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Article

Evolution of Microstructure and Mechanical Properties of Steam Generator Material After Long-Term Operation in Nuclear Power Plant

1
Faculty of Materials Science and Technology in Trnava, Slovak University of Technology in Bratislava, 811 07 Bratislava, Slovakia
2
VUJE a.s., 918 64 Trnava, Slovakia
*
Author to whom correspondence should be addressed.
Metals 2025, 15(6), 667; https://doi.org/10.3390/met15060667
Submission received: 7 May 2025 / Revised: 7 June 2025 / Accepted: 11 June 2025 / Published: 16 June 2025

Abstract

:
The microstructural evolution and mechanical properties of WWER 440 steam generator steel GOST 22K after long-term operation were thoroughly examined in this study. The samples were taken directly from a steam generator using the small punch test method. The uniqueness of these samples lies in the fact that they were real operating materials used in a nuclear power plant with different years of operation. The microstructure was characterized using optical microscopy and transmission electron microscopy supplemented by selective electron diffraction and semi-quantitative chemical microanalysis. It was found that with the prolongation of the operation time of the steam generator, the density of carbides increased slightly, which was reflected in a decrease in the mean distance between particles, but these differences were very small, which indicates the microstructural stability of GOST 22K steel. The stability of this steel was also confirmed by measuring its mechanical properties, which changed only minimally depending on the years of operation. The tensile strength values were in the range of 508 to 579 MPa. In the case of the ductile-to-brittle transition temperature (DBTT), a slight increase was found after 6 years of operation. The DBTT did not change significantly with subsequent operation.

Graphical Abstract

1. Introduction

The safety of the operation of nuclear power plants (NPPs) is a key requirement of the present as well as the future. Operational experience brings new demands for increasing the safety of nuclear power plants. The current trend in the world is extending the operation of nuclear power plants after their design life has been exhausted [1].
Long-term operation (LTO) enables nuclear power plants (NPPs) to generate reliable and low-cost electricity over extended periods beyond their originally planned lifetime. This also contributes to low-emission energy production. In this way, LTO helps maximize the value of NPPs as a green energy source that protects the environment by minimizing CO2 emissions. Today’s operating nuclear reactors were originally designed for 30 to 40 years of operation, but there is no fixed technical limit to reactor lifetimes. LTO of NPPs has been successfully demonstrated and is increasingly recognized internationally as standard practice. LTO of an NPP may be conditioned by life-limiting processes and features of structures, systems, and components—the emphasis is on the primary circuit components and their construction steels [2]. In EU countries, 19 water–water energetic reactor 440 (WWER 440) units are in operation. In additional 15 WWER units are operated in Ukraine. The high required level of safety, effectivity, reliability, and capability of LTO beyond the projected lifetime of nuclear reactors up to 60–80 years is a real and very actual challenge for the European nuclear community [3].
The main degradation mechanism of NPP components is radiation damage, and many studies are devoted to this issue, and a lot of attention is also given to irradiation embrittlement monitoring via Surveillance Specimen Programs (SSPs). However, these processes are situated only in the core region of the reactor pressure vessel (RPV). The main mechanical loads affecting all the individual parts are due to the high pressure of an NPP’s primary circuit at elevated temperatures up to 300 °C [4,5,6,7]. Thermal aging involves a change in the mechanical properties of a material caused by prolonged exposure to temperature. Due to thermal aging, thermal embrittlement occurs, which is a change in the structural state, leading to the appearance of metal brittleness. For NPP equipment, thermal aging has a particular effect during long-term operation; therefore, taking this effect into account is extremely important when extending the service life of NPP equipment. From the experience of long-term operation of an NPP, this degradation mechanism (thermal aging) can affect a number pieces of equipment, and the aging effect (change in mechanical properties) is subject to control [8,9]. Systematic assessment of the resistance of primary circuit materials against the influence of thermal aging at the real operating temperatures of a NPP can be considered a very important experimental topic, and there are relatively few published results. Nevertheless, this degradation mechanism of materials is also an increasingly discussed issue because more than 63% of power reactors have been in operation for more than 30 years. In general, the original design life of NPPs is between 28–32 years. Thirty years is considered a significant milestone in the life of an NPP [10].
The impact of thermal aging is highly dependent on the material composition, operating conditions, and cumulative thermal exposure time. Alloying elements, impurities, and the initial microstructure play a significant role in determining the susceptibility to and progression of thermal aging. Accurate assessment of this degradation mechanism requires advanced analytical techniques, such as transmission electron microscopy, atom probe tomography, and mechanical testing, to monitor the microstructural evolution and its correlation with macroscopic material properties [11,12].
The concept of a temperature aging monitoring program is based on a fundamental requirement—the ability to monitor material degradation directly during plant operation. This specifically refers to degradation mechanisms affecting the materials of the primary circuit. Monitoring is performed under real operating conditions and on actual components in service within an NPP.
The overall concept of evaluating the impact of temperature aging on the evaluated materials can be divided into two separate units:
  • long-term exposure of blocks of materials that are exposed to the same temperature load as real monitored NPPs, using a sample carrier,
  • collection of material samples from operating facilities and their subsequent detailed material analysis [13,14].
One of the important components of an NPP is the steam generator (SG). SGs in WWERs are large heat exchangers. They transfer heat from the primary reactor coolant to produce steam on the secondary side, which then drives the turbine generators. The primary coolant operates at a higher pressure than the secondary coolant. As a result, any leakage caused by defects in the tubes or WWER collectors leads to flow from the primary side to the secondary side. In the event of a tube rupture or collector failure, radioactive material can be released into the environment outside the reactor containment. This release may occur through the pressure relief valves of the secondary system [15,16,17].
The present article presents the results of the temperature aging of long-term-operated steam generator material, which was taken from the operating equipment at the Bohunice nuclear power plant in Slovakia.

2. Materials and Methods

The steam generator base material used in WWER 440 type NPP (Železárny Vítkovice, Vitkovice, Czech Republic) is GOST 22K carbon steel with a ferritic—pearlitic structure [18]. It is a common type of high-quality structural carbon steel for pressure vessels with prescribed chemical (Table 1) and mechanical properties (Table 2).
The required strength properties are prescribed in technical specifications for SG materials given by one of the SG manufacturers Železárny Vítkovice with the respect to the GOST 5520-79 standard [18]; the contractual yield strength is RP0.2, the tensile strength is Rm, the ductility is A, the contraction is Z, and the impact strength is KCU.
Table 3 summarizes the samples that were analyzed as part of the study to examine the impact of long-term operation on the character of the microstructure and selected mechanical properties.

2.1. Sampling from Operating Facilities

Samples were taken as part of the temperature aging monitoring program, where a device is used, which is designed as a universal system for taking samples without significantly affecting the surface and without the need to subsequently repair or adjust the sampling site. It is a quasi-non-destructive sampling of material using a SSamTM-2 device from Rolls-Royce (Rolls-Royce Power Engineering, Derby, UK). The machine’s unique hemispherical cutter can remove a sample without mechanical distortion or thermal degradation of the material. The sampling procedure produces a depression in the base material approximately 0.8 mm deeper than the sample thickness. A schematic depiction of the surface sample removal process is shown in Figure 1. Due to a lack of material from surface sampling, a critical aspect of material evaluation involves cutting and preparing specimens [19]. Figure 2 illustrates the cut sample from the outer surface.
Next step of preparing samples (Figure 3) for material analysis was the precise cutting of samples to obtain semi-finished specimens was carried out using by the computer controlled electrical discharge machine (EDM) with a very thin molybdenum wire ø 0.1 mm [20].

2.2. Small Punch Test Methods

In general, the small punch test (SPT) method is based on a punch with a hemispherical tip or ball that is pushed through a clamped disc specimen along its axis (Figure 4). The SPT method is displacement-controlled, i.e., the punch is pushed at a constant velocity of the cross head through the specimen, and the force required to keep the punch moving is measured as a function of the punch displacement (at the punch tip) or specimen deflection (measured on the lower side of the specimen, opposite to the contact point between the punch and the specimen) [21].
The testing can be performed on a standard tensile testing machine equipped with a load and deflection recording device for the registration of load–deflection curves [22]. Depending on the testing temperatures, special testing rigs are utilized for the realization of the SPT test. The samples are machined from material blocks by electrical discharge machining (EDM) and subsequently polished with abrasive paper up to P1200 grit to obtain the required thickness. The polynomial function, because of compliance correction measurements, is introduced into the system [23]. The second-degree polynomial function is as follows:
E C = A F 2 + B F + C
It is used for compliance correction, where A, B, and C are coefficients obtained through measurements of compliance on a reference metal sample and F represents the force [N] used for the calculation of Ec. The final SPT results are then adjusted by the value of the compliance Ec. The use of the second-degree polynomial function has proven to be fully sufficient, providing the most accurate results. The testing conditions (Table 4) were chosen according to the procedure accepted by the Nuclear Regulatory Authority of the Slovak Republic [24] and the EN 10371 standard [22].
For estimating the ultimate tensile strength (Rm) and yield strength (Re), the correlation coefficients (βRm, βRe) between Rm/Re were used according to the following equations:
R m = β R m   F m h 0   u m
R e = β R e   F e h 0 2 ,
where Fm (N) is the maximum load reached during the test, Fe (N) is the elastic–plastic transition load, um (mm) corresponds to the deflection, and h0 (mm) is the specimen thickness. βRm and βRe represent correlation coefficients that need to be determined experimentally. The value of βRm = 0.278 is commonly used based on the results of SPT testing according to Annex C2 of the EN 10371 standard [25], and the recommended value for βRe, for steels with Re between 200 and 1000 MPa is 0.510. However, in order to increase the accuracy of the SPT results, a specific correlation relationship for each tested material and testing machine can be used. A specific correlation coefficient may be used when testing materials with unique properties (for example, steels with Re outside the range of 200–1000 MPa or steels with a very fine grain size or specific heat treatments). Additionally, when the standard correlation coefficient does not provide sufficiently accurate results for a particular application or test setup when and it is expected that the same material will be tested periodically, it is advisable to use a correlation coefficient obtained by the laboratory. On the other hand, when testing materials that are commonly used (such as regular austenitic or ferritic steels), the correlation coefficients (βRm, βRe) stated in the standard have been proven to provide accurate results [26].
A typical recording curve from the SPT test of a tough material at room temperature is shown in Figure 5, where Py is the force at the beginning of plastic deformation, and Pmax is the maximum force.

2.3. Chemical Analysis

Long-term operation can also cause changes in the chemical composition of the steam generator material. From the point of view of safe operation of the NPP, it is also necessary to know the chemical stability of the material. Therefore, the experiments also focused on measuring the chemical composition. The chemical composition of 22K steel was analyzed as a result of long-term operation. The chemical composition was measured with a Q4 TASMAN optical emission spectrometer (OES), Bruker, Karlsruhe, Germany. An OES involves applying electrical energy in the form of a spark generated between an electrode and a metal sample, whereby the vaporized atoms are brought to a high-energy state within a so-called “discharge plasma”. These excited atoms and ions in the discharge plasma create a unique emission spectrum specific to each element [27].

2.4. Microstructure Analysis

The observation of the microstructure and the identification of secondary phases were carried out through a combination of light optical microscopy (LOM) and transmission electron microscopy (TEM). A Zeiss Neophot 32 light optical microscope, CarlZeiss, Jena, Germany was used for LOM. A Philips 300CM transmission electron microscope, Philips Electron Optics, Eindhoven, The Netherlands was used for the TEM analysis. The resolution of the TEM was 1 nm. The phase identification was carried out using selected area electron diffraction. Energy-dispersive X-ray spectroscopy (EDS) with a resolution of ±1 wt.% was used for semi-quantitative chemical analysis of the precipitates.
The samples for LOM observation were prepared by the classic method of metallographic preparation: mechanical grinding on SiC papers with graded grits of 280, 600 and 1200 was carried out. This was followed by mechanical polishing using diamond suspensions of 9 and 3 µm. The metallographic preparation was completed by chemical etching in a 3% solution of nitric acid in ethanol to develop the microstructure.
Thin foils for TEM observation were prepared by final electrolytic polishing using a TenuPol 5 twin-jet, Struers A/S, Ballerup, Denmark in a solution of 30 vol.% HNO3 and 70 vol.% CH3OH at −20 °C using a voltage of 15 V. Meanwhile, semi-finished products for thin films in the form of targets with a diameter of 3 mm and a thickness of 90 µm were prepared using a computer-controlled electrical discharge machine.
For the statistical evaluation of the precipitates, stereographic projection methods were applied [28]. The following parameters were evaluated within the framework of statistics:
D = L N N
N A = N A ,
N V = N A t ,
L = 1 N V · D 2 3   D ,
where D (m) is the average particle size, LN (m) is the total length of the particles, N is the number of particles, NA is the number of particles per unit area (m−2), A is the unit area (m2), NV is the number of particles per unit volume (m−3), t is the thickness of the foils (m), and L is the mean distance between particles.

3. Results

3.1. Microstructure Evaluation

The microstructure of the samples observed by LOM is shown in Figure 6. The microstructure of sample A is shown in Figure 6a. Observation by LOM showed a slightly heterogeneous microstructure. The matrix was composed of ferrite with a polyhedral (Figure 6a, area enclosed by the circle) and acicular morphology (Figure 6a, area marked by the square). The size of the ferritic grains was in the range from 5 to 30 µm. Small pearlite islands were also observed in the ferritic matrix. Comparing the microstructures of samples A and B (Figure 6b), no significant differences were found. The observed microstructures were very similar. The observed character of the microstructure corresponded to 22K steel. The microstructures of samples C and D were very similar (Figure 6c,d). Light microscopy did not reveal significant differences in the microstructures between the individual samples.
Based on the knowledge of other authors who dealt with similar issues, changes in the microstructure at the nanometric level were expected [27,28,29,30,31,32]. Therefore, the experiments were expanded to include TEM analysis, which allows monitoring changes related to the thermal aging process, especially in terms of precipitation [33,34,35,36].
The TEM observation confirmed the expected changes in the microstructure caused by operation, especially in the size and density of the precipitates. The TEM observation confirmed the presence of particles with a quasi-globular morphology in all the analyzed states (Figure 7). The individual samples differed mainly in the size of their precipitates (Table 5) and their distribution. Precipitates in the initial state (Figure 7a) were observed mainly at the boundaries of the ferritic grains. No precipitates were observed in the ferritic grains. A very similar microstructure was also observed in the case of sample B. Figure 7b documents the detail of the ferritic grain boundaries. Small particles were observed at the boundaries. A more significant change in the microstructure was observed in the case of sample C (Figure 7c). An increased density of precipitates was observed not only at the grain boundaries but also inside the ferritic grains. The presence of very fine particles was also confirmed by the TEM observation of sample D (Figure 7d). These particles were precipitated mainly inside the ferritic grains.
Details of the particles precipitated in the ferritic grains are shown in Figure 8a. A relatively uniform distribution of the particles in the ferritic grains can be observed. A dark-field image (Figure 8b) was used to better document the distribution and morphology of the particles. These particles were identified as a M3C carbide solution of the electron diffraction pattern (Figure 8c). The orientation of the chemical composition of these particles was measured using EDS. A characteristic spectrum of these types of particles is shown in Figure 8d. The EDS measurements of the M3C carbide particles did not confirm any significant changes between the individual samples. The chemical composition of the particles was usually 96 ± 1 wt.% Fe and 4 ± 1 wt.% Mn.
The TEM observation confirmed that the size and distribution of the precipitates changed with the operating time. To qualitatively confirm these changes, a statistical evaluation of the particles was performed. The change in the precipitate size with respect to the operating time was measured. Figure 9 summarizes the statistical evaluation, based on which it can be concluded that the proportion of fine particles, particularly in the size range of 100 to 200 nm, increased as the time of operation increased. This change in proportion was mainly caused by the precipitation of very fine particles in the ferritic grains, which was observed especially after 16 years of operation.
Table 5 summarizes the results of the statistically evaluated average particle size (D), number of particles per unit volume (NV), and mean distance between particles (L). Based on the results, it can be concluded that long-term operation did not cause significant changes in the density of the secondary precipitated particles. This is also proven by the graphical dependence of the change in the mean distance between the particles depending on the operation time (Figure 10). A slight increase in the density of the precipitates was observed after 16 years of operation, which was also associated with a slight decrease in the mean distance between the particles. However, the state after 28 years of operation no longer showed significant changes. The differences found were at the level of deviation.

3.2. Analysis of the Chemical Composition

The experiments also monitored any changes in the chemical composition of the GOST 22K steam generator material caused by long-term operation. Table 6 summarizes the results of the measurements of the chemical composition of the analyzed samples. Since the values of the chemical composition of the initial state were not available, the chemical composition of the 22K steel is given in the case of sample A. By comparing the measured values of samples B, C, and D, it can be stated that long-term operation did not cause any changes in the chemical composition. The differences in the content of individual elements were only at the level of measurement uncertainty.

3.3. SPT Test and Evaluation of the Changes in Mechanical Properties Based on the Operation Period

SPT tests were performed on small disc-shaped samples with a diameter of 8 mm and a thickness of 0.5 mm. The LaborTech LabTest 5.10ST testing machine, LaborTech, s.r.o, Opava, Czech Republic was used for the testing of the load force sensor, transversal movement sensor, strain gauge, and recording device for recording the parameters, i.e., the loading force and the displacement during loading. To determine the tensile properties, the tests were performed at room temperature for the determination of fracture properties, i.e., the tests of the energy required to perforate the sample were conducted at room temperature as well as at reduced and elevated temperatures. The SPT load–deflection curve (of sample D) is shown in Figure 11. From the results of the SPT test, it was possible to determine the ultimate strength and yield strength. The results of the evaluation of the tensile properties of the sample are summarized in Table 7. The observed increase in strength properties can be explained by the effect of irradiation-induced hardening. Over time, irradiation-induced hardening may degrade materials, increasing the risk of failure in critical components; thus, regular monitoring and evaluation of mechanical properties plays a crucial role in nuclear safety.
In order to determine the value of the transition temperature, 15 SPT tests were performed at different temperatures, ranging from room temperature to −172 °C. From the energy of the individual tests (area under the curve at maximum load), a transition curve with the corresponding transition temperatures was constructed. Transition curves obtained using the SPT tests are shown in Figure 12. The curves are formed by two functions; the first describes the brittle and transition mode (a low-energy plateau that is extrapolated to a temperature of 50K), and the second describes the ductile tough mode. These functions are described by exponential and power polynomials. The intersection of these two curves (the upper energy plateau) indicates the energy maximum [37,38]. The transition temperature obtained using the SPT method was calculated according to the following relationship:
D B T T S P T = S P m a x + S P m i n 2
where the ductile-to-brittle transition temperature (DBTT) is obtained according to Equation (8), with the average value of the upper energy plateau and lower energy plateau corresponding to the energy at a temperature of 50 °C. Table 8 shows the transition temperatures for the individual analyzed states. In Figure 12, the DBTT values are marked by red and green arrows, representing the temperatures (in Kelvins) calculated from Equation (8). Table 8 shows the transition temperatures (in Celsius) for the individual analyzed states after the correlation coefficient was applied.

4. Conclusions

To study the effect of long-term operation, samples of 22K steel were analyzed with different times of operation. The conclusions drawn from this study are as follows:
  • The steam generator steel did not show significant embrittlement characteristics after long-term operation. The measured values of the mechanical properties did not show significant changes. The presented data demonstrate a relatively stable state of mechanical properties, with negligible impact from radiation-induced embrittlement observed over 28 years of operational exposure. Under both conditions, i.e., room temperature and +270 °C, the mechanical strength properties exhibited an initial decline, followed by stabilization, with values oscillating around a consistent baseline. Only the tensile strength at room temperature showed considerable variation with years of operation.
  • It was shown that after an initial increase in the DBTT observed during the first 6 years of operation, no further significant increase was detected over the subsequent 28 years. As expected, long-term operation increased the ductile-to-brittle transition temperature (DBTT) due to radiation-induced microstructural changes and thermal aging of precipitates, which restrained dislocation motion and reduced ductility.
  • The microstructural analysis confirmed the phase stability of the 22K steel. No significant changes in microstructure were found between individual samples. The statistical analysis of secondary precipitated particles showed a slight increase in particle density between the initial state and the state after 16 years of operation. However, the monitored statistical parameters, especially the mean distance between particles, changed only minimally between the steels that had operated for 16 and 28 years. The differences found were only at the level of measurement uncertainty.
The COST 22K steam generator steel exhibited no significant embrittlement after 28 years of operation. The mechanical properties, including the tensile strength and ductility, remained stable, with only a minor decline followed by stabilization under both room temperature and 270 °C conditions. A notable variation was observed only in the tensile strength at room temperature. The DBTT showed an initial increase within the first 6 years, with no substantial shift thereafter, indicating a saturation of embrittlement effects. The microstructural analysis confirmed the phase stability of the 22K steel, with only slight increases in precipitate density over time; changes in key statistical parameters, such as the mean particle spacing, were within the margin of measurement uncertainty.
Despite the results obtained using SPT samples, there is still a need for the continuous monitoring of the condition of structural materials in operating NPPs. This can be achieved through, as presented, exposure in a real working environment, as well as through research projects that support the long-term operation of nuclear units. Such an international research project is the DELISA-LTO project (no.101061201: HORIZON-EURATOM-NRT). The project is primarily focused on assessing the impact of thermal aging on structural materials obtained from the decommissioned Jaslovské Bohunice NPP EBO V1. Extensive experimental work in the project includes an assessment of structural changes and an assessment of corrosion stability using standard samples. The results of the DELISA-LTO project will seamlessly follow-up on our work.

Author Contributions

Conceptualization: D.S., M.A. and M.D. Methodology: D.S., M.D., M.A. and J.P. Validation: M.D., J.P., K.B., M.K. and M.G. Formal analysis: K.B., M.K., M.G. and M.A. Writing—original draft: D.S., M.D., K.B., M.K. and M.G. Writing—review and editing: D.S., M.D., K.B., M.K. and M.G. Funding acquisition: M.D. and J.P. Supervision: M.D. and J.P. Project administration: D.S. and M.A. All authors have read and agreed to the published version of the manuscript.

Funding

The authors would like to thank the European Union project DELISA-LTO (no. 101061201): DEscription of the extended LIfetime and its influence on the SAfety operation and construction materials performance—Long Term Operation with no compromises in the safety for financial support.

Data Availability Statement

The data presented in this study are available on request from the corresponding author. The data are not publicly available due to privacy.

Conflicts of Interest

Authors David Slnek, Marek Adamech and Jana Petzová were employed by the company VUJE a.s. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

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Figure 1. Schematic depiction of the surface sample removal from the steam generator [19].
Figure 1. Schematic depiction of the surface sample removal from the steam generator [19].
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Figure 2. The sample taken from outer surface using the SSamTM-2 device.
Figure 2. The sample taken from outer surface using the SSamTM-2 device.
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Figure 3. Removed sample after EDM cutting.
Figure 3. Removed sample after EDM cutting.
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Figure 4. Graphical representation of the small punch test [22].
Figure 4. Graphical representation of the small punch test [22].
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Figure 5. Recording curve from the SPT test of a tough material [24].
Figure 5. Recording curve from the SPT test of a tough material [24].
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Figure 6. Microstructure of experimental 22K steel observed by LOM: (a) sample—initial state, (b) sample—6 years of operation, (c) sample —16 years of operation, (d) sample—30 years of operation.
Figure 6. Microstructure of experimental 22K steel observed by LOM: (a) sample—initial state, (b) sample—6 years of operation, (c) sample —16 years of operation, (d) sample—30 years of operation.
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Figure 7. Bright field image of the microstructure of the experimental steel 22K observed by TEM: (a) sample—initial state, (b) sample—6 years of operation, (c) sample—16 years of operation, (d) sample—28 years of operation.
Figure 7. Bright field image of the microstructure of the experimental steel 22K observed by TEM: (a) sample—initial state, (b) sample—6 years of operation, (c) sample—16 years of operation, (d) sample—28 years of operation.
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Figure 8. Detail of secondary precipitated particles in the ferritic matrix in sample C observed by TEM: (a) bright-field image, (b) dark-field image, where reflection (011)M3C (Figure 8c) was used for the dark-field image, (c) electron diffraction pattern of small particles, which were identified as M3C carbide, (d) EDS spectrum of the small particles.
Figure 8. Detail of secondary precipitated particles in the ferritic matrix in sample C observed by TEM: (a) bright-field image, (b) dark-field image, where reflection (011)M3C (Figure 8c) was used for the dark-field image, (c) electron diffraction pattern of small particles, which were identified as M3C carbide, (d) EDS spectrum of the small particles.
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Figure 9. Histogram of particle size with respect to long-term operation.
Figure 9. Histogram of particle size with respect to long-term operation.
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Figure 10. Graphical dependence of the change in the mean distance between particles on the operating time.
Figure 10. Graphical dependence of the change in the mean distance between particles on the operating time.
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Figure 11. The SPT load-deflection curve of sample D.
Figure 11. The SPT load-deflection curve of sample D.
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Figure 12. The transition curve obtained using an SPT tests.
Figure 12. The transition curve obtained using an SPT tests.
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Table 1. Chemical composition of 22K steel [18].
Table 1. Chemical composition of 22K steel [18].
SteelChemical Composition (wt.%)
CSiMnNiSPCrCu
GOST
5520-79
0.19–0.260.20–0.450.75–1.050.30–0.50max. 0.025max. 0.04max. 0.30max 0.30
Table 2. Mechanical properties of 22K steel [18].
Table 2. Mechanical properties of 22K steel [18].
T
(°C)
RP0.2
(MPa)
Rm
(MPa)
A
(%)
Z
(%)
KCU
(J/cm2)
20255–265430–5902250min. 39
270min. 196min. 353min. 18min. 45-
Table 3. Designation of the samples and state of the material.
Table 3. Designation of the samples and state of the material.
SampleState of the Sample
AInitial state
B6 years of operation
C16 years of operation
D28 years of operation
Table 4. SPT testing parameters.
Table 4. SPT testing parameters.
SampleTest piece diameter (mm)8 ± 0.1
Test piece thickness (mm)0.5 ± 0.005
min. test pieces/material3 pcs
GeometryPunch tip diameter (mm)2.5
Receiving hole edge (mm)R 0.2
Testing conditionsTemperature (°C)23 ± 2
Moment (torque) (Nm)10
Measured parametersForce–deflection
Load rate (mm·m−1)0.5
Table 5. Statistically evaluated structural parameters.
Table 5. Statistically evaluated structural parameters.
SampleD
(10−9 m)
NV
(1019 m−3)
L
(10−7 m)
A232 ± 341.349 ± 0.2773.863 ± 0.450
B261 ± 391.178 ± 0.3873.563 ± 0.951
C215 ± 282.327 ± 0.5032.716 ± 0.417
D227 ± 301.889 ± 0.3513.096 ± 0.397
Table 6. Chemical composition of experimental steels measured by OES.
Table 6. Chemical composition of experimental steels measured by OES.
SampleChemical Composition (wt.%)
CSiMnNiSPCrCu
A0.19–0.260.20–0.450.75–1.050.30–0.50max 0.025max 0.04max 0.30max 0.30
B0.22 ± 0.010.28 ± 0.010.91 ± 0.010.43 ± 0.010.0075 ± 0.0008<0.0070.24 ± 0.010.053 ± 0.005
C0.24 ± 0.010.29 ± 0.020.92 ± 0.010.42 ± 0.010.0079 ± 0.00080.007 ± 0.0010.27 ± 0.010.051 ± 0.003
D0.24 ± 0.010.31 ± 0.020.92 ± 0.010.42 ± 0.010.0082 ± 0.00080.009 ± 0.0010.27 ± 0.010.053 ± 0.003
Table 7. Tensile strength and yield strength values of individual samples determined on the basis of the SPT test.
Table 7. Tensile strength and yield strength values of individual samples determined on the basis of the SPT test.
SampleTemperature (°C)Mechanical Properties Measured by SPT Test
Rm (MPa)Rp0.2 (MPa)
A20525 ± 5342 ± 2
270503 ± 5277 ± 2
B20579 ± 2379 ± 4
270448 ± 1259 ± 5
C20508 ± 2370 ± 2
270449 ± 1268 ± 5
D20558 ± 2370 ± 2
270452 ± 1272 ± 5
Table 8. The results of determining the transition temperature for individual analyzed states.
Table 8. The results of determining the transition temperature for individual analyzed states.
SampleDDTT (°C)
A- 29.2
B- 6.2
C- 2.4
D- 3.9
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Slnek, D.; Dománková, M.; Adamech, M.; Petzová, J.; Bártová, K.; Kudláč, M.; Gavalec, M. Evolution of Microstructure and Mechanical Properties of Steam Generator Material After Long-Term Operation in Nuclear Power Plant. Metals 2025, 15, 667. https://doi.org/10.3390/met15060667

AMA Style

Slnek D, Dománková M, Adamech M, Petzová J, Bártová K, Kudláč M, Gavalec M. Evolution of Microstructure and Mechanical Properties of Steam Generator Material After Long-Term Operation in Nuclear Power Plant. Metals. 2025; 15(6):667. https://doi.org/10.3390/met15060667

Chicago/Turabian Style

Slnek, David, Mária Dománková, Marek Adamech, Jana Petzová, Katarína Bártová, Marek Kudláč, and Matúš Gavalec. 2025. "Evolution of Microstructure and Mechanical Properties of Steam Generator Material After Long-Term Operation in Nuclear Power Plant" Metals 15, no. 6: 667. https://doi.org/10.3390/met15060667

APA Style

Slnek, D., Dománková, M., Adamech, M., Petzová, J., Bártová, K., Kudláč, M., & Gavalec, M. (2025). Evolution of Microstructure and Mechanical Properties of Steam Generator Material After Long-Term Operation in Nuclear Power Plant. Metals, 15(6), 667. https://doi.org/10.3390/met15060667

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