1. Introduction
This work is interdisciplinary. It may contribute to the theoretical base to establish collapsing of glass tubes as a precise, contact-free method to measure temperature-dependent viscosities [
1,
2,
3,
4,
5,
6,
7,
8,
9,
10,
11] and surface tensions [
9,
10] of molten glasses. There is a general consensus that molten glasses should be treated as highly viscous Newtonian fluids. This shows that exclusively laminar flow can occur. Our work may also contribute to succeed in the analytic treatment of boundary value problems of the Stokes equation, in particular, if the viscosity rapidly varies on length scales of the confinement, so that asymptotic methods [
11] fail.
When an axial section of a glass tube is heated such that the glass becomes a viscous fluid, the tube will collapse back upon itself inside the heating zone, driven by the surface tension. We will focus here on collapsing under steady-state conditions only, and the term “collapsing” will be exclusively used for steady-state collapsing. This occurs if the heat source moves uniformly along the tube. Then an observer comoving with the heat source becomes aware of a steady-state collapsing profile narrowed against the direction of motion. It is provided, of course, that the comoving observer measures, at the same time, an accompanying steady-state temperature field. If, in addition, different axial streaming velocities are impressed on both sides of the heating zone such that the impressed flow difference will play the role of the proper driving force, one speaks of “drawing”.
Collapsing and drawing are known, first at all, as fundamental technology steps in the fabrication of optical fibers and complex fiber structures (for a survey on theoretical problems in the area of collapsing, see, e.g., [
2,
9,
11], and drawing, see, e.g., [
12,
13,
14,
15,
16,
17]). The principle of collapsing is also applied to the so-called redraw process to produce highly precise glass sheets for optical applications (see, e.g., [
18,
19]). In our work, we focus on preferably simple arrangements where a comprehensive understanding of all aspects of collapsing is essential. The horizontal collapsing arrangement studied here is sketched in
Figure 1. It is the same as investigated in [
11].
The glass tube may be fixed in the labor frame. The tube wall may be represented by two infinitely extended circular, coaxial cylinders. A mobile heat source (simply called “torch” in the following) may move along the tube with uniform velocity and create, steady-state conditions provided, a comoving steady-state peak of the tube temperature. If the maximum temperature is large enough so that the glass becomes a viscous fluid, the surface tension induces a radial force towards the cylinder axis. Then the moving torch becomes accompanied by a comoving cone-like reduction of the tube dimensions against the moving direction (see
Figure 1). To determine the temperature-dependent dynamical glass viscosity (simply called “viscosity” in the following), the input data from steady-state collapsing measurements are the tube radii and tube wall thickness, respectively, before collapsing, the torch velocity, and the reduction of the outer tube radius and increasing of the wall thickness, respectively, after collapsing. These data are supplied by the current axial course of the tube temperature. All input data can be precisely determined with the aid of optical and pyrometric tools, respectively (not shown in
Figure 1). For details, see, e.g., [
9,
10].
For perpendicularly arranged drawing equipment, contactless, non-steady-state in situ viscosity measurements on compact glass fibers have been described (for a recent version, see, e.g., [
20]). The measuring principle exploits the time-dependent fiber elongation around a temperature hot spot where the glass becomes a highly viscose fluid and the balance between gravity and resetting force through surface tension is slightly disturbed. The surface tension by itself is determined from the force equilibrium conditions. A strong hydrodynamic analysis is not known so far.
The steady-state viscosity measurement through collapsing requires the knowledge of any ad hoc model relations describing the general temperature dependence of the viscosity for selected material classes. This approach is necessary to determine, by calculation only, that axial viscosity course which correlates with the measured axial temperature course. More precisely, the measurement of the temperature-dependent glass viscosity through collapsing comprises the determination of two or more parameters involved in such ad hoc model relations, e.g., the Arrhenius law and the Vogel-Fulcher law with two and three parameters, respectively (for details, see, e.g., [
21]). Assuming, for a moment, these parameters are known, the precise axial viscosity course is known, too, and the collapsing theory should be able to verify the measured steady-state collapsing profile. The inverse problem, namely the back-calculation of those parameters in question from experimental data is more complicated and to some degree straightforward only if preconditions are met to use the asymptotic analysis. We refer to
Section 4 und
Section 5. Clearly, the determination of two or more unknown parameters entering formulae of the temperature-dependent viscosity requires two or more independent collapsing measurements. Finally, measurements of the surface tension of molten glasses can be involved into collapsing experiments [
9,
10]. The idea is, in principle, a modification of the well-known bubble pressure method [
22], applied to collapsing equipment. We refer to
Section 4.2.
The collapsing theory outlined here as well as in previous papers is based on the Stokes equation for incompressible liquids, regarding the extremely low Reynolds number of molten glasses under collapsing conditions of about
. Initially, very simple mathematical approximations motivated more by physical intuition were used to describe the collapse process [
1,
2,
5,
6,
7,
8,
9]. In [
11], a comprehensive analysis has been given, applying the ideas of the asymptotic multi scale analysis (AMSA). It is ad hoc provided there that the spatial dependence of hydrodynamic and geometric quantities is governed by different length scales
h and
l in radial and axial direction, respectively, where
. As far as this fundamental premise holds true in practice, AMSA considerably facilitates the analysis of collapsing. In particular, it allows an entangled perturbation treatment of hydrodynamic equations, boundary conditions, and kinematics in powers of
, which is also the base to classify various complex effects contributing to collapsing.
h and
l naturally stand for the outer tube radius before collapsing, and the axial width of the reciprocal viscosity, respectively, where
l is also a measure of the axial width of the temperature peak. In practice, the AMSA in zeroth order dealing with the radial flow component only, and in first order, dealing with both the radial and axial flow component, can be performed with reasonable effort (in [
11] denoted as 1D and 2D theory, respectively). The error estimation [
11] shows that AMSA becomes successively erroneously for
where the data evaluation through AMSA becomes questionably.
Unfortunately, the preconditions where AMSA works well do not sufficiently meet two basic experimental requirements to arrive at a highly precise ascertainment of the above-mentioned input data after collapsing. First, the tube radii should be chosen as large as possible (≥1 cm) to minimize the error in the optical shrinking measurements [
9,
10]. Secondly, the exact record of the temperature course requires the entire visibility of the glass tube crossing the heating zone. This latter condition is well satisfied by equipment applying oxyhydrogen ring burners [
9,
10] which can produce, in addition, rather sharp and well reproducible temperature peaks. But the optimum choice regarding both the preconditions is found for about
. Earlier attempts to operate with tube-shaped furnaces where the collapsing zone is invisible and the peak temperature must be estimated [
23] are not helpful, although the axial length of the heating zone could be arbitrarily chosen.
To the authors knowledge, no strong analytical solutions of more complex boundary value problems of the Stokes equation have been published, which could serve as a guide for the problem to be solved here. The general attention regarding variable viscosities seems still focused on finding of rigorous analytical solutions as such in the first place. In this context, the early work of Martin (1971) [
24] is still of interest (see, e.g., [
25,
26,
27]), which exploits a relationship between a variable viscosity and the vorticity. However, completely different methods, e.g., mode coupling [
28,
29] have been investigated, too, for geophysical applications [
29,
30], but mainly to find so-called benchmark solutions to adjust computer calculations [
30,
31].
Thus, our mathematical approach is novel, and without exploiting abstract functional-analytic methods. We present a classical analysis of the hydrodynamics of collapsing without the ad hoc restriction to sufficiently broad peaks of the axial temperature course and reciprocal viscosity, respectively. We focus on model courses of the axially dependent reciprocal viscosity chosen as Gaussians. The Stokes equation with the full set of boundary conditions is solved for infinitely extended tubes with constant radii. This implies the exact description of the collapsing kinematics for the limiting case of large torch velocities. We use the conception of AMSA only for error estimations for more general viscosity courses, as well as for torch velocities below the asymptotic limit. In
Section 2, we start with the Stokes equation for incompressible liquids. In particular, we focus on the transformed version for axial symmetry and an axial viscosity dependence outlined in [
11], given as coupled equations for the stream function, vorticity and pressure. A program to arrive at a clearly arranged treatment of boundary conditions is carried out in
Section 3. The stream function discussed in
Section 3.1 is shown to be closely related to the balance of the normal forces on both the surfaces, meanwhile the vorticity analyzed in
Section 3.2 is governed through the tangential force balance even there. Both the functions will induce separate, space-dependent contributions to the pressure, discussed in
Section 3.3. Because, vice versa, the pressure participates in the normal force balance, an equation to guarantee the self-consistency of all hydrodynamic functions is established and solved in
Section 3.4. The collapsing kinematics is discussed in
Section 4. We point out that the earlier concise formulae from AMSA for determining of the viscosity from collapsing data must be supplied by a correction factor only, meanwhile the surface tension can be measured through suppression of collapsing, where no knowledge of the viscosity course is required at all. The general discussion in
Section 5 is focused on optimized experimental conditions to minimize unavoidable systematic errors in the viscosity measurement.
2. Equations and Boundary Conditions
The collapsing tube walls and the main components of the viscous flow and vorticity are sketched in
Figure 2. The axis of the collapsing tube may be the
z-axis of a cylinder coordinate system (
r,
,
z). The outer and inner tube radius before collapsing may be denoted by
, and
, respectively.
For incompressible fluids, the Stokes equations read
is the viscous flow vector,
p the pressure inside the tube,
the viscosity, and
that part of the stress tensor originated by the viscous material properties.
, and
denote the normal and tangential vector at the outer and inner tube surface, respectively. We will focus on the analysis of the viscous flow field if the outer and inner tube radius can be provided as constant, i.e., independent of
z (see
Section 4 and
Section 5 for a detailed discussion). Then the flow field is determined as solution of (
1) and (
2) with the boundary conditions (see, e.g., [
11])
where (
3) and (
4) is the balance condition of the normal and tangential force on both the tube surfaces, respectively.
is the surface tension, which is assumed to be constant (see also
Section 4.2). We will denote (
3) and (
4) as the radial boundary conditions. The latter must be supplied by axial boundary conditions. In what follows, we will consider an infinitely extended tube where away from the heating zone, the viscosity continuously but unlimited increases so that the viscous flow driven by limited external forces must expire. Thus, we have the axial boundary condition
The torch may move along the tube with the constant velocity
in
-direction. We will restrict to steady-state conditions, i.e., an observer which comoves with the torch may measure steady-state quantities in his frame of reference. In particular, we will assume a model viscosity course, which is steady-state in the comoving frame of reference, according to
where
and
denote the minimum viscosity, and the half of the axial width where the viscosity increases to its
e-fold minimum value, respectively. The Stokes Equations (
1) and (
2) and the boundary conditions (
3) to (
5) are invariant against the transformation (
7) from labor coordinates (
r,
,
z) to coordinates (
r,
,
) which comove with the torch. Therefore, we will make the agreement to change generally to comoving coordinates, so that an explicit time-dependence disappears in describing the steady state in comoving coordinates. More precisely, the viscous flux and the stress tensor are understood to be measured in the labor frame, but treated as functions of the comoving coordinates, as with all other hydrodynamic quantities. In the following,
z may denote the comoving axial coordinate.
Following [
11] we will make the second agreement to change to dimensionless quantities and coordinates so that (
1) to (
4) remain invariant. Based on three benchmarks
(length benchmark),
, and
, the dimensionless radial and axial coordinate
, and
are introduced by
, and
, respectively, and the velocity
v and pressure
p in physical units become scaled through the corresponding dimensionless quantities
and
by
, and
, respectively. The dimensionless viscosity
and surface tension are given by
, and
, respectively.
will be chosen as
. For further details see [
11]. All mathematical expressions outlined below will be given in dimensionless units, where we will renounce the overbar (for clearness, the symbol
will be used furthermore). Then the model course of the dimensionless reciprocal viscosity yields
where
.
Through the boundary conditions (
3), (
4) and the precondition (
6), our problem becomes an axial-symmetrical one so that all quantities of interest will depend upon
r and
z only. The further treatment according to [
11] aims at the elimination of the inconvenient restriction (
2). This is done introducing the vector potential
according to
In cylinder coordinates,
reads
with
as the azimuthal unit vector. The azimuthal component
of the vector potential is the stream function of our problem, from which the radial and axial flux component,
and
, respectively, are derived according to
It is shown in [
11] that, starting from (
9), (
10), the Stokes Equation (
1) can be transformed into three coupled equations for the stream function
, an auxiliary function
, and the pressure
, according to
where the operator
stands for
The auxiliary function
introduced in [
11] guarantees the compatibility of the ansatzes (
9), (
10) with (
1). One can show (the author thanks one of the referees of [
11] for this suggestion) that
agrees with the azimuthal component of the vorticity vector
. Indeed, evaluating the r. h. s. of the foregoing relation and observing
, as concluded from (
10), we arrive at
(see, e.g., [
32]), and the argued result follows from (
13).
For the remaining of this paper, we abbreviate
will be denoted as the vorticity function, the equation of which is simply found substituting (
17) into (
14). At this point, we take a step further to circumvent complicated expressions of
involved in (
14). If we ad hoc commit ourselves to the model course (
8) of the reciprocal viscosity, further substitute
on the r. h. s. of (
14) via (
13), and divide by
, where
, we obtain
To derive the radial boundary conditions of
and
to be applied in practice we need the following tensor components of
(see, e.g., [
32])
to be substituted in (
3) and (
4), respectively. Because
is expressed in terms of the streaming function
only, apparently,
would become over-constrained through the four boundary conditions (
3), (
4) regarding the radial dependence. Indeed, the vorticity function
provides the missing degrees of freedom required to satisfy all balance conditions on both the tube boundaries, as seen below.
The pressure
is given by the radial integration of (
15) up to an arbitrary constant
, as shown in [
11]. In what follows, it is very useful to subdivide
into a constant and a variable part,
and
, respectively, according to
where the radial integration of (
15) may be carried out such that
We will call
the variable “hydrodynamic” pressure part, because depending upon the viscous flow only. The boundary condition (
3) can be rewritten, taking into account (
19):
where the upper and lower sign on the r.h.s. of (
23) is valid for
and
, respectively.
The boundary condition of the tangential force balance (
4) will be reformulated to become a boundary condition for the vorticity function. This boundary condition remains dependent upon the stream function. Observing (
20) and introducing
according to (
13) and (
17), we get
The reciprocal viscosity
governs the axial symmetry of the hydrodynamic functions. The model course (
8) of
as well as
are even in
z, meanwhile the stream function
, its contributions
and
introduced below, as well as
S are odd in
z. The same symmetry properties hold true for the axial Fourier transforms discussed in the next sections.
6. Summary
We improve the theoretical base to understand collapsing of glass tubes, as necessary precondition to establish the steady-state collapsing with moving torch as a precise and contact-free method to determine temperature-dependent viscosities and surface tensions of molten glasses. We focus, in particular, on novel analytical solutions of the covering boundary value problem of the Stokes equation for sharply peaked axial courses of the reciprocal viscosity. Our aim is to extend the validity range beyond the limits of the established asymptotic methods (AMSA). The strong solutions derived here neglect the inclinations of the tube boundaries, which meets the conditions of the collapsing kinematics for sufficiently large torch velocities. We take up the ideas of AMSA to estimate the order of the corrections, if the boundary inclination should be taken into account.
Despite the neglected boundary inclination, the presupposed strong axial viscosity dependence leads to a substantial complication of the boundary value problem. For disentanglement, we derive a gradually interdependent hierarchy of equations and boundary conditions for the stream function, the vorticity and pressure, starting from the experimental input conditions. In addition, we introduce axial Fourier transforms to set up of solutions for infinitely extended tubes, which obey axial boundary conditions according to the expiring viscous flow behavior for unboundedly increasing viscosity courses beyond the collapsing zone. We outline model solutions for the course of the reciprocal viscosity specified as Gaussians, the axial half-width of which may be much smaller than the outer tube radius.
We show that for sufficiently sharply peaked axial temperature courses, a connection exists between the steepness of the axial course of reciprocal viscosity, the vorticity of the viscous flow, and the radial pressure gradient. The latter acts against the surface tension and retards the collapsing kinematics. This effect is not predicted by the established asymptotic theory. Thus, the minimum viscosity attributed to the peak temperature, if evaluated from experimental date according to the asymptotic1D and 2D theory, is found to be too large up to one order of magnitude.
For data evaluation in practice, in particular, for the back-calculation of the viscosity from experimental input data, we outline a simple extension of convenient formulae from the 1D theory in virtue of a correction factor only. In addition, we outline error estimations regarding both the unavoidable boundary inclination and convective heat conduction within the tube wall. Both systematic errors will work against each other, if the torch velocity is considered to be a run parameter. But model calculations predict the existence of a reasonable compromise.