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Article
Peer-Review Record

Synthesis, Structure, and Spectroscopic Properties of Luminescent Coordination Polymers Based on the 2,5-Dimethoxyterephthalate Linker

Chemistry 2023, 5(2), 965-977; https://doi.org/10.3390/chemistry5020065
by Aimée E. L. Cammiade, Laura Straub, David van Gerven, Mathias S. Wickleder and Uwe Ruschewitz *
Reviewer 1:
Reviewer 2:
Chemistry 2023, 5(2), 965-977; https://doi.org/10.3390/chemistry5020065
Submission received: 31 March 2023 / Revised: 14 April 2023 / Accepted: 19 April 2023 / Published: 22 April 2023
(This article belongs to the Special Issue Commemorating 150 Years of Justus von Liebig’s Legacy)

Round 1

Reviewer 1 Report

In this manuscript, the authors report two new MOFs and compare the related properties with already reported Mn and Zn congeners. The topic itself is interesting and this paper might suitable for the publication on Chemistry, but before publication, revision should be made. More detail comments are as follows:

1. All the reported four MOFs are synthesized with closed experimental methods and processes. But, the last one, that is, Mg-based MOF show different structure. It is better to analyze the origin of this difference.

2. The final R indexes for Mg-based MOF is higher than that of Co-based one? Why? Is this due to the poor data or crystal quality?

In this manuscript, the authors report two new MOFs and compare the related properties with already reported Mn and Zn congeners. The topic itself is interesting and this paper might suitable for the publication on Chemistry, but before publication, revision should be made. More detail comments are as follows:

1. All the reported four MOFs are synthesized with closed experimental methods and processes. But, the last one, that is, Mg-based MOF show different structure. It is better to analyze the origin of this difference.

2. The final R indexes for Mg-based MOF is higher than that of Co-based one? Why? Is this due to the poor data or crystal quality?

Author Response

Please see the attachment

Author Response File: Author Response.pdf

Reviewer 2 Report

This paper reports on the structural characterization and luminescence properties of two new coordination polymers based on DMT linker.  This study shows clear results and deserves publication in Chemistry.  I have one comment the authors should consider. Since the originality of the Mn and Zn complexes belongs to the authors of reference 20, they should not be treated with similar numbering in this paper. Even in the table, it should be clearly distinguished from the Co and Mg complexes and treated as comparison targets.

Author Response

Please see the attachment.

Author Response File: Author Response.pdf

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