Mixed-Matrix Organo-Silica–Hydrotalcite Membrane for CO2 Separation Part 1: Synthesis and Analytical Description
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation
2.1.1. Hydrotalcite
2.1.2. Organo-Silica Matrix
2.1.3. Mixed-Matrix
2.2. Analytical Methods
2.2.1. X-ray Diffraction (XRD)
2.2.2. IR Analysis
2.2.3. Raman Spectroscopy (RS)
2.2.4. Thermal Analysis (TA)
3. Results and Discussion
3.1. XRD Results
3.2. IR Spectroscopy
3.3. Raman Spectroscopy
3.4. Thermal Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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XRD Results | Samples | ||||
---|---|---|---|---|---|
u.c.p. | 1 | 2a | 2b | 3 | 4 |
a (Å) | 3.07(1) | 3.066(1) | 3.14(1) | 3.10(5) | 3.064(1) |
c (Å) 3R | 25.25(1) | 23.683(2) | 23.557(2) | 24.22(1) | 24.25(1) |
c (Å) 2H | 16.833(7) | 15.788(1) | 15.705(2) | 16.19(1) | 16.181(7) |
crystal size (nm) | 1.6(1) | 10.6(2) | 8.42(7) | 3.2(1) | 3.4(1) |
Hydrotalcite | BTESE, HTlc-Modified Organo-Silica Membrane | |||||
---|---|---|---|---|---|---|
Sample | 1 | 2a,b | 3 | Sample | BTESE | 4 |
Band Assignment | Band Positions (cm−1) | Band Assignment | Band Positions (cm−1) | |||
ν Mg(Al)-O | 630 | ν Mg(Al)-O | 650–700 | |||
OH libration | 775 | OH libration | 765 | |||
ν2 (CO3) | 870 | 860 | 853 | ν1 Si-O | 800 | 830 |
ν1 (CO3) | 1075 | 1075 | 1075 | Si–OH | 950sh | 909 |
ν3 (CO3) | 1365 | 1365 | 1370 | ν3 Si-O | 1035s | 1022 |
M,Bν3 (CO3), ν2 CH3 | 1400–1500 | 1390 | ν1 (CO3) | 1086 | ||
δ H2O | 1645 | 1635 | 1635 | ν3 Si-O | 1150sh | 1152 |
H-bonding | 3000–3400 | 3100–3400 | 3200–3400 | ν Si-C | 1280 | 1270 |
ν1 OH(H2O) | 3425 | 3420 | 3475 | ν3 (CO3) 1370 M,Bν3 (CO3) 1405 | ||
δ H2O | 1638 | |||||
ν-CH2 | 2890 | |||||
ν-CH3 | 2980 | |||||
H-bonding ν1 OH(H2O | 3260 3370 |
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Bünger, L.; Garbev, K.; Ullrich, A.; Stemmermann, P.; Stapf, D. Mixed-Matrix Organo-Silica–Hydrotalcite Membrane for CO2 Separation Part 1: Synthesis and Analytical Description. Membranes 2024, 14, 170. https://doi.org/10.3390/membranes14080170
Bünger L, Garbev K, Ullrich A, Stemmermann P, Stapf D. Mixed-Matrix Organo-Silica–Hydrotalcite Membrane for CO2 Separation Part 1: Synthesis and Analytical Description. Membranes. 2024; 14(8):170. https://doi.org/10.3390/membranes14080170
Chicago/Turabian StyleBünger, Lucas, Krassimir Garbev, Angela Ullrich, Peter Stemmermann, and Dieter Stapf. 2024. "Mixed-Matrix Organo-Silica–Hydrotalcite Membrane for CO2 Separation Part 1: Synthesis and Analytical Description" Membranes 14, no. 8: 170. https://doi.org/10.3390/membranes14080170