Next Article in Journal
Chemistry, Synthesis, and Structure Activity Relationship of Anticancer Quinoxalines
Previous Article in Journal
Recognizing New Types of Stacking Interactions by Analyzing Data in the Cambridge Structural Database
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Chemistry
Volume 5
Issue 4
10.3390/chemistry5040165
chemistry-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Review

Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data

by
Georgii Misikov
,
Maya Trofimova
* and
Igor Prikhodko
Department of Chemical Thermodynamics and Kinetics, Institute of Chemistry, Saint Petersburg State University, Saint Petersburg 198504, Russia
*
Author to whom correspondence should be addressed.
Chemistry 2023, 5(4), 2542-2565; https://doi.org/10.3390/chemistry5040165
Submission received: 22 October 2023 / Revised: 10 November 2023 / Accepted: 11 November 2023 / Published: 13 November 2023
(This article belongs to the Section Physical Chemistry and Chemical Physics)
Review Reports Versions Notes

Abstract

This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.
Keywords: vapor-liquid equilibrium; ethyl acetate; thermodynamic consistency vapor-liquid equilibrium; ethyl acetate; thermodynamic consistency

Share and Cite

MDPI and ACS Style

Misikov, G.; Trofimova, M.; Prikhodko, I. Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data. Chemistry 2023, 5, 2542-2565. https://doi.org/10.3390/chemistry5040165

AMA Style

Misikov G, Trofimova M, Prikhodko I. Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data. Chemistry. 2023; 5(4):2542-2565. https://doi.org/10.3390/chemistry5040165

Chicago/Turabian Style

Misikov, Georgii, Maya Trofimova, and Igor Prikhodko. 2023. "Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data" Chemistry 5, no. 4: 2542-2565. https://doi.org/10.3390/chemistry5040165

APA Style

Misikov, G., Trofimova, M., & Prikhodko, I. (2023). Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data. Chemistry, 5(4), 2542-2565. https://doi.org/10.3390/chemistry5040165

Article Metrics

Back to TopTop