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Review

Gases in Food Production and Monitoring: Recent Advances in Target Chemiresistive Gas Sensors

1
Department of Physics, College of Science, King Faisal University, Al-Ahsa 31982, Saudi Arabia
2
Physics Department, Faculty of Science, Assiut University, Assiut 71516, Egypt
3
Egyptian Petroleum Research Institute, Nasr City 11727, Egypt
4
Department of Physics, School of Engineering, University of Petroleum & Energy Studies, Dehradun 248007, India
*
Author to whom correspondence should be addressed.
Chemosensors 2022, 10(8), 338; https://doi.org/10.3390/chemosensors10080338
Submission received: 5 July 2022 / Revised: 5 August 2022 / Accepted: 12 August 2022 / Published: 17 August 2022
(This article belongs to the Section Nanostructures for Chemical Sensing)

Abstract

:
The rapid development of the human population has created demand for an increase in the production of food in various fields, such as vegetal, animal, aquaculture, and food processing. This causes an increment in the use of technology related to food production. An example of this technology is the use of gases in the many steps of food treatment, preservation, processing, and ripening. Additionally, gases are used across the value chain from production and packaging to storage and transportation in the food and beverage industry. Here, we focus on the long-standing and recent advances in gas-based food production. Although many studies have been conducted to identify chemicals and biological contaminants in foodstuffs, the use of gas sensors in food technology has a vital role. The development of sensors capable of detecting the presence of target gases such as ethylene (C2H4), ammonia (NH3), carbon dioxide (CO2), sulfur dioxide (SO2), and ethanol (C2H5OH) has received significant interest from researchers, as gases are not only used in food production but are also a vital indicator of the quality of food. Therefore, we also discuss the latest practical studies focused on these gases in terms of the sensor response, sensitivity, working temperatures, and limit of detection (LOD) to assess the relationship between the gases emitted from or used in foods and gas sensors. Greater interest has been given to heterostructured sensors working at low temperatures and flexible layers. Future perspectives on the use of sensing technology in food production and monitoring are eventually stated. We believe that this review article gathers valuable knowledge for researchers interested in food sciences and sensing development.

1. Introduction

Due to global population growth, technology has played a large role in food production as food needs become more demanding in societies. Concerns about the production of poor-quality foods have been linked to increased rates of death, disease, and human suffering, which places a greater economic burden on humanity [1,2,3]. To reduce waste, poisoning, and spoilage in food, great efforts have been made in the industrial sector [4]. Technology has developed and has economic importance and plays a vital role in the quality of foods. Therefore, it has become necessary for food production and the industry to undergo food quality assurance that complies with international food safety rules. Thus, the importance of food science and technology has increased in terms of publications that gained a high h-index over the last five years (2017–2021), which was recently indicated by the google metric [5], as shown in Figure 1. The h5-index is defined as the h-index for articles published in the last five complete years. It is the largest number h, such that h articles published in 2017–2021 have at least h citations each [6]. Food chemistry gained the highest h5-index with 122, followed by trends in food science and technology, and critical reviews in food science and nutrition. Food control and food quality also have a high h5-index, with 77 and 66, respectively.
The global gas sensors market was valued at $2.50 billion in 2021. It is expected to expand at a compound annual growth rate (CAGR) of 8.9% from 2022 to 2030 [7]. The main factor driving the gas sensor market is the development of miniaturization and wireless capabilities, along with improvements in communication technologies that enable them to be integrated into various devices and machines to detect toxic gases at a safe distance. The CO2 sensor segment dominated the market in 2021 and captured more than 31.0% of the global revenue share. CO2 sensors are primarily used to monitor indoor air quality in homes, office buildings, automobiles, healthcare, agriculture, and other applications. The agricultural sector captured a share of about 10% of the global revenue of the gas sensing market in 2021. Agricultural gas sensors are used to monitor and detect hazardous gases used in food production and food quality control. Food and beverage producers and processors use and produce hazardous gases in many stages, including the processing of food, waste, and by-products and the preservation of food until it is opened. Essentially, gases are used at every step of the food chain, from field to fork. Gases are used in many sectors of the food industry, such as meat and fish [8], vegetables, fruits [9], bakeries [10], and wine and beer [11]. They is used in many applications such as hydrogenation processes for oils, carbonation processes for vegetables [12], food preservation processes, and packaging processes [13]. Gases are also used and produced during various beverage manufacturing processes, as shown in Figure 2. Gases are byproducts of the processes of ripening and spoilage of foods such as meat [14], vegetables, and fruits [15,16]. Gases are used in the food industry, agriculture, and with animals [17]. In animal production, gases are used in anesthetic processes before the slaughter process or in oxygenation processes in aquatic organisms. In plant production, gases are produced and used in greenhouses to provide a suitable climate for the process of growth, maturation, and storage, and to control pests [18,19]. Figure 2 shows the emitted and used gases in different processes in food production. The type of gas differs according to the stage of the purpose of utilization. SO2 gas is used in drink production, such as Oenology and microalgae cultivation, which is wine and beer production. CO2 is the most utilized gas, and is used in different processes. It is used in the anesthesia of animals in large quantities, greenhouses, microalgae cultivation, modified atmospheric packaging (MAP), and food storage. Other important gases are emitted due to the spoilage of food, indicating low quality or bad food conditions. These gases are emitted due to changes in the microorganisms in food, such as C2H4 and C2H5OH in fruit and vegetable ripening; nitrogen dioxide in microalgae; and NH3, hydrogen sulfate, and some rare detectable gases in meat spoilage.
One of the most important uses of gases is the process of preserving foods in packaging technology called modified atmospheric packaging (MAP), a technique used to preserve fresh or processed foods for long periods. In this technique, the air is replaced with other gases through which the chemical processes or oxidation reactions of enzymes can be slowed down, in addition to preventing the growth of pathogens and aerobic and anaerobic bacteria. Many foods are prepared in modified packages so that the food tastes and appears fresh for a long time without any modification of the food itself. The type of gas mixture used depends on the target and the type of food. The MAP process is a common occurrence in food packaging. As a result, manufacturers have greater control over product quality, availability, and costs. They can eliminate product turnover, removal, and re-stocking, reducing costs and eliminating waste.
Gas sensors are necessary devices to accurately monitor and determine the concentrations of different gases when producing foods. The gas sensors used must be able to monitor and analyze the gas in real time. Thus, the sensors must provide high-accuracy and high-quality online sensing capabilities to detect the gases produced or used in food and beverages. Nanotechnology has changed many life applications, as nanomaterials have been applied in different fields because they have unique application properties. Nanomaterials prepared in various forms improve the properties of the materials and open new avenues for their application in industrial food. For example, nanomaterials, such as metal oxides [20], carbon nanotubes [15,21], and graphene, have been used in many chemical gas sensors to identify the existence of volatile organic compounds that are produced in food products owing to their spoilage and dangerous processes that may occur during the ripening, storage, and transportation of food [22,23,24].
In this review, our goal is to prepare an article on the most used or produced gases during the different stages of food production and monitoring, and the state of the art of chemiresistive sensor technology for the target gases. Thus, (1) we focus on the gases that have been consumed during oenology, animal production, greenhouse crops, modified atmospheric packaging, and microalgae cultivation. Additionally, attention is given to monitoring of food quality by detecting gases in meat spoilage, fruit and vegetable ripening, and humidity during food storage. (2) We focus on the most recent available sensors able to work under low temperatures and low levels of detection suitable for the real-time monitoring of gases during the various stages of the food chain.

2. Long-Standing and Recent Advances in Gas-Based Food Production

2.1. Gases in Drink Production

The fabrication of drinks needs to use some toxic gases, such as SO2, which has antioxidant properties [25]. This gas is toxic, heavier than air, stable under normal conditions, and corrosive of metals. However, it is critical for the production of wine, since it shields the wine from microbials and oxidation. It is added to prevent the unwanted development of microorganisms, as an antioxidant to inhibit polyphenol oxidases (laccase and tyrosinase), and as a dissolvent. SO2 is also a food additive (E220) [26] that is commonly applied in the food industry. Oxidation processes negatively affect the organoleptic properties of the wine and lead to a loss of nutritional value. Phenols are the basis of the oxidation process, which causes enzymatic and non-enzymatic browning. Quinones are produced as by-products from the oxidation of phenol and hydrogen peroxide (H2O2), which is a strong oxidant. When SO2 is used, it reduces quinones, inhibits oxidative enzymes, and reacts with H2O2. SO2 works as an antimicrobial in the synthesized wine [27,28]. In addition to its main application in wine science, SO2 is observed in dried fruits, meats, beer and fermented beverages, candied fruits, and jellies. Additionally, one of the most dangerous compounds is ethyl carbamate (EC). EC is a carcinogenic material that is commonly observed in alcoholic beverages [29]. Much research work has focused on this compound, which is considered a significant challenge that exists in the beverage industry.

2.2. Gases in Anesthesia of Animals

One of the methods used in the process of slaughtering animals is the use of CO2 for stunning. This gas causes unconsciousness after inhalation of a CO2-based atmosphere mixed with air or nitrogen (N2), oxygen (O2), or argon (Ar) [17]. The use of gas in this process takes a few minutes because extremely high levels of CO2 greater than 30% cause the animal to have conscious convulsions. Accordingly, the animal is exposed to CO2, the level of which is gradually increased until it reaches a maximum concentration level of 70% of CO2 to create a severe stun [30]. To ensure the animal is exposed to different concentrations of gas, the animal passes through a room in which the CO2 content is increased continuously or passes through two rooms that contain different levels of gas, where the first has a limited concentration of CO2 and the second has a high percentage of CO2. The consumption of CO2 is based on some parameters such as weight. In the case of pigs, the value of CO2 is about 100–500 g/pig. The specific CO2 consumption of poultry depends on the equipment design and the breed and weight of the animal. In the case of chickens, the average value of CO2 is about 15 g/kg [31].

2.3. Gases in Greenhouses

CO2 has been used in commercial greenhouses for more than four decades, which is a byproduct of burning natural gas that is used to heat the greenhouses [32]. Farmers of vegetables, flowers, and plants use different methods and rates to enrich CO2. Greenhouses can use either compressed or liquid CO2 depending on how much gas is needed. The compressed CO2 is converted from a liquid to a gas and then released into the greenhouse. Farmers can also use CO2 stoves or generators to fertilize CO2. Some farmers use self-produced CO2 while others use industrial CO2. However, some farmers found that when they used two to three times more CO2 than the existing outside level, they obtained higher yields of their crops. To date, day and night greenhouse heating management technology depends on the frequency of the situation. Photosynthesis is the use of light as an energy source for the manufacture of organic materials using CO2 in the atmosphere and water, accompanied by the production of oxygen by the plant. CO2 is absorbed by the plant at a concentration of 0.03% (300 ppm), and if the concentration drops to 120–150 ppm, this prevents the photosynthesis processes. In greenhouses, this minimum level can be attained in a few hours if the greenhouse contains a lot of plants. Thus, by introducing CO2, the required minimum can be restored. Additionally, the required level varies according to the cultivated species of plants. It was found that the growth rate can be increased by increasing the level of CO2 in the greenhouse. Thus, CO2 with a level of 200 to 1500 ppm ensures an increase in the yield in terms of the weight and number of crops [33,34,35,36]. It also supports faster growth, earlier harvest, stronger stems, better flower color quality, and healthy growth with disease resistance. Greenhouses are closed environments in which the conditions are optimized for plant growth. Optimal controls require information from both the indoor and outdoor environments. Typically, CO2 is measured inside greenhouses. A CO2 m is needed to both monitor CO2 and control CO2 enrichment in the greenhouse. Handheld, stationary, and computer-controlled sensors are available and vary in their level of sophistication and accuracy. To date, the greenhouse environment has been monitored and controlled using CO2 sensors, usually an infrared gas analyzer (IRGA), to monitor the minimum and maximum CO2 levels [37]. This is carried out by distributing more than one IRGA inside the greenhouse, which is controlled by sensors connected to a computer to control the environment. A metal oxide-sensitive layer is also used to monitor CO2 [38].

2.4. Gases in Modified Atmospheric Packaging (MAP)

Many of the foods we consume such as fruits, vegetables, meats, and baked goods are packaged in a modified atmosphere to extend their shelf life [39]. The modified atmosphere ensures the food taste the same and looks fresher for longer without modifying the food itself [40]. Modified atmosphere packaging (MAP) is achieved by replacing the air around the food with a mixture of gases designed specifically for food items, where CO2 may change from 20% to 100% [41]. MAP is often used in dairy, meat, poultry, seafood, dried fruit and vegetable, bakery, and medical applications. The MAP process lowers the volume of oxygen within the space of the packaging containing the product. Thus, the oxygen inside the package is often replaced with other gases. The gases that are most used in the packaging process are nitrogen, CO2, and oxygen. In some cases, argon and carbon monoxide are used to preserve the color of red meat in a low-oxygen atmosphere. The ambient air contains 78% N2, 21% O2, and 1% Ar, in addition to rare gases. O2 gas must be carefully used because it may react with the food or provide conditions for the growth of microorganisms, which leads to food spoilage. MAP is widely used because it provides a way to extend food life without the addition of any chemical additives or preservatives. For example, meat benefits from MAP containing 70–80% of O2 while seafood needs a low level of O2 and high levels of CO2. The concentration of CO2 used varies according to the type of packaging, as loose packaging requires very high concentrations of CO2. The use of ideal gas compositions also differs between the storage of fish and meat due to the presence of myoglobin in meat, an iron-containing protein that has a purple color and can react with oxygen gas molecules to form oxymyoglobin, which has a red color associated with fresh meat. However, if it largely reacts with oxygen, it forms methemoglobin [42], which is the brown color associated with spoiled food. Thus, it depends on the concentration of oxygen in the surrounding atmosphere. Likewise, for cooked foods, an oxygen-free environment is ideal for preserving food, and CO2 is the preferred gas in this case. The role of CO2 is to exclude oxygen, which leads to deterioration of the state of food, unlike raw meat. In higher concentrations, CO2 acts as an insecticide and protects products from pests. Cooked meat needs at least 30% CO2 to preserve food for a longer period. Additionally, cheese, bakery products, fish, ready-made meals, and vegetables need a concentration of CO2 up to 50%. In the case of plant foods, oxygen sometimes helps the plant to breathe. Therefore, balancing of the gas mixture between oxygen and CO2 is important to slow the breathing process and maintain the freshness of food. Carbon monoxide (CO) is sometimes used in raw meat in a low-oxygen atmosphere. Carbon monoxide is similar to oxygen, as it reacts with myoglobin to form carboxymyoglobin, which gives it a cherry color. However, this gas has no taste, color, or odor, and it is poisonous. Carbon monoxide is a poisonous gas and in industry, it can indicate meat is fresh even if it is spoiled. It is dangerous.

2.5. Gases in Microalgae Cultivation

Microalgae selection criteria relate to the particular growth and high tolerance of strains of microalgae of flue gas, including elevated levels of CO2, SOx, and NOx [43]. In addition, these strains tolerate the high temperatures that usually accompany the flue gas supply. An appropriate strain should be chosen to be investigated or made. It is exciting to recover the bibliographic work with the initial cultivation experiments that can be achieved in a lab scale-photobioreactor. There are three modes of microalgae cultivation. The first is autotrophic, in which mineral compounds and light are used. The second is a heterotrophic mode, in which organic compounds such as glucose are used. The third is a nutrition mixture called mixotrophically, which is a mixture between the first and second modes. The first and second modes are related to the use of flue gases in agriculture. In this type of farming, in addition to controlling the use of light, the gas distribution, air quality, and mixing quality of the cultivation are also controlled. This is to carry out the process of transferring CO2 as the main source of carbon and to avoid the deposition of microalgae cells. The bio-fixations of CO2 by microalgae depend on the choice of the microalgae strains that are cultivated [44]. Microalgae use CO2 to create and develop cells and ensure their metabolism. In some species of microalgae, optimum CO2 removal occurs when the CO2 level is reduced to 1%. The higher the CO2 content, the higher the percentage of lipids and acids produced by the microalgae, which represents a clean environment and economic area of interest to humanity. The total lipids are 30% to 50% of the CO2 level when the O2 level is low, affecting enzymatic saturation. The removal of CO2 depends on the microalgae species, cultivation system, temperature, CO2 concentration, and growth rate. The control of the CO2 concentration is an effective parameter in this type of cultivation; thus, the measurement of its level should be accurate. Flue gases must be known before they can be used in microalgae culture, as some untreated flue gases exhibit higher levels of SOx, CO2, and NOx. However, being aware of these components enables the selection of strains that are biologically resistant to the toxic gases and that offer a high growth rate. Without this, the cultural process may be inhibited and fail or die [45,46,47]. The more tolerant the breeds are of these toxic gases, the lower the cost of pre-culture gas treatment. The CO2, SOx, and NOx concentrations for different strains’ performance were 30–70%, 30–100 ppm, and 50–100 ppm, respectively [44].

2.6. Gases in Meat Spoilage

Meat spoilage is a metabolic process that alters the organoleptic properties of meat and is not acceptable for use or human consumption. If favorable conditions are provided for the spoilage process, such as increased humidity, low oxygen, and low temperatures, these are ideal conditions for the growth of microbes [48,49]. When microbes grow and damage meat, poultry, and fish products, volatile nitrogen-containing compounds are produced in large amounts. The blood circulation of the animal stops after the slaughter process, in addition to the respiratory system, so the meat undergoes the anaerobic glycolysis process, which lowers the pH, and autolysis of protein produces amino acids that make the meat vulnerable to microbial spoilage. This is followed by the formation of volatile compounds such as H2S and NH3 gases, the most known compounds with a pungent odor [48]. Therefore, the concentrations of H2S and NH3 are the main indicators used to determine the freshness of meat during storage periods. Therefore, measurement of these concentrations reflects the freshness of meat in the market [50]. There are a few other types of gases and volatiles produced by meat spoilage. For example, in fish spoilage, CO, CH4, SO2, alcohols, amines, and sulfurs are observed [51].

2.7. Gases in Fruit and Vegetable Ripening

Monitoring fresh fruits and vegetables after harvest is a very important matter. Therefore, the process of controlling the surrounding atmosphere must be carefully controlled [52,53]. Researchers found that fruits absorb oxygen and then produce CO2, and they found that fruits that were kept in an atmosphere that did not contain oxygen did not ripen. The implementation of commercial “controlled atmosphere” storage is widely used for many fresh fruits and vegetables in many countries. Extension of the shelf life of some types of fruits can be achieved in controlled weather for several months. This atmosphere slows maturation and maintains firmness, causing a delay in the development of the flavor while the sweetness and texture can be maintained to an extent. This is carried out by reducing the oxygen in an airtight storage room, thus reducing the respiration of the fruit. Ordinary air contains 21% oxygen, which is reduced to 1–3% by pumping nitrogen gas into closed rooms. The optimum levels of O2, CO2, and C2H4 vary between fruits and vegetables and even between varieties and production areas [54]. However, the high level of the CO2 concentration in the store leads to spoilage of the fruit and vegetables. Additionally, if the level of oxygen is decreased, the respiration of fruits changes from aerobic to fermentation, which results in volatile substances such as ethyl acetate, acetaldehyde, and C2H5OH. This shows us C2H5OH gas can be collected and measured to monitor the state of fermentation that has just begun, and accordingly, the oxygen level can be increased to prevent the spoilage of fruits.
C2H4 gas is an unsaturated hydrocarbon molecule, produced in most fruits, and it is the ripening hormone in fruit [16]. The level of C2H4 gas varies according to the state of ripening of the fruits. Thus, it is at a very low level in the case of immature fruits and increases with the growth of the fruits as large quantities are produced, causing an increase in the ripening process until it reaches the peak and then the production of C2H4 begins to decrease again due to the beginning of spoilage [16]. The level of C2H4 also varies according to the type of fruit. If large quantities of C2H4 are produced from fruits, it is difficult to store them once this happens. For example, the McIntosh apple fruit produces huge quantities of C2H4. Therefore, the harvesting process must take place before the C2H4 level begins to increase rapidly in the case of months of storage.
Peaches and plums are very sensitive to C2H4 hormone, so they ripen quickly after being harvested [55]. However, some types of fruits can be stored for longer periods if the C2H4 production process is suppressed. Moreover, the adaptability and performance of crops are also affected by C2H4 under stress conditions. Controlled atmosphere storage tests at C2H4 concentrations ranging from 0.001 to 10 ppm have proven successful in prolonging the storage life of commercial products for several weeks depending on the species [56,57]. C2H4 is harmful to stored fruit and vegetables but is useful in other cases. Some fruits are harvested in an early state and the greenery remains in these fruits. These fruits (especially bananas) are placed in ripening rooms and exposed to C2H4 gas. C2H4 can be used in the form of liquids, such as ethyl, to produce C2H4 when sprayed on the fruit. C2H4 is also used in gaseous form, with a ratio of 5% to 95% of nitrogen.

3. Recent Advances in Target Gas Sensing

Although many studies have been conducted to identify the chemical and biological contaminants in foodstuffs, the use of gas sensors in food technology plays a vital role. The development of sensors capable of detecting the presence of gases such as C2H4, NH3, CO2, SO2, and C2H5OH has been the target of study of many researchers, as gases are not only used in food production but are also a vital indicator of the quality of food. Therefore, in this section, we will discuss the latest practical articles that deal with these gases and their response, sensitivity, working temperatures, and limit of detection (LOD). We attempt to focus on the most recent research work, especially for sensors working in low temperatures and flexible sensors, if any.

3.1. Recent Advances in C2H4 Gas Sensors

The process of measuring the percentage of C2H4 is complicated and expensive because it uses advanced laboratory equipment to detect the presence of C2H4 to determine whether the fruits are storable or not. In the distribution chains of fruits, it is necessary to control ripening through the level of C2H4 to evaluate the fruit quality in the markets. Recently, the literature has concentrated on the detection of the ripening of agricultural products to avoid food waste by controlling C2H4 [58,59,60]. Xiao et al. [16] reported a significant study on important ripeness restrictions depending on C2H4 production in bananas in case of natural ripeness. They reported that C2H4 production in natural ripening fruits increased drastically after day 15 of green banana storage, reached the highest production on day 18, and then decreased. The lowest concentration of C2H4 depends on the ripening days and amount of food, such as fruits or vegetables. Banana produces 1.5 µL/kg of C2H4 gas, as a maximum value, for natural ripening. However, the production of C2H4 depends on the ripening stage of the fruits. The C2H4 concentration ranges from 0.5 µL/kg (0.5 ppm/kg) on the first day of ripening and then increases up to 1.5 µL/kg (1.5 ppm/kg) as the maximum ripening stage before spoilage. Thus, the detection of C2H4 at a value lower than 0.5 ppm is required for early detection. Chemiresistive sensors are promising due to their low cost and easy integration. However, the challenge for these sensors is still working in high temperatures. Thus, development is ongoing in terms of obtaining a high-performance C2H4 sensor. Recently, an C2H4 sensor was fabricated based on a palladium-loaded tin oxide sensor to assess fruit quality [61]. The sensor showed an optimal performance with a response of 11 toward an C2H4 concentration of 100 ppm at a high temperature of 250 °C, although its LOD was 50 ppb with good stability. Fong et al. [58] designed a novel sensor for C2H4 built with doped CNTs and based on a mechanism called Wacker oxidation. This mechanism is based on the incorporation of a noble metal catalyst such as palladium to add oxygen to the C2H4 molecule with an oxidation process. Additionally, Shaalan et al. [15,21] developed an C2H4 gas sensor based on the defect-induced MWCNTs. These defect-induced CNTs were produced using Ni/Cr as catalyst layers in the PECVD system. They assessed the sensor at room temperature (RT) in a low C2H4 concentration of 130 to 10 ppm. The sensor can also monitor natural fruits’ ripeness at various stages in terms of its measurement accuracy, reliability, and reproducibility. The sensor can detect C2H4 released from a single banana, as shown in Figure 3. Figure 3a exhibits the measured sensor response over five days of monitoring of bananas. Figure 3b shows the sensor signal corresponding to the ripening level observed in Figure 3c. More recent attempts toward C2H4 are recorded in Table 1 for the most recent literature. As reported in [16], the emitted amount of C2H4 depends on the ripening day, where the level of C2H4 increases with the ripening days, reaching the highest ripening level, and then decreases at the start of the spoilage stage. As shown in Figure 3, the as-received banana has a whitish green color, which shows a low peak of the sensor signal. On the second and third days of the experiment, the color changes from green to yellow, which gives a higher sensor signal. It is observed that on the fourth day, the dark color appears on the banana surface and increases by the fifth day, and, again, a low signal is detected compared to the third day due to the start of the spoilage.

3.2. Recent Advances in NH3 Gas Sensors

According to the German Environment Agency, agriculture is the main source of NH3 emissions, accounting for 95%. The pollutant NH3 is mainly produced in animal husbandry because the excrements of farm animals contain urea and protein, which are converted into NH3. Additionally, NH3 is a toxic and harmful gas, and it is one of the compounds produced due to the spoilage of meat and fish. It must be monitored in environments in which meat and fish is stored in stores or warehouses. To develop signs of spoilage in meat, the NH3 concentration must be relatively high (>15 ppm) and/or the exposure time relatively long (>120 min) [67]. There are some cases where it is difficult to tell if meat has spoiled by detecting NH3, especially after the frozen storage period. However, contamination with low levels of NH3 would greatly speed up the development of the rancid flavor. Therefore, there is a need to detect NH3 at low concentrations and at RT to monitor food quality. Many efforts have been committed to developing high-performance sensors that are able to detect a low limit, and this challenge still faces many difficulties, especially those related to chemiresistive sensors in terms of the low operating temperature, response, and selectivity. A highly sensitive and flexible NH3 sensor was fabricated from polyaniline/SrGe4O9 (PSN) nanocomposite [68]. They reported that when the PSN sensor was subjected to 0.2 to 10 ppm at 25 °C and 60% RH, it exhibited a significant response of 20.59% each 1.0 ppm. The sensor response of PSN was twice that of pristine PANI. In addition to its flexibility, the PSN sensor showed repeatability, stability, and selectivity to NH3 at RT. Thus, this sensor has provided a very low NH3 detection limit. Recently, promising chemical sensors for NH3 have been developed for food spoilage monitoring based on organic field-effect transistors (OFETs) [69,70]. These OFET gas sensors were fabricated using solution-processable techniques and operated at low voltages. They provided a reliable sensing performance over multiple cycles of NH3 exposure (2 to 50 ppm), with an estimated detection limit of less than 1 ppm and 2.17 ppb. Li et al. [71] studied CeO2 nanoparticles annealed at a high temperature, which demonstrated good sensing toward NH3. The sensor response was about 25 and the response and recovery times were 3 and 116 s. It also offers reliable selectivity toward NH3 and repeatability in the range of 0.5 to 1000 ppm. Recently, many good attempts at the detection of NH3 using electrochemical sensing technology were carried out between 2017 and 2022. Some are shown in Table 2. Andre et al. [72] reported hybrid layer-by-layer films combined with polyaniline (PANI)-graphene oxide (GO)-zinc oxide ZnO) for NH3 sensing. They found that the films with tri-layers were the most adequate for sensing NH3 in the range of 25 to 500 ppm. The prepared films were operated at RT and their response time was about 30 s. Lee et al. [73] developed a GO composite of Ti3C2Tx/MXene layers. The MXene/rGO hybrid showed a significant improvement in the performance of the NH3 response with low power consumption. The flexible structure of this composite also withstood the bending stress test. Accordingly, they sewed highly elastic MXene/rGO hybrid mixes into a lab coat using simple conventional weaving, showing a reliable sensing capability. Wearable sensors are of great importance due to their ability to monitor the workplace in real time. Therefore, the applications of wearable sensors in various fields have motivated researchers to develop the most reliable and efficient sensors. Wearable sensors are mainly based on flexible sensors that withstand mechanical deformations during use. For more about the development of these sensors based on two-dimensional materials, some of them have been monitored in [74]. We believe that this type of sensor creates a new path in the use of such sensors in the clothes of workers in markets and storage of meat, as such sensors provide quick results for determining whether that the products are in good condition or beginning to spoil.

3.3. Recent Advances in SO2 Gas Sensors

Sulphites can harm drinks’ sensory properties, delay the onset of malolactic fermentation, and cause some health concerns in case of high concentrations in the final drinks. Thus, the SO2 level in drinks is regulated, and it must be displayed on the label when found above 10 ppm or 10 mg/L [81]. Consequently, it is important in the drink-making process to control and manage the SO2 content to maintain the lowest possible concentration while preserving its interesting properties. The recommended airborne exposure limit (REL) is 2 ppm over 10 h or 5 ppm for 5 min at a maximum [82]. Thus, several attempts have been made to detect SO2 using various heterostructures to achieve a reliable and stable sensing layer at low temperatures (Table 3). Liu et al. [83] recently reported an ultra-sensitive sensor based on the use of nickel atoms attached to SnO2 nanorods (SAC-Ni/H-SnO2), which are oxygen-rich vacancy sensing materials. The sensor response was 48 toward 20 ppm of SO2 gas with a detection limit of 100 ppb. The sensing layer was characterized by DRIFTS and ESR, which demonstrate the coupling effects of SAC-Ni and adjacent oxygen vacancy on the surface of SnO2 to enhance SO2 uptake and the activation of chemically adsorbed oxygen as well. This efficient monoatomic catalyst provides innovative insight into the complex gas sensing layer. It also demonstrates a promising approach to using the monoatomic effect in sensing applications. However, the optimal operating temperature is still as high as 250 °C. Shinde et al. [84] developed a nano-hybrid sensing layer with a high response of 61.5% at 150 °C. This nano-hybrid layer was based on zinc–chromium hydroxide (ZC-LDH) and hexapotassium (HNb) nanosheets (ZCNb nanohybrids). The results clearly show that the lattice-designed 2D ZCNb nano-hybrids are very effective at not only improving the gas sensor activity but also in developing a new type of closely coupled LDH metal oxide-based hybrid material.
It is advantageous that micro-electromechanical systems (MEMSs) are used in gas sensor design, which may increase the accuracy and sensitivity of the sensors [85]. An MEMS was used to test low concentrations of SO2 with SnO2 layers and the heterogeneous structure of double NiO/SnO2. The sensing result confirmed that the NiO/SnO2 sensing layer has better sensing properties than the single-SnO2 layer because of the p-n junction formation. The NiO/SnO2 sensing layer had the highest response of 20% at 400 ppb of SO2 concentration, and 30% at 2000 ppb. The sensor works at a high temperature of 250 °C, although it shows selectivity towards SO2 gas. Another study was conducted on the use of MEMSs in sensor design. Au nanoparticles with a diameter of about 5 nm were loaded onto the surfaces of La2O3-NPs, which were integrated by the MEMS into an Au/La2O3-NPs/ZnO/MEMS sensor [86]. In the presence of SO2 gas at a concentration of 300 ppb, the Au/La2O3-NPs/ZnO/MEMS sensor displayed a higher response than the ZnO/MEMS or La2O3-NPs/MEMS sensors. The sensor was more sensitive to SO2 than the other tested gases. However, it was operating at a temperature of 260 °C.
In a study investigating a ternary compound La1-xCaxFeO3 to low SO2 concentrations, the La0.6Ca0.4FeO3 thin film showed an excellent sensing performance [87]. It was found that La0.6Ca0.4FeO3 displayed the best gas sensing performance, with a sensor response of 7.6 at an SO2 concentration of 3 ppm at a low working temperature of 120 °C. The thin film was made using the DC-sputtering technique. The sensor showed a preferential selectivity for the detection of SO2 gas under the operating condition compared to CH4, CO2, and CO. An MWCNT/MoS2 nanocomposite prepared via a simple chemical method was proposed as a low-energy and RT operating sensor layer [88]. The device is selective towards SO2 gas. A systematic examination of gas sensing using this film indicates a response of 0.22–1.81% in the concentration range of 500 ppb–3 ppm. The sensor was operating at RT and had a low bias voltage of 100 mV. The LOD level of the sensor was 500 ppb. We end this section with an important monograph, in which Zhai et al. presented a strategy for MOF sensor fabrication, describing a strategy for the development of a flexible sensor layer of UiO-66-NH2 nanofiber through electrospinning and aqueous manufacture [89]. The sensor has high porosity and good flexibility; therefore, the sensor generated by the UiO-66-NH2 nanofibers membrane combined with carbon nanotubes displayed a great response and stability to SO2 for a gas concentration of 125 to 1.0 ppm at RT. The sensor showed selectivity towards SO2 compared to other hazardous gases.
Table 3. The most recent chemiresistive SO2 sensors reported in the literature.
Table 3. The most recent chemiresistive SO2 sensors reported in the literature.
MaterialsOperating Temp. (°C)SO2
Concentration
Response %Limit of DetectionRef.
SAC-Ni/H-SnO225020 ppm48100 ppb[83]
ZCNb nanohybrids150100 ppm61.5100 ppb[84]
MWCNT/MoS2RT1.0 ppm1.9500 ppb[88]
NiO/SnO22502.0 ppm30400 ppb[85]
La0.6Ca0.4 FeO3 thin film1603.0 ppm7.6--[87]
Au/La2O3-NPs/ZnO2601.0 ppm44100 ppb[86]
PAN@UiO-66-NH2RT100 ppm2251.0 ppm[89]
Ni-MOF/–OH-SWNTsRT1.5 ppm281.0 ppm[90]
PVF/TiO2 nanocomposites150600 ppm8350 ppm[91]

3.4. Recent Advances in CO2 Gas Sensors

Artificial CO2 is widely used in the food production process, especially in greenhouses, and the food preservation process. As we mentioned in Section 2.3, artificial fertilization of CO2 is among the most common ways used to improve the environment in greenhouse applications for growth processes. The concentration levels of CO2 are maintained at between 200 and 1500 ppm by CO2 injection systems to optimize the growing conditions. If the level exceeds a concentration of 1500 ppm, it obstructs the productivity of the crops [33,34,35,36]. Thus, a sensing material should be sensitive of these CO2 levels to be suitable for this application.
Various materials have been fabricated as sensing layers of CO2 gas (Table 4). Recently, Thomas et al. [92] reported a high-performance sensor for CO2. The sensor was built from a porous p-Si/MoO3 nanohybrid structure, which was synthesized through vacuum thermal evaporation on a microporous silicon substrate. The sensor presented an outstanding performance with a sensitivity of 15% for 150 ppm. It showed repeatability and a fast response of 8.0 s for 100 ppm at a high temperature of 250 °C. It was operated at a low temperature of 150 °C and a lower detection limit of 50 ppm. Bag and Pal [93] presented a polymer composite sensor functionalized with MWCNTs. The sensors were tested in different humidity conditions, showing a good performance. It showed the highest sensitivities from 500–5000 ppm under various relative humidity levels of 30 to 70% RH at RT. The fabrication of the sensing layer in an n-PSi/p-CuO/n-Cu2O bilayer heterostructure might be promising for CO2 gas sensing [94]. The fabricated sensing layer was characterized at RT, showing sensitivity and reproducibility behavior. Additionally, the hybrid of CuO/rGO is intended for CO2 sensing at RT [95]. The presence of multifunctional groups in the CuO/rGO hybrid and the high surface area created a highly sensitive sensing layer for CO2 at RT. The thin layer of the CuO/rGO hybrid demonstrated a twice-sensing response compared to the rGO-based sensor for CO2. Additionally, the manufacture of sensors from hybrid materials is constantly increasing, for example, SnO2 with reduced graphene oxide (rGO) together in a sensing layer to detect CO2 at RT [96]. Due to the harmonious effect of mixing the near conductivity of metallic rGO and SnO2, the sensor showed an enhancement in the detection limit of 5 ppm of CO2. Moreover, it showed excellent sensing at RT and a humidity level of 58% RH. The sensor response was recorded, with a value of 1.206 toward 100 ppm of CO2, which was 6 times higher than the pure rGO sensing layer. The ternary hybrid sensing layer of rGO/NiO-In2O3 displayed a good sensing performance when exposed to 5 ppm CO2, with quick response/recovery times of 6/5s at RT and an LOD of 5 ppm [97].
Mixing organic and inorganic materials appears to be fruitful in responding to gases, and this field is supposed to provide an opportunity for the manufacture of hybrid material-based electronic devices for sensing applications. Nasirian et al. [98] prepared a polyaniline/SnO2 nanocomposite (PSN) sensor with various SnO2 concentrations. They built a good sensor for the detection of CO2 at RT. It showed a 39.2% response to about 5000 ppm CO2. Furthermore, the sensor exhibited reproducibility, reliability, and a selective response over multiple cycles for different CO2 levels. In another study, sensors containing stacked layers of LaNiSbWO4-G-PPy (G: graphene, PPy: polymer polypyrrole) were fabricated [99]. The gas sensor showed a high response to CO2 gas in the range of 200 to 4000 ppm at RT. It also showed a high selectivity. This gas sensor provided reproducibility, repeatability, and measurement accuracy. Continuing with the hybrid materials, a composite of multi-walled carbon nanotubes (MWCNTs) and a polypyrrolytic polymer (PPY) was synthesized as a sensing material [100]. The sensor displayed a response of 7.2 at a CO2 concentration of 1000 ppm. The response and recovery times were 30 and 37 s at 250 ppm, respectively. In general, the sensing mechanism of CO2 on the surface of the sensing layer mostly depends on the availability of highly reactive oxygen species. O2 molecules are adsorbed on the sensing layer surface, forming O species, which are reported to be highly reactive. Species of O are considered to affect the adsorption process and react with the CO2 molecules in the following processes [101]:
O 2   ( g a s )   O 2 ( a d s )  
O 2 ( a d s ) + 2   e   2   O
C O 2 ( g a s )   C O 2 ( a d s )
C O 2 ( a d s ) + O   C O 3
Table 4. The most recent chemiresistive CO3 sensors reported in the literature.
Table 4. The most recent chemiresistive CO3 sensors reported in the literature.
MaterialsOperating Temp. (°C)CO2
Concentration
Response %Limit of DetectionRef.
p-Si/MoO3250150 ppm12.050 ppm[92]
Sulfonated polyether ether ketoneRT5000 ppm47500 ppm[93]
CuO/rGO hybridRT500 ppm450--[95]
SnO2-rGO HybridRT500 ppm4.510 ppm[96]
rGO/NiO(8)-In2O3RT50 ppm405 ppm[97]
PANI-SnO2-UVRT5000 ppm47.43000 ppm[98]
G-LaNiSbWO4 -PPyRT1800 ppm120400 ppm[99]
MWCNT/PPYRT1000 ppm7.2250 ppm[100]
PDDA- MWCNTsRT20 ppm4.0---[102]
Au/PAni nanocompositesRT4000 ppm2.0--[103]

3.5. Recent Advances in C2H5OH Gas Sensors

The level of C2H5OH released due to spoilage of fruits or vegetables depends on the amount and level of fermentation. C2H5OH is a naturally occurring substance resulting from the fermentation of fruit sugars by yeast. Fruits and vegetables are more susceptible to spoilage than grains due to their nature and composition. In this regard, Satish Babu [104] attempted to produce C2H5OH from vegetables rich in spoiled starch such as wild potatoes and sweet potatoes, which contain abundant starch. In the presence of enzyme-mediated amylase- and polysaccharide-producing microorganisms, starch is converted to glucose monosaccharide. This sugared starch was subjected to alcoholic fermentation. They obtained an C2H5OH yield of about 7.5 mg/mL (7500 ppm) with enzyme-mediated glycation followed by inactivated yeast fermentation. The unripe fruits did not release any C2H5OH; however, the ripe and over-ripe fruits of the Neotropical palm contained C2H5OH within the pulp at average concentrations of 0.9% and 4.5% [105]. Fruit ripening was associated with significant changes in the color, sugar level, and C2H5OH content. However, the C2H5OH level required to detect spoilage of fruits and vegetable should be very low for early detection because the release of C2H5OH is due to the fermentation stage, which may occur after the ripening stage, which can be monitored by C2H4 detection. As mentioned above, wasted or spoiled vegetables and fruits contain sugar since 80% of the bio C2H5OH is produced [106]. Thus, C2H5OH sensors are considered as important for the detection of spoilage of stored food. Thus, an ultra-sensitive C2H5OH sensor was developed based on highly defected CNTs [107]. The CNTs were fabricated by the PECVD method, as shown in Figure 4a. The sensor was operated at a low temperature of RT. It showed a response of 8.8% against an C2H5OH concentration of 50 ppm. Moreover, it demonstrated an LOD of 5 ppm with a high capability of detecting different concentrations, as shown in Figure 4b. Coulomb interaction was proposed as the sensing mechanism, considering the polarity nature of C2H5OH due to the hydroxyl group bonded to the carbon atom end, since the oxygen and hydrogen electronegativities are 3.44 and 2.2, respectively. Based on this truth, the physical adsorption of the C2H5OH molecules can create Coulomb force (electric dipole) between the CNTs and C2H5OH, as shown in Figure 4c.
As mentioned earlier, the use of hybrid sensing layers has a positive influence on the sensing properties (Table 5). Mono-oxides are still being developed by organic materials to meet the sensing requirements because of their ease of manufacture and low complexity. For example, regarding ZnO spheres assembled by porous nanosheets via a one-step hydrothermal method, their properties influence the C2H5OH gas sensing response by adjusting the amount of polyvinylpyrrolidone (PVP) [108]. A sensor based on a ZnO nanosphere compound manufactured by 3.3 g PVP achieved a response of ~58.4 to 100 ppm C2H5OH but was operated at high temperatures of 250 °C. It is worth noting that this response is about 9.4 times higher than that observed for the ZnO nanosheet layer fabricated without PVP. Moreover, the LOD can attain a ppb level, where a response of 1.17 was observed to an C2H5OH concentration of 500 ppb. However, In2O3 nanotube composites derived from MOF and Cr2O3 nanoparticles have been used as the sensing layer [109]. The In2O3/Cr2O3 composite sensor showed an excellent performance in sensing C2H5OH at RT for a concentration as low as 5 ppm. It also showed excellent selectivity, good repeatability, quick response/recovery time, and long-term stability. Additionally, Yu et al. [110] obtained hollow ZnSnO3 microspheres decorated with CeO2 nanoparticles with heterogeneous structures to meet the requirements for C2H5OH detection. The hollow microspheres of CeO2/ZnSnO3 showed a response of 219.2 to 100 ppm of C2H5OH compared with pure ZnSnO3, which showed a much lower response. It also exhibited superior selectivity and a quick recovery response to C2H5OH compared to other gases. These properties of C2H5OH were explained by the large quantity of oxygen dissociation and the n-n hetero bonding of ZnSnO3/CeO2. Not only do the binary compounds show an optimal response to C2H5OH but the synthesis of a tri-compound, such as MoO2-Ni-graphene, sensing material also has attractive sensing properties [111]. By testing the gas sensing performance of this layer to C2H5OH, a significant improvement in the response of up to 105 was found when exposed to 1000 ppm at RT. The LOD at RT was 15 ppm. A great impact regarding the improvement of the sensing properties of C2H5OH was observed due to the metallic nature of Mo and Ni on the surface of graphene. This sensor has been tested for long periods and has enhanced its stability as a good candidate for the commercial market.
At the end of this section, we explain a good approach to sensor development. Interestingly, a self-powered sensor for C2H5OH was fabricated based on an Ag/ZnO nanowire array [112]. The self-power was served by the piezoelectric phenomena of the Ag/ZnO array. At the same time, it could sense the concentration of C2H5OH at RT by changing the piezoelectric output. The piezoelectric output was significantly increased by the addition of Ag. The piezoelectric voltage decreased from 1.7–0.2 V when the sensor was exposed to 10–1000 ppm of C2H5OH. The change in the output voltage was attributed to Ag, where Ag atoms play a catalytic role, in addition to the formation of Schottky barriers between Ag and ZnO. This sensor design provides an opportunity to achieve a self-powered gas sensor in various applications. Additionally, a promising sensor was fabricated by Raghu et al. [113]. They developed flexible sheets of TiO2 grafted with 2D-TiC nanoparticles (TiO2@2DTiC) operating at RT. The flexible sensor showed high selectivity towards C2H5OH gas at a concentration of 10 ppb to 60 ppm. This was attributed to the availability of electron-hole synthesis at the TiO2/2D-TiC interfaces. This wearable sensor can be electronically printed for use in the environmental monitoring sectors of long-term stored foods.

4. Future Perspectives and Conclusions

In summary, toxic gas sensors play an important role in food production and control. Therefore, researchers have recently devoted significant attention to various gas sensing materials to achieve high-performance gas sensors. However, knowledge of the aspects of the applications and the appropriateness of the environment in which the sensor is intended to be used may help a lot in the development of optimal sensors. The prospects for the use of sensor technology in food production and monitoring are: (1) Development of simple sensors that operate at low temperatures and preferably RT to save energy consumed during the monitoring process and the lifespan of the sensing material and accordingly, (2) the development of reliable sensors that can be woven into the clothing of workers in meat and fish stores to identify their condition in real time; (3) the identification of promising candidates for reducing device circuit complexity, which can be integrated into portable devices with low-energy-density batteries; and (4) the design of high-precision sensors to monitor the strategic stock of foodstuffs, especially C2H4 gas, to monitor the quality of stored fruits and vegetables and control their age. Chemiresistive sensors are easy to manufacture, cheap, and easy to integrate. It is noted that the most suitable sensing layers for these environments are those made of polymer and nanocarbon materials combined with oxides. Researchers are interested in obtaining improvements in the sensitivity, selectivity, limit of detection, and operating temperature using a new mixture of nanomaterials that display different shapes. However, challenges remain. Thus, we reported the use of gases in food production, processing, and monitoring to provide knowledge for the sensing community.

Author Contributions

Conceptualization, N.M.S., F.A., O.S. and S.K.; methodology, N.M.S., F.A., O.S. and S.K.; formal analysis, N.M.S., F.A., O.S. and S.K.; writing—original draft preparation, N.M.S. and F.A.; writing—review and editing, N.M.S., O.S. and S.K.; visualization, N.M.S.; supervision, N.M.S.; project administration, N.M.S.; funding acquisition, N.M.S. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported by the Deanship of Scientific Research, Vice Presidency for Graduate Studies and Scientific Research, King Faisal University, Saudi Arabia [Grant No. CHAIR60].

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Acknowledgments

We extend our appreciation to the Deanship of Scientific Research, Vice Presidency for Graduate Studies and Scientific Research, King Faisal University, Saudi Arabia, for extending the grant to [Grant No. GRANT1379].

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. The h5-index for articles published in the last five complete years (2017–2021) in food science and technology.
Figure 1. The h5-index for articles published in the last five complete years (2017–2021) in food science and technology.
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Figure 2. Scheme of the gases used in or produced from food operations.
Figure 2. Scheme of the gases used in or produced from food operations.
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Figure 3. (a) Sensor response of a single banana as a function of the ripening days, detecting the ripening of banana over five days; (b) Repeated sensor signal (five cycles) for (c) different bananas at different ripening levels. Figures adapted with permission from [21].
Figure 3. (a) Sensor response of a single banana as a function of the ripening days, detecting the ripening of banana over five days; (b) Repeated sensor signal (five cycles) for (c) different bananas at different ripening levels. Figures adapted with permission from [21].
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Figure 4. (a) Scheme of the synthesis of CNTs and sensing device fabrication; (b) signal as a function of time at different gas concentrations for the sensor prepared by 18 and 24 nm of Ni catalyst layer; and (c) the C2H5OH sensing mechanism. Figures reproduced with permission from [107].
Figure 4. (a) Scheme of the synthesis of CNTs and sensing device fabrication; (b) signal as a function of time at different gas concentrations for the sensor prepared by 18 and 24 nm of Ni catalyst layer; and (c) the C2H5OH sensing mechanism. Figures reproduced with permission from [107].
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Table 1. The most recent chemiresistive C2H4 sensors reported in the literature.
Table 1. The most recent chemiresistive C2H4 sensors reported in the literature.
MaterialsOperating Temp. (°C)C2H4 ConcentrationResponse %Limit of
Detection
Ref.
Defective-CNTsRT300 ppb~2.7130 ppb[15,21]
TiO2-WO3250100 ppm1.28.0 ppm[60]
Pd-SnO2250100 ppm11.150 ppb[61]
PANI/MWCNTs/SnO2RT100 ppm1.210 ppm[62]
Pd/rGO/α-Fe2O2501000 ppm16010 ppb[63]
SnO23752.5 ppm15---[64]
Cr2O3-SnO23502.5 ppm17---
β-MnO225025 ppm10.010 ppm[65]
ZnO-Ag0.6RT30 ppm5.6--[66]
Table 2. The most recent chemiresistive NH3 sensors reported in the literature.
Table 2. The most recent chemiresistive NH3 sensors reported in the literature.
MaterialsOperating Temp. (°C)NH3 ConcentrationResponse %Limit of DetectionRef.
PANI/SrGe4O2RT200 ppb16.0 250 ppt[68]
DPPT-TT-based OFETs-based sensorsRT2 ppm
21 ppb
~8.0
~22
500 ppb
2.17 ppb
[69,70]
CeO2RT500 ppm25500 ppb[71]
PANI/GO/PANI/ZnORT100 ppm38.323 ppm[72]
MXene/rGORT100 ppm7.0 ---[73]
Carbon doped-TiO2RT100 ppm18---[75]
Black phosphorus (BP)RT100 ppm1.2100 ppb[76]
Ce-TiO2RT20 ppm23.9140 ppb[77]
TiO2 Nanospheres250300 ppm2.1--[78]
N-TiO2RT3 ppm1.21.0 ppm[79]
TiO2/Ti3C2TxRT10 ppm1.03500 ppb[80]
Table 5. The most recent chemiresistive C2H5OH sensors reported in the literature.
Table 5. The most recent chemiresistive C2H5OH sensors reported in the literature.
Sensor Operating Temp. (°C)C2H5OH
Concentration
Response %Limit of
Detection
Ref.
MWCNTsRT50 ppm8.85 ppm[107]
ZnO microspheres250100 ppm58.41.17 ppb[108]
CeO2/ZnSnO3200100 ppm2190.5 ppm[110]
In2O3/Cr2O3RT50 ppm15.65 ppm[109]
MoO2-Ni-GrapheneRT1000 ppm10515 ppm[111]
Ag/ZnO nano-generatorRT800 ppm8810 ppm[112]
TiO2@2D-TiCRT60 ppm39010 ppm[113]
PEG/MWCNTsRT50 ppm2.9--[114]
Au-CNFsRT100 ppm6.350 ppm[115]
High-density CNTsRT50 ppm0.18--[116]
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Shaalan, N.M.; Ahmed, F.; Saber, O.; Kumar, S. Gases in Food Production and Monitoring: Recent Advances in Target Chemiresistive Gas Sensors. Chemosensors 2022, 10, 338. https://doi.org/10.3390/chemosensors10080338

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Shaalan NM, Ahmed F, Saber O, Kumar S. Gases in Food Production and Monitoring: Recent Advances in Target Chemiresistive Gas Sensors. Chemosensors. 2022; 10(8):338. https://doi.org/10.3390/chemosensors10080338

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Shaalan, Nagih M., Faheem Ahmed, Osama Saber, and Shalendra Kumar. 2022. "Gases in Food Production and Monitoring: Recent Advances in Target Chemiresistive Gas Sensors" Chemosensors 10, no. 8: 338. https://doi.org/10.3390/chemosensors10080338

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