Unbiased and Signal-Weakening Photoelectrochemical Hexavalent Chromium Sensing via a CuO Film Photocathode
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Reagents
2.2. Preparation of the CuO Film Photoelectrode
2.3. Material Characterizations
2.4. Photoelectrochemical Measurements
3. Results and Discussion
Sensing Component | Test Conditions | Sensitivity (µA μM−1) | Linear Range (µM) | LOD (µM) | Method | Ref. |
---|---|---|---|---|---|---|
FTO/TiO2/Au NPs photoanode | −0.2 V b Simulated sunlight | 11.88 | 0.01–100 | 0.004 | PEC Signal enhancing | [18] |
Bi/BiPO4/BiOI photocathode | −0.2 V b Visible light | 0.315 0.111 | 0.5–10 10–180 | 0.3 | PEC Signal enhancing | [19] |
FTO/TiO2 NRs/Au NPs photoanode | −0.2 V b Simulated sunlight | 13.94 | 0.01–50 | 0.006 | PEC Signal enhancing | [31] |
BiOI/CN photoanode | 0.3 V b Visible light | 0.0027 0.0003 | 0.5–15 15–190 | 0.1 | PEC Signal enhancing | [32] |
ITO/MoS2/BiOI photocathode | 0 V b Visible light | 0.3174 0.0388 | 0.05–10 10–160 | 0.01 | PEC Signal enhancing | [33] |
Ti/TiO2 NTA/NiCoLDHs photoanode | 0 V a UV light | 2.15 lgC 6.50 lgC 1.10 lgC | 0.5–20 20–40 400–1800 | 0.12 | PEC Signal weakening | [38] |
BiVO4 photoanode | 0.4 V Visible light | 0.123 logC | 2–10 | 0.01 | PEC Signal enhancing | [39] |
Ti/TiO2 NTs/Au NPs electrode | 0.28 V a | 6.91 | 0.1–105 | 0.03 | EC | [40] |
GCE/Ag film electrode | 0.59 V a | 1.590 | 0.35–40 | 0.1 | EC | [41] |
MWCNTs/Au NPs electrode | 0.52 V b | 0.28 | 0.8–230 | 0.72 | EC | [42] |
FTO/CuO film photocathode | Rel 0 V b Simulated sunlight | 4.22 | 0.08–2 | 0.0028 | PEC Signal weakening | This work |
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Testing Time (min) | Immersion Time (min) | Cr(VI) Concentration (µM) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
40 | 60 | 80 | 0 | 20 | 40 | 0.08 | 0.16 | 0.8 | 4 | 12 | 16 | ||
Rs (Ω) | 47.58 | 46.95 | 47.55 | 55.16 | 47.6 | 50.25 | 53.04 | 47.89 | 49.7 | 51.9 | 52.86 | 50.51 | |
Rct (Ω) | 55.46 | 134.6 | 277.4 | 85.81 | 109.5 | 156.1 | 92.74 | 131.8 | 136.2 | 206.4 | 968.5 | 1917 |
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Lu, W.; Ma, L.; Ke, S.; Zhang, R.; Zhu, W.; Qin, L.; Wu, S. Unbiased and Signal-Weakening Photoelectrochemical Hexavalent Chromium Sensing via a CuO Film Photocathode. Nanomaterials 2023, 13, 1479. https://doi.org/10.3390/nano13091479
Lu W, Ma L, Ke S, Zhang R, Zhu W, Qin L, Wu S. Unbiased and Signal-Weakening Photoelectrochemical Hexavalent Chromium Sensing via a CuO Film Photocathode. Nanomaterials. 2023; 13(9):1479. https://doi.org/10.3390/nano13091479
Chicago/Turabian StyleLu, Wenxiang, Lu Ma, Shengchen Ke, Rouxi Zhang, Weijian Zhu, Linling Qin, and Shaolong Wu. 2023. "Unbiased and Signal-Weakening Photoelectrochemical Hexavalent Chromium Sensing via a CuO Film Photocathode" Nanomaterials 13, no. 9: 1479. https://doi.org/10.3390/nano13091479