The Influence of Ultrasonic Vibration Frequency on the Properties of TiN Coated Biomedical Ti–13Zr–13Nb
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
- Ultrasonic frequency effects on TiN coating properties after subjected with ultrasonic treatment were noted: as the ultrasonic frequency increased, the more intense the coating deformation, the less the number of microdroplets, the less the coating thickness, and the higher the coating’s hardness.
- It was found that the corrosion properties of the TiN coating significantly improved after treated with ultrasonic vibrations. It seems that the ultrasonic vibration was able to deform the coating and fill up the pinholes thus improving the corrosion resistance of the coated sample. Charge transfer resistance and current density increased from 2816 to 3766 and 0.261 to 0.185, respectively, when the ultrasonic frequency increased. This indicates that there was less penetration from the simulated body fluids into the coating due to the compactness of the coating properties created at extreme conditions using the ultrasonic treatment.
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Samples | Maximum Depth (nm) | Hardness (GPa) | Elastic Modulus, E (GPa) | H3/E2 Ratio |
---|---|---|---|---|
Without Ultrasonic | 364.580 | 2.765 | 138.25 | 0.0011 |
8 kHz | 286.876 | 4.210 | 165.78 | 0.0027 |
16 kHz | 259.524 | 5.511 | 185.21 | 0.0049 |
Samples | Ecorr (mv) | Icorr (µA/cm2) | Corrosion Rate (mm/Year) | Rct | Cdl |
---|---|---|---|---|---|
Without Ultrasonic | −110.11 | 0.971 | 18.6323 × 10−3 | 1883 | 2.7 × 10−5 |
8 kHz | 49.07 | 0.261 | 4.9241 × 10−3 | 2816 | 1.73 × 10−5 |
16 kHz | −122.07 | 0.185 | 3.7843 × 10−3 | 3766 | 8.8 × 10−6 |
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Shah, A.; Izman, S.; Ismail, S.N.F.; Mas Ayu, H.; Che Kob, C.G.; Daud, R.; Abdul Kadir, M.R. The Influence of Ultrasonic Vibration Frequency on the Properties of TiN Coated Biomedical Ti–13Zr–13Nb. Metals 2018, 8, 317. https://doi.org/10.3390/met8050317
Shah A, Izman S, Ismail SNF, Mas Ayu H, Che Kob CG, Daud R, Abdul Kadir MR. The Influence of Ultrasonic Vibration Frequency on the Properties of TiN Coated Biomedical Ti–13Zr–13Nb. Metals. 2018; 8(5):317. https://doi.org/10.3390/met8050317
Chicago/Turabian StyleShah, A., S. Izman, Siti Nurul Fasehah Ismail, H. Mas Ayu, Che Ghani Che Kob, R. Daud, and Mohammed Rafiq Abdul Kadir. 2018. "The Influence of Ultrasonic Vibration Frequency on the Properties of TiN Coated Biomedical Ti–13Zr–13Nb" Metals 8, no. 5: 317. https://doi.org/10.3390/met8050317