Gelating Abilities of Two-Component System of Catecholic Derivatives and a Boronic Acid
Abstract
:1. Introduction
2. Results and Discussion
3. Conclusions
4. Materials and Methods
4.1. General
4.2. Typical Procedure for Syntheses of 2a–d
4.3. Typical Procedure for Syntheses of 4a–d
4.4. Typical Procedure for Syntheses of 6a–d
4.5. Procedure for Synthesis of 9
Author Contributions
Funding
Conflicts of Interest
References
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2a | 2b | 2c | 2d | 4a | 4b | 4c | 4d | |
---|---|---|---|---|---|---|---|---|
Hexane | I | I | I | I | I | I | I | I |
Cyclohexane | I | I | I | I | I | I | I | I |
Toluene | I | P | G(7.0) | G(5.5) | S | G(4.5) | G(3.5) | G(2.5) |
Benzene | S | P | G(7.0) | G(5.0) | S | PG | PG | G(4.0) |
Chloroform | I | P | P | G(3.0) | I | P | PG | G(3.0) |
EtOH | S | S | S | S | S | S | S | G(1.0) |
MeOH | S | S | S | S | S | S | S | S |
DMF | S | S | S | S | S | S | G(2.0) | G(1.5) |
DMSO | S | S | S | S | S | S | S | G(3.0) |
6a | 6b | 6c | 6d | 7 | 8 | |
---|---|---|---|---|---|---|
Hexane | I | I | I | I | I | I |
Cyclohexane | I | I | I | I | I | I |
Toluene | I | P | PG | G(4.5) | S | G(0.8) |
Benzene | I | P | PG | G(4.5) | S | G(0.8) |
Chloroform | I | S | G(7.0) | S | S | G(1.0) |
EtOH | S | S | PG | S | S | G(1.5) |
MeOH | S | S | PG | S | S | S |
DMF | S | S | S | S | S | S |
DMSO | S | S | S | G(3.0) | S | S |
2c/9 | 2b/9 | 4b/9 | 4c/9 | 4d/9 | 6b/9 | 6c/9 | 6d/9 | |
---|---|---|---|---|---|---|---|---|
Toluene | S | S | G(7.0) | G(6.5) | G(4.5) | P | G(3.5) | G(2.5) |
Benzene | S | S | G(7.5) | G(7.0) | G(5.5) | P | G(3.5) | G(2.5) |
Chloroform | P | S | P | PG | G(8.0) | S | G(4.0) | G(4.0) |
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Tsuge, A.; Kamoto, R.; Yakeya, D.; Araki, K. Gelating Abilities of Two-Component System of Catecholic Derivatives and a Boronic Acid. Gels 2019, 5, 45. https://doi.org/10.3390/gels5040045
Tsuge A, Kamoto R, Yakeya D, Araki K. Gelating Abilities of Two-Component System of Catecholic Derivatives and a Boronic Acid. Gels. 2019; 5(4):45. https://doi.org/10.3390/gels5040045
Chicago/Turabian StyleTsuge, Akihiko, Ryota Kamoto, Daisuke Yakeya, and Koji Araki. 2019. "Gelating Abilities of Two-Component System of Catecholic Derivatives and a Boronic Acid" Gels 5, no. 4: 45. https://doi.org/10.3390/gels5040045