1. Introduction
Aggregation (coagulation) and fragmentation are fundamental mechanisms that occur in particulate processes such as granulation and crystallization in the pharmaceutical industry [
1]. When two particles merge to form a larger one, this process is defined as aggregation. In reverse, fragmentation leads to the formation of smaller particles after the breakup of the mother particle. The aggregation process is inherently nonlinear, while fragmentation is of two types (a) linear, and (b) nonlinear. If fragmentation is spontaneous and driven by an external agent then the process is linear. However, if the process occurs due to the interactions (collisions) between the particles in the system, then it is recognized as a nonlinear fragmentation. The byproducts of the original fragmentation undergo repeated collisions and breakages to drive this process forward. The collisional-induced fragmentation can also be observed in various fields of science and engineering, including the formation of raindrops [
2], communication systems [
3] and milling processes [
4]. Both aggregation and fragmentation mechanisms have been intensively used in the literature for developing mathematical models corresponding to granulation processes [
1].
Mathematically, both aggregation and collisional-induced fragmentation mechanisms are represented by a nonlinear integro-partial differential equation. The mathematical expression for tracking the changes in the distribution
via these mechanisms can be written as:
with the initial data
Here, stands for the partial derivative with respect to the time t. is the number density function for particles of volume x at time t. The kernel is the aggregation rate at which two particles with particle properties x and y combine to form a larger cluster. is the collision kernel which describes the rate at which particles of properties x and y are colliding. It is worth noting that both the kernels and are symmetric, that is, and . is the rate at which particles of property y breaks into fragments of property x due to its impact with a particle of property z. The breakage kernel satisfies the following properties.
- (i)
is non negative and symmetric with respect to
y and
z, that is
- (ii)
- (iii)
Number of particles after fragmentation
The first integral on the right-hand side of Equation (
1) represents the formation of the particle property
x due to the merging of particles of properties
and
y. The second term denotes the disappearance of the particle property
x from the system. The third integral describes the formation of the particle property
x from
y due to its collision with another particle
z at a specific breakup rate
. In this term, there is no restriction on the particle property
z, which acts as a catalyst, as it collides with the fragmenting particle property
y, which leads to the formation of
x. The final term explains the disappearance of particle property
x due to their collision with the other particles present in the system at a specific collision rate
.
To represent the full dynamical systems (specifically granulation and crystallization), it is also required to identify the integral properties such as the total number of particles, total volume in the system and total area of the particles. For this reason, the moments of number density
must also be defined. Let
denote the
order moment of the number density function
, and it is defined as follows:
The zeroth order moment gives the total number of particles, whereas the total volume in the system is given by the first order moment. The property of volume conservation is expected to hold during both aggregation and fragmentation events.
Smoluchowski [
5] was the first to develop an aggregation kinetics discrete model, now known as the discrete Smoluchowski coagulation equation (SCE). Müller [
6] proposed a continuous model for the volume distribution of particles, which included other phenomena such as particle fragmentation. Dubovskiǐ and Stewart [
7] established the existence and uniqueness of the solution for this continuous model. In 1988, Cheng and Redner [
8,
9] were the first to formulate a model on the nonlinear breakage equation. The analytical solutions of the general nonlinear breakage equation were studied by Kostoglou and Karabelas [
10]. Ernst and Pagonabarraga [
11] studied the collision-induced nonlinear fragmentations caused by binary interactions. Vigil et al. [
12] and Ke et al. [
13] provided the extensive analysis on coagulation with collision-induced fragmentation. Some other existence and uniqueness studies can also be found in [
14,
15]. Various numerical approaches in 1D and 2D for solving these models have been discussed in detail by [
16,
17,
18,
19,
20,
21,
22].
In the SCE, the only possibility for the clusters is to continue growing due to the aggregation mechanism, that is, smaller particles cannot be formed in the system. This restricts the application of only the coagulation process in the granulation process, however, it is still useful for polymerization process. This completely eliminates the possibility of the system to reach a steady state or equilibrium solution. Thus, this presents an opportunity for studying the Smoluchowski equation along with the fragmentation process, allowing the system to reach equilibrium. We have highlighted some of the works conducted in this regard in the above literature review. Our work in this article is another extension of the previously mentioned articles, albeit with the establishment of a new model.
In the present work, we introduce an entirely new model for continuous coagulation with collisional breakage. Earlier works have analysed equations with collsional breakage but this is the first time that such a model has been studied. The model mentioned includes the coagulation terms from the continuous SCE and the fragmentation process is represented by the third and fourth terms in (
1). This allows us to study the existence of an equilibrium solution for these mechanisms and discuss the well-posedness of Equation (
1). The current research work is majorly focused on establishing this well-posedness for compactly supported kernels. Furthermore, it is hypothesized that the breakage distribution function has the structure of a power law. The volume conservation law and uniqueness of the solution will also be proven to hold true.
Let us now mention the spaces considered in this article. For a fixed
, consider a strip
and define
to be the space of all continuous functions
with the norm
Furthermore, consider
the set of all non-negative functions from
. In this article, we prove the existence of strong solutions for the coagulation fragmentation of Equation (
1) and (
2) under the following assumptions over the kinetic kernels;
- (A1)
is a non-negative and continuous function on .
- (A2)
is a non-negative, continuous function satisfying the condition
where
and
are considered to be positive constants.
A breakdown of the various sections of this paper is as follows: In
Section 2, we state and provide a detailed proof of the existence of solutions for the IVP (
1) and (
2). In
Section 3, the theoretical results for the volume conservation property of the solution is provided. Meanwhile in
Section 4, the uniqueness of the solution is proved. The last section is devoted to some important remarks and conclusions.
2. Existence of Solutions
Theorem 1. Let the functions and be nonnegative and continuous on and respectively, and satisfy the conditions , . Moreover, the kernel and have compact support for each time . Then, the IVP (1) and (2) has at least one solution . Proof. We prove the theorem in the following steps;
Local existence of the solution, that is, there exists a
such that the IVP (
1) and (
2) has at least one solution
;
Nonnegativity of the local solution;
Global existence of the unique solution to the space .
Existence of local solution: Let us consider that there is a fixed
, the coagulation and fragmentation kernels
and
have compact supports in the intervals
for each
. Followed from Equation (
1), we have
Hence, the solution to (
1) and (
2) for
takes the value
The relation (
8) provides an approximate solution function beyond the right hand side of the compact domain, where the
tails of the solution
, that is, larger size particles, does not alter at all and matches with the
tails of the initial distribution
. Let us now focus to show that the local existence of a unique solution for
.
In this regard, let us define the integral operator
as follows;
Since
and
have compact supports and
is a nonnegative continuous function, the integral operator
is well-defined on
. This result will be proven via the contraction mapping principle. We began this exercise by showing that for small
there exists a closed ball in
, which is invariant relatively to the mapping
. Let
be a constant such that
Multiplying Equation (
7), with
on both hand sides and after performing the integration over
x, we reached
Further, we use the application of the Fubini theorem followed by changing the order of integration and considering
, then, one can obtain the following
Since
and
both have compact support, their supremiums exist. Let
and
. Applying this inequality in (
10), we obtain
Further, let
; then, the expression (
11) reduces to
Hence,
, if
. This inequality holds if
and
Presently, our focus will be to demonstrate that the mapping of
is contracting. Using the relation in (
7), we have
where
.
The first expression in the above inequality (
13) can be estimated, as follows
Furthermore, the second expression in the above inequality (
13) is simplified using the Fubini’s theorem with respect to
z and
x followed by interchanging the order of integration with respect to
y and
x, which gives the following expression
Using this estimation on the relation (
13), the following is obtained
Further, let
, then the inequality (
14) reduces to
Thus, the mapping
is contractive on
for
. Using this result together with the inequality (
12), there exists an invariant ball of radius
for sufficiently small
and in this ball,
is contractive. Consequently, the ball contains a fixed point of
.
Nonnegativity: Case I: Consider
for all
. Since
is continuous, there exists a small strip
, where
is strictly positive. For a particular
, we can find an
such that
is the point with the property that
Since the solution is continuous and satisfies (
7) it must be continuously differentiable with respect to
t. Therefore,
If
, then
for all
and
. The positivity of the right hand side of (
17) implies
.
If
, we use the property (
3) of the breakage function to obtain
Thus, from the Equation (
17), we have
.
The positive value of the time derivative establishes that there exists a point
, with
such that
. However, this counters the hypothesis that
is a point bearing a property provided by relation (
16). Hence, the point
where the solution vanishes does not exist.
Further, when
by (
7) and the compactly supported kernels
and
, the solution coincides with the initial data. Hence, again it becomes positive. Consequently,
is strictly positive provided that the initial distribution is strictly positive.
Case II: Suppose
is not strictly positive. Then, we construct the sequence
of the positive function to satisfy the conditions listed in Theorem 1, which then converges to
uniformly in
with respect to
. We have established earlier that the family of operators
, defined as
is a contraction mapping. Therefore, as
, we have
Since the mapping is contractive in
, therefore
which implies
This shows that for a positive initial data, the solution is also positive.
Global existence of unique solution: Let us first discuss the boundedness of the moments
for compactly supported kernels. Simple calculations will lead us to the following results:
and so on. Here, terms
,
are all constants. Furthermore, it is important to note that the boundedness of the
moment ensures the boundedness of the
moment for
. Thus, using the aforementioned results, we can conclude that the
implies that the solution of IVP (
1) and (
2) is bounded in the norm
. Taking into account the positivity/nonnegativity of the local solution, it is easy to extend it for
. Recalling Theorem
of [
23], the global existence of the unique solution belonging to
can easily be proved. □