Search Results (5)

The application of photocatalytic materials has been intensively researched in recent decades. The process of nitric oxide (NO) oxidation during photocatalysis has been observed to result in the formation of nitric dioxide (NO₂). This is a significant factor of the photocatalysis process, as NO₂ is more toxic than NO. However, it has been reported that ozone (O₃) is also formed during the photocatalytic reaction. This study analyzed the formation and oxidationof O₃ during the photocatalytic oxidation of NO under ultraviolet irradiation using commercial photocatalytic powders: AEROXIDE^® TiO₂ P25 by Evonik, KRONOClean^® 7050 by KRONOS^®, and KRONOClean^® 7000 by KRONOS^®. An NO concentration of 100 ppb was assumed in laboratory tests based on the average nitric oxide concentrations recorded by the monitoring station in Warsaw. A mix flow-type reactor was applied in the study, and the appropriateness of its application was verified using a numerical model. The developed model assumed an empty reactor without a photocatalytic material, as well as a reactor with a photocatalytic material at its bottom to verify the gas flow in the chamber. The analysis of the air purification performance of photocatalytic powders indicated a significant reduction of NO and NO_x and typical NO₂ formation. However, no significant formation of O₃ was observed. This observation was verified by the oxidation of pure ozone in the process of photocatalysis. The results indicated the oxidation of ozone concentration during the photocatalytic reaction, but self-decomposition of a significant amount of the gas. Full article

In this study, a series of TiO₂/rGO photocatalysts were obtained with a two-step procedure: a solvothermal method and calcination at 300–900 °C in an argon atmosphere. It was noted that the presence of rGO in photocatalysts had an important role in the changes in crystallite size and specific surface area. In TiO₂/rGO samples, different surface functional groups, such as C−C_graph, C−C_aliph, C−OH, C=O, and CO(O), were found. It was observed that rGO modification suppressed the anatase-to-rutile phase transformation. The photocatalytic activity of the obtained nanomaterials was investigated through the decomposition of methylene blue under UV and artificial solar light irradiation. It was found that the adsorption degree played an important role in methylene blue decomposition. The experimental results revealed that TiO₂/rGO samples exhibited superior removal efficiency after calcination for methylene blue compared toTiO₂ without rGO, as well as a commercial photocatalyst KRONOClean 7000. It was noted that photocatalytic activity increased with the increase in the calcination temperature. The highest activity was observed for the sample calcined at 700 °C, which consisted of 76% anatase and 24% rutile. This study clearly demonstrated that TiO₂/rGO samples calcined in argon can be used as efficient photocatalysts for the application of methylene blue decomposition. Full article

This article reports a novel photocatalytic lime render for indoor and outdoor air quality improvement that is composed of a lime binder and doped TiO₂ (KRONOClean 7000^®) nanoparticles. These nanoparticles were distributed throughout the bulk of the finishing render, instead of as a thin coating, thus ensuring the durability of the photocatalytic properties upon superficial damage. The physical properties of these renders were not affected by the addition of nanoparticles except in the case of surface area, which increased significantly. In terms of their photocatalytic activity, these novel lime renders were shown to degrade up to 12% NO_x under UV light and up to 11% formaldehyde under visible light. Full article

Although titanium dioxide gathers many of the required properties for its application in photocatalytic processes, its lack of activity in the visible range is a major hurdle yet to be overcome. Among different strategies, the post-synthesis modification of TiO₂ powders with organic compounds has already led to commercially available materials, such as KRONOClean 7000. In this work, we apply diffuse reflectance transient absorption spectroscopy on this visible-light active photocatalyst and study the dynamics of the charge carriers alternatively induced by UV or visible light laser irradiation, under inert or reactive atmospheres. Our results can be interpreted by considering the material as TiO₂ sensitized by an organic-based layer, in agreement with previous studies on it, and show that the oxidative power of the material is considerably diminished under visible light irradiation. By complementarily performing continuous visible light irradiation photocatalysis experiments in aerated aqueous suspensions, we show that, although the oxidation of methanol proceeds at a very slow rate, the oxidation of chlorpromazine occurs much faster thanks to its better suited redox potential. Full article

A commercial carbon-modified titanium dioxide, KRONOClean 7000, was applied as a UV(A) and visible-light active photocatalyst to investigate the conversion of the antipsychotic pharmaceutical chlorpromazine in aqueous phase employing two monochromatic light sources emitting at wavelengths of 365 and 455 nm. Photocatalytic and photolytic conversion of chlorpromazine under both anaerobic and aerobic conditions was analyzed using a HPLC-MS technique. Depending on the irradiation wavelength and presence of oxygen, varying conversion rates and intermediates revealing different reaction pathways were observed. Upon visible light irradiation under aerobic conditions, chlorpromazine was only converted in the presence of the photocatalyst. No photocatalytic conversion of this compound under anaerobic conditions upon visible light irradiation was observed. Upon UV(A) irradiation, chlorpromazine was successfully converted into its metabolites in both presence and absence of the photocatalyst. Most importantly, chlorpromazine sulfoxide, a very persistent metabolite of chlorpromazine, was produced throughout the photolytic and photocatalytic conversions of chlorpromazine under aerobic conditions. Chlorpromazine sulfoxide was found to be highly stable under visible light irradiation even in the presence of the photocatalyst. Heterogeneous photocatalysis under UV(A) irradiation resulted in a slow decrease of the sulfoxide concentration, however, the required irradiation time for its complete removal was found to be much longer compared to the removal of chlorpromazine at the same initial concentration. Full article