Analytical Chemistry: Tasks, Resolutions and Future Standpoints of the Quantitative Analyses of Environmental Complex Sample Matrices
Abstract
:1. Introduction
2. Pre-Treatment Procedures
3. Instrumental Configurations and New Materials
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Matrix | Analyte/S | Material | Phase System/Fields/Technique | Sensitivity (in Terms of LOD) | Ref. |
---|---|---|---|---|---|
Environmental | Pollutants | Engineered enzyme-conjugated materials | Dehalogenating enzymes | Lower than 2 ppt | [32] |
Water | Metals | ILs | DLLME | 10–4.0 × 10−4 ppb | [40] |
Water | Metals | Surfactants | CPE | 0.5–1.1 × 10−3 ppb | |
Water | Metals | DESs | DLLME/LLME | 2.9–0.12 ppb | |
Water | Metals | Nanomaterials combined with alternative solvent system | MSPE/D-μ-SPE | 0.11–1.1 × 10−3 ppb | |
Water | Pesticides | Graphene-based nanosorbents | MSPE/SPE/DSPE | - | |
Water | Fungicides | Graphene-based nanosorbents | MSPE/SPE/DSPE | - | |
Water | Herbicides | Graphene-based nanosorbents | MSPE/SPE/DSPE | - | |
Environmental | Pesticides | Carbon nanomaterials | Enzyme-based | 99–2.5 × 10−5 ppb | [41] |
Antibody-based | 8 ppb | ||||
Aptamer-based | 1.1–4.0 × 10−5 ppb | ||||
MIP-based | 470–4.2 × 10−3 ppb | ||||
General | 905–6.5 × 10−4 ppb | ||||
Water | Glimepiride | LAY-FOMM 60 | SPE sorbent 3D-printed | - | [42] |
Water | As, Se | BV-007 resin and TiO2 NPs | Column holders 3D-printed | - | [43] |
Water | Fe | Clear photoactive resin | Disk-based SPE 3D-printed | - | [44] |
Groundwater and leachate | 14 trace metals | Clear photoactive resin | Extraction disks 3D-printed | 1.3–0.03 ppb | [45] |
Water | Organophosphate pesticides | ILs | [C4MIm][NTf2] | 5–16 × 10−3 ppb | [46] |
Water | 4-n-nonylphenol 4-Tert-octylphenol Bisphenol A Phenol | ILs | DDAC | 3 × 103 ppb | [47] |
Water | Metals | ILs | [OPy]+[BF4]− | 0.1 ppb | [48] |
Wastewater | Fluoxetine and Citalopram | MSPE | Fe3O4 @PPy-GO | 1.6 ppb | [49] |
Water | Pirimicarb and Fenitrothion | FPSE | PCL-PDMS-PCL | 3 ppb | [50] |
Water | Propoxur and Fenitrothion | MSPE | Decanoic Acid Modified | 1.4 ppb | [51] |
Water | 4-Cyanophenol and 3-Nitrophenol | SPE | MWCN | 0.1 μg | [52] |
Soil | Epoxiconazole, Fluroxypyr Metribuzin Oxyfluorfen | ILs | (VBHDIM-NTf2) [ViC10OHIM][Nf2T]) | 0.4 ppb | [53] |
Matrix | Analyte/S | Instrument Configuration | Sensitivity | Ref. |
---|---|---|---|---|
Water | Organophosphate pesticides | GC–MS | 5–16 × 10−3 ppb | [46] |
Water | 4-n-nonylphenol 4-Tert-octylphenol Bisphenol A Phenol | UV/Vis spectroscopy | 3 × 103 ppb | [47] |
Water | Metals | ICP–MS or AFS | 0.1 ppb | [48] |
Wastewater | Fluoxetine and Citalopram | HPLC–PDA | 1.6 ppb | [49] |
Water | Pirimicarb and Fenitrothion | HPLC–PDA | 3 ppb | [50] |
Water | Propoxur and Fenitrothion | HPLC-PDA | 1.4 ppb | [51] |
Water | 4-Cyanophenol and 3-Nitrophenol | CE | 0.1 μg | [52] |
Soil | Epoxiconazole, Fluroxypyr Metribuzin Oxyfluorfen | GC–MS | 0.4 ppb | [53] |
Water | Metformin | CE | 104 ppb | [89] |
Water | Heavy metals | Portable sensing–optical | 0.5 ppb | [90] |
Water | Heavy metals | Portable sensing–colorimetric | 3 ppb | [91] |
Water | Heavy metals | Portable sensing–electrochemical | 0.15 ppb | [92] |
Water | Heavy metals | SWASV | 0.0096 μM | [93] |
River water | Methyl parathion | DPV | 0.015 μM | [94] |
Water | Nitrite | Amperometry | 0.03 μM | [95] |
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Rosato, E.; Merone, G.M.; Locatelli, M.; D’Ovidio, C.; Bonelli, M.; de Grazia, U.; Santavenere, F.; Rossi, S.; Ali, I.; Ulusoy, H.I.; et al. Analytical Chemistry: Tasks, Resolutions and Future Standpoints of the Quantitative Analyses of Environmental Complex Sample Matrices. Analytica 2022, 3, 312-324. https://doi.org/10.3390/analytica3030022
Rosato E, Merone GM, Locatelli M, D’Ovidio C, Bonelli M, de Grazia U, Santavenere F, Rossi S, Ali I, Ulusoy HI, et al. Analytical Chemistry: Tasks, Resolutions and Future Standpoints of the Quantitative Analyses of Environmental Complex Sample Matrices. Analytica. 2022; 3(3):312-324. https://doi.org/10.3390/analytica3030022
Chicago/Turabian StyleRosato, Enrica, Giuseppe Maria Merone, Marcello Locatelli, Cristian D’Ovidio, Martina Bonelli, Ugo de Grazia, Francesco Santavenere, Sandra Rossi, Imran Ali, Halil Ibrahim Ulusoy, and et al. 2022. "Analytical Chemistry: Tasks, Resolutions and Future Standpoints of the Quantitative Analyses of Environmental Complex Sample Matrices" Analytica 3, no. 3: 312-324. https://doi.org/10.3390/analytica3030022