Ionic Liquids for Development of Heterogeneous Catalysts Based on Nanomaterials for Biocatalysis
Abstract
:1. Introduction
2. Stabilization of Enzymes via Ionic Liquids
3. Supported Ionic Liquid Phases in Biocatalysis
4. Contribution of Nanomaterials to Effectiveness of Supported Ionic Liquid Phases
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Type of Technique | Ionic Liquid | Enzyme | Reaction | Ref. |
---|---|---|---|---|
SILC | Imidazolium cation [Cl]− anion | CRL (16 U/mg) 1 | Esters hydrolysis | [13] |
SILC | Imidazolium cation [PF6]− anion | PPL (659.4 U/g) | Triacetin hydrolysis | [14] |
SILC | Imidazolium cation [PF6]− anion | PPL (882.1 U/g) | Triacetin hydrolysis | [15] |
SILC | Ammonium cation [C4H9COO]− anion | BCL (3801 U/g) | Hydrolysis and transesterification of different oils α between 70 and 98% 2 | [16] |
SCIL | Pyridinium cation [PF6]− anion | CALB 3 | Esterification of fatty acids α between 25 and 65% | [17] |
SCIL | Imidazolium cation [PF6]− anion | CALB 3 | Ring-opening polymerization of lactone α = 60% | [18] |
SCIL | Imidazolium cation [NTf2]− anion | CALB 3 | Ring-opening polymerization of lactone Y = 62% 4 | [19] |
SILP | Imidazolium cation [NTf2]− anion | CALB (1.7 U/mg) | Kinetic resolution of 1-phenylethanol via transesterification ee > 99.9% 5 | [24] |
SILP | Imidazolium cation [NTf2]− anion | CALB (71 U/mg) | Transesterification of vinyl butyrate S = 99% 6 | [24] |
SILP | Imidazolium cation [NTf2]− anion | CALB (9.1 U/mg) | Kinetic resolution of 1-phenylethanol via transesterification ee > 99.9% | [25] |
SILP | Imidazolium cation [BF4]− anion | CALB (58 U/mg) | Transesterification of vinyl butyrate α = 96% | [26] |
SILLP | Imidazolium cation [Cl]− anion | CALB (20 U/mg) | Transesterification of vinyl propionate Y = 93% | [27] |
SILLP | Imidazolium cation [NTf2]− anion | CALB (1138.3 U/g) | Kinetic resolution of 1-phenylethanol via transesterification Y = 81%, ee = 94% | [28] |
SILLP | Imidazolium cation [NTf2]− anion | CALB (49.8 U/g) | Triolein transesterification Y = 85% | [29] |
Type | Nanomaterial | Ionic Liquid | Enzyme | Reaction | Ref. |
---|---|---|---|---|---|
SILLP | Chitosan–silica hybrid | Imidazolium [BF4]− | PLL (2482 U/g 1, 132.1 mg/g 2) | Triacetin hydrolysis 35 °C, 10 cycles | [67] |
SILLP | Chitosan–Fe3O4 hybrid | Imidazolium [PF6]− | PPL (2879 U/g, 118 mg/g) | Triacetin hydrolysis 50 °C, 10 cycles | [68] |
SILLP | Fe3O4 | Imidazolium [PF6]− | CRL (132.3 U/g, 639 mg/g) | Oleic acid esterification 30 °C, 5 cycles | [69] |
SILLP | Fe3O4 | Imidazolium [Cl]− | Penicillin G acylase (261 U/g, 209 mg/g) | Penicillin G potassium salts hydrolysis 37 °C, 10 cycles | [70] |
SILLP | Fe3O4–silica hybrid | Imidazolium [Cl]− | CRL | Palm stearin interesterification 45 °C, 4 cycles | [71] |
SILLP | MWCNTs | Imidazolium [PF6]− | CALB (19,354 U/g, 96 mg/g) | Triacetin hydrolysis 60 °C, 4 cycles | [75] |
SILLP | MWCNTs | Imidazolium [PF6]− | CALB (25,350 U/g, 114 mg/g) | Triacetin hydrolysis 60 °C, 4 cycles | [76] |
SILLP | MWCNTs | Imidazolium [PF6]− | CALB (13,636 U/g, 66 mg/g) | Triacetin hydrolysis 60 °C, 4 cycles | [77] |
SILP | MWCNTs | D-glucose based [NTf2]− | CALB (42 mg/g) | Acrylic acid esterification 25 °C, 5 cycles, Y = 99% 3 | [78] |
SILLP | MWCNTs | Imidazolium [Oc2PO4]− | CALB (64 mg/g) | 2-adamantanone oxidation 20 °C, 5 cycles, α = 91% 4 | [79] |
SILP | MWCNTs | Imidazolium [NTf2]− | CALB (22 mg/g) | 2-adamantanone oxidation 20 °C, 4 cycles, α = 99% | [79] |
SILLP | Silica | Imidazolium [BF4]− | PPL (975 U/mg) | Triacetin hydrolysis 36 °C, 5 cycles | [81] |
SILLP | Silica | Imidazolium [BF4]− | PPL (975 U/mg) | Triacetin hydrolysis 35 °C, 5 cycles | [82] |
SILLP | Silica | Imidazolium [BF4]− | BCL (10205 U/g, 230 mg/g) | Triacetin hydrolysis 50 °C, 3 cycles | [83] |
SILLP | Silica | Imidazolium [BF4]− | PPL (720 U/g, 227.5 mg/g) | Triacetin hydrolysis 35 °C, 4 cycles | [84] |
SILLP | Silica | Imidazolium L-lysine | PPL (244 U/g, 197 mg/g) | Triacetin hydrolysis 50 °C, 5 cycles | [85] |
SILLP | Silica | Imidazolium [BF4]− | PPL (392 U/g, 245 mg/g) | Triacetin hydrolysis 50 °C, 5 cycles | [86] |
SILLP | Silica | Imidazolium [BF4]− | PPL (760 U/g, 117 mg/g) | Triacetin hydrolysis 45 °C, 5 cycles | [87] |
SILLP | Silica | Imidazolium [BF4]− | PPL (468 U/g, 186 mg/g) | Triacetin hydrolysis 45 °C, 5 cycles | [88] |
SILLP | Silica | Imidazolium [Cl]− | Papain (0.8 U/mg, 261 mg/g) | L-tyrosine synthesis 50 °C | [89] |
SILLP | Organosilica | Imidazolium [Cl]− | Amylase from Bacillus amyloliquefaciens (29.35 U/mg, 80 mg/g) | Starch hydrolysis 70 °C, 4 cycles | [90] |
SILLP | Silica | Imidazolium [BF4]− | CALB (5044.44 U/g) | Corn oil glycerolysis 50 °C, 5 cycles, α = 70.94% | [91] |
SILP | Silica aerogel | Ammonium [C4H9COO]− | BCL (83% 5) | Olive oil hydrolysis 37 °C, 23 cycles | [92] |
SILP | Silica aerogel | Ammonium [C4H9COO]− | BCL (337 mg/g) | Coconut oil esterification 40 °C, α = 70% | [93] |
SILP | Silica | Phosphonium [NTf2]− | BCL (91.1%) | Olive oil hydrolysis 37 °C, 17 cycles | [94] |
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Wolny, A.; Chrobok, A. Ionic Liquids for Development of Heterogeneous Catalysts Based on Nanomaterials for Biocatalysis. Nanomaterials 2021, 11, 2030. https://doi.org/10.3390/nano11082030
Wolny A, Chrobok A. Ionic Liquids for Development of Heterogeneous Catalysts Based on Nanomaterials for Biocatalysis. Nanomaterials. 2021; 11(8):2030. https://doi.org/10.3390/nano11082030
Chicago/Turabian StyleWolny, Anna, and Anna Chrobok. 2021. "Ionic Liquids for Development of Heterogeneous Catalysts Based on Nanomaterials for Biocatalysis" Nanomaterials 11, no. 8: 2030. https://doi.org/10.3390/nano11082030