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Keywords = GO-CF/EP composites

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16 pages, 6732 KB  
Article
Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites
by Weihua Bai, Wenjun Liu, Weidong Li, Zewen Lin, Hong Qiu and Xiaolan Hu
Materials 2023, 16(11), 4005; https://doi.org/10.3390/ma16114005 - 26 May 2023
Cited by 5 | Viewed by 2220
Abstract
In the present study, surface properties of three types of carbon fibers (CCF300, CCM40J, and CCF800H) on the interface properties of carbon fiber/epoxy resin (CF/EP) were analyzed. The composites are further modified by graphene oxide (GO) to obtain GO/CF/EP hybrid composites. Meanwhile, the [...] Read more.
In the present study, surface properties of three types of carbon fibers (CCF300, CCM40J, and CCF800H) on the interface properties of carbon fiber/epoxy resin (CF/EP) were analyzed. The composites are further modified by graphene oxide (GO) to obtain GO/CF/EP hybrid composites. Meanwhile, the effect of the surface properties of CFs and the additive graphene oxide on the interlaminar shear properties and dynamic thermomechanical properties of GO/CF/EP hybrid composites are also analyzed. The results show that the higher surface oxygen-carbon ratio of carbon fiber (CCF300) has a positive effect on improving the glass transition temperature (Tg) of the CF/EP composites. The Tg of CCF300/EP is 184.4 °C, while the Tg of CCM40J/EP and CCF800/EP are only 177.1 °C and 177.4 °C, respectively. Furthermore, deeper and more dense grooves on the fiber surface (CCF800H and CCM40J) are more conducive to improving the interlaminar shear performance of the CF/EP composites. The interlaminar shear strength (ILSS) of CCF300/EP is 59.7 MPa, and that of CCM40J/EP and CCF800H/EP are 80.1 MPa and 83.5 MPa, respectively. For the GO/CF/EP hybrid composites, graphene oxide with abundant oxygen-containing groups is beneficial to improve the interfacial interaction. Graphene oxide can significantly improve the glass transition temperature and interlamellar shear strength of GO/CCF300/EP composites fabricated by CCF300 with a higher surface oxygen-carbon ratio. For the CCM40J and CCF800H with lower surface oxygen-carbon ratio, graphene oxide has a better modification effect on the glass transition temperature and interlamellar shear strength of GO/CCM40J/EP composites fabricated by CCM40J with deeper and finer surface grooves. Regardless of the type of carbon fiber, the GO/CF/EP hybrid composites with 0.1% graphene oxide have the optimized interlaminar shear strength, and the GO/CF/EP hybrid composites with 0.5% graphene oxide have the maximum glass transition temperature. Full article
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12 pages, 5110 KB  
Article
Influence of Extrusion Temperature on Properties of Graphene Oxide-Carbon Fiber/Epoxy Composite Prepared by Vacuum Infiltration Hot-Press-Forming Experimental System
by Yuqin Ma, Fei Li, Wei Xu, Yuyang Zhang, Yi Xu, Haiyin Guo and Yatao Li
Nanomaterials 2022, 12(21), 3839; https://doi.org/10.3390/nano12213839 - 30 Oct 2022
Cited by 2 | Viewed by 2204
Abstract
Graphene oxide-carbon fiber/epoxy (GO-CF/EP) composites with extrusion temperatures of 30, 40, 50, 60 and 70 °C were prepared by a vacuum infiltration hot-press-forming experimental system (VIHPS). The effects of extrusion temperature on the microstructure, fracture mechanism and mechanical properties of GO-CF/EP composites were [...] Read more.
Graphene oxide-carbon fiber/epoxy (GO-CF/EP) composites with extrusion temperatures of 30, 40, 50, 60 and 70 °C were prepared by a vacuum infiltration hot-press-forming experimental system (VIHPS). The effects of extrusion temperature on the microstructure, fracture mechanism and mechanical properties of GO-CF/EP composites were investigated. It was found that the best mechanical property of composites and infiltration effect of the matrix in the fiber gap were obtained at the temperature of 50 °C, and the bending strength of the composite reached 728 MPa. The fiber was pulled out and broken under the wrapping of the matrix. The matrix viscosity was high, and the fluidity was poor when the extrusion temperature was low. The poor infiltration of the matrix resulted in many fibers failing to bond together, resulting in the disorderly breakage of fiber bundles. Under the condition of higher temperature, the flow speed of the matrix could be improved. However, part of the matrix was extruded during the extrusion process, and cracks and other defects occurred during the loading, which caused the brittle fracture of the specimen. Full article
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15 pages, 3842 KB  
Article
Effect of Four Groups of GO-CF/EP Composites with Ideal Infiltration Structure and Different Layering Ways on Damping Properties
by Feichao Cai, Soo-Ho Jo, Yuqin Ma, Haiyin Guo, Yi Xu, Wei Xu and Fei Li
Polymers 2022, 14(12), 2358; https://doi.org/10.3390/polym14122358 - 10 Jun 2022
Cited by 5 | Viewed by 2326
Abstract
In this paper, four groups of graphene oxide and carbon fiber hybrid-reinforced resin matrix (GO-CF/EP) composites with different layering ways were prepared by a vacuum infiltration hot pressing system (VIHPS). The damping properties of the specimens with different layering ways were tested by [...] Read more.
In this paper, four groups of graphene oxide and carbon fiber hybrid-reinforced resin matrix (GO-CF/EP) composites with different layering ways were prepared by a vacuum infiltration hot pressing system (VIHPS). The damping properties of the specimens with different layering ways were tested by the force hammer method, and the micromorphology of the specimens was photographed by scanning electron microscope. The experimental results showed that the damping properties of GO-CF/EP composites gradually increased with the increase in the number of Y-direction layers. The [XYXYXY]6 has the best damping property, with a damping ratio of 1.187%. The damping ratio is 5.3 times higher than that of [XXXXXX]6 layer mode, and the first-order natural frequency is 77.7 Hz. This is mainly because the stiffness of the X-direction layer is larger than that of the Y-direction layer, and its resistance to deformation is considerable. Therefore, its decay rate is slower. The Y-direction layer has weak resistance to deformation and fast energy attenuation. The increase in the number of Y-direction layers will lead to the overall increase in, and the improvement of, the damping properties of GO-CF/EP composites. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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14 pages, 18453 KB  
Article
Effect of Fiber Mass Fraction on Microstructure and Properties of 2D CF-GO/EP Composite Prepared by VIHPS
by Yuqin Ma, Yi Chen, Fei Li, Yiren Xu, Wei Xu, Yatao Zhao, Haiyin Guo, Yatao Li, Zedu Yang and Yi Xu
Nanomaterials 2022, 12(7), 1184; https://doi.org/10.3390/nano12071184 - 1 Apr 2022
Cited by 7 | Viewed by 2344
Abstract
Graphene is often used to improve interlaminar fracture toughness of carbon fiber/epoxy resin (CF/EP) composites. It is still a challenge to improve the toughness while maintaining the in-layer properties. In this study, 2D graphene oxide carbon fiber reinforced epoxy resin matrix (2D CF-GO/EP) [...] Read more.
Graphene is often used to improve interlaminar fracture toughness of carbon fiber/epoxy resin (CF/EP) composites. It is still a challenge to improve the toughness while maintaining the in-layer properties. In this study, 2D graphene oxide carbon fiber reinforced epoxy resin matrix (2D CF-GO/EP) composites were prepared by a vacuum infiltration hot-press forming experimental system (VIHPS), and three-point flexural and end notch flexural (ENF) tests were carried out. With the increase of the fiber mass fraction in the composites, the mode II interlaminar fracture toughness (GIIC) layers decrease gradually, and the bond property between the fiber and matrix interface layer becomes worse, because the accumulation of dense fiber bundles reduces the matrix penetration ability of cracks. However, the flexural properties increased first and then decreased, and reached the best flexural properties at 64.9%. When the fiber mass fraction is too high, the interlamellar bonding properties will decrease, and the fiber bundles will compress and affect each other. The delamination phenomenon will occur between the layers of the composites, which affects the overall bearing strength and stress limit of the composites. The results of the study show that the composites prepared by VIHPS have excellent mechanical properties, and the content of carbon fiber plays an important role in the influencing factors of the interlaminar and in-layer properties of composites. Full article
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23 pages, 5851 KB  
Article
The Influence of Graphene Oxide on Nanoparticle Emissions during Drilling of Graphene/Epoxy Carbon-Fiber Reinforced Engineered Nanomaterials
by Kristof Starost and James Njuguna
Atmosphere 2020, 11(6), 573; https://doi.org/10.3390/atmos11060573 - 1 Jun 2020
Cited by 4 | Viewed by 3113
Abstract
Graphene oxide (GO) nanoparticles are increasingly being used to tailor industrial composites. However, despite the advantages, GO has shown conceivable health risks and toxicity to humans and the environment if released. This study investigates the influence that GO concentrations have on nanoparticle emissions [...] Read more.
Graphene oxide (GO) nanoparticles are increasingly being used to tailor industrial composites. However, despite the advantages, GO has shown conceivable health risks and toxicity to humans and the environment if released. This study investigates the influence that GO concentrations have on nanoparticle emissions from epoxy-reinforced carbon fiber hybrid composites (EP/CF) during a lifecycle scenario, that is, a drilling process. The mechanical properties are investigated and an automated drilling methodology in which the background noise is eliminated is used for the nanoparticle emissions measurements. Real-time measurements are collected using a condensation particle counter (CPC), a scanning mobility particle sizer spectrometer (SMPS), a real-time fast mobility particle spectrometer (DMS50) and post-test analytical methods. The results observe that all three nanoparticle reinforced samples demonstrated a statistically significant difference of up to a 243% increase in mean peak particle number concentration in comparison to the EP/CF sample. The results offer a novel set of data comparing the nanoparticle release of GO with varying filler weight concentration and correlating it the mechanical influence of the fillers. The results show that the release characteristics and the influence in particle number concentration are primarily dependent on the matrix brittleness and not necessarily the filler weight concentration within the nanocomposite. Full article
(This article belongs to the Special Issue Emissions, Transport and Fate of Pollutants in the Atmosphere)
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