Multifunctionalized Mesostructured Silica Nanoparticles Containing Mn2 Complex for Improved Catalase-Mimicking Activity in Water
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthsis of the Mesoporous Silica Nanoparticles
2.2. Encapsulation of the Dinuclear Manganese Complex
2.3. Nanoparticle’s Characterization
2.4. Resistance to Protein-Induced Aggregation and Colloidal Stability
2.5. Catalytic Tests
3. Results and Discussion
3.1. Synthesis and Characterisations
3.2. H2O2 Catalytic Dismutation Reaction
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Abbreviations
References
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Sample | TEOS | 1,4-pyr | SBS |
---|---|---|---|
MSN | 1 | 0 | 0 |
MSN-1a | 0.99 | 0.01 | 0 |
MSN-1b | 0.95 | 0.05 | 0 |
MSN-1c | 0.9 | 0.1 | 0 |
MSN-2 | 1 | 0 | 0.04 |
MSN-3a | 0.99 | 0.01 | 0.04 |
MSN-3b | 0.95 | 0.05 | 0.04 |
MSN-3c | 0.9 | 0.1 | 0.04 |
Sample | Composition b | M (g mol−1) | SBET (m2 g−1) | Pore Size (nm) | dTEM (nm) |
---|---|---|---|---|---|
MSNa | (SiO2)1(CTA)0.005 | 62.7 | 547 | 19.4 | 100.4 ± 10.8 |
MSN-1a | (SiO2)1(CTA)0.005(1,4-pyr)0.008 | 63.2 | 480 | 12.6 | 79.3 ± 8.4 |
MSN-1b | (SiO2)1(CTA)0.006(1,4-pyr)0.047 | 72.2 | 442 | 7.7 | 63.8 ± 5.7 |
MSN-1c | (SiO2)1(CTA)0.007(1,4-pyr)0.090 | 82.1 | 407 | - | 63.7 ± 6.3 |
MSN-2a | (SiO2)1(CTA)0.005 (SBS)0.030 | 70.8 | 480 | 17.1 | 102.9 ± 13.2 |
MSN-3a | (SiO2)1(CTA)0.005(1,4-pyr)0.017(SBS)0.030 | 74.5 | 360 | 14.5 | 81.3 ± 1.8 |
MSN-3b | (SiO2)1(CTA)0.001(1,4-pyr)0.048(SBS)0.028 | 79.7 | 423 | 7.6 | 66.8 ± 5.7 |
MSN-3c | (SiO2)1(CTA)0.002(1,4-pyr)0.096(SBS)0.027 | 90.1 | 400 | - | 72.7 ± 6.3 |
MSN-4a | (SiO2)1(CTA)0.001(1,4-pyr)0.096(SBS)0.027(Mn-cat)0.0096 | 98.4 | 235 | - | 72.5 ± 5.8 |
MSN-4b | (SiO2)1(CTA)0.001(1,4-pyr)0.096(SBS)0.027(Mn-cat)0.048 | 136.1 | 166 | - | 71.1 ± 5.4 |
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Pelluau, T.; Sene, S.; Garcia-Cirera, B.; Albela, B.; Bonneviot, L.; Larionova, J.; Guari, Y. Multifunctionalized Mesostructured Silica Nanoparticles Containing Mn2 Complex for Improved Catalase-Mimicking Activity in Water. Nanomaterials 2022, 12, 1136. https://doi.org/10.3390/nano12071136
Pelluau T, Sene S, Garcia-Cirera B, Albela B, Bonneviot L, Larionova J, Guari Y. Multifunctionalized Mesostructured Silica Nanoparticles Containing Mn2 Complex for Improved Catalase-Mimicking Activity in Water. Nanomaterials. 2022; 12(7):1136. https://doi.org/10.3390/nano12071136
Chicago/Turabian StylePelluau, Tristan, Saad Sene, Beltzane Garcia-Cirera, Belen Albela, Laurent Bonneviot, Joulia Larionova, and Yannick Guari. 2022. "Multifunctionalized Mesostructured Silica Nanoparticles Containing Mn2 Complex for Improved Catalase-Mimicking Activity in Water" Nanomaterials 12, no. 7: 1136. https://doi.org/10.3390/nano12071136