Search Results (7)

The erosion caused by high-temperature calcium–magnesium–alumina–silicate (CMAS) has emerged as a critical impediment to the advancement of thermal barrier coating (TBC). In this study, a series of high-entropy rare earth zirconates, (La_0.2Sm_0.2Dy_0.2Er_0.2Gd_0.2)₂(Zr_1−xCe_x)₂O₇ (x = 0, 0.2, 0.4, 0.5) were synthesized through a solid-phase reaction, and their corrosion behavior against CMAS was investigated. Our findings demonstrate that numerous rare earth elements impede element diffusion, facilitate the formation of a compact oxide layer, and effectively hinder CMAS infiltration. Furthermore, rare earth elements with larger ionic radii exhibit enhanced solubility in apatite, whereas those with smaller ionic radii are more readily soluble in ZrO₂. In general, the utilization of the high-entropy strategy is an effective approach to significantly improving corrosion resistance against CMAS. Full article

To achieve the goal of “dual-carbon”, induction furnaces with high efficiency and energy-saving advantages are paid more attention in the foundry and metallurgy industries. The service life and safety of induction furnaces strongly depended on the lining because expansion and forward sintering could result in the erosion and slag resistance of the lining. Focusing on the tailoring properties of alumina–magnesia-based dry ramming mixes, calcined magnesia particles were replaced with the novel multi-component materials of calcium magnesium aluminate (CaO-MgO-Al₂O₃, CMA) with a size of 200 mesh. Properties such as the bulk density, apparent porosity, strength, and slag corrosion resistance of alumina–magnesia-based dry ramming mix containing CMA were evaluated contrastively. The results demonstrate that the penetration index of manganese-bearing slag in dry ramming mixes first decreased and then slightly increased with the addition of CMA. Meanwhile, the permanent linear change in dry ramming mixes was gradually reduced. When the addition of CMA reached 4 wt%, the strength of the dry ramming mixes was slightly greater than the reference, and the slag penetration index was just 75% of the latter. Full article

In this paper, a novel concept in the field of phase composite ceramics has been proposed and applied for creating the topcoats of durable thermal barrier coatings (TBCs), which is one of the most critical technologies for advanced high-efficiency gas turbine engines in extreme environments. The phase composite ceramic TBCs were designed to demonstrate superior and comprehensive performance-related merits, benefits, and advantages over conventional single-phase TBCs with a topcoat of 8YSZ or Gd₂Zr₂O₇, including thermal phase stability, thermal shock durability, low thermal conductivity, and solid particle erosion resistance. In this paper, we review and summarize the development work conducted so far related to the phase composite ceramic concept, coatings processing, and experimental investigation into TBC behaviors at elevated temperatures (typically, ≥1250 °C) using different evaluation and characterization methods, including isothermal sintering, a burner rig test, a solid particle-impinging erosion test, and a CMAS corrosion test. Two-phase (t’+c) zirconia-based TBCs demonstrated improved thermal shock and erosion resistance in comparison to conventional single-phase (t’), 8YSZ TBC, and Gd₂Zr₂O₇ TBC, when used separately. Additionally, a triple-phase (t’+c+YAG) TBC sample demonstrated superior CMAS resistance. The TBC’s damage modes and failure mechanisms for thermal phase stability, thermal cycling resistance, solid particle erosion behavior, and CMAS infiltration are also characterized and discussed in detail, in terms of microstructural characterization and performance evaluation. Full article

Many ancient landslides in the upper reaches of the Jinsha River seriously threaten the safety of residents on both sides of the river. The river erosion and groundwater infiltration have greatly reduced the stability of the ancient landslides along the Jinsha River and revived many large landslides. Studying their deformation characteristics and mechanisms and predicting possible failure processes are significant to the safety of residents and hydropower projects. We used SBAS-InSAR and three-dimensional decomposition techniques in our study. Our results showed that the trailing edge and middle part of the landslide have rapidly deformed. The maximum vertical annual displacement rate was 12 cm/a period from July 2017 to July 2019. Correlation analysis showed that creep deformation is closely related to the river damming of the Baige landslide events and that the rising river level was an important factor in the resurrection and accelerated destruction of the Xiaomojiu landslide. As a result, we predicted the possible failure process of the Xiaomojiu landslide, which might have lasted 80 s and eventually formed a landslide deposit with a height of about 150 m, a length of approximately 1500 m, and an average width of 450 m. Our results provide data references for displacement monitoring and instability risk simulation of large landslides along the Jinsha River. Full article

The erosion of the unmelted CaO-MgO-Al₂O₃-SiO₂ (CMAS) particle is one of the dominating factors that causes microcracks in thermal barrier coatings (TBCs) when an aeroengine operates under actual service conditions. The microcracks provide a pathway for the erosion of the TBCs by the molten CMAS particles, which accelerates the failure of the coating. Herein a simplified model to mimic the erosion of YSZ (Y₂O₃ stabilized ZrO₂) TBCs by the CMAS particles with high speed is proposed. The finite element method was utilized to systematically investigate the physical damage behaviors of the TBCs by the CMAS particles under various contact configurations, impact velocities and impact angles. We show that the contact configuration has a significant impact on the residual stress of the coating surfaces as well as the formation and types of microcracks. Furthermore, the increment of the erosion velocity gave rise to irreversible deformation around the point of contact, which aggravated the stress conditions of the top layer and led to the delamination failure of the coating. Finally, the larger the erosion angle, the more mechanical energy was converted into internal energy, which accumulated in the YSZ and caused it to finally delaminate. Full article

Permafrost degradation caused by contemporary climate change significantly affects arctic regions. Active layer thickening combined with the thaw subsidence of ice-rich sediments leads to irreversible transformation of permafrost conditions and activation of exogenous processes, such as active layer detachment, thermokarst and thermal erosion. Climatic and permafrost models combined with a field monitoring dataset enable the provision of predicted estimations of the active layer and permafrost characteristics. In this paper, we present the projections of active layer thickness and thaw subsidence values for two Circumpolar Active Layer Monitoring (CALM) sites of Eastern Chukotka coastal plains. The calculated parameters were used for estimation of permafrost degradation rates in this region for the 21st century under various IPCC climate change scenarios. According to the studies, by the end of the century, the active layer will be 6–13% thicker than current values under the RCP (Representative Concentration Pathway) 2.6 climate scenario and 43–87% under RCP 8.5. This process will be accompanied by thaw subsidence with the rates of 0.4–3.7 cm∙a⁻¹. Summarized surface level lowering will have reached up to 5 times more than current active layer thickness. Total permafrost table lowering by the end of the century will be from 150 to 310 cm; however, it will not lead to non-merging permafrost formation. Full article

This research applied terrestrial LiDAR for laboratory beach evolution experiments to quantify the impact of resolution on topographic mapping and change analyses. The multi-site registration and multi-temporal scanning processes produced high accuracy (−0.002 ± 0.003 m) topographic models in a wave tank environment. Morphological analyses based on surface change and profiles showed that models of all resolutions were capable of capturing major sediment changes in relatively smooth areas. However, higher resolution models were necessary in areas with rough surfaces and sudden elevation changes, while coarser resolution models smoothed the roughness and underestimated feature height (e.g., peaks and troughs). Decreasing resolutions from 1 to 10 cm resulted in a 2% underestimation of erosional volumes with a linear regression of y = −0.0964x + 0.4185 (R² = 0.9651) and 3.5% overestimation of depositional volumes with a linear regression of y = 0.0664x + 0.3308 (R² = 0.3645). However, its impact on erosion and deposition volume assessment based on object-oriented beach evolution analysis is less significant, except when fragment objects dominate the sediment changes. For Coastal Morphology Analyst (CMA), the impact of resolution is more observable through 2D object mapping in terms of object size, number, and spatial distribution. Finally, wave modeling experiments proved that resolutions caused significant changes on the behavior of the maximum wave height, the shape of the wave fronts and magnitudes of the currents. Full article