Gemological Properties of Tepeyurt (Tokat) Jaspers. Master’s Thesis, Kırşehir Ahi Evran University, Institute of Science, Kırşehir, Turkey, 2020; p. 62. [Google Scholar]
- Başıbüyük, Z. Mineralogical, geochemical, and gemological characteristics of silicic gemstone in Aydıncık (Yozgat–Turkey). Arab. J. Geosci. 2018, 11, 292. [Google Scholar] [CrossRef]
- Kaydu Akbudak, İ.; Başıbüyük, Z.; Gürbüz, M. Investigation of mineralogy-petrography and economics of Yozgat “Aydıncık” chalcedony-amethyst formations. Dicle Univ. Fac. Eng. J. Eng. 2018, 9, 313–324. [Google Scholar]
- Fernie, W.T. The Occult and Curative Powers of Precious Stones; Rudolph Steiner Publications: Blauvelt, NY, USA, 1973. [Google Scholar]
- Petrov, V.P.; Bogatikov, O.A.; Petrov, R.P. Petrographical Dictionary; Nedra: Moscow, Russia, 1981. [Google Scholar]
- Kostov, I.R. Review of the Mineralogical Systematics of Jasper and Related Rocks. In Archeometrial Mühely; 2010; pp. 209–214. Available online: https://www.academia.edu/1122501/Review_on_the_mineralogical_systematics_of_jasper_and_related_rocks (accessed on 15 May 2020).
- Zaba, J. The Illustrated Encyclopedia of Minerals and Rocks; VideoGraf II: Chorzow, Poland, 2010; p. 503. [Google Scholar]
- Lazzarelli, H.N. Blue Chart Gem Identification. 2010. Available online: http://www.gembluechart.com (accessed on 10 March 2020).
- Schumann, W. Gemstones of the World; Robert Hale Ltd.: London, UK, 2001. [Google Scholar]
- Barsonav, G.P.; Yakovleva, M.E. Mineralogy of Jaspers from the USSR; (Ural, Altai), Nauka: Moscow, Russia, 1978; p. 88. [Google Scholar]
- Kievlenko, E.Y. Prospecting and Evaluation of Deposits of Gem and Decorative Stones; Nedra: Moscow, Russia, 1980; p. 263. [Google Scholar]
- Putolova, L.S.; Menchinskaya, T.I.; Baranova, T.L.; Vdovenko, A.P. Decorative Varieties of Coloured Stone in the USSR; Nedra: Moscow, Russia, 1989; p. 272. [Google Scholar]
- Kunz, F.G. The Curious Lore of Precious Stones; Dover Publications: New York, NY, USA, 1971. [Google Scholar]
- Atmann, J. Gem and Stone: Jewelry of Earth, Sea, and Sky; Chronicle Books: San Francisco, CA, USA, 2012. [Google Scholar]
- MTA 1/500.000 Scale Geological Map of Turkey, General Directorate of Mineral Research and Exploration, Ankara. 2002. Available online: https://www.mta.gov.tr/en/maps/geological-500000 (accessed on 21 February 2020).
- MTA 07-40-JHS-01-H37a1 Sheet 1/25.000 Scale Geological Map. Available online: https://www.mta.gov.tr/en/maps/geological-100000 (accessed on 15 January 2024).
- Ekincioğlu, G. Non-destructive methods determination of thermal shock resistance of natural building stones applicated with different water repellent chemicals on their surfaces. Gospod. Surowcami Miner. Miner. Resour. Manag. 2023, 39, 81–101. [Google Scholar]
- Ekincioğlu, G.; Akbay, D. Estimation of Specific Cutting Energy and Noise Level in Circular Saw Cutting Process by Leeb, Shore and Schmidt Hardness Values of Rocks. J. Min. Sci. 2023, 59, 368–379. [Google Scholar] [CrossRef]
- Baranov, P.; Shevchenko, S.; Heflik, W.; Natkaniec-Nowak, L.; Dumanska-Slowik, M. Jaspilite—The gemstone of Ukraine. J. Gemmol. Proc. Gemmol. Assoc. Great Br. 2009, 31, 163–169. [Google Scholar] [CrossRef]
- Kuresevic, L.; Vusovic, O.; Delic-Nikolic, I. Geology of gemstone deposit Ugljarevac (Central Serbia) and contributions to genetic model. Geol. Maced. 2017, 1, 67–76. [Google Scholar]
- Koch, S.; Grasselly, G. The Manganese Ore Mineral Occurrences of Hungary. Acta Min. Peti. Univ. Szegediensis 1951, 5, 1–14. [Google Scholar]
- Park, C.F. Manganese deposits of Cuba. In Geologic Investigations in the American Republics; Bulletin 935-B; United States Department of the Interior: Washington, DC, USA, 1941; pp. 75–97. [Google Scholar]
- Arık, F.; Özen, Y. Mineralogical-petrographical, geochemical properties and use of jasper formations in Tokat region as gemstone. Niğde Ömer Halisdemir Univ. J. Eng. Sci. 2020, 1, 451–460. [Google Scholar]
- Kuresevic, L.; Devic, S. Mineralogical and geochemical characterization of silica-carbonate gemstone veins from Gaj-Lazine (Central Serbia). Geol. Maced. 2015, 2, 177–182. [Google Scholar]
- Powolny, T.; Dumanska-Slowik, M. True colors of “Dalmatian Jasper”. Notes New Tech. Gems Gemol. 2017, 53, 325–331. [Google Scholar] [CrossRef]
- Kinnunen, K.A. Primary sedimentary features in Kittila jasper Finnish Lapland. Bull. Geol. Soc. 1982, 1–2, 69–76. [Google Scholar] [CrossRef]
- Mallik, S.B.; Sherwood, G.J.; Das, K. The Magnetic Mineralogy of the Precambrian Banded Haematite Jasper Formation, Orissa, India. J. Geomag. Geoelectr. 1992, 1, 155–165. [Google Scholar] [CrossRef]
- Liu, C. Gemological Characteristics of Guilin “Chicken-Blood-Red Jasper”. Guilin Gongxueyuan Xuebao/J. Guilin Univ. Technol. 2010, 30, 223–228. [Google Scholar]
(%Mass) | TA-12 (Host Rock) | TK-25 (Jasper) |
---|---|---|
SiO2 | 48.000 | 82.500 |
CaO | 13.300 | 1.070 |
Fe2O3 | 12.700 | 15.500 |
Al2O3 | 11.500 | 0.283 |
MgO | 7.830 | 0.119 |
Na2O | 2.580 | 0.054 |
TiO2 | 2.580 | 0.000 |
K2O | 0.761 | 0.026 |
P2O5 | 0.307 | 0.126 |
MnO | 0.196 | 0.256 |
SO3 | 0.055 | 0.066 |
SrO | 0.036 | 0.000 |
ZnO | 0.021 | 0.021 |
NiO | 0.014 | 0.000 |
CuO | 0.010 | 0.000 |
Cl | 0.000 | 0.012 |
(%Mass) | TM-1 (Manganese) |
---|---|
SiO2 | 13.75 |
Mn | 48.45 |
Fe(total) | 1.16 |
Conc. [ppm] | TA-12 (Host Rock) | TK-25 (Jasper) |
---|---|---|
ppm | ppm | |
Li | 20.240 | 0.000 |
Be | 0.620 | 0.010 |
B | 10.780 | 0.000 |
Na | 5335.020 | 212.330 |
Mg | 12,385.090 | 3735.460 |
Al | 61,258.530 | 4185.100 |
P | 1946.040 | 117.610 |
K | 21,213.770 | 1355.730 |
Ca | 11,254.900 | 6497.600 |
Sc | 26.620 | 1.220 |
Ti | 7902.020 | 91.750 |
V | 263.390 | 27.950 |
Cr | 206.280 | 204.640 |
Mn | 2566.540 | 8246.810 |
Fe | 79,165.770 | 41,905.180 |
Co | 42.080 | 15.520 |
Ni | 97.960 | 136.610 |
Cu | 51.260 | 72.200 |
Zn | 106.310 | 35.690 |
Ga | 22.230 | 1.950 |
Se | 0.710 | 0.000 |
Rb | 6565.420 | 504.870 |
Sr | 287.220 | 43.910 |
Y | 20.490 | 0.850 |
Nb | 3594.220 | 393.970 |
Sb | 0.590 | 0.220 |
Cs | 77,041.350 | 176,483.000 |
Ba | 412.070 | 10.330 |
La | 11.640 | 0.590 |
Ce | 27.560 | 0.980 |
Pr | 3.860 | 0.080 |
Nd | 18.230 | 0.500 |
Sm | 4.530 | 0.040 |
Eu | 1.730 | 0.000 |
Gd | 5.190 | 0.080 |
Tb | 0.710 | 0.000 |
Dy | 4.280 | 0.070 |
Ho | 0.750 | 0.000 |
Er | 2.010 | 0.010 |
Tm | 0.190 | 0.000 |
Yb | 1.430 | 0.000 |
Lu | 0.120 | 0.000 |
Pb | 2.430 | 0.240 |
U | 0.240 | 0.000 |
TJ-20: White | TJ-12 Black | TJ-8: Red | |
---|---|---|---|
ppm | ppm | ppm | |
Na | 592.566 | 796.082 | 264.680 |
Mg | 104.641 | 1153.210 | 363.541 |
Al | 400.235 | 3396.955 | 1604.638 |
Si | 186,041.958 | 186,928.229 | 241,341.791 |
P | 29.591 | 1322.346 | 262.354 |
K | 315.775 | 395.322 | 0.000 |
Ca | 1293.392 | 1302.551 | 463.350 |
Ti | 9.821 | 78.183 | 42.947 |
V | 4.376 | 69.949 | 39.148 |
Mn | 935.878 | 6040.407 | 3219.715 |
Fe | 6975.496 | 96,431.074 | 46,893.906 |
Co | 1.475 | 17.000 | 4.810 |
Ni | 14.439 | 48.921 | 74.757 |
Cu | 2813.686 | 2894.646 | 6129.106 |
Zn | 1652.259 | 1662.692 | 3512.637 |
Se | 1.926 | 0.000 | 0.000 |
Pb | 196.377 | 171.763 | 387.341 |
Cs | 78,614.384 | 13,945.647 | 36,836.487 |
Rb | 0.104 | 0.210 | 0.098 |
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Yüzbaşıoğlu, T.Y.; Kaydu Akbudak, İ. Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye. Minerals 2024, 14, 1072. https://doi.org/10.3390/min14111072
Yüzbaşıoğlu TY, Kaydu Akbudak İ. Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye. Minerals. 2024; 14(11):1072. https://doi.org/10.3390/min14111072
Chicago/Turabian StyleYüzbaşıoğlu, Taha Yasin, and İlkay Kaydu Akbudak. 2024. "Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye" Minerals 14, no. 11: 1072. https://doi.org/10.3390/min14111072
APA StyleYüzbaşıoğlu, T. Y., & Kaydu Akbudak, İ. (2024). Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye. Minerals, 14(11), 1072. https://doi.org/10.3390/min14111072