Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Preparation of the Photocatalysts
2.2.1. Synthesis of Carbon Nitride (CN)
2.2.2. Synthesis of Alkalized Carbon Nitride (AKCN)
2.2.3. Synthesis of Fe3+-Doped Alkalized Carbon Nitride (AKCN-xFe)
2.3. Characterization
2.4. Photocatalytic Experiments
3. Results and Discussion
3.1. Morphology
3.2. Structure and Composition
3.3. Band Structure
3.4. Photodegradation Performance
3.5. Photocatalytic Antibacterial Performance
3.6. Photocatalytic Mechanism
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
- Sboui, M.; Bouattour, S.; Gruttadauria, M.; Marci, G.; Liotta, L.F.; Boufi, S. Paper functionalized with nanostructured TiO2/AgBr: Photocatalytic degradation of 2-Propanol under solar light irradiation and antibacterial activity. Nanomaterials 2020, 10, 470. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Li, S.J.; Xue, B.; Wu, G.Y.; Liu, Y.P.; Zhang, H.Q.; Ma, D.Y.; Zuo, J.C. A novel flower-like Ag/AgCl/BiOCOOH ternary heterojunction photocatalyst: Facile construction and its superior photocatalytic performance for the removal of toxic pollutants. Nanomaterials 2019, 9, 1562. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Shan, W.; Hu, Y.; Bai, Z.; Zheng, M.; Wei, C. In situ preparation of g-C3N4/bismuth-based oxide nanocomposites with enhanced photocatalytic activity. Appl. Catal. B Environ. 2016, 188, 1–12. [Google Scholar] [CrossRef]
- Yao, Y.; Lu, F.; Zhu, Y.; Wei, F.; Liu, X.; Lian, C.; Wang, S. Magnetic core–shell CuFe2O4@C3N4 hybrids for visible light photocatalysis of Orange II. J. Hazard. Mater. 2015, 297, 224–233. [Google Scholar] [CrossRef] [PubMed]
- Shi, H.; Chen, G.; Zhang, C.; Zou, Z. Polymeric g-C3N4 Coupled with NaNbO3 Nanowires toward Enhanced Photocatalytic Reduction of CO2 into Renewable Fuel. ACS Catal. 2014, 4, 3637–3643. [Google Scholar] [CrossRef]
- Dai, K.; Lu, L.; Liu, Q.; Zhu, G.; Wei, X.; Bai, J.; Xuan, L.; Wang, H. Sonication assisted preparation of graphene oxide/graphitic-C3N4 nanosheet hybrid with reinforced photocurrent for photocatalyst applications. Dalton Trans. 2014, 43, 6295–6299. [Google Scholar] [CrossRef]
- Christoforidis, K.C.; Montini, T.; Bontempi, E.; Zafeiratos, S.; Jaén, J.J.D.; Fornasiero, P. Synthesis and photocatalytic application of visible-light active β-Fe2O3/g-C3N4 hybrid nanocomposites. Appl. Catal. B Environ. 2016, 187, 171–180. [Google Scholar] [CrossRef]
- Wang, X.; Maeda, K.; Chen, X.; Takanabe, K.; Domen, K.; Hou, Y.; Fu, X.; Antonietti, M. Polymer Semiconductors for Artificial Photosynthesis: Hydrogen Evolution by Mesoporous Graphitic Carbon Nitride with Visible Light. J. Am. Chem. Soc. 2009, 131, 1680–1681. [Google Scholar] [CrossRef]
- Wang, Y.; Wang, X.; Antonietti, M. ChemInform Abstract: Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry. ChemInform 2012, 43. [Google Scholar] [CrossRef]
- Yan, S.C.; Li, Z.S.; Zou, Z.G. Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine. Langmuir 2009, 25, 10397–10401. [Google Scholar] [CrossRef]
- Li, X.-H.; Zhang, J.; Chen, X.; Fischer, A.; Thomas, A.; Antonietti, M.; Wang, X. Condensed Graphitic Carbon Nitride Nanorods by Nanoconfinement: Promotion of Crystallinity on Photocatalytic Conversion. Chem. Mater. 2011, 23, 4344–4348. [Google Scholar] [CrossRef]
- Kailasam, K.; Epping, J.D.; Thomas, A.; Losse, S.; Junge, H. Mesoporous carbon nitride–silica composites by a combined sol–gel/thermal condensation approach and their application as photocatalysts. Energy Environ. Sci. 2011, 4, 4668–4674. [Google Scholar] [CrossRef] [Green Version]
- Wang, X.; Chen, X.; Thomas, A.; Fu, X.; Antonietti, M. Metal-Containing Carbon Nitride Compounds: A New Functional Organic–Metal Hybrid Material. Adv. Mater. 2009, 21, 1609–1612. [Google Scholar] [CrossRef]
- Kumar, S.; Surendar, T.; Baruah, A.; Shanker, V. Synthesis of a novel and stable g-C3N4–Ag3PO4 hybrid nanocomposite photocatalyst and study of the photocatalytic activity under visible light irradiation. J. Mater. Chem. A 2013, 1, 5333–5340. [Google Scholar] [CrossRef]
- Zhang, Y.; Mori, T.; Niu, L.; Ye, J. Non-covalent doping of graphitic carbon nitride polymer with graphene: Controlled electronic structure and enhanced optoelectronic conversion. Energy Environ. Sci. 2011, 4, 4517–4521. [Google Scholar] [CrossRef]
- Wang, Y.; Li, H.; Yao, J.; Wang, X.; Antonietti, M. Synthesis of boron doped polymeric carbon nitride solids and their use as metal-free catalysts for aliphatic C–H bond oxidation. Chem. Sci. 2010, 2, 446–450. [Google Scholar] [CrossRef]
- Zhang, J.; Zhang, M.; Zhang, G.; Wang, X. Synthesis of Carbon Nitride Semiconductors in Sulfur Flux for Water Photoredox Catalysis. ACS Catal. 2012, 2, 940–948. [Google Scholar] [CrossRef]
- Zhang, Y.; Thomas, A.; Antonietti, M.; Wang, X. Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments. J. Am. Chem. Soc. 2009, 131, 50–51. [Google Scholar] [CrossRef]
- Su, F.; Mathew, S.C.; Moehlmann, L.; Antonietti, M.; Wang, X.; Blechert, S. ChemInform Abstract: Aerobic Oxidative Coupling of Amines by Carbon Nitride Photocatalysis with Visible Light. ChemInform 2011, 42. [Google Scholar] [CrossRef]
- Pan, C.; Xu, J.; Wang, Y.; Li, D.; Zhu, Y. Dramatic Activity of C3N4/BiPO4 Photocatalyst with Core/Shell Structure Formed by Self-Assembly. Adv. Funct. Mater. 2012, 22, 1518–1524. [Google Scholar] [CrossRef]
- Huang, L.; Xu, H.; Li, Y.; Li, H.; Cheng, X.; Xia, J.; Xu, Y.; Cai, G. Visible-light-induced WO3/g-C3N4 composites with enhanced photocatalytic activity. Dalton Trans. 2013, 42, 8606–8616. [Google Scholar] [CrossRef] [PubMed]
- Wang, M.; Ju, P.; Zhao, Y.; Li, J.; Han, X.; Hao, Z. In situ ion exchange synthesis of MoS2/g-C3N4 heterojunctions for highly efficient hydrogen production. New J. Chem. 2018, 42, 910–917. [Google Scholar] [CrossRef]
- Yang, Y.; Zhang, C.; Huang, D.; Zeng, G.; Huang, J.; Lai, C.; Zhou, C.; Wang, W.; Guo, H.; Xue, W.; et al. Boron nitride quantum dots decorated ultrathin porous g-C3N4: Intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation. J. Am. Chem. Soc. 2019, 245, 87–99. [Google Scholar] [CrossRef]
- Yoon, M.; Oh, Y.; Hong, S.; Lee, J.S.; Boppella, R.; Kim, S.H.; Marques Mota, F.; Kim, S.O.; Kim, D.H. Synergistically enhanced photocatalytic activity of graphitic carbon nitride and WO3 nanohybrids mediated by photo-Fenton reaction and H2O2. Appl. Catal. B Environ. 2017, 206, 263–270. [Google Scholar] [CrossRef]
- Isaka, Y.; Oyama, K.; Yamada, Y.; Suenobu, T.; Fukuzumi, S. Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts. Catal. Sci. Technol. 2016, 6, 681–684. [Google Scholar] [CrossRef] [Green Version]
- Kofuji, Y.; Ohkita, S.; Shiraishi, Y.; Sakamoto, H.; Tanaka, S.; Ichikawa, S.; Hirai, T. Graphitic Carbon Nitride Doped with Biphenyl Diimide: Efficient Photocatalyst for Hydrogen Peroxide Production from Water and Molecular Oxygen by Sunlight. ACS Catal. 2016, 6, 7021–7029. [Google Scholar] [CrossRef]
- Shi, L.; Yang, L.; Zhou, W.; Liu, Y.; Yin, L.; Hai, X.; Song, H.; Ye, J. Photoassisted Construction of Holey Defective g-C3N4 Photocatalysts for Efficient Visible-Light-Driven H2O2 Production. Small 2018, 14, 1703142. [Google Scholar] [CrossRef]
- Shiraishi, Y.; Kanazawa, S.; Sugano, Y.; Tsukamoto, D.; Sakamoto, H.; Ichikawa, S.; Hirai, T. Highly Selective Production of Hydrogen Peroxide on Graphitic Carbon Nitride (g-C3N4) Photocatalyst Activated by Visible Light. ACS Catal. 2014, 4, 774–780. [Google Scholar] [CrossRef]
- Zhang, P.; Sun, D.; Cho, A.; Weon, S.; Lee, S.; Lee, J.; Han, J.W.; Kim, D.-P.; Choi, W. Modified carbon nitride nanozyme as bifunctional glucose oxidase-peroxidase for metal-free bioinspired cascade photocatalysis. Nat. Commun. 2019, 10, 940. [Google Scholar] [CrossRef] [Green Version]
- Zhu, J.-N.; Zhu, X.-Q.; Cheng, F.-F.; Li, P.; Wang, F.; Xiao, Y.-W.; Xiong, W.-W. Preparing copper doped carbon nitride from melamine templated crystalline copper chloride for Fenton-like catalysis. Appl. Catal. B Environ. 2019, 256, 117830. [Google Scholar] [CrossRef]
- Li, Y.; Ouyang, S.; Xu, H.; Wang, X.; Bi, Y.; Zhang, Y.; Ye, J. Constructing Solid–Gas-Interfacial Fenton Reaction over Alkalinized-C3N4 Photocatalyst To Achieve Apparent Quantum Yield of 49% at 420 nm. J. Am. Chem. Soc. 2016, 138, 13289–13297. [Google Scholar] [CrossRef] [PubMed]
- Shiraishi, Y.; Kanazawa, S.; Kofuji, Y.; Sakamoto, H.; Ichikawa, S.; Tanaka, S.; Hirai, T. Sunlight-Driven Hydrogen Peroxide Production from Water and Molecular Oxygen by Metal-Free Photocatalysts. Angew. Chem. Int. Ed. 2014, 53, 13454–13459. [Google Scholar] [CrossRef] [PubMed]
- Kumar, A.; Kumar, S.; Bahuguna, A.; Kumar, A.; Sharma, V.; Krishnan, V. Recyclable, bifunctional composites of perovskite type N-CaTiO3 and reduced graphene oxide as an efficient adsorptive photocatalyst for environmental remediation. Mater. Chem. Front. 2017, 1, 2391–2404. [Google Scholar] [CrossRef]
- Zhang, X.; Zhang, J.; Yu, J.; Zhang, Y.; Cui, Z.; Sun, Y.; Hou, B. Fabrication of InVO4/AgVO3 heterojunctions with enhanced photocatalytic antifouling efficiency under visible-light. Appl. Catal. B Environ. 2018, 220, 57–66. [Google Scholar] [CrossRef]
- Xiang, Z.; Wang, Y.; Zhang, D.; Ju, P. BiOI/BiVO4 p-n heterojunction with enhanced photocatalytic activity under visible-light irradiation. J. Ind. Eng. Chem. 2016, 40, 83–92. [Google Scholar] [CrossRef]
- Kim, J.; Lee, C.W.; Choi, W. Platinized WO3 as an Environmental Photocatalyst that Generates OH Radicals under Visible Light. Environ. Sci. Technol. 2010, 44, 6849–6854. [Google Scholar] [CrossRef]
- Zhang, Y.; Zhang, N.; Tang, Z.-R.; Xu, Y.-J. Identification of Bi2WO6 as a highly selective visible-light photocatalyst toward oxidation of glycerol to dihydroxyacetone in water. Chem. Sci. 2013, 4, 1820–1824. [Google Scholar] [CrossRef]
- Ju, P.; Wang, Y.; Sun, Y.; Zhang, D. Controllable one-pot synthesis of a nest-like Bi2WO6/BiVO4 composite with enhanced photocatalytic antifouling performance under visible light irradiation. Dalton Trans. 2016, 45, 4588–4602. [Google Scholar] [CrossRef]
- Lin, X.; Guo, X.; Shi, W.; Zhao, L.; Yan, Y.; Wang, Q. Ternary heterostructured Ag–BiVO4/InVO4 composites: Synthesis and enhanced visible-light-driven photocatalytic activity. J. Alloy. Compd. 2015, 635, 256–264. [Google Scholar] [CrossRef]
- Ishibashi, K.-i.; Fujishima, A.; Watanabe, T.; Hashimoto, K. Detection of active oxidative species in TiO2 photocatalysis using the fluorescence technique. Electrochem. Commun. 2000, 2, 207–210. [Google Scholar] [CrossRef]
- Yang, S.; Gong, Y.; Zhang, J.; Zhan, L.; Ma, L.; Fang, Z.; Vajtai, R.; Wang, X.; Ajayan, P.M. Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light. Adv. Mater. 2013, 25, 2452–2456. [Google Scholar] [CrossRef] [PubMed]
- Gao, J.; Wang, Y.; Zhou, S.; Lin, W.; Kong, Y. A facile one-step synthesis of Fe-doped g-C3N4 nanosheets and their improved visible-light photocatalytic performance. ChemCatChem 2017, 9, 1708–1715. [Google Scholar] [CrossRef] [Green Version]
- Feng, D.; Cheng, Y.; He, J.; Zheng, L.; Shao, D.; Wang, W.; Wang, W.; Lu, F.; Dong, H.; Liu, H.; et al. Enhanced photocatalytic activities of g-C3N4 with large specific surface area via a facile one-step synthesis process. Carbon 2017, 125, 454–463. [Google Scholar] [CrossRef]
- Dong, G.; Ho, W.; Li, Y.; Zhang, L. Facile synthesis of porous graphene-like carbon nitride (C6N9H3) with excellent photocatalytic activity for NO removal. Appl. Catal. B Environ. 2015, 174–175, 477–485. [Google Scholar] [CrossRef]
- Yu, H.; Shi, R.; Zhao, Y.; Bian, T.; Zhao, Y.; Zhou, C.; Waterhouse, G.I.N.; Wu, L.-Z.; Tung, C.-H.; Zhang, T. Alkali-assisted synthesis of nitrogen deficient graphitic carbon nitride with tunable band structures for efficient visible-light-driven hydrogen evolution. Adv. Mater. 2017, 29, 1605148. [Google Scholar] [CrossRef]
- Xiong, T.; Wang, H.; Zhou, Y.; Sun, Y.; Cen, W.; Huang, H.; Zhang, Y.; Dong, F. KCl-mediated dual electronic channels in layered g-C3N4 for enhanced visible light photocatalytic NO removal. Nanoscale 2018, 10, 8066–8074. [Google Scholar] [CrossRef]
- Zhao, Y.; Zhao, F.; Wang, X.; Xu, C.; Zhang, Z.; Shi, G.; Qu, L. Graphitic Carbon Nitride Nanoribbons: Graphene-Assisted Formation and Synergic Function for Highly Efficient Hydrogen Evolution. Angew. Chem. Int. Ed. 2014, 53, 13934–13939. [Google Scholar] [CrossRef]
- Liang, J.; Zheng, Y.; Chen, J.; Liu, J.; Hulicova-Jurcakova, D.; Jaroniec, M.; Qiao, S.Z. Facile Oxygen Reduction on a Three-Dimensionally Ordered Macroporous Graphitic C3N4/Carbon Composite Electrocatalyst. Angew. Chem. Int. Ed. 2012, 51, 3892–3896. [Google Scholar] [CrossRef]
- Yu, H.; Shang, L.; Bian, T.; Shi, R.; Waterhouse, G.; Zhao, Y.; Zhou, C.; Wu, L.-Z.; Tung, C.-H.; Zhang, T. Nitrogen-Doped Porous Carbon Nanosheets Templated from g-C3N4 as Metal-Free Electrocatalysts for Efficient Oxygen Reduction Reaction. Adv. Mater. 2016, 28, 5080–5086. [Google Scholar] [CrossRef]
- Yang, L.; Huang, J.; Shi, L.; Cao, L.; Yu, Q.; Jie, Y.; Fei, J.; Ouyang, H.; Ye, J. A surface modification resultant thermally oxidized porous g-C3N4 with enhanced photocatalytic hydrogen production. Appl. Catal. B Environ. 2017, 204, 335–345. [Google Scholar] [CrossRef]
- Cao, S.; Low, J.; Yu, J.; Jaroniec, M. Polymeric Photocatalysts Based on Graphitic Carbon Nitride. Adv. Mater. 2015, 27, 2150–2176. [Google Scholar] [CrossRef]
- Xu, H.; Wu, Z.; Wang, Y.; Lin, C. Enhanced visible-light photocatalytic activity from graphene-like boron nitride anchored on graphitic carbon nitride sheets. J. Mater. Sci. 2017, 52, 9477–9490. [Google Scholar] [CrossRef]
- Ye, C.; Li, J.-X.; Li, Z.-J.; Li, X.-B.; Fan, X.-B.; Zhang, L.-P.; Chen, B.; Tung, C.-H.; Wu, L.-Z. Enhanced driving force and charge separation efficiency of protonated g-C3N4 for Photocatalytic O2 Evolution. ACS Catal. 2015, 5, 6973–6979. [Google Scholar] [CrossRef]
- Gao, H.; Yan, S.; Wang, J.; Huang, Y.A.; Wang, P.; Li, Z.; Zou, Z. Towards efficient solar hydrogen production by intercalated carbon nitride photocatalyst. Phys. Chem. Chem. Phys. 2013, 15, 18077–18084. [Google Scholar] [CrossRef] [PubMed]
- Rahman, M.Z.; Zhang, J.; Tang, Y.; Davey, K.; Qiao, S.-Z. Graphene oxide coupled carbon nitride homo-heterojunction photocatalyst for enhanced hydrogen production. Mater. Chem. Front. 2017, 1, 562–571. [Google Scholar] [CrossRef]
- Liu, J.; Liu, Y.; Liu, N.; Han, Y.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S.-T.; Zhong, J.; Kang, Z. Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 2015, 347, 970–974. [Google Scholar] [CrossRef]
- Schwinghammer, K.; Mesch, M.B.; Duppel, V.; Ziegler, C.; Senker, J.; Lotsch, B.V. Crystalline Carbon Nitride Nanosheets for Improved Visible-Light Hydrogen Evolution. J. Am. Chem. Soc. 2014, 136, 1730–1733. [Google Scholar] [CrossRef] [PubMed]
- Martha, S.; Mansingh, S.; Parida, K.M.; Thirumurugan, A. Exfoliated metal free homojunction photocatalyst prepared by a biomediated route for enhanced hydrogen evolution and Rhodamine B degradation. Mater. Chem. Front. 2017, 1, 1641–1653. [Google Scholar] [CrossRef]
- Zhao, S.; Zhang, Y.; Zhou, Y.; Wang, Y.; Qiu, K.; Zhang, C.; Fang, J.; Sheng, X. Facile one-step synthesis of hollow mesoporous g-C3N4 spheres with ultrathin nanosheets for photoredox water splitting. Carbon 2018, 126, 247–256. [Google Scholar] [CrossRef]
- Zhao, W.; Yang, X.R.; Liu, C.X.; Qian, X.X.; Wen, Y.R.; Yang, Q.; Sun, T.; Chang, W.Y.; Liu, X.; Chen, Z. Facile construction of all-solid-state Z-scheme g-C3N4/TiO2 thin film for the efficient visible-light degradation of organic pollutant. Nanomaterials 2020, 10, 600. [Google Scholar] [CrossRef] [Green Version]
- Xu, J.; Meng, W.; Zhang, Y.; Li, L.; Guo, C. Photocatalytic degradation of tetrabromobisphenol A by mesoporous BiOBr: Efficacy, products and pathway. Appl. Catal. B Environ. 2011, 107, 355–362. [Google Scholar] [CrossRef]
- Natarajan, K.; Bajaj, H.C.; Tayade, R.J. Effective removal of organic pollutants using GeO2/TiO2 nanoparticle composites under direct sunlight. Mater. Chem. Front. 2018, 2, 741–751. [Google Scholar] [CrossRef]
- Wang, Y.; Rao, L.; Wang, P.; Guo, Y.; Shi, Z.; Guo, X.; Zhang, L. Synthesis of nitrogen vacancies g-C3N4 with increased crystallinity under the controlling of oxalyl dihydrazide: Visible-light-driven photocatalytic activity. Appl. Surf. Sci. 2020, 505, 144576. [Google Scholar] [CrossRef]
- Li, L.; Yan, J.; Wang, T.; Zhao, Z.-J.; Zhang, J.; Gong, J.; Guan, N. Sub-10 nm rutile titanium dioxide nanoparticles for efficient visible-light-driven photocatalytic hydrogen production. Nat. Commun. 2015, 6, 5881. [Google Scholar] [CrossRef]
- Li, P.; Li, J.; Feng, X.; Li, J.; Hao, Y.; Zhang, J.; Wang, H.; Yin, A.; Zhou, J.; Ma, X.; et al. Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning. Nat. Commun. 2019, 10, 2177. [Google Scholar] [CrossRef]
- She, X.; Wu, J.; Xu, H.; Zhong, J.; Wang, Y.; Song, Y.; Nie, K.; Liu, Y.; Yang, Y.; Rodrigues, M.-T.F.; et al. High efficiency photocatalytic water splitting using 2D α-Fe2O3/g-C3N4 Z-scheme catalysts. Adv. Energy Mater. 2017, 7, 1700025. [Google Scholar] [CrossRef]
- Teng, Z.; Yang, N.; Lv, H.; Wang, S.; Hu, M.; Wang, C.; Wang, D.; Wang, G. Edge-functionalized g-C3N4 nanosheets as a highly efficient metal-free photocatalyst for safe drinking water. Chem 2019, 5, 664–680. [Google Scholar] [CrossRef] [Green Version]
- Liu, C.; Kong, D.; Hsu, P.-C.; Yuan, H.; Lee, H.-W.; Liu, Y.; Wang, H.; Wang, S.; Yan, K.; Lin, D.; et al. Rapid water disinfection using vertically aligned MoS2 nanofilms and visible light. Nat. Nanotechnol. 2016, 11, 1098–1104. [Google Scholar] [CrossRef]
- Zhang, J.; Wang, J.; Zhu, Q.; Zhang, B.; Xu, H.; Duan, J.; Hou, B. Fabrication of a novel AgBr/Ag2MoO4@InVO4 composite with excellent visible light photocatalytic property for antibacterial use. Nanomaterials 2020, 10, 1541. [Google Scholar] [CrossRef]
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Gao, Y.; Duan, J.; Zhai, X.; Guan, F.; Wang, X.; Zhang, J.; Hou, B. Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride. Nanomaterials 2020, 10, 1751. https://doi.org/10.3390/nano10091751
Gao Y, Duan J, Zhai X, Guan F, Wang X, Zhang J, Hou B. Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride. Nanomaterials. 2020; 10(9):1751. https://doi.org/10.3390/nano10091751
Chicago/Turabian StyleGao, Ying, Jizhou Duan, Xiaofan Zhai, Fang Guan, Xiutong Wang, Jie Zhang, and Baorong Hou. 2020. "Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride" Nanomaterials 10, no. 9: 1751. https://doi.org/10.3390/nano10091751