Study of The Reaction Mechanism to Produce Nanocellulose-Graft-Chitosan Polymer
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Grafting Methodology
3.2. CNF-g-CH Applications
4. Conclusions
Authors Contributions
Acknowledgments
Conflicts of Interest
References
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Parameter | Unit | CMF | CNF |
---|---|---|---|
Concentration | (% by weight) | 1.08 | 0.94 |
Nanofibrillation degree | (%) | 39 | 82 |
Carboxylic groups | (mmol COOH/g) | 0.07 | 0.79 |
Cationic demand | (meq/g) | 0.04 | 0.46 |
Kappa number | (-) | 135.9 | 31.2 |
Polymerization degree | (monomeric units) | 703 | 235 |
Transmittance 400 nm | (%) | 1.8 | 12.2 |
Transmittance 800 nm | (%) | 8.7 | 27.6 |
Name (Nomenclature in the Text) | Copper Phthalocyanine Blue (Blue Ink) | Carbon Black (Black Ink) | Methyl Orange (Orange Dye) |
---|---|---|---|
Core structure | |||
Maximum wavelength (λmax), nm | 615 | 500 | 460 |
Concentration, ppm | 4.5 | 2 | 4.5 |
Compound | Commercial Chitosan (%) | Dry Commercial Chitosan (%) |
---|---|---|
Chitosan | 72.7 | 81.6 |
Chitin | 16.3 | 18.4 |
Water | 11.0 | - |
Compound | Dry CMF (%) | Dry CNF (%) |
---|---|---|
Cellulose | 77.4 | 81.8 |
Oxidized cellulose | 1.2 | 13.0 |
Lignin | 21.4 | 5.2 |
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Sanchez-Salvador, J.L.; Balea, A.; Monte, M.C.; Blanco, A.; Negro, C. Study of The Reaction Mechanism to Produce Nanocellulose-Graft-Chitosan Polymer. Nanomaterials 2018, 8, 883. https://doi.org/10.3390/nano8110883
Sanchez-Salvador JL, Balea A, Monte MC, Blanco A, Negro C. Study of The Reaction Mechanism to Produce Nanocellulose-Graft-Chitosan Polymer. Nanomaterials. 2018; 8(11):883. https://doi.org/10.3390/nano8110883
Chicago/Turabian StyleSanchez-Salvador, Jose Luis, Ana Balea, M. Concepcion Monte, Angeles Blanco, and Carlos Negro. 2018. "Study of The Reaction Mechanism to Produce Nanocellulose-Graft-Chitosan Polymer" Nanomaterials 8, no. 11: 883. https://doi.org/10.3390/nano8110883