Advances in Single-Chain Nanoparticles for Catalysis Applications
Abstract
:1. Introduction
2. Single-Chain Nanoparticles as Bioinspired Nanoreactors/Nanocontainers
2.1. Synthesis of Nanomaterials
2.2. Synthesis of Polymers
2.3. Synthesis of Chemical Compounds
2.4. CO2 Capture and Release
3. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Catalyst Type | c 1 | Mn (kDa) 2 | Ð 3 | Ieff (%) 4 | Reference |
---|---|---|---|---|---|
Laccase | 0.87 | 36.2 | 1.8 | 36 | [37] |
SCNPs | 0.97 | 60.9 | 1.1 | 24 | [18] |
Catalyst Type | c | Mn (kDa) | Ð | Ieff (%) | Reference |
---|---|---|---|---|---|
Hemoglobin | 0.73 | 200 | 2.2 | 3.2 | [39] |
SCNPs | 0.63 | 50.7 | 1.8 | 6.4 | [18] |
Reaction type 1 | Solvent 2 | T (°C) 3 | t (h) | c (%) 4 | TOF (h−1) 5 | Reference |
---|---|---|---|---|---|---|
Imprinted particle | ||||||
Carbonate hydrolysis | H2O/MeCN | 10 | - | - | 4.4 × 10−3 | [26] |
Hydrophobic cavity | ||||||
Hydrogenation of ketones | H2O | 40 | 50 | 98 | 20 | [28] |
Oxidation of secondary alcohols | H2O | r.t. | 7 × 10−2 | >99 | 600 | [48] |
Aldol reaction | H2O | 25 | 24 | 99 | 8 | [49] |
CuAAC | PBS | r.t. | 0.2 | >99 | 13 | [50] |
Mono-depropargylation reaction | PBS | r.t. | 5 | >99 | 0.2 | [50] |
Bis-depropargylation reaction | PBS | r.t. | 25 | >99 | 0.04 | [50] |
Benzoin condensation reaction | THF | 80 | 24 | 65 | 0.3 | [51] |
Enantioselective sulfoxidation | H2O | 25 | 1 | 99 | 198 | [52] |
Concurrent binding/folding | ||||||
Reduction of α-diketones | CH2Cl2 | r.t. | 0.1 | 96 | 5580 | [30] |
Alkyne dimerization | Bulk | 60 | 8 | >98 | 25 | [14] |
Reduction of secondary amines | THF | r.t. | 16 | >99 | 0.6 | [53] |
Allylation of benzophenone | THF | 35 | 24 | 97 | 8 | [53] |
Biphenyl formation | THF | 80 | 16 | >99 | 0.2 | [53] |
Sonogashira coupling | HN(C2H5)2 | r.t. | 24 | 45 | 21 | [54] |
CuAAC | H2O | 50 | 24 | >99 | 16,667 | [13] |
Photoreduction of CO2 | DMF | 80 | 1.5 | - | 2529 | [55] |
Amination of allyl alcohol | C6D6 | 100 | 24 | 99 | 16 | [56] |
Hydroxylation of phenol | H2O | 60 | 1 | 28 | 872 | [31] |
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Rubio-Cervilla, J.; González, E.; Pomposo, J.A. Advances in Single-Chain Nanoparticles for Catalysis Applications. Nanomaterials 2017, 7, 341. https://doi.org/10.3390/nano7100341
Rubio-Cervilla J, González E, Pomposo JA. Advances in Single-Chain Nanoparticles for Catalysis Applications. Nanomaterials. 2017; 7(10):341. https://doi.org/10.3390/nano7100341
Chicago/Turabian StyleRubio-Cervilla, Jon, Edurne González, and José A. Pomposo. 2017. "Advances in Single-Chain Nanoparticles for Catalysis Applications" Nanomaterials 7, no. 10: 341. https://doi.org/10.3390/nano7100341