Search Results (7,584)

The extensive use of clothianidin pesticide poses significant risks to non-target organisms and water resources. In this study, NiO-GO is reported as an effective photocatalyst for the degradation of clothianidin in aqueous medium. Nickel oxide (NiO) nanoparticles were synthesized by a green method using Pisum sativum (pea) peel extract, which serves as a natural reducing and stabilizing agent, and subsequently integrated with graphene oxide (GO) through ultrasonication to form a NiO-GO composite in a 1:1 ratio. The materials were characterized by various techniques. Photocatalytic degradation of clothianidin under natural sunlight was systematically investigated, assessing the effects of pH, catalyst dosage, initial pollutant concentration, and agitation speed. The NiO-GO composite exhibited superior photocatalytic performance (96% degradation at pH 3 within 60 min) compared to pristine NiO and GO, with a rate constant 4.4 and 3.3 times higher, respectively. The as-prepared NiO-GO photocatalyst exhibited nearly consistent degradation efficiency over two successive cycles, demonstrating its excellent structural stability and reusability. The enhanced performance is attributed to improved charge separation afforded by GO support. This low-cost, green, and efficient NiO-GO photocatalyst demonstrates promising potential for sustainable pesticide remediation in aqueous environments. Full article

Protected areas are essential for conserving biodiversity and sustaining ecosystems, yet their effective management requires a clear understanding of soil and water quality, which underpin ecological processes. This study evaluated 15 soil and seven water samples to assess their physico-chemical properties, focusing on heavy metal concentrations. Results showed that soils were generally neutral to alkaline, with Hashwan-2 exhibiting the highest concentrations of calcium (26.5 meq/L), magnesium (11.2 meq/L), carbonates (0.32 meq/L), bicarbonates (3.66 meq/L), and chloride (35.43 meq/L). Heavy metal analysis indicated elevated nickel (51.628 mg/kg) and chromium (76.29 mg/kg) at Albuyitlar-2, and chromium (68.015 mg/kg) at Shabak-Mateam-1 1 1, exceeding US-EPA permissible limits of 45 mg/kg for nickel and 64 mg/kg for chromium. Water samples revealed high levels of aluminum (12.681 mg/L), manganese (0.146 mg/L), and iron (7.055 mg/L), also exceeding the US-EPA thresholds of 0.2, 0.1, and 0.5 mg/L, respectively. In contrast, more toxic metals such as arsenic, cadmium, lead, and mercury remained within safe limits. These findings highlight localized concerns regarding heavy metal contamination that warrant continued monitoring to ensure ecosystem health. Full article

Heterogeneous catalysts comprising immobilized nickel(II) complexes bearing a fluorine- or trifluoromethyl-substituted iminopyridine ligand (X_n-C₆H_5–n-N=C (CH₃)-C₅H₅N, X = F or CF₃) in fluorotetrasilicic mica interlayers were prepared by reacting Ni²⁺-exchange fluorotetrasilicic mica with the appropriate ligand. Upon activating the precatalyst with triethylaluminum or triisobutylaluminum, the generated active species showed catalytic activity for ethylene oligomerization, yielding low-molecular-weight polyethylene (PE), ethylene oligomers, and wax-like PE. The oligomer distribution almost agreed with what we expected according to the Schultz–Flory distribution. However, the amount of solid products was much higher than the theoretical value, indicating that at least two active species were formed, i.e., the oligomer and low-molecular-weight PE. The precatalyst with a 2,4-F₂C₆H₃ group on the imino nitrogen atom activated by triethylaluminum showed the highest catalytic activity for ethylene oligomerization (408 g-C₂ g-cat⁻¹ h⁻¹), with selectivities to the liquid and solid products of 51.0% and 11.5%, respectively, with the rest of the product corresponding to wax-like PE. Meanwhile, the highest selectivity to the liquid product (66.7% at 233 g-C₂ g-cat⁻¹ h⁻¹) was obtained using the precatalyst with a 2-FPh group on the imino nitrogen atom activated by triisobutylaluminum. Full article

By accelerating the migration of sulfate ions in potassium magnesium phosphate cement (PMPC) paste through an electric field, its sulfate resistance can be quickly evaluated, thereby making up for the defect of long test cycles in existing evaluation methods. Through sulfate concentration analysis, strength tests, microanalysis and theoretical analysis, this paper investigated the SO₄²⁻ migration behavior of PMPC specimens subjected to electro-pulse-accelerated corrosion. The conclusions are as follows: the distribution of SO₄²⁻ concentration c (x, t) in PMPC specimens followed a polynomial pattern with corrosion period t. The surface SO₄²⁻ concentration c (0, t), measured SO₄²⁻ migration depth h₀, and c (x, t) of specimens increased with the t. After 56 days, the c (0, 56 days) and h₀ of the PN containing nickel slag powder and the PS containing silica fume were lower than that of the reference P0. Their calculated SO₄²⁻ migration depth h₀₀ and SO₄²⁻ migration coefficient D were smaller than that of P0. The h₀₀ and D could be estimated based on t due to a logarithmic relationship between t and h₀₀, D. The strength of specimens at the pulse cathode end gradually improved with t. The 56-day strength for P0, PN, and PS specimens increased by 7.14%, 7.94%, and 8.42%, respectively. The research findings provided a theoretical foundation for the application and quality evaluation of PMPC-based material. Full article

Extreme working conditions place high demands on material properties. For example, tools for friction stir welding of titanium alloys must be highly wear-resistant, have high strength at high temperatures, and also have high adhesion properties. These requirements complicate the selection of materials for tool manufacturing. One of the possible solutions is heat-resistant nickel superalloys, such as the ZhS6U alloy. However, since these alloys have not been commonly used in friction pairs, they have hardly been studied in the context of friction. This work experimentally investigates the friction and wear characteristics of the nickel alloy ZhS6U and commercial pure titanium under dry friction in a pin-on-disc scheme. The research found that during friction, an oxidized mechanically mixed transfer layer is composed of wear products, and it can reduce the friction coefficient. Only adhesive wear was observed in the selected range of sliding speeds (0.46 m/s–1.84 m/s). It was found that the values of the friction coefficient, the mass loss of the titanium disc, and the width and depth of the friction track correlate with each other—as the speed increases, they first increase to a maximum value and then decrease. Minimal disc wear was observed at a speed of 0.46 m/s. The maximum friction coefficient was 0.79 and was observed at a sliding speed of 0.92 m/s. It was also found that the friction surface area is linearly dependent on the sliding speed, and the wear rate of the pins increases with increasing sliding speed according to an exponential law. Full article

The effect of KOH concentration as a boron-free coolant for prospective use in Small Modular Reactors (SMRs) on the corrosion of Alloy 690 is studied by in situ impedance spectroscopy at 280 °C/9 MPa during 168 h exposure in a flow-through cell connected to a high-temperature/high-pressure loop. To follow further oxidation of the passive film, the samples were subsequently polarized up to potentials 0.5 V more positive than the corrosion potential. The formed oxides were analyzed ex situ by measuring the atomic concentration of the constituent elements via glow discharge optical emission spectroscopy (GDOES) depth profiling. The Mixed-Conduction Model for Oxide Films (MCM) was employed to quantitatively interpret the impedance results. The estimated parameters are used to quantify the influence of KOH concentration and anodic polarization on oxide formation and soluble product release rates. Results are compared to those obtained in the nominal primary chemistry of pressurized water reactors and indicate that Alloy 690 can also be successfully used as a steam generator tube material in SMRs. Full article

The development of materials for the remediation and monitoring of water environments remains a significant challenge in the field of environment and materials science. In this study, a nickel-based coordination polymer, [Ni(L)(H₂O)₃]_n·nH₂O (1), was synthesized employing 4,4′-(1H,1′H-[2,2′-biimidazole]-1,1′-diyl)dibenzoic acid (H₂L). Single-crystal X-ray diffraction analysis showed that L²⁻ ligands connect Ni²⁺ ions into 1D Z-shaped chains via two coordination modes. The chains are further assembled into a 3D supramolecular structure through hydrogen bonding interactions. The photocatalytic test showed that complex 1 could effectively degrade the organic dye methylene blue (MB). Under the conditions of catalyst dosage 5 mg, MB initial concentration 20 ppm and pH 7, the degradation efficiency reached 87.7% within 180 min. In addition, complex 1 can be used for the electrochemical detection of norfloxacin (NOR) by differential pulse voltammetry (DPV), exhibiting a linear response in the concentration range of 2–197 μM and the detection limit (LOD) of 1.74 μM. These results demonstrate that complex 1 has bifunctional properties of photocatalytic degradation of organic dyes and electrochemical sensing of antibiotic NOR, making it a promising candidate material for the synergistic treatment of complex pollutants. Full article

Thin films of nickel oxide (NiO) were deposited on a 5° miscut magnesium oxide (MgO)(100) substrate using electron-beam evaporation to pursue morphology-directed resistive switching. The atomic force microscope (AFM) confirmed a stepped surface with a terrace width of ~85 nm and a step height of ~7 nm. After deposition, the film resistance decreased from 200 MΩ to 25 MΩ by annealing under ambient air at 400 °C, attributed to the increase in the p-type conductivity through nickel vacancy formation. Top electrodes of Ag (500 nm width, 180 nm gap) were patterned parallel or perpendicular to the substrate steps using UV and electron-beam lithography. Devices aligned parallel to the step showed reproducible unipolar switching with 100% yield between forming voltages 20–70 V and HRS/LRS~10² at ±5 V. In contrast, devices formed perpendicular to the steps (8/8) subsequently failed catastrophically during electroforming, with scanning electron microscopy (SEM) showing breakdown holes on the order of ~100 nm at the step crossings. The anisotropic electrodynamic response is due to step-guided electric field distribution and directional nickel vacancy migration, illustrating how substrate morphology can deterministically influence filament nucleation. These results highlighted stepped MgO as a template to engineer the anisotropic charge transport of NiO, exhibiting a reliable ReRAM as well as directional electrocatalysis for energy applications. Full article

2,5-diformylfuran (DFF) is a significant biomass derivative that is employed in a variety of industries. One approach to synthesizing it is through the oxidation of 5-hydroxymethylfurfural (HMF). The challenges in DFF production arise from the need for extreme conditions, issues with overoxidation, and the limitations of noble materials used in neutral or acidic environments. By using a mildly alkaline electrolyte, DFF can be produced electrochemically alongside hydrogen gas generation, eliminating extreme conditions and allowing for the study of a wide range of transition metals. Moreover, the performance of bimetallic electrocatalysts has been studied, and it has been found to be more active in many kinds of processes, particularly Layered Double Hydroxides (LDH). Electrodeposition, once widely chosen among various LDH production methods, is preferred for producing controlled and uniform thin layers. This work examines the electrocatalytic properties of NiCo-LDH and NiFe-LDH in the production of DFF. Cobalt, which exhibits strong adsorption, will be compared to iron, which has a weak adsorption characteristic toward HMF. This study demonstrates that NiCo-LDH gives 1.49 V vs. RHE onset potential, 600 mV lower compared to NiFe-LDH (1.55 V vs. RHE) for HMF oxidation reaction. NiCo-LDH also converts twice the amount of HMF compared to NiFe-LDH for the same amount of charge passed at 0.25 mA/cm⁻² in 0.1 M Na₂B₄O₇. However, strong adsorption promotes reactant activation and reduces the energy barrier while reducing DFF selectivity in NiCo-LDH (23.4%) due to overoxidation, compared to NiFe-LDH (31.6%). In order to achieve optimal electrocatalyst performance, a careful balance of adsorption strength and reaction pathway management is required. Proper optimization of these parameters is essential to improve efficiency and selectivity in the electrocatalytic process. Full article

Comprehensive studies of hydrogen embrittlement in high-strength austenitic alloys under cryogenic conditions are scarce, leaving the combined effect of hydrogen charging and extreme temperatures largely unexplored. Given the demands of cryogenic applications such as hydrogen storage and transport, understanding material behavior under these conditions is crucial. Here, we present the first systematic study of hydrogen’s effect at liquid helium temperature (4.2 K) on the mechanical properties of precipitation hardened austenitic alloys, specifically the nickel-based Alloy 718 and austenitic stainless steel A286. Both materials were subjected to pressurized hydrogen charging at 473 K followed by slow strain rate tensile testing at room temperature and at 4.2 K. Hydrogen charging caused significant ductility loss at room temperature in both alloys. In contrast, testing at 4.2 K resulted in increased strength and no evidence of hydrogen embrittlement. Notably, materials pre-charged with hydrogen and tested at 4.2 K exhibited higher stress drop amplitudes and increased strain accumulation during serration events, suggesting persistent hydrogen–dislocation interactions and possible enhanced dislocation pinning by obstacles such as Lomer–Cottrell locks. These results indicate that while hydrogen influences plasticity mechanisms at cryogenic temperatures, embrittlement is suppressed, providing new insight into the safe development of austenitic alloys in cryogenic hydrogen environments. Full article

In this study, a highly conductive nickel (Ni) layer was deposited onto a P-type (Zr,Ti)Co(Sn,Sb) half-Heusler (HH) thermoelectric (TE) material using a low-cost electro-brush plating technique. Before depositing Ni on the TE material, the plating process was optimised on a stainless steel (SS) substrate. An optimal medium-rate deposition voltage of 6V was identified on the SS substrate, with the desired thickness, superior mechanical performance, reduced sheet resistance and surface roughness, and enhanced electrical conductivity. The optimised deposition condition was then applied to the P-type (Zr,Ti)Co(Sn,Sb) material, resulting in a Ni layer that significantly enhanced its electrical and thermal stability. After thermal exposure at 500 °C for 10 h, the Ni coating effectively protected the TE surface against oxidation and sublimation, suggesting that the interfacial contact properties of P-type (Zr,Ti)Co(Sn,Sb) TE material can be effectively enhanced by depositing a highly conductive, oxidation-resistant Ni layer using the cost-effective, straightforward electro-brush plating technique. Full article

The pursuit of higher current densities and device miniaturization intensifies gas evolution in alkaline water electrolysis, thereby reducing catalyst utilization and degrading system performance. In this work, a visualized alkaline electrolysis system was developed to investigate bubble dynamics on vertically oriented nickel wire electrodes. High-speed imaging coupled with a Yolov8 deep learning model enabled quantitative analysis of oxygen evolution behavior, revealing distinct bubble evolution modes such as isolated growth and coalescence. Systematic experiments demonstrated that current density, electrode diameter, and KOH concentration exert significant influences on bubble size distribution. Further correlation with electrochemical performance showed that increases in bubble population and size result in higher overpotentials, while bubble volume exhibits a strong linear relationship with the system’s ohmic resistance. These findings provide mechanistic insights into the coupling between bubble evolution and electrochemical performance, offering guidance for the design of efficient alkaline electrolyzers. Full article

Composites based on the AlSi12 aluminum alloy reinforced with Saffil^TM fibers (Composite I) and with both Saffil^TM fibers and nickel-coated graphite flakes (Composite II) were developed using the squeeze casting method in the fabrication process. The objective of this work was to evaluate the influence of the employed reinforcements on the mechanical properties and corrosion behavior of the obtained materials. To achieve this, investigations were conducted, including SEM analysis, flexural strength testing, Brinell hardness testing, linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). Corrosion measurements were performed in a 3.5% NaCl solution at room temperature. Mechanical investigations revealed a significant increase in flexural strength and hardness for Composite I compared to the plain matrix alloy. In contrast, Composite II’s flexural strength was reduced by the weakening effect of graphite flakes. Performance under bending improved by 46% for Composite I and 25% for Composite II compared to the AlSi12. The corrosion resistance of the tested materials followed the order AlSi12 > Composite I > Composite II. The LSV and EIS results indicate that the explanation for this may be differences in the properties of the protective oxide/hydroxide layer. Furthermore, SEM images showed a weak bond between nickel and graphite. Full article

Shape memory alloys are key to sustainable technology and future industries, with one of the most remarkable materials at present being Nitinol (NiTi), which is known to have unique driving properties and applications, working in extreme conditions and capable of being applied in specific actuation tasks. In this context, this work presents an actuator prototype using versatile springs composed of nickel–titanium to produce angular displacements, beginning with contextual findings on the latest trends and opportunities for solutions in the field of Nitinol (NiTi) devices. Considering the research and industry concerns regarding shape memory materials and the need for research, design, and innovation in the development and investigation of various prototypes of Nitinol-based (NiTi) actuators, the functionalities, physical design, and static/dynamic performance of this newly proposed angular actuator offer strong potential. This work also presents and discusses the results of both experimental model testing and an analytical model simulation within MATLAB and Simulink R2022b. Full article