Development, Optimization, and Validation of Radium-226 Measurement in Oyster, a Sentinel Organism by Mass Spectrometry
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Sample Preparation
2.3. Analysis
2.4. Method Validation and Application
3. Results and Discussion
3.1. Mineralization Efficiency
3.2. Separation Efficiency
3.3. Ra Spike Recovery
3.4. Oyster Samples
3.5. Method Validation and Figures of Merit
4. Conclusions and Perspectives
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Element | Certified Values (µg/g) | Recovery Percentage |
---|---|---|
Na | 19,700 ± 2300 | 91 ± 17% |
Mg | 3080 ± 390 | 91 ± 2% |
Ca | 2430 ± 280 | 113% ± 8% |
Zn | 727 ± 48 | 99% ± 18% |
V | 0.9 ± 0.1 | 80% ±3% |
Mn | 66.7 ± 5.3 | 95% ± 1% |
Fe | 131 ± 12 | 89% ± 4% |
Cu | 146 ± 13 | 108% ± 1% |
As | 11.9 ± 0.9 | 91% ± 2% |
Rb | 5.14 ± 0.59 | 96% ± 4% |
Sr | 20.6 ± 1.6 | 92% ± 3% |
Pb | 0.36 ± 0.05 | 96% ± 5% |
Concentration in Digestate of O-SoftT (µg/L) | % of Elimination after Resin Separation (Vdigestate = 120 mL) | Concentration in Digestate in O-Shell (µg/L) | % of Elimination after Resin Separation (Vdigestate = 2.5 mL) | |
---|---|---|---|---|
Li | 38 | 100% | 64 | 100% |
Na | 1,232,000 | 100% | 255,000 | 100% |
Mg | 162,000 | 100% | 60,400 | 100% |
Al | 150 | 5% | <5130 | - |
K | 534,000 | 100% | 10,700 | 92% |
Ca | 127,000 | 100% | 12,120,000 | 100% |
V | 27 | 100% | <0.2 | - |
Mn | 130 | 100% | 5220 | 100% |
Fe | 2674 | 100% | 3040 | 99% |
Co | 9 | 100% | <21 | - |
Ni | 37 | 99% | <190 | - |
Cu | 2600 | 100% | 36 | 96% |
Zn | 66,600 | 100% | 470 | 97% |
As | 1300 | 99% | 20 | 95% |
Rb | 190 | 100% | <7 | - |
Sr | 2230 | 100% | 31,600 | 100% |
Ba | 366 | 75% | 39 | 88% |
Pb | <8 | - | <2 | - |
U | 12 | 100% | 4 | 100% |
Method LOQ (fg/g) | Oyster 1 | Oyster 2 | |
---|---|---|---|
Dry O-SoftT One aliquot of 48 mL on one resin column set | 0.3 (n = 9) | 20.9 ± 0.4 (n = 5) | 3.7 ± 0.6 (n = 6) |
O-Shell One aliquot of 2.5 mL on one resin column set | 23 (n = 7) | 25.3 (n = 1) | <LOQ |
O-Shell Three aliquots of 2.5 mL on three resin column sets | 7.7 fg/g (n = 7) | - | 15.1 (n = 3) |
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Landry, A.; Banville, S.; Clarisse, O. Development, Optimization, and Validation of Radium-226 Measurement in Oyster, a Sentinel Organism by Mass Spectrometry. Separations 2023, 10, 529. https://doi.org/10.3390/separations10100529
Landry A, Banville S, Clarisse O. Development, Optimization, and Validation of Radium-226 Measurement in Oyster, a Sentinel Organism by Mass Spectrometry. Separations. 2023; 10(10):529. https://doi.org/10.3390/separations10100529
Chicago/Turabian StyleLandry, Alexandre, Samuel Banville, and Olivier Clarisse. 2023. "Development, Optimization, and Validation of Radium-226 Measurement in Oyster, a Sentinel Organism by Mass Spectrometry" Separations 10, no. 10: 529. https://doi.org/10.3390/separations10100529