Verification of Possibility of Molten Steels Decopperization with ZnAl2O4
Abstract
:1. Introduction
2. Materials and Methods
2.1. ZnAl2O4 Substrates’ Preparation
2.2. Fe-Cu Alloys’ Preparation and Experimental Setup
3. Results and Discussion
3.1. Experimental Observation
3.2. Interfacial and Cross Sectional Analysis
3.3. The Composition of Fe-Cu Alloys
3.4. Copper Evaporation Mechanism
3.5. Effect of Oxygen on Copper Evaporation
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Armco Iron | Fe (wt%) | C | Mn | Si | Al | O |
99.8 | 40 | 30 | 262 | 11 | 92 |
Fe-Cu (wt%) | ZnAl2O4 | Al2O3 |
---|---|---|
0.5% Cu, 40 ppm C | 90 min | 90 min |
0.5% Cu, 0.5% C | 90 min | 90 min |
1% Cu, 40 ppm C | 90 min | 90 min |
1% Cu, 0.5% C | 90 min | 90 min |
10% Cu, 40 ppm C | 90 min | - |
wt% | C | Si | Mn | Al | O | Cu Wt% | Cu Loss (%) |
---|---|---|---|---|---|---|---|
0.5% Cu Al2O3 | 40 | 58 | 16 | 36 | 72 | 0.382 | 23.4 |
0.5% Cu ZnAl2O4 | 15 | 138 | 13 | 41 | 423 | 0.411 | 17.6 |
1% Cu Al2O3 | 40 | 91 | 15 | 55 | 80 | 0.718 | 28.2 |
1% Cu ZnAl2O4 | 13 | 77 | 13 | 28 | 559 | 0.908 | 9.2 |
0.5% C 0.5% Cu Al2O3 | 0.516 wt% | 50 | 27 | 38 | 51 | 0.35 | 25.0 |
0.5% C 0.5% Cu ZnAl2O4 | 14 | 50 | 13 | 38 | 252 | 0.321 | 31.3 |
0.5% C 1% Cu Al2O3 | 0.457 wt% | 50 | 15 | 45 | 62 | 0.757 | 24.3 |
0.5% C 1% Cu ZnAl2O4 | 18 | 66 | 13 | 46 | 301 | 0.722 | 27.8 |
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Wei, X.; Dudczig, S.; Chebykin, D.; Aneziris, C.G.; Volkova, O. Verification of Possibility of Molten Steels Decopperization with ZnAl2O4. Metals 2021, 11, 2030. https://doi.org/10.3390/met11122030
Wei X, Dudczig S, Chebykin D, Aneziris CG, Volkova O. Verification of Possibility of Molten Steels Decopperization with ZnAl2O4. Metals. 2021; 11(12):2030. https://doi.org/10.3390/met11122030
Chicago/Turabian StyleWei, Xingwen, Steffen Dudczig, Dmitry Chebykin, Christos G. Aneziris, and Olena Volkova. 2021. "Verification of Possibility of Molten Steels Decopperization with ZnAl2O4" Metals 11, no. 12: 2030. https://doi.org/10.3390/met11122030