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Article

Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors

by
Liyang Lin
1,2,*,
Susu Chen
3,
Tao Deng
1,2 and
Wen Zeng
4
1
School of Aeronautics, Chongqing Jiaotong University, Chongqing 400074, China
2
The Green Aerotechnics Research Institute, Chongqing Jiaotong University, Chongqing 400714, China
3
College of Aerospace Engineering, Chongqing University, Chongqing 400044, China
4
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
*
Author to whom correspondence should be addressed.
Nanomaterials 2021, 11(2), 372; https://doi.org/10.3390/nano11020372
Submission received: 7 January 2021 / Revised: 23 January 2021 / Accepted: 26 January 2021 / Published: 2 February 2021
(This article belongs to the Special Issue State-of-the-Art Nanomaterials and Nanotechnology in China)
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Abstract

:
The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.

Graphical Abstract

1. Introduction

With the development of society and the improvement of the level of science and technology, people are increasingly improving their own quality of life. In particular, terms such as health, safety, and convenience frequently appear in the public’s field of vision [1,2,3]. Therefore, environmental safety monitoring, human safety monitoring and green energy are facing huge business opportunities and challenges, including electrochemical energy storage devices [4,5,6], gas sensor devices [7,8,9], pressure sensor devices [10,11,12], and so on. This also puts forward higher requirements for the comprehensive performance of the material.
Whether in electrochemical energy storage devices or gas sensors, metal oxides such as NiO [13,14], ZnO [15,16], Co3O4 [17,18], SnO2 [19,20], etc. play a very important role in their material design and composition. However, these metal oxides themselves have poor electrical conductivity. Moreover, it is inevitable to introduce polymers used as binders when assembling devices. Even a very small amount will cause the electron or ion transport channels to be cut off and significantly reduce the performance. In recent years, a large number of researches have been conducted on the use of metal oxide nanomaterials as the matrix and the selection of suitable carbon materials for doping to form metal oxide/carbon nanocomposites [21,22,23]. The synergistic effect due to compounding can effectively improve the overall characteristics, especially the conductivity. However, carbon nanomaterials such as graphene are prone to agglomeration due to their own characteristics, so the performance improvement effect is not obvious, which greatly limits the advantages of this method [24]. Fortunately, recent studies have shown that changing the surface properties of metal oxides by creating oxygen vacancies can effectively improve performance, which provides a new idea for the synthesis of metal oxide/carbon composites [25,26,27,28,29].
SnO2 is an important semiconductor material for gas sensors and supercapacitors. At present, the main method to improve the gas-sensing performance of SnO2 materials is to increase the crystal defects by creating oxygen vacancies or doping impurities, thereby increasing its carrier density [30]. Bunpang et al. synthesized flame-spray-made Cr-doped SnO2 nanoparticles to improve its gas-sensing performance toward CH4 [31]. Bonu et al. studied the influence of in-plane and bridging oxygen vacancies of SnO2 nanostructures on CH4 sensing at low operating temperatures [32]. Kooti et al. prepared SnO2 nanorods–nanoporous graphene hybrids and speculated that the substantial enhancement in the gas detection of SnO2 NRs-NPG nanohybrid should be attributed to its larger specific surface area, the nanoporous graphene as a good conductor, and the synergistic effect [33]. In contrast, SnO2 as a supercapacitor electrode material has not achieved satisfactory electrochemical performance, and even the use of carbon materials for compounding cannot effectively improve its specific capacitance and rate performance. Notably, the effect of oxygen vacancies on the electrochemical property of SnO2 has never been systematically investigated.
In this work, graphene modified oxygen-deficient SnO2 nanocomposite (r-SnO2/GN) was successfully synthesized via the solvothermal method and annealing treatment. Different from the reported SnO2 nanostructures [34,35,36,37], this paper synthesized SnO2 hollow spheres with large specific surface area and stable structure by means of concentrated acid and organic solution at appropriate reaction temperature and reaction time. At the same time, chemical treatment and heat treatment were reasonably combined in the introduction of oxygen vacancies, which not only achieved the deep reduction of GO but also introduced a large number of oxygen vacancies in SnO2 under the premise of ensuring the phase stability. A series of characterizations such as XRD, Raman, SEM, TEM, BET, and XPS were conducted to reveal its stable hybrid microstructure, perfect composition and abundant oxygen vacancies before the assembling of r-SnO2/GN nanomaterials. Both as the electrode material of supercapacitors and gas-sensing material, it shows excellent performance.

2. Materials and Methods

2.1. Material Preparation

Preparation of GO: GO nanomaterials were synthesized from natural graphite by the popularly used Hummers method [38].
Synthesis of Hollow SnO2 nanospheres: 0.190 g of SnCl4 (Reagent. Chengdu Kelong Co. Ltd., Chengdu, China) was fully dissolved in a mixed solution of 5 mL of deionized water and 50 mL of absolute ethanol, and then 0.5 mL of 37% HCl (Reagent. Chongqing Chuandong Chemical Co., Ltd., Chongqing, China) was added. The above solution was ultrasonically stirred for 30 min and then transferred into 100 mL Teflon-lined stainless steel autoclave at 200 °C for 24 h. The white precursor was centrifuged and washed with deionized water and absolute ethanol three times. The powder was annealed further at 400 °C in air for 2 h.
Preparation of r-SnO2/GN nanocomposite: As-obtained SnO2 (60 mg) and GO (10 mg) were dispersed in 40 mL of deionized water for 1.5 h using an ultrasonic reactor, then stirred with a planetary mixer for 5 min. The mixture was immersed in NaBH4 solution (10 mg mL−1) for 10 h. After centrifugal cleaning and drying, the black powder was then placed in a tube furnace filled with nitrogen and calcined at 500 °C for 3 h.

2.2. Material Characterization

Morphologies and nanostructures were characterized with FE-SEM (JEOL, JSM-7800F, Tokyo, Japan) and TEM (FEI, TALOS F200, Waltham, MA, USA). The composition and phase of the samples were evaluated by XRD (BRUKER, D2 PHASER, Karlsruher, Germany) and XPS (Thermo Fisher Scientific, ESCALAB 250Xi, Waltham, MA, USA). Raman spectra of the samples were obtained by a micro-Raman system (HORIBA Jobin Yvon, LabRAM ARAMIS, Paris, France). Nitrogen adsorption−desorption isotherm was used to examine the specific surface area and pore structure (MicrotracBEL, BELSORP-max II, Japan).

2.3. Electrochemical Measurements

Preparation of working electrodes: Samples SnO2 and r-SnO2/GN were separately blended with carbon black and Polyvinylidene Fluoride (PVDF) at a mass ratio of 7:2:1 in NMP. The above slurry was smearing immediately onto the as-cleaned Ni foam substrate and then dried at 50 °C in vacuum for 12 h (the coating area was controlled to be 1 cm × 1 cm).
Measurement conditions: Pt foil, saturated calomel electrode (SCE), and 3.0 M KOH solution was used as counter electrode, reference electrode, and electrolyte, respectively. The specific capacitance was calculated by the common formula Cm = IΔt/mΔU in the discharge measurements, where I is discharge current density, Δt is the discharging time, m is the mass of the active materials, and ΔU is the width of the potential window [39]. The frequency of the electrochemical impedance spectra was collected from 0.01 Hz to 100 kHz. The mass loading of the active material for SnO2 and r-SnO2/GN electrodes was about 3.6 mg cm−2 and 3.5 mg cm−2, respectively.

2.4. Gas-Sensing Measurements

Preparation of gas sensors: Typically, samples SnO2 and r-SnO2/GN were separately dispersed into distilled water using an ultrasonic cleaner. The obtained slurries were uniformly coated onto the surface of specific alumina ceramic tubes and then dried in an oven [40].
Measurement conditions: Gas-sensing properties were measured by a chemical gas sensor-8 intelligent gas-sensing analysis system (Beijing Elite Tech. Co., Ltd., Beijing, China). The response (S) was defined as S = Ra/Rg, where Ra and Rg were initial and real-time resistance, respectively.

3. Results and Discussion

Figure 1a shows XRD patterns of two samples SnO2 (I) and r-SnO2/GN (II). For sample I, it can been seen that six characteristic peaks at 26.6°, 33.9°, 37.9°, 51.8°, 54.8°, and 65.9° correspond to (110), (101), (200), (211), (220), and (301) planes of the tetragonal phase of SnO2 (JCPDS 41-1445). All these peaks are sharp and clean without any impurity peaks. It can also be seen from the figure that the diffraction pattern of r-SnO2/GN is very similar to that of SnO2. In addition, there is no obvious characteristic peak at 25.1° corresponding to GN. Raman spectra for SnO2 (I) and r-SnO2/GN (II) are shown in Figure 1b. Compared with pure SnO2, r-SnO2/GN nanocomposite exhibits intense peaks at 1360 and 1575 cm−1, corresponding to the D and G bands of GO. As we know, the ratio of ID/IG can be used to measure the redox degree of the graphite oxide. The value of ID/IG for the r-SnO2/GN is about 1.16 higher than that of GO (about 0.98), indicating the successful reduction of GO to rGO after the chemical and heat treatments. In addition, there is a wide band with a peak near 570 cm−1 corresponding to SnO2, which reveals the successful formation of r-SnO2/GN nanocomposite. In addition to Raman spectra, the following SEM, TEM, and XPS results will provide more evidence. Therefore, it can be inferred that the surface of SnO2 is coated with disordered stacking but uniform dispersing of GN [41].
SEM images of two samples are shown in Figure 2. At low magnification (Figure 2a), it can be found that the SnO2 powder is composed of spheres with uniform size and rough surface. The diameter of each sphere is about 300 nm. Moreover, it can be observed that the rough spherical surface is composed of countless tiny particles under higher magnification (Figure 2b). Figure 2c,d shows the morphologies of sample r-SnO2/GN. Even after a long time immersion in NaBH4 solution and another heat treatment, the SnO2 nanostructure did not break and still appeared as a sphere with a rough surface. The difference is that the surface is obviously wrapped with gauze-like nanomaterials. Compared with the former, the latter has a small amount and no obvious agglomeration, which verifies the typical GN morphology inferred from XRD results. Besides, EDS mapping including Sn, O, and C elements is also collected and shown in Figure 2e. It can be seen that all these elements are uniformly distributed comparing to the original SEM image, indicating the successful deposition of GN on the surface of r-SnO2 spheres to form a stable composite.
The nanostructures of SnO2 and r-SnO2/GN were further investigated by conducting TEM and HRTEM imaging, as shown in Figure 3. Figure 3a,b shows a close-up of the internal morphology of sample SnO2, revealing its hollow structure. HRTEM image (Figure 3c) of a nanoparticle on the spherical shell exhibits clear and uniformly arranged lattice fringes. The interplanar spacing is about 0.26 nm corresponding to (101) crystal plane of the SnO2 phase. Herein, the formation mechanism of SnO2 hollow sphere is speculated. Due to the presence of concentrated hydrochloric acid, ethanol will be dehydrated to produce H2O. SnCl4 will initially hydrolyze and condense to produce primary SnO2 nanocrystals. Subsequently, these SnO2 nanocrystals aggregate and form large solid microspheres. This process is very fast and completes after a few hours. Therefore, the new solid spheres cannot crystallize well, especially for the nanoparticles inside the solid spheres. Furthermore, these internal nanoparticles with higher surface energy will dissolve under solvothermal conditions to form a core-shell structure. The dissolved Sn4+ will be further hydrolyzed and condensed to form SnO2 nanocrystals on the surface of the sphere. In addition, the temperature of 200 °C and the reaction time of 24 h are also guarantees for uniformly dispersed SnO2 hollow spheres. From Figure 3d, one can see sample r-SnO2/GN maintaining the hollow structure and successfully being covered by gauze-like nanosheets. HRTEM image focusing on the interface (red rectangle in Figure 3e) has been shown in Figure 3f. Obviously, in addition to the lattice fringes corresponding to SnO2, another one with interplanar spacing of 0.35 nm can be determined, which is indexed to (002) crystal plane of the hexagonal phase of C. Moreover, the few-layer GN are curled up and tightly combined with SnO2 grains.
Pore size distribution curve and N2 adsorption–desorption isotherm of two samples are shown in Figure 4. According to the experimental data, the specific surface area of sample SnO2 is 43.58 m2 g−1 and the average pore size is about 3.86 nm. By contrast, sample r-SnO2/GN has a larger specific surface area of 57.86 m2 g−1 and a smaller average pore size of 3.76 nm. Based on these results, it can be confirmed that the sample r-SnO2/GN is mesoporous and has the larger specific surface area. XPS spectrums of sample r-SnO2/GN and sample SnO2 are further obtained and shown in Figure 5. All binding energies are referenced to the C1s at 284.6 eV. Figure 5a displays a survey of r-SnO2/GN indicating the predominant presence of Sn, C, and O elements. According to the high-resolution spectrum (Figure 5b), it can be seen that Sn 3 d spectrum of r-SnO2/GN exhibits two major peaks at 487.4 eV and 495.8 eV, which shifts about 0.9 eV to a higher binding energy comparing to SnO2 (486.5 eV and 494.9 eV). Abundant oxygen vacancies introduced in SnO2 crystals give a high electron-attracting effect to nearby Sn, resulting in the decrease of the electron density of nearby Sn [42,43,44]. The decrease of electron density further gives rise to the increase of the electron binding energy. The above result evidently confirms the abundant oxygen vacancies in r-SnO2/GN. In addition, Figure 5c shows the bonding information for C 1 s including C−C, C−O, and C=O. Obviously, the less intense residual oxygen containing functional group peaks indicates that GO has been reduced more completely [45]. Figure 5d illustrates that O 1 s spectrum of r-SnO2/GN exhibits two major peaks at 530.5 eV and 531.8 eV. The peak located at 530.5 eV is indexed to the lattice oxygen (OL) species, and the peak located at 531.8 eV is assigned to the chemisorbed oxygen (OC) species.
To evaluate their potential application as supercapacitors, electrochemical properties of electrodes SnO2 and r-SnO2/GN were tested. CV curves of two electrodes at a scanning rate of 50 mV s−1 are shown in Figure 6a for comparison. Both of them exhibit two redox peaks revealing their pseudocapacitor characteristics. However, the region surrounded by the CV curve for r-SnO2/GN is much broader than that for SnO2. At the same time, GCD curves of two electrodes at a current density of 2 mA cm−2 are shown in Figure 6b. As expected, the discharge time of electrode r-SnO2/GN is about 663.2 s much longer than that of SnO2 (only 133.0 s). In detail, CV curves of electrodes SnO2 and r-SnO2/GN at different voltage sweep rate are shown in Figure 6c,e, respectively. As the voltage sweep rate increases from 10 to 100 mV s−1, the absolute value of the redox peak (for both current density and potential) increases significantly, showing a relatively low resistance and a rapid redox reaction at the interface between the electrode and the electrolyte, especially for the electrode r-SnO2/GN [46]. GCD curves of two electrodes at different current densities are shown in Figure 6d,f, respectively. When the current density changes from 2 to 20 mA cm−2, the discharge time of the electrode r-SnO2/GN is 663.2, 401.7, 213.6, 100.6, and 44.8 s. Under the same condition, the electrode SnO2 shows 133.0, 82.5, 44.4, 15.8, and 4.7 s.
Figure 7a shows the curve chart of specific capacitance (F g−1). Based on the common formula mentioned in experimental part, the specific capacitance of the electrode r-SnO2/GN can be calculated to be 947.4, 860.8, 762.9, 715.7, and 640.0 F g−1 at a current density of 2, 3, 5, 10, and 20 mA cm−2, respectively. As a contrast, the electrode SnO2 only has 184.7 F g−1 at the low current density of 2 mA cm−2. As far as we know, the observed electrochemical performances are better than other SnO2-based materials, which have been reported before, such as the pure SnO2 (138 F g−1) [34], SnO2-NGO (378 F g−1) [35], SnO2/g-C3N4 (488 F g−1) [47], and the hollow SnO2 (332.7 F g−1) [30] (See Table 1). The cycling stability of two electrodes is shown in Figure 7b. After 1000 GCD cycles, the electrode r-SnO2/GN still retains about 88.2% of initial specific capacitance, better than that of the electrode SnO2 (72.1% remain). Moreover, EIS Nyquist plots of two electrodes (Figure 7c,d) were measured to understand their ion and electron transfer performance. EIS data were fitted according to the equivalent circuit model (the inset of Figure 7c,d). Four main parameters including the charge-transfer Rct, solution resistance Rs, double-layer capacitance Cdl, and Warburg resistance W were considered [48]. Generally, the diameter of semicircle in the high frequency range shows the Rct and the slope of the line at low frequency region means W, which represent the charge transfer at the interface and the diffusion of the redox species in the electrode, respectively. After comparing the EIS data of two electrodes, it can be found that two values (Rct and W) read from the curve of the electrode r-SnO2/GN are smaller than that of the electrode SnO2, indicating that that the former has better ion and electron transport capability. Several advantages of the oxygen-deficient r-SnO2/GN nanocomposite make them a promising candidate as the electrochemical supercapacitors. These features include: (i) Abundant oxygen vacancies facilitate easy access of electrolyte ions into the large surface area of the electrode. (ii) Highly reductive GN as facile electron transfer paths provides good interfacial contact for r-SnO2.
Furthermore, gas-sensing functionalities of two samples were also investigated (Figure 8). Two gas sensors toward methane gas of 500 ppm at different working temperatures were tested. Their response plots are shown in Figure 8a. It can be seen that the sensor r-SnO2/GN exhibits much more remarkable response value than SnO2 from 100 to 200 °C. The best working temperature for r-SnO2/GN is found around 140 °C. The above results also indicate that the sensor r-SnO2/GN remains an n-type semiconductor material even when doped with a certain amount of graphene. After setting the working temperature as 140 °C, the resistances of sensor r-SnO2/GN and SnO2 in air are recorded, respectively. The sensor SnO2 has a resistance of 14.71 MΩ in air. However, for the sensor r-SnO2/GN exposed to air, it exhibits stable and lower resistance (about 0.36 MΩ). From Figure 8b, a particular response curve of the sensor r-SnO2/GN toward methane gas at 140 °C, one can see that the response value keeps stable when the sensor is exposed in air, yet goes up rapidly once 500 ppm methane is injected into the system. It eventually maintains at ~13.8 and decreases quickly when the methane gas is out. In addition, the response values of the sensor r-SnO2/GN toward methane gas of various concentrations were tested and shown in Figure 8c. From 100 to 5000 ppm, the response value is about 3.2, 6.9, 13.8, 16.2, 18.1, and 20.4, respectively, revealing the law that it first increases rapidly and then tends to slow. Particularly, whether in low concentrations or high concentrations (Figure 8d), the response and recovering time is short. It means that the sensor r-SnO2/GN achieves good response ability. The response of r-SnO2/GN is also compared with other SnO2-based materials [36,37,49,50,51] (See Table 2). The long-term stability of the sensor base on r-SnO2/GN is also investigated (Figure 8e). After 6 days testing, the response nearly keeps at a constant value (13.65~13.8), demonstrating excellent long-term stability. The sensitivities of the sensor r-SnO2/GN toward different gases are shown in Figure 8f. In addition to a maximum response value of 13.8 for methane gas, it also has a good effect on ethanol and methanol gases. The sensor r-SnO2/GN possessing good gas-sensing performance should be attributed to its self-characteristics. Large specific surface area with abundant oxygen vacancies creates defect states close to the conduction band minimum, resulting in low activation energy.

4. Conclusions

In summary, oxygen-deficient r-SnO2/GN nanocomposite with large specific surface area was rationally designed and successfully fabricated. As the supercapacitor electrode, it exhibited greatly improved electrochemical performances with an ultrahigh specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity and short response/recovering time toward methane gas. The synergistic effect of vacancy-enriched SnO2 and GN wrapped on its surface makes r-SnO2/GN a promising nanocomposite material for energy storage devices and gas sensors.

Author Contributions

Conceptualization, L.L.; methodology, L.L. and S.C.; validation, L.L. and W.Z.; investigation, S.C.; data curation, L.L.; writing—original draft preparation, L.L. and S.C.; writing—review and editing, L.L.; visualization, S.C.; supervision, L.L.; project administration, L.L. and T.D. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Chinese National Natural Science Fund (Grant No.: 11632004, U1864208), the Key Program for International Science and Technology Cooperation Projects of the Ministry of Science and Technology of China (No. 2016YFE0125900), the Science and Technology Research Key Program of Chongqing Municipal Education Commission (Grant No. KJZD-K202000701), and Key Projects of Technological Innovation and Application Development of Chongqing (Grant No. cstc2019jscx-fxydX0028).

Data Availability Statement

No new data were created or analyzed in this study. Data sharing is not applicable to this article.

Acknowledgments

Here we express our appreciation to Ning Hu and Jianyao Yao for their help during the practical processes.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Wrapp, D.; Wang, N.S.; Corbett, K.S.; Goldsmith, J.A.; Hsieh, C.L.; Abiona, O.; Graham, B.S.; McLellan, J.S. Cryo-EM Structure of the 2019-nCoV Spike In the Prefusion Conformation. Science 2020, 367, 1260–1263. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  2. Yang, C.Y.; Chen, J.; Ji, X.; Pollard, T.P.; Lü, X.J.; Sun, C.J.; Hou, S.; Liu, Q.; Liu, C.M.; Qing, T.T.; et al. Aqueous Li-Ion Battery Enabled by Halogen Conversion-Intercalation Chemistry in Graphite. Nature 2019, 569, 245–250. [Google Scholar] [CrossRef] [PubMed]
  3. Scrosati, B. Bottled Lightning: Superbatteries, Electric Cars, and the New Lithium Economy. Nature 2011, 473, 448–449. [Google Scholar] [CrossRef] [Green Version]
  4. Zhu, Y.W.; Murali, S.; Stoller, M.D.; Ganesh, K.J.; Cai, W.W.; Ferreira, P.J.; Pirkle, A.; Wallace, R.M.; Cychosz, K.A.; Thommes, M.; et al. Carbon-Based Supercapacitors Produced by Activation of Graphene. Science 2011, 332, 1537–1541. [Google Scholar] [CrossRef] [Green Version]
  5. Pomerantseva, E.; Bonaccorso, F.; Feng, X.L.; Cui, Y.; Gogotsi, Y. Energy Storage: The Future Enabled by Nanomaterials. Science 2019, 366, 969. [Google Scholar] [CrossRef] [Green Version]
  6. Simon, P.; Gogotsi, Y. Materials for Electrochemical Capacitors. Nat. Mater. 2008, 7, 845–854. [Google Scholar] [CrossRef] [Green Version]
  7. Tollefson, J. Big Prize for Methane Probe. Nature 2018, 556, 283. [Google Scholar] [CrossRef]
  8. Le, T.H.; Wang, Y.; Liu, L.; Yang, J.N.; Yung, Y.L.; Li, G.H.; Seinfeld, J.H. Unexpected Air Pollution with Marked Emission Reductions During the COVID-19 Outbreak in China. Science 2020, 369, 702–706. [Google Scholar] [CrossRef]
  9. Lee, H.; Choi, T.K.; Lee, Y.B.; Cho, H.R.; Ghaffari, R.; Wang, L.; Choi, H.J.; Chung, T.D.; Lu, N.S.; Hyeon, T.; et al. A Graphene-Based Electrochemical Device with Thermoresponsive Microneedles for Diabetes Monitoring and Therapy. Nat. Nanotechnol. 2016, 11, 566–572. [Google Scholar] [CrossRef]
  10. Hong, Y.N.; Lam, J.W.Y. Aggregation-Induced Emission: Phenomenon, Mechanism and Applications. Chem. Commun. 2009, 29, 4332–4353. [Google Scholar] [CrossRef]
  11. Yamada, T.; Hayamizu, Y.; Yamamoto, Y.; Yomogida, Y.; Izadi-Najafabadi, A.; Futaba, D.N.; Hata, K. A stretchable Carbon Nanotube Strain Sensor for Human-Motion Detection. Nat. Nanotechnol. 2011, 6, 296–301. [Google Scholar] [CrossRef] [PubMed]
  12. Mannsfeld, S.C.B.; Tee, B.C.K.; Stoltenberg, R.M.; Chen, C.V.H.H.; Barman, S.; Muir, B.V.O.; Sokolov, A.N.; Reese, C.; Bao, Z.N. Highly Sensitive Flexible Pressure Sensors with Microstructured Rubber Dielectric Layers. Nat. Mater. 2010, 9, 859–864. [Google Scholar] [CrossRef] [PubMed]
  13. Yuan, C.Z.; Zhang, X.G.; Su, L.H.; Gao, B.; Shen, L.F. Facile Synthesis and Self-assembly of Hierarchical Porous NiO Nano/Micro Spherical Superstructures for High Performance Supercapacitors. J. Mater. Chem. 2009, 19, 5772–5777. [Google Scholar] [CrossRef]
  14. Kim, J.H.; Zhu, K.; Yan, Y.F.; Perkins, C.L.; Frank, A.J. Microstructure and Pseudocapacitive Properties of Electrodes Constructed of Oriented NiO-TiO2 Nanotube Arrays. Nano Lett. 2010, 10, 4099–4104. [Google Scholar] [CrossRef] [PubMed]
  15. Wang, Q.; Yan, J.; Wang, Y.B.; Wei, T.; Zhang, M.L.; Jing, X.Y.; Fan, Z.J. Three-Dimensional Flower-Like and Hierarchical Porous Carbon Materials as High-Rate Performance Electrodes for Supercapacitors. Carbon 2014, 67, 119–127. [Google Scholar] [CrossRef]
  16. Wan, Q.; Li, Q.H.; Chen, Y.J.; Wang, T.H.; He, X.L.; Li, J.P.; Lin, C.L. Fabrication and Ethanol Sensing Characteristics of ZnO Nanowire Gas Sensors. Appl. Phys. Lett. 2004, 84, 3654–3656. [Google Scholar] [CrossRef] [Green Version]
  17. Dong, X.C.; Xu, H.; Wang, X.W.; Huang, Y.X.; Chan-Park, M.B.; Zhang, H.; Wang, L.H.; Huang, W.; Chen, P. 3D Graphene-Cobalt Oxide Electrode for High-Performance Supercapacitor and Enzymeless Glucose Detection. ACS Nano 2012, 6, 3206–3213. [Google Scholar] [CrossRef]
  18. Meher, S.K.; Rao, G.R. Ultralayered Co3O4 for High-Performance Supercapacitor Applications. J. Phys. Chem. C 2011, 115, 15646–15654. [Google Scholar] [CrossRef]
  19. Luan, Y.X.; Nie, G.D.; Zhao, X.W.; Qiao, N.; Liu, X.C.; Wang, H.; Zhang, X.N.; Chen, Y.Q.; Long, Y.Z. The Integration of SnO2 Dots and Porous Carbon Nanofibers for Flexible Supercapacitors. Electrochim. Acta 2019, 308, 121–130. [Google Scholar] [CrossRef]
  20. Cao, M.L.; Cheng, W.L.; Ni, X.H.; Hu, Y.; Han, G.P. Lignin-Based Multi-Channels Carbon Nanofibers @ SnO2 Nanocomposites for High-Performance Supercapacitors. Electrochim. Acta 2020, 345, 136172. [Google Scholar] [CrossRef]
  21. Choudhari, A.; Bhanvase, B.A.; Saharan, V.K.; Salame, P.H.; Hunge, Y. Sonochemical Preparation and Characterization of rGO/SnO2 Nanocomposite: Electrochemical and Gas Sensing Performance. Ceram. Int. 2020, 46, 11290–11296. [Google Scholar] [CrossRef]
  22. Rani, M.U.; Naresh, V.; Damodar, D.; Muduli, S.; Martha, S.K.; Deshpande, A.S. In-Situ Formation of Mesoporous SnO2@C Nanocomposite Electrode for Supercapacitors. Electrochim. Acta 2021, 365, 137284. [Google Scholar] [CrossRef]
  23. Ali, A.; Ammar, M.; Yahya, Z.; Waqas, M.; Jamal, M.A.; Salhabi, E.H.M. A Honeycomb-Like ZnO/SnO2 Nanocomposite on Nickel Foam for High-Performance Asymmetric Supercapacitors. New J. Chem. 2019, 43, 10583–10589. [Google Scholar] [CrossRef]
  24. Zhou, G.M.; Wang, D.W.; Li, F.; Zhang, L.L.; Li, N.; Wu, Z.S.; Wen, L.; Lu, G.Q.; Cheng, H.M. Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries. Chem. Mater. 2010, 22, 5306–5313. [Google Scholar] [CrossRef]
  25. Xu, J.; Ruan, C.H.; Li, P.X.; Xie, Y.B. Excessive Nitrogen Doping of Tin Dioxide Banorod Array Grown on Activated Carbon Fibers Substrate for Wire-Shaped Microsupercapacitor. Chem. Eng. J. 2019, 378, 122064. [Google Scholar] [CrossRef]
  26. Abdollahi, H.; Samkan, M.; Mohajerzadeh, M.A.; Sanaee, Z.; Mohajerzadeh, S. High-Performance Tin-Oxide Supercapacitors Using Hydrazine Functionalising Assisted by Hydrogen Plasma Treatment. Micro Nano Lett. 2019, 14, 1268–1273. [Google Scholar] [CrossRef]
  27. Zhao, X.; Zhao, Y.D.; Liu, Z.H.; Yang, Y.; Sui, J.H.; Wang, H.E.; Cai, W.; Cao, G.Z. Synergistic Coupling of Lamellar MoSe2 and SnO2 Nanoparticles via Chemical Bonding at Interface for Stable and High-Power Sodium-Ion Capacitors. Chem. Eng. J. 2018, 354, 1164–1173. [Google Scholar] [CrossRef]
  28. Wang, Y.C.; Zhou, T.; Jiang, K.; Da, P.M.; Peng, Z.; Tang, J.; Kong, B.A.; Cai, W.B.; Yang, Z.Q.; Zheng, G.F. Reduced Mesoporous Co3O4 Nanowires as Efficient Water Oxidation Electrocatalysts and Supercapacitor Electrodes. Adv. Energy Mater. 2014, 4, 1400696. [Google Scholar] [CrossRef]
  29. Mefford, J.T.; Hardin, W.G.; Dai, S.; Johnston, K.P.; Stevenson, K.J. Anion Charge Storage through Oxygen Intercalation in LaMnO3 Perovskite Pseudocapacitor Electrodes. Nat. Mater. 2014, 13, 726–732. [Google Scholar] [CrossRef]
  30. Kang, Y.R.; Li, Z.; Xu, K.; He, X.J.; Wei, S.X.; Cao, Y.M. Hollow SnO2 Nanospheres with Single-Shelled Structure and the Application for Supercapacitors. J. Alloy. Comp. 2019, 779, 728–734. [Google Scholar] [CrossRef]
  31. Bunpang, K.; Wisitsoraat, A.; Tuantranont, A.; Singkammo, S.; Phanichphant, S.; Liewhiran, C. Highly Selective and Sensitive CH4 Gas Sensors Based on Flame-Spray-Made Cr-doped SnO2 Particulate Films. Sens. Actuators B Chem. 2019, 291, 177–191. [Google Scholar] [CrossRef]
  32. Bonu, V.; Das, A.; Prasad, A.K.; Krishna, N.G.; Dhara, S.; Tyagi, A.K. Influence of In-Plane and Bridging Oxygen Vacancies of SnO2 Nanostructures on CH4 Sensing at Low Operating Temperatures. Appl. Phys. Lett. 2014, 105, 245302. [Google Scholar] [CrossRef] [Green Version]
  33. Kooti, M.; Keshtkar, S.; Askarieh, M.; Rashidi, A. Progress toward a Novel Methane Gas Sensor Based on SnO2 Nanorods-Nanoporous Graphene Hybrid. Sens. Actuators B Chem. 2019, 281, 96–106. [Google Scholar] [CrossRef]
  34. Yadav, A.A. Spray Deposition of Tin Oxide Thin Films for Supercapacitor Applications: Effect of Solution Molarity. J. Mater. Sci. Mater. Electron. 2016, 27, 6985–6991. [Google Scholar] [CrossRef]
  35. Ramesh, S.; Yadav, H.M.; Lee, Y.J.; Hong, G.W.; Kathalingam, A.; Sivasamy, A.; Kim, H.S.; Kim, H.S.; Kim, J.H. Porous Materials of Nitrogen Doped Graphene Oxide@SnO2 Electrode for Capable Supercapacitor Application. Sci. Rep. 2019, 9, 12622. [Google Scholar] [CrossRef] [PubMed]
  36. Min, B.K.; Choi, S.D. Undoped and 0.1 wt.% Ca-Doped Pt-Catalyzed SnO2 Sensors for CH4 Detection. Sens. Actuators B Chem. 2005, 108, 119–124. [Google Scholar] [CrossRef]
  37. Wagner, T.; Bauer, M.; Sauerwald, T.; Kohl, C.D.; Tiemann, M. X-ray Absorption Near-Edge Spectroscopy Investigation of the Oxidation State of Pd Species in Nanoporous SnO2 Gas Sensors for Methane Detection. Thin Solid Film. 2011, 520, 909–912. [Google Scholar] [CrossRef]
  38. Hummers, W.S.; Offeman, R.E. Preparation of Graphitic Oxide. J. Am. Chem. Soc. 1958, 80, 1339. [Google Scholar] [CrossRef]
  39. Zhang, H.; Lin, L.Y.; Wu, B.; Hu, N. Vertical Carbon Skeleton Introduced Three-Dimensional MnO2 Nanostructured Composite Electrodes for High-Performance Asymmetric Supercapacitors. J. Power Sources 2020, 476, 228527. [Google Scholar] [CrossRef]
  40. Lin, L.Y.; Liu, T.M.; Zhang, Y.; Liang, X.B.; Wang, Z.C. Enhancing Ethanol Detection by Heterostructural Silver Nanoparticles Decorated Polycrystalline Zinc Oxide Nanosheets. Ceram. Int. 2016, 42, 3138–3144. [Google Scholar] [CrossRef]
  41. Ahuja, P.; Sahu, V.; Ujjain, S.K.; Sharma, R.K.; Singh, G. Performance Evaluation of Asymmetric Supercapacitor Based on Cobalt Manganite Graphene Nanoribbons. Electrochim. Acta 2014, 146, 429–436. [Google Scholar] [CrossRef]
  42. Xing, M.Y.; Zhang, J.L.; Chen, F.; Tian, B.Z. An Economic Method to Prepare Vacuum Activated Photocatalysts with High Photo-Activities and Photosensitivities. Chem. Commun. 2011, 47, 4947–4949. [Google Scholar] [CrossRef] [PubMed]
  43. Epifani, M.; Prades, J.D.; Comini, E.; Pellicer, E.; Avella, M.; Siciliano, P.; Faglia, G.; Cirera, A.; Scotti, R.; Morazzoni, F.; et al. The Role of Surface Oxygen Vacancies in the NO2 Sensing Properties of SnO2 Nanocrystals. J. Phys. Chem. C 2008, 112, 19540–19546. [Google Scholar] [CrossRef]
  44. Yang, Y.J.; Wang, Y.H.; Yin, S. Oxygen Vacancies Confined in SnO2 Nanoparticles for Desirable Electronic Structure and Enhanced Visible Light Photocatalytic Activity. Appl. Surf. Sci. 2017, 420, 399–406. [Google Scholar] [CrossRef]
  45. Wang, R.H.; Jayakumar, A.; Xu, C.H.; Lee, J.M. Ni(OH)2 Nanoflowers/Graphene Hydrogels: A New Assembly for Supercapacitor. Acs Sustain. Chem. Eng. 2016, 4, 3736–3742. [Google Scholar] [CrossRef]
  46. Ray, A.; Roy, A.; Ghosh, M.; Ramos-Ramón, J.A.; Saha, S.; Pal, U.; Bhattacharya, S.K.; Das, S. Study on Charge Storage Mechanism in Working Electrodes Fabricated by Sol-Gel Derived Spinel NiMn2O4 Nanoparticles for Supercapacitor Application. Appl. Surf. Sci. 2019, 463, 513–525. [Google Scholar] [CrossRef]
  47. Xu, Y.X.; Wang, L.; Zhou, Y.F.; Guo, J.Y.; Zhang, S.Y.; Lu, Y. Synthesis of Heterostructure SnO2/Graphitic Carbon Nitride Composite for High-Performance Electrochemical Supercapacitor. J. Eelectroanal. Chem. 2019, 852, 113507. [Google Scholar] [CrossRef]
  48. Stoller, M.D.; Park, S.J.; Zhu, Y.W.; An, J.H.; Ruoff, R.S. Graphene-Based Ultracapacitors. Nano Lett. 2008, 8, 3498–3502. [Google Scholar] [CrossRef]
  49. Lu, W.B.; Ding, D.G.; Xue, Q.Z.; Du, Y.G.; Xiong, Y.; Zhang, J.Q.; Pan, X.L.; Xing, W. Great Enhancement of CH4 Sensitivity of SnO2 Based Banofibers by Heterogeneous Sensitization and Catalytic Effect. Sens. Actuators B Chem. 2018, 254, 393–401. [Google Scholar] [CrossRef]
  50. Navazani, S.; Shokuhfar, A.; Hassanisadi, M.; Askarieh, M.; Carlo, A.D.; Agresti, A. Facile Synthesis of a SnO2@rGO Nanohybrid and Optimization of Its Methane-sensing Parameters. Talanta 2018, 181, 422–430. [Google Scholar] [CrossRef]
  51. Yao, L.J.; Li, Y.X.; Ran, Y.; Yang, Y.; Zhao, R.J.; Su, L.F.; Kong, Y.L.; Ma, D.; Chen, Y.H.; Wang, Y.D. Construction of Novel Pd–SnO2 Composite Nanoporous Structure as a High-Response Sensor for Methane Gas. J. Alloy. Comp. 2020, 826, 154063. [Google Scholar] [CrossRef]
Nanomaterials 11 00372 g001 550
Figure 1. (a) XRD patterns of two samples SnO2 (I) and r-SnO2/GN (II); (b) Raman spectra of two samples SnO2 (I) and r-SnO2/GN (II).
Figure 1. (a) XRD patterns of two samples SnO2 (I) and r-SnO2/GN (II); (b) Raman spectra of two samples SnO2 (I) and r-SnO2/GN (II).
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Nanomaterials 11 00372 g002 550
Figure 2. SEM images of two samples (a,b) SnO2 and (c,d) r-SnO2/GN; (e) EDS mapping including Sn, O, and C elements for r-SnO2/GN.
Figure 2. SEM images of two samples (a,b) SnO2 and (c,d) r-SnO2/GN; (e) EDS mapping including Sn, O, and C elements for r-SnO2/GN.
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Nanomaterials 11 00372 g003 550
Figure 3. TEM images of two samples (a–c) SnO2 and (d–f) r-SnO2/GN.
Figure 3. TEM images of two samples (a–c) SnO2 and (d–f) r-SnO2/GN.
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Nanomaterials 11 00372 g004 550
Figure 4. N2 adsorption/desorption isotherms of two samples (a) SnO2 and (b) r-SnO2/GN; the inset is the pore size distribution.
Figure 4. N2 adsorption/desorption isotherms of two samples (a) SnO2 and (b) r-SnO2/GN; the inset is the pore size distribution.
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Nanomaterials 11 00372 g005 550
Figure 5. XPS of r-SnO2/GN and SnO2 (a) survey, (b) Sn 3 d, (c) C 1 s, and (d) O 1 s.
Figure 5. XPS of r-SnO2/GN and SnO2 (a) survey, (b) Sn 3 d, (c) C 1 s, and (d) O 1 s.
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Nanomaterials 11 00372 g006 550
Figure 6. (a) CV curves of two electrodes measured at a scan rate of 50 mVs−1; (b) GCD curves of two electrodes tested at a current density of 2 mA cm−2; CV curves for electrodes (c) r-SnO2/GN and (e) SnO2 measured at various voltage sweep rates; GCD curves for electrodes (d) r-SnO2/GN and (f) SnO2 measured at various current densities.
Figure 6. (a) CV curves of two electrodes measured at a scan rate of 50 mVs−1; (b) GCD curves of two electrodes tested at a current density of 2 mA cm−2; CV curves for electrodes (c) r-SnO2/GN and (e) SnO2 measured at various voltage sweep rates; GCD curves for electrodes (d) r-SnO2/GN and (f) SnO2 measured at various current densities.
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Figure 7. (a) Specific capacitance as a function of current density; (b) The cycle stability; EIS Nyquist plots and the equivalent circuit model (the inset) for electrodes (c) r-SnO2/GN and (d) SnO2.
Figure 7. (a) Specific capacitance as a function of current density; (b) The cycle stability; EIS Nyquist plots and the equivalent circuit model (the inset) for electrodes (c) r-SnO2/GN and (d) SnO2.
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Nanomaterials 11 00372 g008 550
Figure 8. (a) Two gas sensors toward methane gas of 500 ppm at different working temperatures; (b) A particular response curve of the sensor r-SnO2/GN toward methane gas at 140 °C; (c) The response value of the sensor r-SnO2/GN toward methane gas vs. log(concentration, ppm) and (d) the corresponding response curve; (e) The stability of the sensor r-SnO2/GN toward methane gas at 140 °C; (f) The response value of the sensor r-SnO2/GN toward various gases.
Figure 8. (a) Two gas sensors toward methane gas of 500 ppm at different working temperatures; (b) A particular response curve of the sensor r-SnO2/GN toward methane gas at 140 °C; (c) The response value of the sensor r-SnO2/GN toward methane gas vs. log(concentration, ppm) and (d) the corresponding response curve; (e) The stability of the sensor r-SnO2/GN toward methane gas at 140 °C; (f) The response value of the sensor r-SnO2/GN toward various gases.
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Table
Table 1. The brief summary of electrochemical performance of SnO2-based supercapacitors.
Table 1. The brief summary of electrochemical performance of SnO2-based supercapacitors.
Electrode MaterialsElectrolyteCurrent DensitySpecific Capacitance (F g−1)Ref.
SnO20.5 M Na2SO41 A g−1138[34]
SnO2-NGO6.0 M KOH4 A g−1378[35]
SnO2/g-C3N41.0 M Na2SO41 A g−1488[47]
Hollow SnO21.0 M KOH1 A g−1332.7[30]
r-SnO2-GN3.0 M KOH2 mA cm−2 (0.57 A g−1)947.4This work
Table
Table 2. The brief summary of sensing performance of SnO2-based CH4 sensors.
Table 2. The brief summary of sensing performance of SnO2-based CH4 sensors.
Sensing MaterialsTemperature (°C)CH4 ConcentrationReponsesRef.
Pt-SnO24001000 ppm1.55 b[36]
Pd-SnO24006600 ppm20 b[37]
Pt-SnO23501000 ppm4.5 b[49]
SnO2-rGO1501000 ppm47.6% a[50]
Pd–SnO23403000 ppm17.6 b[51]
r-SnO2-GN1401000 ppm
5000 ppm		16.2 b
20.4 b		This work
aS = (ΔR/Rg) × 100%. b S = Ra/Rg × 100%.
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Lin, L.; Chen, S.; Deng, T.; Zeng, W. Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors. Nanomaterials 2021, 11, 372. https://doi.org/10.3390/nano11020372

AMA Style

Lin L, Chen S, Deng T, Zeng W. Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors. Nanomaterials. 2021; 11(2):372. https://doi.org/10.3390/nano11020372

Chicago/Turabian Style

Lin, Liyang, Susu Chen, Tao Deng, and Wen Zeng. 2021. "Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors" Nanomaterials 11, no. 2: 372. https://doi.org/10.3390/nano11020372

APA Style

Lin, L., Chen, S., Deng, T., & Zeng, W. (2021). Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors. Nanomaterials, 11(2), 372. https://doi.org/10.3390/nano11020372

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