Surface Coating for Flame Retardancy and Pyrolysis Behavior of Polyester Fabric Based on Calcium Alginate Nanocomposites
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Calcium Alginate/Nano-Calcium Borate Composites Coated Polyester Fabric
2.3. Measurements and Characterizations
2.3.1. Tensile Strength and Elongation
2.3.2. Scanning Electron Microscopy (SEM)
2.3.3. Fourier Transform Infrared (FTIR)
2.3.4. Limiting Oxygen Index (LOI)
2.3.5. Vertical Burning Rate (UL-94)
2.3.6. Cone Calorimeter (CONE)
2.3.7. Thermogravimetric Analysis (TGA)
2.3.8. Pyrolysis-Gas Chromatograpgy-Mass Spectrometry (Py-GC-MS)
3. Results and Discussion
3.1. Tensile Strength and Elongation
3.2. SEM
3.3. FTIR Analysis
3.4. Flame Retardancy and Combustion Behavior of the CAB-PL and PL
3.4.1. LOI
3.4.2. UL-94
3.4.3. CONE
3.4.4. TGA and Differential Thermogravimetry (DTG)
3.5. Py-GC-MS
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Samples | Tensile Strengh (N) | Elongation at Break (%) | LOI (%) | PHRR (Kw/m2) | TSR (MJ/m2) |
---|---|---|---|---|---|
CAB-PL | 592 | 26.9 | 34 | 6.8 | 86 |
PL | 518 | 26.2 | 25 | 11.8 | 757 |
Samples | CAB-PL | PL | ||
---|---|---|---|---|
Print cloth | | | | |
After flame time (s) | 0 | 3.9 | ||
After glow time (s) | 0 | 0 | ||
Dripping | No | Yes | ||
Rate | V-0 | N.R |
S.N. | Molecular Structure | Name of Compound | Time | Area |
---|---|---|---|---|
1 | | carbon dioxide | 1.55 | 3.05 |
2 | | 2,3-butanedione | 1.62 | 3.94 |
3 | | 1,5-hexadiyne | 2.85 | 4.78 |
4 | | 2-hexen-4-yne | 2.91 | 14.56 |
5 | | methylbenzene | 4.32 | 3.17 |
6 | | 1,3-dimethylbenzen | 5.99 | 3.10 |
7 | | phenylpropiolic acid | 6.26 | 0.39 |
8 | | annulene | 6.59 | 7.90 |
9 | | benzaldehyde | 7.87 | 7.68 |
10 | | indene | 9.31 | 0.72 |
11 | | 2-methylbenzyl alcohol | 9.84 | 21.90 |
12 | | 1,3-isobenzofurandione | 9.89 | 5.60 |
13 | | 1-(4-methylphenyl)- acetophenone | 11.63 | 0.65 |
14 | | naphthalene | 11.68 | 0.57 |
15 | | 1-(4-ethylphenyl)- acetophenone | 13.08 | 0.54 |
16 | | 4-benzalacetone | 13.42 | 1.32 |
17 | | 2-ethenyl-naphthalene | 14.55 | 8.87 |
18 | | 1,3-diacetylbenzene | 15.45 | 3.32 |
19 | | benzophenone | 17.67 | 1.53 |
20 | | 1,1′-diphenylethylene | 17.71 | 1.43 |
21 | | diphenylacetylene | 19.46 | 0.49 |
22 | | 4-phenylacetophenone | 19.89 | 2.85 |
23 | | (3-isopropylphenyl) (phenyl) methanone | 21.98 | 0.33 |
24 | | (3-isopropylphenyl) (phenyl) methanone | 22.45 | 0.27 |
25 | | p-terphenyl | 23.45 | 0.57 |
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Liu, Z.; Li, J.; Zhao, X.; Li, Z.; Li, Q. Surface Coating for Flame Retardancy and Pyrolysis Behavior of Polyester Fabric Based on Calcium Alginate Nanocomposites. Nanomaterials 2018, 8, 875. https://doi.org/10.3390/nano8110875
Liu Z, Li J, Zhao X, Li Z, Li Q. Surface Coating for Flame Retardancy and Pyrolysis Behavior of Polyester Fabric Based on Calcium Alginate Nanocomposites. Nanomaterials. 2018; 8(11):875. https://doi.org/10.3390/nano8110875
Chicago/Turabian StyleLiu, Zhenhui, Jiao Li, Xihui Zhao, Zichao Li, and Qun Li. 2018. "Surface Coating for Flame Retardancy and Pyrolysis Behavior of Polyester Fabric Based on Calcium Alginate Nanocomposites" Nanomaterials 8, no. 11: 875. https://doi.org/10.3390/nano8110875