Search Results (4)

This study reports the synthesis and characterization of Co_xNi_1−xFe₂O₄ (x = 0, 0.2, 0.4, 0.6, 0.8, 1) nanoparticles using a co-precipitation method. In this approach, metal ions are precipitated in the presence of a stabilizing agent, which is a common and effective method for nanoparticle preparation. The microstructure and magnetic properties were studied after calcination at 600 °C and heat treatment at 1000 °C. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy confirmed the formation of a single-phase spinel structure. The average crystallite size, calculated using the (311) diffraction peak and the Scherrer equation, ranged from 13 to 19 nm. Scanning electron microscopy (SEM) showed that the nanoparticles had a spherical morphology. Thermogravimetric and differential thermal analysis (TG-DTA) revealed a three-step weight loss process. Magnetic measurements, including remanent magnetization, saturation magnetization, and coercivity, were performed using a vibrating sample magnetometer (VSM) at room temperature. The replacement of Ni²⁺ with Co²⁺ enhanced the magnetic properties, resulting in increased magnetic moment and anisotropy. These effects are attributed to changes in cation distribution, exchange interactions, surface effects, and magnetocrystalline anisotropy. Overall, Co²⁺ doping improved the magnetic behavior of nickel ferrite, indicating its potential for application in memory devices and magnetic recording media. Full article

Supercapacitors (SCs) are widely used in energy storage devices due to their superior power density and long cycle lifetime. However, the limited energy densities of SCs hinder their industrial application to a great extent. In this study, we present a new combination of metallic phosphide–carbon composites, synthesized by directly carbonizing (Ni_1−xCo_x)₅TiO₇ nanowires via thermal chemical vapor deposition (TCVD) technology. The new method uses one-dimensional (1D) (Ni_1−xCo_x)TiO₇ nanowires as precursors and supporters for the in situ growth of intertwined porous CNF microspheres. These 1D nanowires undergo microstructure transformation, resulting in the formation of CoNiP nanoparticles, which act as excellent interconnected catalytic nanoparticles for the growth of porous 3D CNF microspheres. Benefiting from the synergistic effect of a unique 1D/3D structure, the agglomeration of nanoparticles can effectively be prevented. The resulting CNF microspheres exhibit an interconnected conductive matrix and provide a large specific surface area with abundant ion/charge transport channels. Consequently, at a scanning rate of 10 mV s⁻¹, its specific capacitance in 1.0 M Na₂SO₄ + 0.05 M Fe(CN)₆^3−/4− aqueous solution is as high as 311.7 mF cm⁻². Furthermore, the CoNiP@CNFs composite film-based symmetrical SCs show an ultrahigh energy density of 20.08 Wh kg⁻¹ at a power density of 7.20 kW kg⁻¹, along with outstanding cycling stability, with 87.2% capacity retention after 10,000 cycles in soluble redox electrolytes. This work provides a new strategy for designing and applying high-performance binary transition metal phosphide/carbon composites for next-generation energy storage devices. Full article

An efficient and selective drug delivery vehicle for cancer cells can remarkably improve therapeutic approaches. In this study, we focused on the synthesis and characterization of magnetic Ni_1−xCo_xFe₂O₄ nanoparticles (NPs) coated with two layers of methionine and polyethylene glycol to increase the loading capacity and lower toxicity to serve as an efficient drug carrier. Ni_1−xCo_xFe₂O₄@Methionine@PEG NPs were synthesized by a reflux method then characterized by FTIR, XRD, FESEM, TEM, and VSM. Naproxen was used as a model drug and its loading and release in the vehicles were evaluated. The results for loading efficiency showed 1 mg of Ni_1−xCo_xFe₂O₄@Methionine@PEG NPs could load 0.51 mg of the naproxen. Interestingly, Ni_1−xCo_xFe₂O₄@Methionine@PEG showed a gradual release of the drug, achieving a time-release up to 5 days, and demonstrated that a pH 5 release of the drug was about 20% higher than Ni_1−xCo_xFe₂O₄@Methionine NPs, which could enhance the intracellular drug release following endocytosis. At pH 7.4, the release of the drug was slower than Ni_1−xCo_xFe₂O₄@Methionine NPs; demonstrating the potential to minimize the adverse effects of anticancer drugs on normal tissues. Moreover, naproxen loaded onto the Ni_1−xCo_xFe₂O₄@Methionine@PEG NPs for breast cancer cell lines MDA-MB-231 and MCF-7 showed more significant cell death than the free drug, which was measured by an MTT assay. When comparing both cancer cells, we demonstrated that naproxen loaded onto the Ni_1−xCo_xFe₂O₄@Methionine@PEG NPs exhibited greater cell death effects on the MCF-7 cells compared with the MDA-MB-231 cells. The results of the hemolysis test also showed good hemocompatibility. The results indicated that the prepared magnetic nanocarrier could be suitable for controlled anticancer drug delivery. Full article

FeCo/Al₂O₃ nanoparticles thermal sprayed on a steel plate with different Co concentration from 0 to 20% by means of a thermal spraying process, Fe_60−xCo_x(Al₂O₃)₄₀ powder alloy was synthesized using planetary ball mill for different Co concentration at 20 h of milling. The aims of this work are to study the effect of Co concentration and milling time on the magnetic, structural behavior and mechanical properties of the FeCo/Al₂O₃ coating. Appearance of FeCo magnetic Solid solution phase after 20 h of milling, the crystallite sizes reduced from 18nm to 7nm and lattice strains increased from 0.36 to 0.56%, this variation are caused by the diffusion of Co atoms in iron lattice. For the coating, various phase of magnetic domains observed on surface by Atomic Force Microscopy (AFM), apparition the new phases, Al₂FeO₄ at 0%, CoAl₂O₄ at 5%, CoFe₂O₄ at 10% and CoFe at 20%. Saturation magnetization is max at 20 wt% of Ni and coercivity is min at 10 wt% of Co. Microhardeness and Young module were characterized by Nanoidentation techniques that shows an improvement in mechanical properties Full article