Influence of VO2 Nanoparticle Morphology on the Colorimetric Assay of H2O2 and Glucose
Abstract
:1. Introduction
2. Results and Discussions
2.1. Characterization of VO2 Nanoparticles
2.2. Principle
2.3. Effect of pH
2.4. Effect of Buffers
2.5. Effect of VO2 Nanoparticle Morphologies and Concentrations
2.6. Steady-State Kinetic Assay
2.7. Calibration Curve for H2O2 and Glucose Detection
3. Materials and Methods
3.1. Chemicals and Materials
3.2. Synthesis of VO2 Nanoparticles
3.3. Physical Characterization
3.4. H2O2 Detection Using VO2 Nanoparticles as Peroxidase Mimetics
3.5. Glucose Detection Using VO2 Nanoparticles
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Nanozymes | Substrate | KM (mM) | Vmax (M·S−1) |
---|---|---|---|
VO2 nanofibers | TMB | 0.518 | 9.3 × 10−5 |
VO2 nanofibers | H2O2 | 1.043 | 4.66 × 10−4 |
VO2 nanosheets | TMB | 0.111 | 1.68 × 10−4 |
VO2 nanosheets | H2O2 | 2.924 | 9.73 × 10−4 |
VO2 nanorods | TMB | 0.801 | 3.99 × 10−4 |
VO2 nanorods | H2O2 | 6.469 | 1.46 × 10−3 |
V2O5 nanozymes | TMB | 0.738 | 1.85 × 10−5 |
V2O5 nanozymes | H2O2 | 0.232 | 1.29 × 10−5 |
Fe3O4 MNPS | TMB | 0.434 | 10.00 × 10−8 |
Fe3O4 MNPS | H2O2 | 154 | 9.78 × 10−8 |
HRP | TMB | 0.434 | 1.24 × 10−8 |
HRP | H2O2 | 3.70 | 2.46 × 10−8 |
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Tian, R.; Sun, J.; Qi, Y.; Zhang, B.; Guo, S.; Zhao, M. Influence of VO2 Nanoparticle Morphology on the Colorimetric Assay of H2O2 and Glucose. Nanomaterials 2017, 7, 347. https://doi.org/10.3390/nano7110347
Tian R, Sun J, Qi Y, Zhang B, Guo S, Zhao M. Influence of VO2 Nanoparticle Morphology on the Colorimetric Assay of H2O2 and Glucose. Nanomaterials. 2017; 7(11):347. https://doi.org/10.3390/nano7110347
Chicago/Turabian StyleTian, Rui, Jiaheng Sun, Yanfei Qi, Boyu Zhang, Shuanli Guo, and Mingming Zhao. 2017. "Influence of VO2 Nanoparticle Morphology on the Colorimetric Assay of H2O2 and Glucose" Nanomaterials 7, no. 11: 347. https://doi.org/10.3390/nano7110347