Design of Ni(OH)2 Nanosheets@NiMoO4 Nanofibers’ Hierarchical Structure for Asymmetric Supercapacitors
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Synthesis of NiMoO4 Nanofibers
2.3. Synthesis of NiMoO4@Ni(OH)2 Nanofibers
2.4. Characterizations
2.5. Electrochemical Measurements
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Jung, S.; Myung, Y.; Kim, B.N.; Kim, I.G.; You, I.−K.; Kim, T. Activated Biomass−derived Graphene−based Carbons for Supercapacitors with High Energy and Power Density. Sci. Rep. 2018, 8, 1915. [Google Scholar] [CrossRef] [Green Version]
- Yin, Z.; Zhang, S.; Chen, Y.; Gao, P.; Zhu, C.; Yang, P.; Qi, L. Hierarchical nanosheet−based NiMoO4 nanotubes: Synthesis and high supercapacitor performance. J. Mater. Chem. A 2015, 3, 739–745. [Google Scholar] [CrossRef]
- Sahoo, R.; Acharyya, P.; Singh, N.K.; Pal, A.; Negishi, Y.; Pal, T. Advance Aqueous Asymmetric Supercapacitor Based on Large 2D NiCo2O4 Nanostructures and the rGO@Fe3O4 Composite. ACS Omega 2017, 2, 6576–6585. [Google Scholar] [CrossRef] [PubMed]
- He, X.; Li, R.; Liu, J.; Liu, Q.; Chen, R.; Song, D.; Wang, J. Hierarchical FeCo2O4@NiCo layered double hydroxide core/shell nanowires for high performance flexible all−solid−state asymmetric supercapacitors. Chem. Eng. J. 2018, 334, 1573–1583. [Google Scholar] [CrossRef]
- Zhang, Y.; Chang, C.-r.; Gao, H.-l.; Wang, S.-w.; Yan, J.; Gao, K.-z.; Jia, X.-d.; Luo, H.-w.; Fang, H.; Zhang, A.-q.; et al. High−performance supercapacitor electrodes based on NiMoO4 nanorods. J. Mater. Res. 2019, 34, 2435–2444. [Google Scholar] [CrossRef]
- Ding, X.; Liu, J.; Cang, R.; Chang, X.; Zhang, M. Electrospun Hollow Carbon Nanofibers Decorated with CuCo2O4 Nanowires for Oxygen Evolution Reaction. Catalysts 2022, 12, 851. [Google Scholar] [CrossRef]
- Guo, X.; Yu, M.; Chang, X.; Ma, X.; Zhang, M. Cobalt Sulfide Nanoparticles Encapsulated in Carbon NanotubeGrafted Carbon Nanofibers as Catalysts for Oxygen Evolution. ACS Appl. Nano Mater. 2022. [Google Scholar] [CrossRef]
- Yang, B.; Chang, X.; Ding, X.; Ma, X.; Zhang, M. One−dimensional Ni2P/Mn2O3 nanostructures with enhanced oxygen evolution reaction activity. J. Colloid Interface Sci. 2022, 623, 196–204. [Google Scholar] [CrossRef] [PubMed]
- Yu, M.; Guo, X.; Chang, X.; Ma, X.; Zhang, M. Assembled cobalt phosphide nanoparticles on carbon nanofibers as a bifunctional catalyst for hydrogen evolution reaction and oxygen evolution reaction. Sustain. Energy Fuels 2022, 6, 5000–5007. [Google Scholar] [CrossRef]
- Chang, X.; Yang, B.; Ding, X.; Ma, X.; Zhang, M. One−dimensional CoP/MnO hollow nanostructures with enhanced oxygen evolution reaction activity. J. Colloid Interface Sci. 2022, 610, 663–670. [Google Scholar] [CrossRef] [PubMed]
- Cheng, J.P.; Zhang, J.; Liu, F. Recent development of metal hydroxides as electrode material of electrochemical capacitors. RSC Adv. 2014, 4, 38893–38917. [Google Scholar] [CrossRef]
- Xing, H.; Lan, Y.; Zong, Y.; Sun, Y.; Zhu, X.; Li, X.; Zheng, X. Ultrathin NiCo−layered double hydroxide nanosheets arrays vertically grown on Ni foam as binder−free high−performance supercapacitors. Inorg. Chem. Commun. 2019, 101, 125–129. [Google Scholar] [CrossRef]
- Zhang, Y.; Ma, W.; Wang, T.; Guo, J.; Zhang, T.; Yang, D.a. Fabrication coralline Ni−Mo−O−S composites as advanced electrodes for high−performance asymmetric hybrid supercapacitors. J. Energy Storage 2021, 35, 102234. [Google Scholar] [CrossRef]
- Zhang, X.; Xu, Y. The fabrication of hierarchical NiMoO4@Ni(OH)2 nanocomposites and its electrochemical behavior used as supercapacitor electrode. Inorg. Chem. Commun. 2018, 87, 8–11. [Google Scholar] [CrossRef]
- Liao, S.; Lu, S.; Bao, S.; Yu, Y.; Wang, M. NiMoO4 nanofibres designed by electrospining technique for glucose electrocatalytic oxidation. Anal. Chim. Acta 2016, 905, 72–78. [Google Scholar] [CrossRef] [PubMed]
- Pu, J.; Zhang, L.; Li, J.; Wang, Z. In−situ formation of atomic−level Mn−Sn interfacial compounds for enhanced Li−ion integrated anode. Appl. Surf. Sci. 2020, 508, 145243. [Google Scholar] [CrossRef]
- Li, M.; Luo, Y.; Jia, C.; Zhang, Q.; Luo, G.; Zhao, L.; Boukherroub, R.; Jiang, Z. Facile Synthesis of Bimetal Nickel Cobalt Phosphate Nanostructures for High−Performance Hybrid Supercapacitors. J. Alloys Compd. 2022, 893, 162340. [Google Scholar] [CrossRef]
- Qiu, H.; An, S.; Sun, X.; Yang, H.; Zhang, Y.; He, W. MWCNTs−GONRs/Co3O4@Ni(OH)2 core−shell array structure with a high performance electrode for supercapacitor. Chem. Eng. J. 2020, 380, 122490. [Google Scholar] [CrossRef]
- Li, S.; Yu, C.; Yang, J.; Zhao, C.; Zhang, M.; Huang, H.; Liu, Z.; Guo, W.; Qiu, J. A superhydrophilic “nanoglue” for stabilizing metal hydroxides onto carbon materials for high−energy and ultralong−life asymmetric supercapacitors. Energy Environ. Sci. 2017, 10, 1958–1965. [Google Scholar] [CrossRef]
- Jing, C.; Liu, X.; Liu, X.; Jiang, D.; Dong, B.; Dong, F.; Wang, J.; Li, N.; Lan, T.; Zhang, Y. Crystal morphology evolution of Ni–Co layered double hydroxide nanostructure towards high−performance biotemplate asymmetric supercapacitors. CrystEngComm 2018, 20, 7428–7434. [Google Scholar] [CrossRef]
- Wang, D.; Guan, B.; Li, Y.; Li, D.; Xu, Z.; Hu, Y.; Wang, Y.; Zhang, H. Morphology−controlled synthesis of hierarchical mesoporous α−Ni(OH)2 microspheres for high−performance asymmetric supercapacitors. J. Alloys Compd. 2018, 737, 238–247. [Google Scholar] [CrossRef]
- Dong, G.; Fan, H.; Fu, K.; Ma, L.; Zhang, S.; Zhang, M.; Ma, J.; Wang, W. The evaluation of super−capacitive performance of novel g−C3N4/PPy nanocomposite electrode material with sandwich−like structure. Compos. B. Eng. 2019, 162, 369–377. [Google Scholar] [CrossRef]
- Brousse, T.; Bélanger, D.; Long, J.W. To Be or Not To Be Pseudocapacitive? J. Electrochem. Soc. 2015, 162, A5185–A5189. [Google Scholar] [CrossRef] [Green Version]
- Peng, H.; Jing, C.; Chen, J.; Jiang, D.; Liu, X.; Dong, B.; Dong, F.; Li, S.; Zhang, Y. Crystal structure of nickel manganese−layered double hydroxide@cobaltosic oxides on nickel foam towards high−performance supercapacitors. CrystEngComm 2019, 21, 470–477. [Google Scholar] [CrossRef]
- Qiu, H.; An, S.; Sun, X.; Yang, H.; Zhang, Y.; He, W. Excellent performance MWCNTs−GONRs/Ni(OH)2 electrode for outstanding supercapacitors. Ceram. Int. 2019, 45, 18422–18429. [Google Scholar] [CrossRef]
- Zhang, M.; Fan, H.; Zhao, N.; Peng, H.; Ren, X.; Wang, W.; Li, H.; Chen, G.; Zhu, Y.; Jiang, X.; et al. 3D hierarchical CoWO4/Co3O4 nanowire arrays for asymmetric supercapacitors with high energy density. Chem. Eng. J. 2018, 347, 291–300. [Google Scholar] [CrossRef]
- Raymundo−Piñero, E.; Leroux, F.; Béguin, F. A High−Performance Carbon for Supercapacitors Obtained by Carbonization of a Seaweed Biopolymer. Adv. Mater. 2006, 18, 1877–1882. [Google Scholar] [CrossRef]
- Peng, S.; Li, L.; Wu, H.B.; Madhavi, S.; Lou, X.W. Controlled Growth of NiMoO4 Nanosheet and Nanorod Arrays on Various Conductive Substrates as Advanced Electrodes for Asymmetric Supercapacitors. Adv. Energy Mater. 2015, 5, 1401172. [Google Scholar] [CrossRef]
- Yun, H.; Zhou, X.; Zhu, H.; Zhang, M. One−dimensional zinc−manganate oxide hollow nanostructures with enhanced supercapacitor performance. J. Colloid Interface Sci. 2021, 585, 138–147. [Google Scholar] [CrossRef]
- Thommes, M.; Kaneko, K.; Neimark, A.V.; Olivier, J.P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K.S.W. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 2015, 87, 1051–1069. [Google Scholar] [CrossRef]
- Li, X.-P.; Zheng, L.-R.; Liu, S.-J.; Ouyang, T.; Ye, S.; Liu, Z.-Q. Heterostructures of NiFe LDH hierarchically assembled on MoS2 nanosheets as high−efficiency electrocatalysts for overall water splitting. Chin. Chem. Lett. 2022, 33, 4761–4765. [Google Scholar] [CrossRef]
- Geng, B.; Yan, F.; Liu, L.; Zhu, C.; Li, B.; Chen, Y. Ni/MoC heteronanoparticles encapsulated within nitrogen−doped carbon nanotube arrays as highly efficient self−supported electrodes for overall water splitting. Chem. Eng. J. 2021, 406, 126815. [Google Scholar] [CrossRef]
- Zhang, F.; Wang, L.; Park, M.; Song, K.−Y.; Choi, H.; Shi, H.; Lee, H.-J.; Pang, H. Nickel sulfide nanorods decorated on graphene as advanced hydrogen evolution electrocatalysts in acidic and alkaline media. J. Colloid Interface Sci. 2022, 608, 2633–2640. [Google Scholar] [CrossRef] [PubMed]
- Wang, Y.; Yin, Z.; Yan, G.; Wang, Z.; Li, X.; Guo, H.; Wang, J. New insight into the electrodeposition of NiCo layered double hydroxide and its capacitive evaluation. Electrochim. Acta 2020, 336, 135734. [Google Scholar] [CrossRef]
- Xiong, S.; Weng, S.; Tang, Y.; Qian, L.; Xu, Y.; Li, X.; Lin, H.; Xu, Y.; Jiao, Y.; Chen, J. Mo−doped Co3O4 ultrathin nanosheet arrays anchored on nickel foam as a bi−functional electrode for supercapacitor and overall water splitting. J. Colloid Interface Sci. 2021, 602, 355–366. [Google Scholar] [CrossRef]
- Xiong, S.; Wang, L.; Chai, H.; Xu, Y.; Jiao, Y.; Chen, J. Molybdenum doped induced amorphous phase in cobalt acid nickel for supercapacitor and oxygen evolution reaction. J. Colloid Interface Sci. 2022, 606, 1695–1706. [Google Scholar] [CrossRef]
- Zhuang, L.; Ge, L.; Yang, Y.; Li, M.; Jia, Y.; Yao, X.; Zhu, Z. Ultrathin Iron−Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction. Adv. Mater. 2017, 29, 1606793. [Google Scholar] [CrossRef]
- Natarajan, S.; Anantharaj, S.; Tayade, R.J.; Bajaj, H.C.; Kundu, S. Recovered spinel MnCo2O4 from spent lithium−ion batteries for enhanced electrocatalytic oxygen evolution in alkaline medium. Dalton Trans. 2017, 46, 14382–14392. [Google Scholar] [CrossRef] [PubMed]
- Li, S.; Cai, M.; Liu, Y.; Wang, C.; Yan, R.; Chen, X. Constructing Cd0.5Zn0.5S/Bi2WO6 S−scheme heterojunction for boosted photocatalytic antibiotic oxidation and Cr(VI) reduction. Adv. Powder Mater. 2023, 2, 100073. [Google Scholar] [CrossRef]
- Yan, J.; Fan, Z.; Sun, W.; Ning, G.; Wei, T.; Zhang, Q.; Zhang, R.; Zhi, L.; Wei, F. Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density. Adv. Funct. Mater. 2012, 22, 2632–2641. [Google Scholar] [CrossRef]
- Mai, L.-Q.; Yang, F.; Zhao, Y.-L.; Xu, X.; Xu, L.; Luo, Y.-Z. Hierarchical MnMoO4/CoMoO4 heterostructured nanowires with enhanced supercapacitor performance. Nat. Commun. 2011, 2, 381. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Liang, K.; Tang, X.; Hu, W. High−performance three−dimensional nanoporous NiO film as a supercapacitor electrode. J. Mater. Chem. 2012, 22, 11062–11067. [Google Scholar] [CrossRef]
- Zeng, Y.; Lai, Z.; Han, Y.; Zhang, H.; Xie, S.; Lu, X. Oxygen−Vacancy and Surface Modulation of Ultrathin Nickel Cobaltite Nanosheets as a High−Energy Cathode for Advanced Zn−Ion Batteries. Adv. Mater. 2018, 30, 1802396. [Google Scholar] [CrossRef] [PubMed]
- Qing, C.; Yang, C.; Chen, M.; Li, W.; Wang, S.; Tang, Y. Design of oxygen−deficient NiMoO4 nanoflake and nanorod arrays with enhanced supercapacitive performance. Chem. Eng. J. 2018, 354, 182–190. [Google Scholar] [CrossRef]
- Zhang, Y.; Chang, C.-r.; Jia, X.-d.; Huo, Q.-y.; Gao, H.-l.; Yan, J.; Zhang, A.-q.; Ru, Y.; Mei, H.-x.; Gao, K.-z.; et al. Morphology−dependent NiMoO4/carbon composites for high performance Supercapacitors. Inorg. Chem. Commun. 2020, 111, 107631. [Google Scholar] [CrossRef]
- Arshadi Rastabi, S.; Sarraf-Mamoory, R.; Razaz, G.; Blomquist, N.; Hummelgard, M.; Olin, H. Treatment of NiMoO4/nanographite nanocomposite electrodes using flexible graphite substrate for aqueous hybrid supercapacitors. PLoS ONE 2021, 16, 0254023. [Google Scholar] [CrossRef]
- Han, X.; Yang, Y.; Zhou, J.-J.; Ma, Q.; Tao, K.; Han, L. Metal−organic framework−templated 3D hierarchical ZnCo2O4@Ni(OH)2 core−shell nanosheet arrays for high−performance supercapacitor. Chem. A Eur. J. 2018, 24, 18106–18114. [Google Scholar] [CrossRef]
- Wang, X.; Rong, F.; Huang, F.; He, P.; Yang, Y.; Tang, J.; Que, R. Facile synthesis of hierarchical CoMoO4@Ni(OH)2 core−shell nanotubes for bifunctional supercapacitors and oxygen electrocatalysts. J. Alloys Compd. 2019, 789, 684–692. [Google Scholar] [CrossRef]
- Li, H.; Liu, A.; Che, H. Synthesis of hierarchical Cu2O octahedra@Ni(OH)2 nanosheets core−shell heterostructures for high−performance supercapacitor. Mater. Sci. Semicon. Process. 2019, 91, 115–123. [Google Scholar] [CrossRef]
- Xue, Z.; Tao, K.; Han, L. Stringing metal–organic framework−derived hollow Co3S4 nanopolyhedra on V2O5 nanowires for high−performance supercapacitors. Appl. Surf. Sci. 2022, 600, 154076. [Google Scholar] [CrossRef]
- Chen, Y.B.; You, J.J.; Chen, Y.H.; Ma, L.A.; Chen, H.X.; Wei, Z.H.; Ye, X.Y.; Zhang, L. Low−crystalline nickel hydroxide nanosheets embedded with NiMoO4 nanoparticles on nickel foam for high−performance supercapacitor applications. CrystEngComm 2022, 24, 5238–5250. [Google Scholar] [CrossRef]
- Wei, X.; Li, Y.; Peng, H.; Zhou, M.; Ou, Y.; Yang, Y.; Zhang, Y.; Xiao, P. Metal−organic framework−derived hollow CoS nanobox for high performance electrochemical energy storage. Chem. Eng. J. 2018, 341, 618–627. [Google Scholar] [CrossRef]
- Liu, K.; Zhang, W.; Tang, M.; Wang, Z.; Yang, Y.; Li, S.; Long, H. NiCo2O4 nanosheet stereostructure with N−doped carbon/Co array supports derived from Co−MOF for asymmetric supercapacitor. J. Electroanal. Chem. 2022, 923, 116818. [Google Scholar] [CrossRef]
- Chen, T.; Shi, R.; Zhang, Y.; Wang, Z. A MnCo2O4@NiMoO4 Core−Shell Composite Supported on Nickel Foam as a Supercapacitor Electrode for Energy Storage. ChemPlusChem 2019, 84, 69–77. [Google Scholar] [CrossRef]
- Qu, R.; Tang, S.; Qin, X.; Yuan, J.; Deng, Y.; Wu, L.; Li, J.; Wei, Z. Expanded graphite supported Ni(OH)2 composites for high performance Supercapacitors. J. Alloys Compd. 2017, 728, 222–230. [Google Scholar] [CrossRef]
Element | Atomic % | |||
---|---|---|---|---|
NMO | NMH−1 | NMH−2 | NMH−3 | |
O | 72.75 | 77.40 | 72.30 | 64.28 |
Ni | 12.03 | 12.12 | 15.24 | 18.92 |
Mo | 15.22 | 10.48 | 12.46 | 16.80 |
Supercapacitor | Specific Capacitance | Electrolyte | Ref. |
---|---|---|---|
NiMoO4 nanorods | 815 F/g | 3 M KOH | [5] |
NiMoO4/rGO | 706 F/g | 3 M KOH | [45] |
NiMoO4/NG | 441 F/g | 1 M KOH | [46] |
ZnCo2O4@Ni(OH)2 | 1021 F/g | 3 M KOH | [47] |
CoMoO4@Ni(OH)2 | 1246 F/g | 3 M KOH | [48] |
Cu2O@Ni(OH)2 | 892 F/g | 6 M KOH | [49] |
This work | 1293 F/g | 2 M KOH |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Li, J.; Chang, X.; Zhou, X.; Zhang, M. Design of Ni(OH)2 Nanosheets@NiMoO4 Nanofibers’ Hierarchical Structure for Asymmetric Supercapacitors. Nanomaterials 2022, 12, 4079. https://doi.org/10.3390/nano12224079
Li J, Chang X, Zhou X, Zhang M. Design of Ni(OH)2 Nanosheets@NiMoO4 Nanofibers’ Hierarchical Structure for Asymmetric Supercapacitors. Nanomaterials. 2022; 12(22):4079. https://doi.org/10.3390/nano12224079
Chicago/Turabian StyleLi, Junzhu, Xin Chang, Xuejiao Zhou, and Mingyi Zhang. 2022. "Design of Ni(OH)2 Nanosheets@NiMoO4 Nanofibers’ Hierarchical Structure for Asymmetric Supercapacitors" Nanomaterials 12, no. 22: 4079. https://doi.org/10.3390/nano12224079