Next Article in Journal
Effect of Double Pulse Resistance Spot Welding Process on 15B22 Hot Stamped Boron Steel
Previous Article in Journal
Numerical Modeling of Volatile Organic Compounds (VOC) Emissions during Preheating of Magnesia-Carbon Bricks in a Basic Oxygen Furnace
Previous Article in Special Issue
The Impact of Process Factors on Creating Defects, Mainly Lustrous Carbon, during the Production of Ductile Iron Using the Lost-Foam Casting (LFC) Method
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Metals
Volume 10
Issue 10
10.3390/met10101278
metals-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Microstructural Characteristics of AlSi9Cu3(Fe) Alloy with High Melting Point Elements

by
Tomasz Szymczak
1,*,
Grzegorz Gumienny
1,*,
Leszek Klimek
2,
Marcin Goły
3 and
Tadeusz Pacyniak
1
1
Department of Materials Engineering and Production Systems, Lodz University of Technology, 90-924 Lodz, Poland
2
Institute of Materials Science and Engineering, Lodz University of Technology, 90-924 Lodz, Poland
3
Department of Physical & Powder Metallurgy, AGH University of Science and Technology, 30-059 Krakow, Poland
*
Authors to whom correspondence should be addressed.
Metals 2020, 10(10), 1278; https://doi.org/10.3390/met10101278
Submission received: 18 August 2020 / Revised: 16 September 2020 / Accepted: 21 September 2020 / Published: 23 September 2020
(This article belongs to the Special Issue Solidification and Crystallization of Foundry Alloys)
Browse Figures
Review Reports Versions Notes

Abstract

:
The paper presents the results of microstructure tests of EN AC-46000 hypoeutectic Al–Si alloy with and without high-melting-point elements: chromium, molybdenum, vanadium, and tungsten. The above-mentioned elements were used individually or simultaneously in various combinations. The tested castings were made using two technologies: shell molding and high pressure die casting (HPDC). Using X-ray diffraction and microanalysis of the chemical composition an attempt to determine the phase structure of the tested alloy was made. It has been shown that the microstructure of the base alloy consists of dendrites of α(Al) solid solution and complex eutectic mixtures: ternary α(Al) + Al15(Fe,Mn)3Si2 + β(Si) and quaternary α(Al) + Al2Cu + AlSiCuFeMgMnNi + β(Si). High-melting point elements, regardless of the combination used, attach mainly to intermetallic phases rich in Fe and form the Al15(Fe,Mn,M)3Si2 phase, where M is any high melting point element or a combination of such elements. It has been shown that the area fraction of the above-mentioned phase increases with increasing content of high melting point elements. A greater area fraction of the Al15(Fe,Mn,M)3Si2 phase in the casting from the shell mold in relation to the high pressure die casting has been also found.

1. Introduction

Among the many aluminum alloys AlSi9Cu3(Fe) (EN AC-46000) is a typical high pressure die casting alloy. According to the PN EN 1706 standard [1], its chemical composition is as follows: 8.0–11.0 wt % Si; ≤ 1.3 wt % Fe; 2.0–4.0 wt % Cu; ≤ 0.55 wt % Mn; 0.05–0.55 wt % Mg; ≤ 0.15 wt % Cr; ≤ 0.55 wt % Ni; ≤ 1.2 wt % Zn; ≤ 0.35 wt % Pb; ≤ 0.15 wt % Sn, ≤ 0.25 wt % Ti. The ASTM equivalent of the above mentioned alloy is A380. The crystallization process of this alloy is described in [2] by Taylor et al. First dendrites of α(Al) solid solution crystallize out of the liquid. Then, as a result of the peritectic transformation, the lamellar intermetallic phase β-Al5FeSi is formed, and afterwards three eutectic mixtures crystallize successively: α(Al) + β(Si) eutectic mixture and two complex mixtures containing Mg2Si and Al2Cu phases. On the other hand, in [3], the authors present the three-stage process of EN AC-46000 alloy crystallization based on the derivative and thermal analysis. According to the presented data, the crystallization process starts with the crystallization of α(Al) dendrites, then two complex eutectic mixtures crystallize: ternary and quaternary. The ternary eutectic consists of solid solutions α(Al), β(Si), and the Fe-rich intermetallic phase. The quaternary eutectic mixture consists of solutions: α(Al) and β(Si), Al2Cu intermetallic phase and the phase described as AlSiCuFeMgMnNiTi. In [4], Dinnis et al. report that the addition of 0.5 wt % Mn results in the occurrence of the Al15(Fe,Mn)3Si2 intermetallic phase with the morphology of “Chinese writing” instead of the Fe-rich β-Al5FeSi phase. The presence of the β-Al5FeSi phase negatively affects the tensile strength and elongation [2]. The Al15(Fe,Mn)3Si2 phase is assigned a less detrimental effect on the aforementioned properties [2]. The papers [5,6,7] present the results of the HPDC hypoeutectic alloy microstructure. The data presented therein shows the presence of α(Al) solid solution dendrites, α(Al) + β(Si) eutectic mixture, Al2Cu and iron-rich intermetallic phases in the microstructure. These phases, depending on the concentration of Fe, Mn, and Cr, can be characterized by a different phase structure and morphology. The β-Al5FeSi phase crystallizes in the alloy with a relatively low manganese and chromium content. At 0.15 wt % Mn or more, Al15(Fe,Mn)3Si2 phase appears in the microstructure. If 0.15 wt % chromium is present in the alloy, its atoms are attached to this phase. The authors of [5] describe such a phase as α-Alx(Fe,Mn,Cr)ySiz, while in [7] it described as Al15(Fe,Mn,Cr)3Si2. Fe-rich phases in HPDC alloys may be characterized by plate, block or polyhedral morphology, depending on Fe, Mn, and Cr concentrations and casting parameters. The authors of [7] report the possibility of the Al5Si6Mg8Fe2 intermetallic phase crystallization in the above-mentioned alloy. The content of Fe and Mn is also significantly related to the phenomenon of die soldering [5,8,9]. This phenomenon consists in the formation of intermetallic phases on the surface of the pressure die casting mold, mainly in the Al-Fe and Al-Fe-Si systems, as a result of the reaction of the liquid Al-Si alloy with the mold material. This leads to the casting sticking to the mold surface and significantly accelerates its wear. The method of preventing die soldering is to increase the content of Fe and Mn in the alloy. According to [5], the Fe content sufficient to protect the mold is 0.8 wt %. According to [8], the mold can be secured with 1.1 wt % Fe, and the lower Fe content can be compensated by the addition of Mn.
High-melting-point elements can also affect the formation of intermetallic phases in aluminum alloys. In addition to the aforementioned Cr, other elements from this group are also analyzed in this paper: Mo, V, and W. A small number of studies concerning high-melting point elements in Al-Si alloys have revealed two main purposes for using them: the increase in the effect of precipitation strengthening and reducing the detrimental effect of iron on the mechanical properties. It has been shown that Cr, Mo, or V can enhance the precipitation hardening effect, consequently increasing the mechanical properties at both ambient and elevated temperatures [10,11,12,13]. Chromium and molybdenum are the most effective in this respect. The ability to reduce the detrimental effect of iron on the mechanical properties of Al-Si alloys is demonstrated by Cr, Mo, V, and W. The aforementioned elements cause a reduction in the size of the β-Al5FeSi lamellar precipitates or crystallization instead of the lamellar phase the other phases with a morphology considered to be less harmful. Morphological changes having a beneficial effect on the mechanical and plastic properties of Al-Si alloy caused by Cr, Mo, V, and W (added separately) have been described in [5,10,14,15,16]. Depending on the type and amount of high-melting point elements as well as the crystallization conditions, the iron-rich phases may have different morphology: “Chinese writing”, block, polygon, star, or dendritic. The above-described morphological changes were analyzed mainly in the microstructure of die castings. It has been shown that these changes can positively affect the mechanical properties of aluminum alloys. However, the cheaper manganese is most often used as the main additive in reducing the detrimental effect of iron.
The analysis of the Cr, Mo, V, and W interactions in hypoeutectic aluminum alloy was developed on the basis of the two-component Al-Si phase diagrams with the above mentioned elements as well as the phase diagrams between the tested high-melting point elements. The Al-Mo [17] and Al-W [18] phase diagrams show that molybdenum and tungsten are not soluble in solid aluminum. In [19], Okamoto reports that also chromium does not dissolve in aluminum. However, according to [18], the maximum solubility of Cr in Al occurs at the temperature of 661.5 °C and amounts to 0.71 wt %. The Al-V phase diagram [18] shows that the solubility of vanadium in aluminum amounts to a maximum of 0.6 wt %. The lack of solubility of the above-mentioned high-melting point elements in Al or their highly limited solubility causes the precipitation of a number of intermetallic phases. According to the phase diagrams, they crystallize mainly as a result of peritectic transformations. Also, the Cr-Si [18], Mo-Si [20], V-Si [21], and W-Si [22] phase diagrams show the possibility of the formation of numerous intermetallic phases. All these elements practically do not dissolve in silicon. Instead, they show excellent mutual solubility in the solid state. The phase equilibrium systems Cr-Mo [23], Cr-V [24], Cr-W [25], Mo-V [26], Mo-W [18], and V-W [27] show that they form unlimited solutions. The presented analysis of the interaction of Cr, Mo, V, and W in aluminum alloys shows the possibility of crystallization of numerous intermetallic phases. From the point of view of mechanical properties, the intermetallic phases can increase the hardness of the alloy and thus its brittleness. The papers [28,29,30] present the results of a statistical analysis of the effect of Cr, Mo, V, and W in the HPDC aluminum alloy on its mechanical properties (tensile strength, yield point, elongation, and hardness). They show the possibility of increasing the above mentioned properties by the high melting point elements. The authors attribute this possibility to supersaturation of the α(Al) solid solution with high melting point elements. The possibility of the crystal supersaturation with the substance at the front of its crystallization increases with the increase of the nucleation rate and crystal growth [31,32]. Another factor that significantly influences the possibility of supersaturation of the crystal is the amount of the dissolved substance ahead of the crystallization front. It was reported in [33] that the supersaturation of the α(Al) phase is the greater the greater amount of the dissolved substance ahead of the crystallization front. It follows from the above that the supersaturation of the dendrite with the high melting point elements will be more effective the faster the heat transfer from the casting and the higher the concentration of admixtures (including Cr, Mo, V, and W) at the front of dendrite crystallization. A relatively high rate of heat transfer from the casting can be ensured by the use of technology that uses a steel mold, such as die casting and, in particular, high pressure die casting (HPDC). However, to assess the amount of high melting point elements on the dendrite crystallization front, it is important to learn about the crystallization processes and the formation of aluminum alloy microstructure with the different content of these elements.
This paper presents the changes in the microstructure of multi-component Al-Si alloy on the example of EN AC-46000 alloy occurring as a result of Cr, Mo, V, and W additions in various amounts and combinations.

2. Materials and Methods

The range of the chemical composition of the base EN AC-46000 alloy used for the tests has been shown in Table 1. The range of the chemical composition given is determined based on the spectrometric examination of 15 specimens of the base alloy.
The base alloy was melted in a gas-fired shaft furnace type MH II-N 1500/750 by StrikoWestofen (Gummersbach, Germany). Inside the melting furnace, the alloy was refined with the Ecosal Al113.S solid refiner. After smelting and refining, the alloy was deslagged and transported to a holding furnace located at a high pressure die casting machine. The following high melting point elements were added to the base alloy in the holding furnace: Cr, Mo, V, and W. These elements were added in various combinations: singly, in double and triple combinations as well as simultaneously. Due to the relatively high melting point of Cr, Mo, V, and W and the relatively low alloy temperature in the holding furnace (~750 °C), these elements were added in the form of master alloys: AlCr15, AlMo8, AlV10, and AlW8. Master alloys containing high-melting point elements were in the form of pieces weighing about 200 g. The holding time of the master alloys in the furnace at the temperature of 750 °C was 30–40 min. The used combinations, the content of the high-melting elements in a given combination and the step (how the concentration of high-melting point elements was changed) are presented in Table 2. The real tested content of high-melting point elements were within the range of ±0.015 wt % in relation to those indicated in Table 2 nominal values. If more than one high melting point element was added, all the elements were used in equal amount.
For each variant of the chemical composition, pressure and shell castings were made. The pressure castings were in the shape of the side cover of the roller shutter casing, approximately 2 mm thick. They were manufactured on a cold-chamber die casting machine Idra 700S (IDRA, Travagliato, Italy). The shell mold, on the other hand, was made of a shell sand, it had the form of a probe, the dimensions of which are presented in [3]. A thermal and derivative analysis of the crystallization process of the tested alloys was carried out with the use of a above mentioned probe equipped with a PtRh10-Pt thermocouple. Thermal and derivative analysis is a universal method of studying the solidification of alloys. So far, it has been successfully used to study alloys: iron [34], aluminum [35,36], copper [37], magnesium [38], or cobalt [39]. The alloy temperature at the time of pouring the probe was ~1000 °C.
Metallographic tests were carried out on specimens taken from high pressure die castings as well as the from the shell mold. The metallographic specimens were etched with a 2% aqueous solution of hydrofluoric acid. The microstructure was examined using the Nikon Eclipse MA200 optical microscope (Nikon, Tokyo, Japan) and the Hitachi S-3000N scanning electron microscope (SEM) (Hitachi, Tokyo, Japan). The NIS Elements image analysis software (version 3.00, Japan) was used to determine the area fraction of intermetallic phases.
X-ray diffraction was performed on a Bruker D8 Advance diffractometer (Bruker, Karlsruhe, Germany). Filtered radiation of a cobalt lamp with a wavelength of λ = 0.179 nm was used. Phase analysis was performed using EVA software. Patterns from the ICDD (The International Center Diffraction Data) database were used. The point microanalysis of the element concentration and the map of the surface distribution were made using a HITACHI S-3000N scanning electron microscope (Hitachi, Tokyo, Japan) equipped with an EDS detector by Pionieer and the VENTAGE software by NORAN. The acceleration voltage was 15 keV.

3. Results

3.1. Base Alloy

The three-stage process of crystallization of the base alloy is illustrated by the thermal and derivative analysis curves (black color) presented in Figure 1.
The derivative curve shows three thermal effects: CsAB, BEH, and HKL. According to the data presented in [3], these are the effects caused by the crystallization of α(Al) solid solution, ternary eutectic α(Al) + Al15(Fe,Mn)3Si2 + β(Si) and quaternary eutectic α(Al) + Al2Cu + AlSiCuFeMgMnNi + β(Si). The authors of [40,41,42] show that in the case of multicomponent hypoeutectic al-Si alloys, after the crystallization of the primary α(Al) phase, complex eutectic mixtures usually crystallize, in which the α(Al) and β(Si) solid solutions and intermetallic phases appear as component phases. The average solidification rate was 0.23 °C/s for the base alloy, and 0.27 °C/s for the alloy containing 0.20 wt % of all high-melting point elements (red color, Figure 1). The microstructure of the base aluminum alloy from the shell mold is shown in Figure 2. This microstructure is consistent with the results of the thermal and derivative analysis. The component phase of the ternary eutectic marked in the figure is the iron-rich Al15(Fe,Mn)3Si2 phase. This is indicated by the morphology of “Chinese writing” characteristic of this phase and the results of the point analysis of the chemical composition. The studied precipitation with a histogram of the elements concentration is shown in Figure 3a,b. The occurrence of this phase in the microstructure of EN AC-46000 alloy was also found in [5,6,43,44,45]. In [6], the authors also state the possibility of the occurrence of another iron-rich intermetallic phase–β-Al5FeSi.
The presence of the Al2Cu phase within the quaternary eutectic was determined by X-ray diffraction. Figure 4 also shows the presence of α(Al) and β(Si) solid solutions in the tested alloy. The symbol of the AlSiCuFeMgMnNi phase in the quaternary eutectic should be treated conventionally, because it does not mean the intermetallic phase containing all the elements, but a number of phases that can contain these elements. Such a situation is possible due to the high complexity of the chemical composition of the tested alloy. The ‘pushing’ of the elements characterized by reverse microsegregation by the crystallization front of the α(Al) phase and the ternary eutectic may lead to different chemical composition of the residual liquid in different regions of the alloy. Then, in quaternary eutectic, fine intermetallic phases with different chemical composition and phase structure can crystallize. Figure 5 shows, for example, the region of the quaternary eutectic and the map of Al, Si, Mg, and Cu distribution.
From the presented data, it can be concluded that in this region solid solutions α(Al) and β(Si) as well as the intermetallic phases Al2Cu and Mg2Si occur. Analogous analyzes were carried out in other regions of the material; they showed the presence of intermetallic phases crystallizing in the Al-Cu-Ni, Al-Fe-Mn-Si, and Al-Cu-Mg-Si systems within the quaternary eutectic.
Figure 6 shows the microstructure of the HPDC EN AC-46000 base alloy.
The microstructure consists of α(Al) solid solution dendrites and eutectic composed of α(Al), β(Si) solutions and intermetallic phases. Precipitations of the β(Si) phase in eutectic mixture are characterized by lamellar morphology. This microstructure differs from the base alloy from the shell mold mainly in the phases size. This is, of course, due to the much higher heat transfer from the casting to the pressure die casting mold compared to the shell mold. In addition to a significant reduction in the size of the precipitates, intense heat transfer to the pressure die casting mold may result in supersaturation of the α(Al) solid solution with alloying elements. Due to the above, a lower volume fraction of intermetallic phases in the Al-Si alloy can be obtained. High intensity of heat transfer from the casting can also lead to a more compact morphology of intermetallic phases. In the presented microstructure, there are no intermetallic phases with the morphology of “Chinese writing”. Diffraction tests showed the presence of intermetallic phases: Al2Cu, Al2CuMg, and other phases that crystallize in the systems: Al-Fe-Si, Al-Cu-Fe, and Mn-Ni-Si. Due to the very intensive process of solidification in the pressure die casting mold, the chemical composition of the individual phases varies greatly from the equilibrium composition. Figure 7 shows the results of the point analysis of the chemical composition of the selected intermetallic phase in the tested alloy. The results indicate that it may be Al2Cu phase with dissolved magnesium and silicon at a concentration of 0.45 and 5.24 wt %, respectively.

3.2. Al-Si Alloys with High Melting Point Elements from the Shell Mold

Relatively small amounts of high melting point elements in the alloy from the shell mold do not cause significant changes in the thermal and derivative curves as well as the alloy microstructure. These elements attach mainly to the intermetallic phases in eutectic mixtures. There are no ‘new’ phases, and no additional thermal effects are recorded in the thermal and derivative curves. For example, Figure 8 shows the region of the ternary eutectic in the alloy with ~0.2 wt % V and W from the shell sand probe, along with the analysis of the elements’ distribution. The presented data shows the presence of a solid solution α(Al), silicon plates and the intermetallic phase with increased content of Al, Fe, V, Mn, and W within the ternary eutectic. The last of the phases presented is also characterized by an increased concentration of Si. Diffraction studies did not allow for unambiguous identification of this phase, but due to the elements it contains and the characteristic morphology of the “Chinese writing” type, it was assumed that it is Al15(Fe,Mn,V,W)3Si2 phase. Fine precipitations of pure lead adhere to this phase. In the analyzed region, there are also places with an increased concentration of copper, magnesium, and aluminum. This suggests that the quaternary eutectic adheres to the analyzed grain of the ternary eutectic.
An example of the quaternary eutectic region with the distribution analysis of elements is shown in Figure 9.
The increased content of Al, Si, Cu, and Mg in the studied region indicates the possibility of the presence of α(Al) phase, Si crystals, intermetallic phases Al2Cu and Mg2Si or more complex phases containing the above mentioned elements. In the quaternary eutectic, there may also be fine precipitates of the intermetallic phases containing high melting point elements. Analogous analyses of the chemical composition of the phases in the quaternary eutectic of the Al-Si alloy with the high-melting point elements have shown the possibility of the presence of phases that crystallize in the Al-Fe-Si-Mn-M system, where M is any high melting point element or a combination of such elements.
When a certain limit content of high-melting elements is exceeded, the additional thermal effect is registered in the thermal and derivative curves. This effect is presented, for example, on the curves of Al-Si alloy with 0.2 wt % Cr, Mo, V, and W each (Figure 1—red color). It was described as CsA′A″. The precipitation of the ‘new’ phase related to the CsA′A″ effect is shown, for example, in the microstructure of Al-Si alloy containing 0.3 wt % Cr (Figure 10). This phase is characterized by a morphology similar to dendritic. The point analysis of the chemical composition in the ‘new’ phase precipitation presented in Figure 11 indicates that it is probably Al15(Fe,Mn,Cr)3Si2 phase with a small amount of Cu and Ni dissolved. The thermal effect CsA′A″ associated with the Al15(Fe,Mn,Cr)3Si2 phase occurs before the A″AB effect, which is caused by the crystallization of α(Al) solid solution, so with a sufficiently high chromium content this phase may crystallize primarily. Analogous phases (and related CsA′A″ effects on thermal and derivative curves) also occur in alloy containing high melting point elements other than Cr, or any combinations of them, however, with a sufficiently high content of high melting point elements. For simplicity, this phase is designated as Al15(Fe,Mn,M)3Si2, where M is any high melting point element or a combination of them.
The minimum content of high melting point elements at which the primary Al15(Fe,Mn,M)3Si2 intermetallic phases ware observed is shown in Table 3.
In the case of alloys in which Al15(Fe,Mn,M)3Si2 primary phase crystallizes, it was observed that it absorbs so many Fe, Mn, and high melting point elements atoms that within the thermal effect BEH (Figure 1), the ternary eutectic does not crystallize. Instead, the classical α(Al) + β(Si) binary eutectic mixture crystallizes, which does not contain the Al15(Fe,Mn,M)3Si2 phase with the morphology of “Chinese writing”. On the other hand, the quaternary eutectic (HKL effect—Figure 1) is analogous for all tested alloys containing high melting point elements. It consists of α(Al) and β(Si) solid solutions, the Al2Cu phase and the next phase, the composition of which depends on the residual liquid which is differentiated due to microsegregation. Most often, this is Mg2Si or Al15(Fe,Mn,M)3Si2 phase. An example of the quaternary eutectic region in Al-Si alloy containing 0.4 wt % Cr and the map of Al, Si, Fe, Cr, Mn, and Cu distribution are shown in Figure 12. The presented data indicate that in this region there are α(Al), β(Si), Al2Cu, and Al15(Fe,Mn,Cr)3Si2 phases.

3.3. High Pressure Die Casting (HPDC) Al-Si Alloys with High Melting Point Elements

In the case of HPDC alloy, the addition of relatively small amounts of high melting point elements does not cause significant changes in terms of the phases in the microstructure. High melting point elements are mainly built into the intermetallic phases in the eutectic mixture or, due to the high intensity of heat transfer from the casting to the pressure die casting mold, they supersaturate α(Al) solid solution. The average solidification rate of HPDC alloy containing high-melting point elements, calculated on the basis of the secondary dendrite arm spacing (SDAS), was 56.6 °C/s. Similarly to the case of alloy from the shell mold, a certain limit content of high-melting elements also causes the formation of ‘new’ intermetallic phases in the microstructure of the HPDC alloy. Figure 13 shows an example of the microstructure of a HPDC alloy containing V and W.
In Al-Si alloy with the addition of about 0.2 wt % V and W, a ‘new’ intermetallic phase was formed; it is characterized by a compact-block morphology, while increasing the content of V and W to 0.3 wt % also causes the crystallization of this phase, but with a morphology similar to a four-pointed star or polygon. This phase penetrates both the α(Al) dendrites as well as eutectic regions. This allows the conclusion that these phases contain high melting point elements and crystallize directly from the liquid at a temperature higher than the other phases. The content of high melting point elements, at which ‘new’ primary phases were observed in the microstructure of HPDC alloy is shown in Table 4.
Figure 14 shows an example of the region in the microstructure of HPDC Al-Si alloy containing 0.5 wt % Cr with a ‘new’ phase and the map of Si, Fe, Cr, Mn, and Cu distribution.
The increased concentration of Al, Si, Fe, Cr, and Mn in the ‘new’ phase indicates that it is probably Al15(Fe,Mn,Cr)3Si2 intermetallic phase. The high concentration of aluminum and simultaneously aluminum and copper in the region surrounding the analyzed Al15(Fe,Mn,Cr)3Si2 phase indicates the presence of α phase dendrites and eutectic mixture containing Al2Cu phases. The ‘new’ iron-rich phase can contain all high melting point elements tested. This is indicated by the research on the chemical composition of this phases in Al-Si alloy containing about 0.25 wt % of each high melting point elements tested (simultaneously added). The chemical composition was investigated on ten randomly selected precipitates of ‘new’ intermetallic phases. Figure 15 shows an example of the intermetallic phase tested in this alloy while in Table 5 the chemical composition of the 10 randomly selected phases is presented.
Each tested precipitation consists of Al, Si, Fe, Mn as well as Cr, Mo, V, and W. The average concentration of elements indicates that it is a phase similar to Al15(Fe,Mn)3Si2, in which in which Fe and Mn atoms were replaced by Cr, Mo, V, and W. The previously introduced designation Al15(Fe,Mn,M)3Si2 was used to describe this phase. The average concentration of high melting point elements in this phase indicates that it adopts chromium atoms to the greatest extent, molybdenum and vanadium to a lesser extent, and tungsten to the smallest extent. Both in the case of HPDC alloy as well as from the shell mold, the amount and size of the primary Al15(Fe,Mn,M)3Si2 phase increases, which results in an increase in the area fraction. Figure 16 shows, for example, changes in the area fraction of the primary Al15(Fe,Mn,M)3Si2 phase in a Al-Si alloy containing vanadium (a) and simultaneously Cr, Mo, V, and W (b) occurring with an increase in their concentration.
The presented data show that from the moment of the appearance of the primary Al15(Fe,Mn,M)3Si2 phase, further increasing the content of high melting point elements causes an increase in its area fraction. The lack of data on the area fraction of this phase in the vanadium-containing alloy from the shell mold (Figure 16a) results from the fact that this phase does not occur in the alloy microstructure in the studied range of V content (Table 3). The data presented in Figure 16b also shows a greater area fraction of the Al15(Fe,Mn,M)3Si2 phase in the alloy from the shell mold compared to the HPDC alloy.
This section may be divided by subheadings. It should provide a concise and precise description of the experimental results, their interpretation as well as the experimental conclusions that can be drawn.

4. Discussion

The results presented in the paper showed a three-stage solidification process of AlSi9Cu3(Fe) base alloy in a shell mold. The dendrites of α(Al) solid solution are the first to crystallize at the highest temperature. Then the ternary and quaternary eutectic mixtures crystallize. In the ternary eutectic mixture, apart from α(Al) and β(Si) solid solutions, there is an intermetallic Al15(Fe,Mn)3Si2 phase with the morphology of “Chinese writing”. The quaternary eutectic mixture formed from the remains of the liquid consists of the α(Al) and β(Si) solutions, the Al2Cu intermetallic phase as well as another intermetallic phase. The chemical composition of the latter phase depends on the different, as a result of microsegregation, the content of elements in different areas of the liquid metal in the final phase of the solidification process. Most often it is Mg2Si phase, but phases from Al-Cu-Ni, Al-Fe-Mn-Si, and Al-Cu-Mg-Si systems have also been found in the quaternary eutectic mixture. A relatively small amount of high melting point elements does not create ‘new’ phases in the microstructure. These elements attach mainly to iron-rich intermetallic phases which are described as Al15(Fe,Mn,M)3Si2. Exceeding a certain critical content of high melting point elements generally causes crystallization of the Al15(Fe,Mn,M)3Si2 phase at a temperature higher than the crystallization temperature of α(Al) dendrites. This process was not observed in alloys containing vanadium and a combination of vanadium and tungsten in the studied range. The amount of this phase in the microstructure increases with the increase in the content of high melting point elements. The primary crystallization of this phase causes the depletion of the remaining liquid in high melting point elements, which causes the crystallization of the lamellar eutectic α(Al) + β(Si) instead of the ternary eutectic mixture.
The microstructure of AlSi9Cu3(Fe) HPDC alloy without high melting point elements consists of dendrites of α(Al) phase and the eutectic mixture. The eutectic mixture consists of α(Al) and β(Si) solid solutions and relatively fine precipitations of intermetallic phases. These are mainly copper and magnesium phases, and to a lesser extent iron, manganese, and nickel phases. The intensive heat transfer during HPDC process results in a much finer microstructure compared to shell mold castings. The size reduction in α(Al) dendrites and the eutectic mixture phases is observed. The addition of a certain critical content of high melting point elements causes, similarly to the case of alloy from the shell mold, the primary crystallization of the Al15(Fe,Mn,M)3Si2 intermetallic phase. The content of the above-mentioned elements affects both the amount of the primary phase as well as the morphology of its precipitations. As the content of high melting point elements increases, the amount of this phase increases too, and its morphology changes from a compact block to a polygon or star-like.
From the point of view of the possibility of α(Al) phase supersaturation with high melting point elements, the most important factor related to the formation of the microstructure seems to be the amount of the primary Al15(Fe,Mn,M)3Si2 phase. The addition of high melting point elements within the content that does not cause the formation of the primary phase results in an increase in the concentration of these elements before α(Al) dendrite crystallization front. On the other hand, the Al15(Fe,Mn,M)3Si2 phase, which crystallizes at a temperature higher than that of α(Al) dendrites, absorbs a significant amount of high melting point elements and reduces their concentration before the α(Al) phase crystallization front. Due to the above, the greatest possibility of effective supersaturation of α(Al) dendrites with high-melting-point elements is created by their possibly high content in the alloy; which does not, however, cause crystallization of the primary Al15(Fe,Mn,M)3Si2 phase. As the HPDC technology is characterized by a relatively high heat transfer rate from the casting, which favors α(Al) phase supersaturation, it should be considered a great potential for the production of hypoeutectic aluminum alloys with Cr, Mo, V, and W.

5. Conclusions

The research presented in the paper shows the following conclusions:
  • The addition of a small amount of high-melting point elements to the alloy causes their attachment to the constituent phases of the base alloy.
  • Exceeding a certain limit content of high melting point elements causes the crystallization of Al15(FeMnM)3Si2 phase at a temperature higher than the crystallization temperature of the primary α(Al) phase. Further increase in the content of high-melting-point elements causes an increase in the area fraction of the Al15(FeMnM)3Si2 phase in the alloy.
  • High-melting-point elements in the range of content that does not cause formation of the primary Al15(FeMnM)3Si2 phase result in an increase in their concentration before the α(Al) dendrite crystallization front.
  • Primary crystallization of Al15(FeMnM)3Si2 at a temperature higher than the crystallization temperature of α(Al) dendrites, absorbs a significant amount of high melting point elements, thus reducing their concentration in front of α(Al) dendrite crystallization front.
  • The greatest possibility of effective supersaturation of α(Al) dendrites with high-melting-point elements is created by their possibly high content in the alloy, which does not, however, cause the primary crystallization of the Al15(FeMnM)3Si2 phase.

Author Contributions

Conceptualization, validation, formal analysis, writing—review and editing, T.S. and G.G.; methodology and writing—original draft preparation, T.S.; software, M.G. and L.K.; investigation, T.S., G.G, L.K., and M.G.; project administration and funding acquisition, T.P. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Kahler, G.A.; Fisher, F.M.; Sass, R.L. The chemical composition and mechanical properties of the hinge ligament in bivalve molluscs. Biol. Bull. 1976, 151, 161–181. [Google Scholar] [CrossRef] [PubMed]
  2. Taylor, J.A. Iron-Containing Intermetallic Phases in Al-Si Based Casting. In Procedia Materials Science, Proceeding of the 11th International Congress on Metallurgy & Materials SAM/CONAMET, Rosario, Argentina, 18–21 October 2011; pp. 19–33. Available online: https://www.sciencedirect.com/science/article/pii/S2211812812000053 (accessed on 22 September 2020).
  3. Szymczak, T.; Gumienny, G.; Kurowska, B.; Tadeusz, P. Hypoeutectic Al-Si Alloy doped with Chromium, Tungsten and Molybdenum designated for pressure die casting. Arch. Met. Mater. 2017, 62, 1629–1635. [Google Scholar] [CrossRef]
  4. Dinnis, C.M.; Taylor, J.A.; Dahle, A.K. Porosity formation and eutectic growth in Al-Si-Cu-Mg alloys containing Iron and Manganese. In Proceedings of the 9th International Conference on Aluminium Alloys (ICAA9), Brisbane, Australia, 2–5 August 2004; pp. 1016–1021. [Google Scholar]
  5. Timelli, G.; Bonollo, F. The influence of Cr content on the microstructure and mechanical properties of AlSi9Cu3(Fe) die-casting alloys. Mater. Sci. Eng. A 2010, 528, 273–282. [Google Scholar] [CrossRef]
  6. Outmani, I.; Fouilland-Paille, L.; Isselin, J.; El Mansori, M. Effect of Si, Cu and processing parameters on Al-Si-Cu HPDC castings. J. Mater. Process. Technol. 2017, 249, 559–569. [Google Scholar] [CrossRef] [Green Version]
  7. Dos Santos, S.L.; Antunes, R.A.; Santos, S.F. Influence of injection temperature and pressure on the microstructure, mechanical and corrosion properties of a AlSiCu alloy processed by HPDC. Mater. Des. 2015, 88, 1071–1081. [Google Scholar] [CrossRef]
  8. Makhlouf, M.M.; Apelian, D. Casting Characteristics of Aluminum Die Casting Alloys; Advanced Casting Research Center Worcester Polytechnic Institute: Worcester, MA, USA, 2002. [Google Scholar]
  9. Han, Q.; Viswanathan, S. Analysis of the mechanism of die soldering in Aluminum die casting. Met. Mater. Trans. A 2003, 34, 139–146. [Google Scholar] [CrossRef]
  10. Farkoosh, A.R.; Chen, X.G.; Pekguleryuz, M. Dispersoid strengthening of a high temperature Al–Si–Cu–Mg alloy via Mo addition. Mater. Sci. Eng. A 2015, 620, 181–189. [Google Scholar] [CrossRef]
  11. Li, Y.; Yang, Y.; Wu, Y.; Wei, Z.; Liu, X. Supportive strengthening role of Cr-rich phase on Al–Si multicomponent piston alloy at elevated temperature. Mater. Sci. Eng. A 2011, 528, 4427–4430. [Google Scholar] [CrossRef]
  12. Kim, H.Y.; Han, S.W.; Lee, H.M. The influence of Mn and Cr on the tensile properties of A356–0.20Fe alloy. Mater. Lett. 2006, 60, 1880–1883. [Google Scholar] [CrossRef]
  13. Elhadari, H.; Patel, H.; Chen, D.; Kasprzak, W. Tensile and fatigue properties of a cast aluminum alloy with Ti, Zr and V additions. Mater. Sci. Eng. A 2011, 528, 8128–8138. [Google Scholar] [CrossRef]
  14. Mbuya, T.O.; Odera, B.O.; Ng’Ang’A, S.P. Influence of iron on castability and properties of aluminium silicon alloys: Literature review. Int. J. Cast Met. Res. 2003, 16, 451–465. [Google Scholar] [CrossRef]
  15. Lin, B.; Li, H.; Xu, R.; Xiao, H.; Zhang, W.; Li, S. Effects of Vanadium on Modification of Iron-Rich Intermetallics and Mechanical Properties in A356 Cast Alloys with 1.5 wt.% Fe. J. Mater. Eng. Perform. 2018, 28, 475–484. [Google Scholar] [CrossRef]
  16. Bolibruchova, D.; Žihalová, M. Vanadium Influence on Iron Based Intermetallic Phases in AlSi6Cu4 Alloy. Arch. Met. Mater. 2014, 59, 1029–1032. [Google Scholar] [CrossRef]
  17. Okamoto, H. Al-Mo (Aluminum-Molybdenum). J. Phase Equilibria Diffus. 2010, 31, 492–493. [Google Scholar] [CrossRef]
  18. Wood, D.M. Coherent epitaxy, surface effects, and semiconductor alloy phase diagrams. J. Vac. Sci. Technol. B Microelectron. Nanometer Struct. 1992, 10, 1675. [Google Scholar] [CrossRef]
  19. Okamoto, H. Al-Cr (Aluminum-Chromium). J. Phase Equilibria Diffus. 2007, 29, 112–113. [Google Scholar] [CrossRef]
  20. Okamoto, H. Mo-Si (Molybdenum-Silicon). J. Phase Equilibria Diffus. 2011, 32, 176. [Google Scholar] [CrossRef] [Green Version]
  21. Smith, J.F. The Si-V (Silicon-Vanadium) system: Addendum. Bull. Alloy. Phase Diagr. 1985, 6, 266–271. [Google Scholar] [CrossRef]
  22. Guo, Z.; Yuan, W.; Sun, Y.; Cai, Z.; Qiao, Z. Thermodynamic Assessment of the Si-Ta and Si-W Systems. J. Phase Equilibria Diffus. 2009, 30, 564–570. [Google Scholar] [CrossRef]
  23. Venkatraman, M.; Neumann, J.P. The Cr−Mo (Chromium-Molybdenum) system. Bull. Alloy Phase Diagr. 1987, 8, 216–220. [Google Scholar] [CrossRef]
  24. Smith, J.F.; Bailey, D.M.; Carlson, O.N. The Cr-V (Chromium-Vanadium) System. Bull. Alloy Phase Diagr. 1982, 2, 469–473. [Google Scholar] [CrossRef]
  25. Nagender Naidu, S.V.; Sriramamurthy, A.M.; Rama Rao, P. The Cr-W (Chromium-Tungsten) System. Bull. Alloy Phase Diagr. 1984, 5, 289–292. [Google Scholar] [CrossRef]
  26. Zheng, F.; Argent, B.B.; Smith, J.F. Thermodynamic computation of the Mo-V binary phase diagram. J. Phase Equilibria Diffus. 1999, 20, 370–372. [Google Scholar] [CrossRef]
  27. Okamoto, H. V-W (Vanadium-Tungsten). J. Phase Equilibria Diffus. 2010, 31, 324. [Google Scholar] [CrossRef] [Green Version]
  28. Szymczak, T.; Szymszal, J.; Gumienny, G. Statistical Methods Used in the Assessment of the Influence of the Al-Si Alloy’s Chemical Composition on its Properties. Arch. Foundry Eng. 2018, 18, 203–211. [Google Scholar]
  29. Szymczak, T.; Szymszal, J.; Gumienny, G. Evaluation of the Effect of the Cr, Mo, V and W Content in an Al-Si Alloy Used for Pressure Casting on its Proof Stress. Arch. Foundry Eng. 2018, 18, 105–111. [Google Scholar]
  30. Szymczak, T.; Szymszal, J.; Gumienny, G. Evaluation of the Effect of Cr, Mo, V and W on the Selected Properties of Silumins. Arch. Foundry Eng. 2018, 18, 77–82. [Google Scholar]
  31. Nývlt, J. Kinetics of nucleation in solutions. J. Cryst. Growth 1968, 3-4, 377–383. [Google Scholar] [CrossRef]
  32. Nemdili, L.; Koutchoukali, O.; Mameri, F.; Gouaou, I.; Koutchoukali, M.; Ulrich, J. Crystallization study of potassium sulfate-water system, metastable zone width and induction time measurements using ultrasonic, turbidity and 3D-ORM techniques. J. Cryst. Growth 2018, 500, 44–51. [Google Scholar] [CrossRef]
  33. Chai, G.; Bäckerud, L.; Rolland, T.; Arnberg, L. Dendrite coherency during equiaxed solidification in binary aluminum alloys. Met. Mater. Trans. A 1995, 26, 965–970. [Google Scholar] [CrossRef]
  34. Gumienny, G.; Kacprzyk, B.; Gawroński, J. Effect of Copper on the Crystallization Process, Microstructure and Selected Properties of CGI. Arch. Foundry Eng. 2017, 17, 51–56. [Google Scholar] [CrossRef] [Green Version]
  35. Pezda, J. Effect of The T6 Heat Treatment On Change Of Mechanical Properties Of The AlSi12CuNiMg Alloy Modified With Strontium. Arch. Met. Mater. 2015, 60, 627–632. [Google Scholar] [CrossRef]
  36. Władysiak, R.; Kozuń, A.; Dębowska, K.; Tadeusz, P. Analysis of Crystallization Process of Intensive Cooled AlSi20CuNiCoMg Alloy. Arch. Foundry Eng. 2017, 17, 137–144. [Google Scholar] [CrossRef] [Green Version]
  37. Pisarek, B. Model of Cu-Al-Fe-Ni Bronze Crystallization. Arch. Foundry Eng. 2013, 13, 72–79. [Google Scholar] [CrossRef]
  38. Rapiejko, C.; Pisarek, B.; Tadeusz, P. Effect of Cr and V Alloy Additions on the Microstructure and Mechanical Properties of Am60 Magnesium Alloy. Arch. Met. Mater. 2014, 59, 761–765. [Google Scholar] [CrossRef]
  39. Kacprzyk, B.; Szymczak, T.; Gumienny, G.; Klimek, L. Effect of the Remelting on Transformations in Co-Cr-Mo Prosthetics Alloy. Arch. Foundry Eng. 2013, 13, 47–50. [Google Scholar] [CrossRef] [Green Version]
  40. Belov, N.A.; Eskin, D.G.; Aksenov, A.A. Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys; Elsevier: London, UK, 2005. [Google Scholar]
  41. Glazoff, M.V.; Khvan, A.V.; Zolotorevsky, V.S.; Belov, N.A.; Dinsdale, A.T. Casting Aluminum Alloys; Elsevier: Oxford, UK, 2019. [Google Scholar]
  42. Pietrowski, S. Al-Si Alloys; Lodz University of Technology Publishing House: Lodz, Poland, 2019. [Google Scholar]
  43. Hurtalová, L.; Tillová, E.; Chalupová, M.; Ďuriníková, E. Effect of Chemical Composition of Secondary Al-Si Cast Alloy on Intermetallic Phases. In Machines, Technologies, Materials, Proceedings of the 9th International Congress, Varna, Bulgaria, 19–21 September 2012; pp. 23–26. Available online: https://scholar.google.com.hk/scholar?hl=en&as_sdt=0%2C5&q=Effect+of+Chemical+Composition+of+Secondary+Al-Si+Cast+Alloy+on+Intermetallic+Phases&btnG= (accessed on 22 September 2020).
  44. Tillová, E.; Závodská, D.; Kuchariková, L.; Chalupová, M.; Belan, J. Study of Bending Fatigue Properties of Al-Si Cast Alloy. Arch. Met. Mater. 2017, 62, 1591–1596. [Google Scholar] [CrossRef] [Green Version]
  45. Kuchariková, L.; Tillová, E.; Matvija, M.; Belan, J.; Chalupová, M. Study of the precipitation hardening process in recycled Al-Si-Cu cast alloys. Arch. Met. Mater. 2017, 62, 397–403. [Google Scholar] [CrossRef] [Green Version]
Metals 10 01278 g001 550
Figure 1. Thermal and derivative analysis curves of the base alloy (black color) and containing 0.20 wt % Cr, Mo, V, and W (red color).
Figure 1. Thermal and derivative analysis curves of the base alloy (black color) and containing 0.20 wt % Cr, Mo, V, and W (red color).
Metals 10 01278 g001
Metals 10 01278 g002 550
Figure 2. Microstructure of the base Al-Si alloy in the casting from the shell sand probe: α, α + Al15(Fe,Mn)3Si2 + β, α + Al2Cu + AlSiCuFeMnMgNi + β.
Figure 2. Microstructure of the base Al-Si alloy in the casting from the shell sand probe: α, α + Al15(Fe,Mn)3Si2 + β, α + Al2Cu + AlSiCuFeMnMgNi + β.
Metals 10 01278 g002
Metals 10 01278 g003 550
Figure 3. Precipitation of Al15(Fe,Mn)3Si2 phase (a) with a histogram of the concentration of the constituent elements (b).
Figure 3. Precipitation of Al15(Fe,Mn)3Si2 phase (a) with a histogram of the concentration of the constituent elements (b).
Metals 10 01278 g003
Metals 10 01278 g004 550
Figure 4. X-ray diffraction pattern for phase identification in the base alloy from the shell mold, identified phases: α(Al), Al2Cu, β(Si).
Figure 4. X-ray diffraction pattern for phase identification in the base alloy from the shell mold, identified phases: α(Al), Al2Cu, β(Si).
Metals 10 01278 g004
Metals 10 01278 g005 550
Figure 5. An example of the quaternary eutectic region of EN AC-4600 alloy and a map of Al, Si, Cu, and Mg distribution.
Figure 5. An example of the quaternary eutectic region of EN AC-4600 alloy and a map of Al, Si, Cu, and Mg distribution.
Metals 10 01278 g005
Metals 10 01278 g006 550
Figure 6. Microstructure of the high-pressure die casting (HPDC) EN AC-46000 base alloy: α(Al), eutectic region.
Figure 6. Microstructure of the high-pressure die casting (HPDC) EN AC-46000 base alloy: α(Al), eutectic region.
Metals 10 01278 g006
Metals 10 01278 g007 550
Figure 7. Results of the point analysis of the chemical composition of the intermetallic phase in the microstructure of HPDC EN AC-46000 alloy. The arrow indicates the phase under analysis.
Figure 7. Results of the point analysis of the chemical composition of the intermetallic phase in the microstructure of HPDC EN AC-46000 alloy. The arrow indicates the phase under analysis.
Metals 10 01278 g007
Metals 10 01278 g008 550
Figure 8. Region of the ternary eutectic in the alloy with ~0.2 wt % V and W from the shell sand probe and the distribution analysis of elements.
Figure 8. Region of the ternary eutectic in the alloy with ~0.2 wt % V and W from the shell sand probe and the distribution analysis of elements.
Metals 10 01278 g008
Metals 10 01278 g009 550
Figure 9. Region of the quaternary eutectic in the alloy with ~0.2 wt % V and W from the shell sand probe and the distribution analysis of elements.
Figure 9. Region of the quaternary eutectic in the alloy with ~0.2 wt % V and W from the shell sand probe and the distribution analysis of elements.
Metals 10 01278 g009
Metals 10 01278 g010 550
Figure 10. Microstructure of Al-Si alloy with approximately 0.3 wt % Cr in the shell sand probe: Al15(Fe,Mn,Cr)3Si2, α(Al), α + β, α + Al2Cu + AlSiCuFeMgMnNiCr + β.
Figure 10. Microstructure of Al-Si alloy with approximately 0.3 wt % Cr in the shell sand probe: Al15(Fe,Mn,Cr)3Si2, α(Al), α + β, α + Al2Cu + AlSiCuFeMgMnNiCr + β.
Metals 10 01278 g010
Metals 10 01278 g011 550
Figure 11. Point analysis of the chemical composition of the primary intermetallic phase in the microstructure of the tested alloy from the shell sand probe.
Figure 11. Point analysis of the chemical composition of the primary intermetallic phase in the microstructure of the tested alloy from the shell sand probe.
Metals 10 01278 g011
Metals 10 01278 g012 550
Figure 12. An example of the quaternary eutectic region of Al-Si alloy containing 0.4 wt % and the map of Al, Si, Fe, Cr, Mn, and Cu distribution.
Figure 12. An example of the quaternary eutectic region of Al-Si alloy containing 0.4 wt % and the map of Al, Si, Fe, Cr, Mn, and Cu distribution.
Metals 10 01278 g012
Metals 10 01278 g013 550
Figure 13. Microstructure of the HPDC Al-Si alloy with the addition of V and W in an amount of approximately (a) 0.2 wt %, (b) 0.3 wt %. The microstructure: ‘new’ intermetallic phase, α(Al), eutectic mixture.
Figure 13. Microstructure of the HPDC Al-Si alloy with the addition of V and W in an amount of approximately (a) 0.2 wt %, (b) 0.3 wt %. The microstructure: ‘new’ intermetallic phase, α(Al), eutectic mixture.
Metals 10 01278 g013
Metals 10 01278 g014 550
Figure 14. An example of the region in the microstructure of Al-Si alloy containing 0.5 wt % Cr with a ‘new’ phase and the map of Si, Fe, Cr, Mn, and Cu distribution.
Figure 14. An example of the region in the microstructure of Al-Si alloy containing 0.5 wt % Cr with a ‘new’ phase and the map of Si, Fe, Cr, Mn, and Cu distribution.
Metals 10 01278 g014
Metals 10 01278 g015 550
Figure 15. Microstructure of the HPDC Al-Si alloy containing approximately 0.25 wt % Cr, Mo, V, and W each with a marked example of the tested phase.
Figure 15. Microstructure of the HPDC Al-Si alloy containing approximately 0.25 wt % Cr, Mo, V, and W each with a marked example of the tested phase.
Metals 10 01278 g015
Metals 10 01278 g016 550
Figure 16. Changes in the area fraction of the primary Al15(Fe,Mn,M)3Si2 phase in a Al-Si alloy containing vanadium (a) and simultaneously Cr, Mo, V, and W (b).
Figure 16. Changes in the area fraction of the primary Al15(Fe,Mn,M)3Si2 phase in a Al-Si alloy containing vanadium (a) and simultaneously Cr, Mo, V, and W (b).
Metals 10 01278 g016
Table
Table 1. Range of the chemical composition of the base EN AC-46000 alloy used for the tests.
Table 1. Range of the chemical composition of the base EN AC-46000 alloy used for the tests.
Chemical Composition, wt %
SiCuZnFeMgMnNiTiAl
8.69 ÷ 9.352.09 ÷ 2.430.90 ÷ 1.070.82 ÷ 0.970.21 ÷ 0.320.18 ÷ 0.250.05 ÷ 0.130.042 ÷ 0.049al.
Table
Table 2. Content of high melting point elements in the tested alloys.
Table 2. Content of high melting point elements in the tested alloys.
Combinations of High Melting Point ElementsContent Range, wt %Step, wt %
Single elementsCr0.0 ÷ 0.50.1
Mo
V
W
Double combinationsCr, Mo0.0 ÷ 0.4 each
Cr, V
Cr, W
Mo, V
Mo, W
V, W
Triple combinationsCr, Mo, V0.00 ÷ 0.25 each0.05
Mo, V, W
Cr, V, W
Cr, Mo, W
SimultaneouslyCr, Mo, V, W
Table
Table 3. Minimum content of high melting point elements, at which the primary intermetallic Al15(Fe,Mn,M)3Si2 phases were observed.
Table 3. Minimum content of high melting point elements, at which the primary intermetallic Al15(Fe,Mn,M)3Si2 phases were observed.
Combinations of High Melting Point ElementsContent of High Melting Point Elements, at which the Primary Crystallization of the Al15(Fe,Mn,M)3Si2 Phase Was Observed; wt %
Single elementsCr0.2
Mo0.5
V- *
W0.5
Double combinationsCr, Mo0.1 each
Cr, V0.1 each
Cr, W0.1 each
Mo, V0.4 each
Mo, W0.3 each
V, W- *
Triple combinationsCr, Mo, V0.25 each
Cr, Mo, W0.25 each
Cr, V, W0.20 each
Mo, V, W0.25 each
SimultaneouslyCr, Mo, V, W0.10 each
Note: * probably the primary crystallization of the Al15(Fe,Mn,M)3Si2 phase occurs out of range of the tested content of high melting point elements.
Table
Table 4. Minimum content of high melting point elements, at which the primary ‘new’ intermetallic phases were observed.
Table 4. Minimum content of high melting point elements, at which the primary ‘new’ intermetallic phases were observed.
Combinations of High Melting Point ElementsThe Content of High Melting Point Elements, at which the Primary Al15(Fe,Mn,M)3Si2 Phase Was Observed; wt %
Single elementsCr0.2
Mo0.2
V0.2
W0.2
Double combinationsCr, Mo0.2 each
Cr, V0.2 each
Cr, W0.2 each
Mo, V0.2 each
Mo, W0.2 each
V, W0.2 each
Triple combinationsCr, Mo, V0.2 each
Cr, Mo, W0.2 each
Cr, V, W0.2 each
Mo, V, W0.2 each
SimultaneouslyCr, Mo, V, W0.05 each
Table
Table 5. The chemical composition of ten randomly selected phases.
Table 5. The chemical composition of ten randomly selected phases.
Phase No.Concentration, wt %
AlSiFeMnCrMoVW
156.049.5015.564.256.405.102.640.52
256.289.2819.734.826.563.302.740.29
356.478.8616.275.385.293.803.080.86
458.8112.3315.034.694.202.572.120.25
556.869.1015.784.176.443.722.960.99
656.789.0515.594.156.034.172.301.93
769.736.409.573.333.412.581.273.71
857.008.9116.315.665.233.762.830.40
959.759.1015.624.915.312.782.120.40
1056.469.0017.124.086.103.702.550.99
Average58.429.1515.664.545.503.552.461.03

Share and Cite

MDPI and ACS Style

Szymczak, T.; Gumienny, G.; Klimek, L.; Goły, M.; Pacyniak, T. Microstructural Characteristics of AlSi9Cu3(Fe) Alloy with High Melting Point Elements. Metals 2020, 10, 1278. https://doi.org/10.3390/met10101278

AMA Style

Szymczak T, Gumienny G, Klimek L, Goły M, Pacyniak T. Microstructural Characteristics of AlSi9Cu3(Fe) Alloy with High Melting Point Elements. Metals. 2020; 10(10):1278. https://doi.org/10.3390/met10101278

Chicago/Turabian Style

Szymczak, Tomasz, Grzegorz Gumienny, Leszek Klimek, Marcin Goły, and Tadeusz Pacyniak. 2020. "Microstructural Characteristics of AlSi9Cu3(Fe) Alloy with High Melting Point Elements" Metals 10, no. 10: 1278. https://doi.org/10.3390/met10101278

APA Style

Szymczak, T., Gumienny, G., Klimek, L., Goły, M., & Pacyniak, T. (2020). Microstructural Characteristics of AlSi9Cu3(Fe) Alloy with High Melting Point Elements. Metals, 10(10), 1278. https://doi.org/10.3390/met10101278

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop