Biogenic Silver Nanoparticles for Trace Colorimetric Sensing of Enzyme Disrupter Fungicide Vinclozolin
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Reagents
2.2. Instrumentation
2.3. Synthesis of Clove-AgNPs
2.4. Colorimetric Sensing of VIN with Clove-AgNPs
2.5. Sensing of VIN in Real Water Samples with Clove-AgNPs
3. Results and Discussion
3.1. UV-Vis Spectroscopy of Clove Extract-Derived AgNPs
3.2. FTIR and PXRD Analyses
3.3. Colorimetric Sensing of VIN by Aggregation-Based Mechanism (TEM Imaging)
3.4. Calibration Study
3.5. Selectivity of the Sensor
3.6. Figure of Merit of the Developed VIN Sensor
3.7. Analysis of VIN in Real Water Samples
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Method | LOD | Remarks | Reference |
---|---|---|---|
GC–MS/MS | 0.5 ppb | Sensitive, but costly and complicated | [5] |
HPLC | 0.745 µM | Low sensitivity; high chemical consumption | [6] |
SPME–GC–ECD | 11.0 ppb | Sensitive, but costly and complicated | [7] |
SPME–HPLC | 4.0 ppb | Sensitive, slow, and complicated | [8] |
GC–MS/MS | 0.5 ppb | Sensitive, but costly and complicated | [9] |
Electrochemical | 11 nM | Sensitive; selectivity not studied | [10] |
UV-Vis Spectrometry based on AgNP sol | 21 nM | Sensitive, simple, and novel; reported for the first time | This work |
Water Sample from Turkey | VIN Added (µM) | VIN Found (µM) | Recovery (%) |
---|---|---|---|
Mediterranean Sea | 05 | 05.10 ± 0.02 | 102.0 |
Ilgin Lake | 10 | 10.30 ± 0.11 | 103.0 |
City Centre Konya | 15 | 14.80 ± 0.15 | 098.7 |
Selcuk University Konya | 15 | 14.90 ± 0.21 | 099.3 |
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Hussain, M.; Nafady, A.; Sirajuddin; Avcı, A.; Pehlivan, E.; Nisar, J.; Sherazi, S.T.H.; Balouch, A.; Shah, M.R.; Almaghrabi, O.A.; et al. Biogenic Silver Nanoparticles for Trace Colorimetric Sensing of Enzyme Disrupter Fungicide Vinclozolin. Nanomaterials 2019, 9, 1604. https://doi.org/10.3390/nano9111604
Hussain M, Nafady A, Sirajuddin, Avcı A, Pehlivan E, Nisar J, Sherazi STH, Balouch A, Shah MR, Almaghrabi OA, et al. Biogenic Silver Nanoparticles for Trace Colorimetric Sensing of Enzyme Disrupter Fungicide Vinclozolin. Nanomaterials. 2019; 9(11):1604. https://doi.org/10.3390/nano9111604
Chicago/Turabian StyleHussain, Masood, Ayman Nafady, Sirajuddin, Ahmet Avcı, Erol Pehlivan, Jan Nisar, Syed Tufail Hussain Sherazi, Aamna Balouch, Muhammad Raza Shah, Omar A. Almaghrabi, and et al. 2019. "Biogenic Silver Nanoparticles for Trace Colorimetric Sensing of Enzyme Disrupter Fungicide Vinclozolin" Nanomaterials 9, no. 11: 1604. https://doi.org/10.3390/nano9111604