Antioxidant Activities, Phenolic Profiles, and Organic Acid Contents of Fruit Vinegars
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals and Materials
2.2. Determination of FRAP, TEAC, TPC, and TFC Values
2.3. Phenolic Composition Analysis
2.4. Organic Acid Analysis
2.5. Data Analysis
3. Results and Discussion
3.1. Antioxidant Activities of Fruit Vinegars
3.2. TPC and TFC Values
3.3. Correlations Among FRAP, TEAC, TPC, and TFC Values
3.4. Polyphenols and Organic Acids in Fruit Vinegars
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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No. | Product | Producing Place | FRAP value (μmol Fe(II)/mL) | TEAC value (μmol Trolox/mL) | TPC value (mg GAE/L) | TFC value (mg QE/L) |
---|---|---|---|---|---|---|
1 | Apple vinegar (Hai Tian) | Foshan, China | 0.84 ± 0.01 k | 0.29 ± 0.01 j | 149.77 ± 3.94 h | 7.85 ± 0.35 d |
2 | Apple vinegar (Ba Zhen) | Dongguan, China | 1.43 ± 0.04 i,j | 0.43 ± 0.01 i,j | 249.18 ± 2.42 g | 20.77 ± 0.16 d |
3 | Apple vinegar (Guang Wei Yuan) | Guangzhou, China | 0.80 ± 0.02 k | 0.23 ± 0.01 j | 123.67 ± 1.51 h,i | 12.88 ± 0.08 d |
4 | Apple vinegar (Heng Shun) | Zhenjiang, China | 2.96 ± 0.01 f | 1.01 ± 0.02 g | 495.52 ± 20.59 e | 31.39 ± 0.43 c,d |
5 | Apple vinegar (Zi Lin) | Taiyuan, China | 1.83 ± 0.01 h | 0.69 ± 0.02 h | 398.17 ± 8.25 f | 12.78 ± 0.29 d |
6 | Apple vinegar (Cu Bo Shi) | Xinxiang, China | 0.23 ± 0.01 l | 0.03 ± 0.00 k | 66.90 ± 0.87 h,i | 5.86 ± 0.10 d |
7 | Apple vinegar (Sempio) | Seoul, South Korea | 0.22 ± 0.01 l | 0.04 ± 0.00 k | 43.75 ± 0.34 i | 2.22 ± 0.16 d |
8 | Apple vinegar (Galletti) | Gremona, Italy | 1.28 ± 0.02 i,j | 0.49 ± 0.02 i | 256.13 ± 1.86 g | 12.32 ± 0.16 d |
9 | Apple vinegar (Kühne) | Hamburg, Germany | 1.37 ± 0.01 i,j | 0.53 ± 0.02 i | 198.14 ± 0.33 g,h | 11.14 ± 0.28 d |
10 | Apple cider vinegar (Heinz) | Pittsburgh, America | 1.05 ± 0.04 j,k | 0.31 ± 0.01 j | 163.28 ± 0.15 h | 13.11 ± 0.14 d |
11 | Apple cider vinegar (Xin He) | Jinan, China | 2.40 ± 0.05 g | 0.90 ± 0.03 g | 426.72 ± 14.52 e,f | 28.04 ± 0.51 c,d |
12 | Apple vinegar beverage (Hua Sheng Tang) | Zhongshan, China | 0.19 ± 0.01 l | 0.06 ± 0.00 k | 62.19 ± 0.40 h,i | 5.41 ± 0.22 d |
13 | Apple vinegar beverage (Tian Di Yi Hao) | Jiangmen, China | 0.15 ± 0.00 l | 0.04 ± 0.00 k | 29.64 ± 0.16 i | 5.79 ± 0.14 d |
14 | Apple vinegar beverage (Long He Kuan) | Beijing, China | 3.99 ± 0.04 e | 1.69 ± 0.03 e | 469.10 ± 8.79 e,f | 4.52 ± 0.14 d |
15 | Red wine vinegar (Galletti) | Gremona, Italy | 8.04 ± 0.11 c | 3.17 ± 0.06 c | 993.51 ± 23.19 c | 50.34 ± 2.43 c |
16 | Red wine vinegar (Kühne) | Hamburg, Germany | 5.35 ± 0.09 d | 2.09 ± 0.03 d | 654.95 ± 39.52 d | 51.47 ± 0.99 c |
17 | Italian red wine vinegar (Ponti) | Ghemme, Italy | 3.71 ± 0.02 e | 1.36 ± 0.01 f | 396.40 ± 2.68 f | 19.75 ± 0.49 d |
18 | White wine vinegar (Galletti) | Gremona, Italy | 1.53 ± 0.03 i | 0.52 ± 0.01 i | 229.60 ± 2.14 g,h | 5.58 ± 0.30 d |
19 | White wine vinegar (Kühne) | Hamburg, Germany | 1.28 ± 0.03 i,j | 0.46 ± 0.02 i | 153.90 ± 2.13 h | 6.54 ± 0.16 d |
20 | Italian white wine vinegar (Ponti) | Ghemme, Italy | 1.21 ± 0.03 j | 0.30 ± 0.00 j | 117.00 ± 2.82 h,i | 5.09 ± 0.14 d |
21 | Balsamic vinegar of Modena (Galletti) | Modena, Italy | 23.52 ± 0.33 a | 7.30 ± 0.16 a | 3216.60 ± 132.67 a | 699.67 ± 24.08 b |
22 | Aceto Balsamico di Modena (Monari Federzoni) | Bomporto, Italy | 13.39 ± 0.25 b | 4.49 ± 0.09 b | 1901.92 ±16.06 b | 753.19 ± 36.85 a |
23 | Fruit vinegar (Wan Jia Xiang) | Taiwan, China | 0.89 ± 0.03 k | 0.26 ± 0.01 j | 194. 65 ± 0.32 g,h | 23.54 ± 0.99 c,d |
Correlation Coefficient (R2) | FRAP Value | TEAC Value | TPC Value | TFC Value |
---|---|---|---|---|
FRAP value | 1 | 0.989 * | 0.990 * | 0.804 * |
TEAC value | - | 1 | 0.971 * | 0.767 * |
TPC value | - | - | 1 | 0.832 * |
TFC value | - | - | - | 1 |
No. | Products | Gallic Acid | Protocatechuic Acid | Chlorogenic Acid | Caffeic Acid | p-Coumaric Acid | Ferulic Acid |
---|---|---|---|---|---|---|---|
1 | Apple vinegar (Hai Tian) | - | - | 2.79 ± 0.16 c | - | - | - |
2 | Apple vinegar (Ba Zhen) | - | - | 0.32 ± 0.01 d | - | - | - |
3 | Apple vinegar (Guang Wei Yuan) | - | - | - | - | - | - |
4 | Apple vinegar (Heng Shun) | - | 1.54 ± 0.05 b | 2.99 ± 0.21 c | - | - | - |
5 | Apple vinegar (Zi Lin) | - | 0.82 ± 0.04 e | 10.91 ± 0.80 a | - | 0.17 ± 0.01 e | - |
6 | Apple vinegar (Cu Bo Shi) | - | - | - | - | - | - |
7 | Apple vinegar (Sempio) | - | 0.08 ± 0.00 h | 0.11 ± 0.00 d | - | - | - |
8 | Apple vinegar (Galletti) | - | 0.37 ± 0.01 g | 3.13 ± 0.11 c | - | - | - |
9 | Apple vinegar (Kühne) | - | 1.09 ± 0.04 d | 5.30 ± 0.29 b | - | 0.10 ± 0.00 e | - |
10 | Apple cider vinegar (Heinz) | - | 1.00 ± 0.06 d | 0.23 ± 0.00 d | - | - | - |
11 | Apple cider vinegar (Xin He) | - | - | 4.67 ± 0.21 b | - | - | - |
12 | Apple vinegar beverage (Hua Sheng Tang) | - | - | - | - | - | - |
13 | Apple vinegar beverage (Tian Di Yi Hao) | - | 0.19 ± 0.01 h | 0.59 ± 0.02 d | - | - | - |
14 | Apple vinegar beverage (Long He Kuan) | - | - | - | - | - | - |
15 | Red wine vinegar (Galletti) | 4.10 ± 0.18 d | 0.47 ± 0.04 f,g | - | 1.48 ± 0.10 c | 1.13 ± 0.05 c | - |
16 | Red wine vinegar (Kühne) | 9.99 ± 0.58 b | 1.38 ± 0.05 c | - | - | 1.39 ± 0.01 b | - |
17 | Italian red wine vinegar (Ponti) | 4.36 ± 0.33 d | 0.49 ± 0.01 f | - | 1.73 ± 0.01 b | 0.81 ± 0.02 d | - |
18 | White wine vinegar (Galletti) | - | - | - | - | 0.18 ± 0.00 e | - |
19 | White wine vinegar (Kühne) | - | 0.32 ± 0.01 g | - | 0.32 ± 0.01 d | 0.15 ± 0.01 e | 0.31 ± 0.01 |
20 | Italian white wine vinegar (Ponti) | - | 0.16 ± 0.00 h | - | - | - | - |
21 | Balsamic vinegar of Modena (Galletti) | 12.56 ± 0.86 a | 3.29 ± 0.05 a | - | 3.58 ± 0.14 a | 1.97 ± 0.05 a | - |
22 | Aceto Balsamico di Modena (Monari Federzoni) | 7.50 ± 0.60 c | - | - | - | 1.17 ± 0.06 c | - |
23 | Fruit vinegar (Wan Jia Xiang) | - | - | - | - | - | - |
No. | Products | Tartaric Acid (μg/mL) | Malic Acid (μg/mL) | Lactic Acid (μg/mL) | Citric Acid (μg/mL) | Succinic Acid (μg/mL) |
---|---|---|---|---|---|---|
1 | Apple vinegar (Hai Tian) | - | 480.72 ± 5.12 d | - | - | - |
2 | Apple vinegar (Ba Zhen) | 14.71 ± 0.27 e | 372.61 ± 7.95 d | - | - | - |
3 | Apple vinegar (Guang Wei Yuan) | - | 7691.98 ± 435.24 a | 2541.64 ± 107.29 a | 6485.24 ± 389.42 a | - |
4 | Apple vinegar (Heng Shun) | - | 1771.35 ± 117.77 c | - | - | - |
5 | Apple vinegar (Zi Lin) | - | 613.05 ± 41.96 d | - | - | 1637.36 ± 67.61 a |
6 | Apple vinegar (Cu Bo Shi) | - | 1707.76 ± 105.42 c | - | 5263.43 ± 215.07 b | 1775.77 ± 113.27 a |
7 | Apple vinegar (Sempio) | - | 588.03 ± 11.69 d | - | - | - |
8 | Apple vinegar (Galletti) | - | 402.11 ± 23.26 d | - | - | - |
9 | Apple vinegar (Kühne) | - | 236.38 ± 3.01 d | - | - | - |
10 | Apple cider vinegar (Heinz) | - | - | - | - | - |
11 | Apple cider vinegar (Xin He) | - | 4102.22 ± 253.95 b | - | - | 991.08 ± 13.89 b |
12 | Apple vinegar beverage (Hua Sheng Tang) | - | 573.18 ± 18.66 d | - | - | - |
13 | Apple vinegar beverage (Tian Di Yi Hao) | - | 594.91 ± 42.89 d | - | - | - |
14 | Apple vinegar beverage (Long He Kuan) | - | 4386.73 ± 326.85 b | 50.20 ± 1.06 b | 787.96 ± 24.81 c | - |
15 | Red wine vinegar (Galletti) | 383.29 ± 5.74 d | - | - | - | 252.60 ± 6.50 c |
16 | Red wine vinegar (Kühne) | 948.01 ± 54.86 b | - | - | - | - |
17 | Italian red wine vinegar (Ponti) | 1030.86 ± 75.33 b | 187.36 ± 4.47 d | - | - | - |
18 | White wine vinegar (Galletti) | 760.55 ± 8.73 c | - | - | - | 346.04 ± 6.56 c |
19 | White wine vinegar (Kühne) | 1566.48 ± 94.47 a | - | - | - | - |
20 | Italian white wine vinegar (Ponti) | 1066.64 ± 65.49 b | - | - | - | - |
21 | Balsamic vinegar of Modena (Galletti) | 96.15 ± 1.15 e | - | - | - | - |
22 | Aceto Balsamico di Modena (Monari Federzoni) | 393.77 ± 13.37 d | 603.48 ± 15.38 d | - | - | - |
23 | Fruit vinegar (Wan Jia Xiang) | - | - | - | - | - |
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Liu, Q.; Tang, G.-Y.; Zhao, C.-N.; Gan, R.-Y.; Li, H.-B. Antioxidant Activities, Phenolic Profiles, and Organic Acid Contents of Fruit Vinegars. Antioxidants 2019, 8, 78. https://doi.org/10.3390/antiox8040078
Liu Q, Tang G-Y, Zhao C-N, Gan R-Y, Li H-B. Antioxidant Activities, Phenolic Profiles, and Organic Acid Contents of Fruit Vinegars. Antioxidants. 2019; 8(4):78. https://doi.org/10.3390/antiox8040078
Chicago/Turabian StyleLiu, Qing, Guo-Yi Tang, Cai-Ning Zhao, Ren-You Gan, and Hua-Bin Li. 2019. "Antioxidant Activities, Phenolic Profiles, and Organic Acid Contents of Fruit Vinegars" Antioxidants 8, no. 4: 78. https://doi.org/10.3390/antiox8040078