Formation of Interfacial Reaction Layers in Al2O3/SS 430 Brazed Joints Using Cu-7Al-3.5Zr Alloys
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Reaction of Cu-7Al-3.5Zr Alloy with Substrates
3.2. Formation of the Interfacial Reaction Layers Brazed at 1000 °C
4. Conclusions
Author Contributions
Acknowledgments
Conflicts of Interest
References
- Fernie, J.A.; Drew, R.A.L.; Knowles, K.M. Joining of engineering ceramics. Inter. Mater. Rev. 2013, 54, 283–331. [Google Scholar] [CrossRef]
- Fernandez, J.M.; Asthana, R.; Singh, M.; Valera, F.M. Active metal brazing of silicon nitride ceramics using a Cu-based alloy and refractory metal interlayers. Ceram. Int. 2016, 42, 5447–5454. [Google Scholar] [CrossRef]
- Cui, W.; Li, S.; Yan, J.; He, J.; Liu, Y. Ultrasonic-assisted brazing of sapphire with high strength Al–4.5Cu–1.5Mg alloy. Ceram. Int. 2015, 41, 8014–8022. [Google Scholar] [CrossRef]
- Zhao, Y.X.; Wang, M.R.; Cao, J.; Song, X.G.; Tang, D.Y.; Feng, J.C. Brazing TC4 alloy to Si3N4 ceramic using nano-Si3N4 reinforced AgCu composite filler. Mater. Des. 2015, 76, 40–46. [Google Scholar] [CrossRef]
- Jung, K.; Heo, H.-J.; Lee, J.-H.; Park, Y.-C.; Kang, C.-Y. Enhanced corrosion resistance of hypo-eutectic Al–1Mg–xSi alloys against molten sodium attack in high temperature sodium sulfur batteries. Corros. Sci. 2015, 98, 748–757. [Google Scholar] [CrossRef]
- Jung, K.; Lee, S.; Park, Y.-C.; Kim, C.-S. Finite element analysis study on the thermomechanical stability of thermal compression bonding (TCB) joints in tubular sodium sulfur cells. J. Power Sources 2014, 250, 1–14. [Google Scholar] [CrossRef]
- Simões, S. Recent progress in the joining of titanium alloys to ceramics. Metals 2018, 8, 876. [Google Scholar] [CrossRef]
- Xu, Y.; Jung, K.; Park, Y.-C.; Kim, C.-S. Selection of container materials for modern planar sodium sulfur (NaS) energy storage cells towards higher thermo-mechanical stability. J. Energy Storage 2017, 12, 215–225. [Google Scholar] [CrossRef]
- Siegmund, P.; Guhl, C.; Schmidt, E.; Roßberg, A.; Rettenmayr, M. Reactive wetting of alumina by Ti-rich Ni–Ti–Zr alloys. J. Mater. Sci. 2016, 51, 3693–3700. [Google Scholar] [CrossRef]
- Ali, M.; Knowles, K.M.; Mallinson, P.M.; Fernie, J.A. Interfacial reactions between sapphire and Ag–Cu–Ti-based active braze alloys. Acta Mater. 2016, 103, 859–869. [Google Scholar] [CrossRef]
- Bobzin, K.; Öte, M.; Wiesner, S.; Kaletsch, A.; Broeckmann, C. Characterization of reactive air brazed ceramic/metal joints with unadapted thermal expansion behavior. Adv. Eng. Mater. 2014, 16, 1490–1497. [Google Scholar] [CrossRef]
- Singh, M.; Martinez Fernandez, J.; Asthana, R.; Rico, J.R. Interfacial characterization of silicon nitride/silicon nitride joints brazed using Cu-base active metal interlayers. Ceram. Int. 2012, 38, 2793–2802. [Google Scholar] [CrossRef]
- Jacobson, D.M.; Humpston, G. Principles of Brazing; Asm International: Geauga County, OH, USA, 2005. [Google Scholar]
- Ali, M.; Knowles, K.M.; Mallinson, P.M.; Fernie, J.A. Microstructural evolution and characterisation of interfacial phases in Al2O3/Ag–Cu–Ti/ Al2O3 braze joints. Acta Mater. 2015, 96, 143–158. [Google Scholar] [CrossRef]
- Lee, D.; Woo, J.; Park, S. Oxidation behavior of Ag–Cu–Ti brazing alloys. Mater. Sci. Eng. A 1999, 268, 202–207. [Google Scholar] [CrossRef]
- Heo, H.; Park, Y.-C.; Kang, C.-Y.; Jung, K. Dealloying of a Ag–Cu–Ti alloy in liquid sodium at 350 °C. Corros. Sci. 2018, 144, 35–43. [Google Scholar] [CrossRef]
- Heo, H.; Kim, G.; Park, Y.-C.; Jung, K.; Kang, C.-Y. Effect of bonding temperature on crack occurrences in Al2O3/SS430 joints using cu-based brazing alloys. Metals 2018, 8, 752. [Google Scholar] [CrossRef]
- Loehman, R.; Tomsia, A. Reactions of Ti and Zr with aln and Al2O3. Acta Metall. Mater. 1992, 40, S75–S83. [Google Scholar] [CrossRef]
- Kim, J.-H.; Yoo, Y.-C. Bonding of alumina to metals with Ag–Cu–Zr brazing alloy. J. Mater. Sci. Lett. 1997, 16, 1212–1215. [Google Scholar] [CrossRef]
- Loehman, R.; Hosking, F.; Gauntt, B.; Kotula, P.; Lu, P. Reactions of Hf-ag and Zr-Ag alloys with Al2O3 at elevated temperatures. J. Mater. Sci. 2005, 40, 2319–2324. [Google Scholar] [CrossRef]
- Wang, G.; Lannutti, J. Chemical thermodynamics as a predictive tool in the reactive metal brazing of ceramics. Metall. Mater. Trans. A 1995, 26, 1499–1505. [Google Scholar] [CrossRef]
- Loehman, R.E.; Gauntt, B.D.; Michael Hosking, F.; Kotula, P.G.; Rhodes, S.; Stephens, J.J. Reaction and bonding of Hf and Zr containing alloys to alumina and silica. J. Eur. Ceram. Soc. 2003, 23, 2805–2811. [Google Scholar] [CrossRef]
- Yoo, Y.C.; Kim, J.H.; Park, K. Microstructural characterization of Al2O3/AISI 8650 steel joint brazed with Ag–Cu–Sn–Zr alloy. Mater. Lett. 2000, 42, 362–366. [Google Scholar] [CrossRef]
- Roine, A. Hsc chemistry 7.0 user′s guide-chemical reaction and equilibrium software with extensive thermochemical database and flowsheet simulation [computer program]. Outotec. 2009. Available online: www.hsc-chemistry.com (accessed on 24 November 2018).
- Bang, K.S.; Liu, S. Interfacial reactions between Cu-Zr filler metal and alumina and kinetics of reaction layer growth. Metals Mater. 1998, 4, 151–155. [Google Scholar] [CrossRef]
- Robie, R.A.; Hemingway, B.S. Thermodynamic Properties of Minerals and Related Substances at 298.15 K and 1 Bar (105 Pascals) Pressure and at Higher Temperatures; US Government Printing Office: Washington, D.C., WA, USA, 1995; Volume 2131.
- Niu, G.B.; Wang, D.P.; Yang, Z.W.; Wang, Y. Microstructure and mechanical properties of Al2O3 ceramic and TiAl alloy joints brazed with Ag–Cu–Ti filler metal. Ceram. Int. 2016, 42, 6924–6934. [Google Scholar] [CrossRef]
- Zhou, Y.; Ikeuchi, K.; North, T.H.; Wang, Z. Effect of plastic deformation on residual stresses in ceramic/metal interfaces. Metall. Trans. A 1991, 22, 2822–2825. [Google Scholar] [CrossRef]
- Zhou, Y.; Bao, F.; Ren, J.; North, T. Interlayer selection and thermal stresses in brazed Si3N4− Steel joints. Mater. Sci. Technol. 1991, 7, 863–868. [Google Scholar] [CrossRef]
- Blugan, G.; Kuebler, J.; Bissig, V.; Janczak-Rusch, J. Brazing of silicon nitride ceramic composite to steel using SiC-particle-reinforced active brazing alloy. Ceram. Int. 2007, 33, 1033–1039. [Google Scholar] [CrossRef]
- Davis, J.R. Copper and Copper Alloys; ASM international: Geauga County, OH, USA, 2001. [Google Scholar]
- Chawla, K.K. Ceramic matrix composites; Springer Science & Business Media: Berlin, Germany, 2013. [Google Scholar]
- Vianco, P.T.; Walker, C.A.; De Smet, D.J.; Kilgo, A.C.; McKenzie, B.B.; Kotula, P.G.; Grant, R.P. Understanding the Run-Out Behavior of a Ag-Cu-Zr Braze Alloy when Used to Join Alumina to an Fe-Ni-Co Alloy; Sandia National Lab. (SNL-NM): Albuquerque, NM, USA, 2015. [Google Scholar]
No. | Cu | Al | Zr | O | Possible Phase |
---|---|---|---|---|---|
#1 | - | 41.5 | - | 68.5 | α-Al2O3 |
#2 | 89.1 | 10.9 | - | - | α-Cu |
#3 | - | - | 42.3 | 57.7 | ZrO2 |
#4 | 57.9 | 22.1 | 20.0 | - | AlCu2Zr |
#5 | 89.5 | 10.5 | - | - | α-Cu |
Materials | α (10−6 K−1) CTE | (MPa) Yield Str. |
---|---|---|
α-Al2O3 | 7.0 | - |
SS 430 | 10.4 | 310 |
Cu-7Al-3.5Zr | 16.2 | 133 |
ZrO2 | 10.0 | - |
α-Cu | 18.0 | 185 |
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Heo, H.; Joung, H.; Jung, K.; Kang, C.-Y. Formation of Interfacial Reaction Layers in Al2O3/SS 430 Brazed Joints Using Cu-7Al-3.5Zr Alloys. Metals 2018, 8, 990. https://doi.org/10.3390/met8120990
Heo H, Joung H, Jung K, Kang C-Y. Formation of Interfacial Reaction Layers in Al2O3/SS 430 Brazed Joints Using Cu-7Al-3.5Zr Alloys. Metals. 2018; 8(12):990. https://doi.org/10.3390/met8120990
Chicago/Turabian StyleHeo, Hoejun, Hyeonim Joung, Keeyoung Jung, and Chung-Yun Kang. 2018. "Formation of Interfacial Reaction Layers in Al2O3/SS 430 Brazed Joints Using Cu-7Al-3.5Zr Alloys" Metals 8, no. 12: 990. https://doi.org/10.3390/met8120990