Strong Biomimetic Immobilization of Pt-Particle Catalyst on ABS Substrate Using Polydopamine and Its Application for Contact-Lens Cleaning with H2O2
Abstract
:1. Introduction
2. Results and Discussion
2.1. External Appearance
2.2. Confirmation of the Formation of a PDA Film by X-Ray Photoelectron Spectroscopy (XPS)
2.3. Observation of Pt Particles by SEM
2.4. Pt-Loading Weight Determined by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)
2.5. Catalytic Activity for H2O2 Decomposition
2.6. Catalytic Durability during H2O2 Decomposition
2.7. Effect of Plasma Treatment on Catalytic Durability
3. Materials and Methods
3.1. PDA Coating and Immobilization of Pt Particles on ABS
3.2. Characterization
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample ID | Pt(0) | Pt(II) | Pt(IV) |
---|---|---|---|
Pt/ABS-untreated | 69.1 | 16.4 | 14.5 |
Pt/ABS-PDA(24h) | 81.1 | 11.0 | 7.9 |
Pt/ABS-plasma-PDA(24h) | 86.7 | 7.1 | 6.2 |
Sample ID | Plasma pre-treatment | PDA coating | Pt-particle deposition |
---|---|---|---|
Glass-untreated | ― | ― | ― |
Glass-PDA(1h) | ― | ◯ | ― |
Glass-PDA(3h) | ― | ◯ | ― |
Glass-PDA(24h) | ― | ◯ | ― |
ABS-untreated | ― | ― | ― |
ABS-PDA(1h) | ― | ◯ | ― |
ABS-PDA(3h) | ― | ◯ | ― |
ABS-PDA(24h) | ― | ◯ | ― |
ABS-plasma | ◯ | ― | ― |
ABS-plasma-PDA(24h) | ◯ | ◯ | ― |
Pt/ABS-untreated | ― | ― | ◯ |
Pt/ABS-PDA(1h) | ― | ◯ | ◯ |
Pt/ABS-PDA(3h) | ― | ◯ | ◯ |
Pt/ABS-PDA(24h) | ― | ◯ | ◯ |
Pt/ABS-plasma-PDA(24h) | ◯ | ◯ | ◯ |
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Ohkubo, Y.; Aoki, T.; Kaibara, D.; Seino, S.; Mori, O.; Sasaki, R.; Endo, K.; Yamamura, K. Strong Biomimetic Immobilization of Pt-Particle Catalyst on ABS Substrate Using Polydopamine and Its Application for Contact-Lens Cleaning with H2O2. Nanomaterials 2020, 10, 114. https://doi.org/10.3390/nano10010114
Ohkubo Y, Aoki T, Kaibara D, Seino S, Mori O, Sasaki R, Endo K, Yamamura K. Strong Biomimetic Immobilization of Pt-Particle Catalyst on ABS Substrate Using Polydopamine and Its Application for Contact-Lens Cleaning with H2O2. Nanomaterials. 2020; 10(1):114. https://doi.org/10.3390/nano10010114
Chicago/Turabian StyleOhkubo, Yuji, Tomonori Aoki, Daisuke Kaibara, Satoshi Seino, Osamu Mori, Rie Sasaki, Katsuyoshi Endo, and Kazuya Yamamura. 2020. "Strong Biomimetic Immobilization of Pt-Particle Catalyst on ABS Substrate Using Polydopamine and Its Application for Contact-Lens Cleaning with H2O2" Nanomaterials 10, no. 1: 114. https://doi.org/10.3390/nano10010114