Preparation of Micro-Nano Material Composed of Oyster Shell/Fe3O4 Nanoparticles/Humic Acid and Its Application in Selective Removal of Hg(II)
Abstract
:1. Introduction
2. Experimental Section
2.1. Preparation of Oyster Shell (OS)
2.2. Synthesis of Magnetic Nanomaterials
2.3. Adsorption Experiments
2.4. Experimental Analyses
3. Results and Discussion
3.1. Material Characterization
3.2. Optimization of pH in Hg(II) Ion Adsorption
3.3. Adsorption Isotherms
3.4. Adsorption Kinetics
3.5. Adsorption Mechanism
3.6. Efficient and Selective Adsorption
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Langmuir Model | Freundlich Model | ||||
---|---|---|---|---|---|
b (L·mg−1) | qmax (mg·g−1) | R2 | kf (L·mg−1) | n | R2 |
0.18 | 141.57 | 0.991 | 19.81 | 1.55 | 0.968 |
Pseudo-First-Order Model | Pseudo-Second-Order Model | ||||
---|---|---|---|---|---|
k1 (min−1) | qe (mg·g−1) | R2 | k2 (g·mg−1·min−1) | qe (mg·g−1) | R2 |
0.1225 | 86.52 | 0.951 | 1.98 × 10−3 | 90.45 | 0.998 |
Adsorbent | Equilibration Time (h) | qmax (mg·g−1) | Reference |
---|---|---|---|
Thiol-functionalized magnetic activated carbon | ~4 h | 366.3 | [47] |
Lewatit MP 62 | 2 h | 151.5 | [48] |
Purolite S 920 | 2 h | 29.2 | [48] |
Thiol-modified Fe3O4@SiO2 | 4 h | 148.8 | [46] |
Glutamic acid-modified cellulose fibrous | 10 min | 44.9 | [32] |
Carbon nanotube | ~90 min | 100 | [49] |
Coal-based activated carbon | ~3 h | 48.0 | [50] |
HA/Fe3O4/OS | ~1 h | 141.6 | This work |
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He, C.; Qu, J.; Yu, Z.; Chen, D.; Su, T.; He, L.; Zhao, Z.; Zhou, C.; Hong, P.; Li, Y.; et al. Preparation of Micro-Nano Material Composed of Oyster Shell/Fe3O4 Nanoparticles/Humic Acid and Its Application in Selective Removal of Hg(II). Nanomaterials 2019, 9, 953. https://doi.org/10.3390/nano9070953
He C, Qu J, Yu Z, Chen D, Su T, He L, Zhao Z, Zhou C, Hong P, Li Y, et al. Preparation of Micro-Nano Material Composed of Oyster Shell/Fe3O4 Nanoparticles/Humic Acid and Its Application in Selective Removal of Hg(II). Nanomaterials. 2019; 9(7):953. https://doi.org/10.3390/nano9070953
Chicago/Turabian StyleHe, Chuxian, Junhao Qu, Zihua Yu, Daihuan Chen, Tiantian Su, Lei He, Zike Zhao, Chunxia Zhou, Pengzhi Hong, Yong Li, and et al. 2019. "Preparation of Micro-Nano Material Composed of Oyster Shell/Fe3O4 Nanoparticles/Humic Acid and Its Application in Selective Removal of Hg(II)" Nanomaterials 9, no. 7: 953. https://doi.org/10.3390/nano9070953