Search Results (4,452)

Ocean Literacy (OL) can be broadly defined as a framework for understanding the complex and evolving relationships between people and the ocean. It is increasingly recognized as a vital component of marine conservation and sustainability efforts. OL is inherently interdisciplinary, and psychology, while being a particularly relevant field, remains an underutilized field in this space. This paper demonstrates how psychological theories, frameworks, and validated measures can meaningfully inform OL strategies across its ten proposed dimensions: knowledge, awareness, attitudes, behavior, activism, communication, emotional connections, access and experience, adaptive capacity, and trust and transparency. Full article

Neopestalotiopsis zimbabwana is an emerging phytopathogen with multiple hosts. Considering the environmental, toxicological, and resistance issues linked to synthetic fungicides, Origanum vulgare L. essential oil (OEO) was evaluated through in vitro, in vivo, and in silico approaches. The pathogen, isolated from Watsonia borbonica L., was molecularly identified. Gas chromatography–mass spectrometry (GC–MS) analysis showed hexadecanoic acid (15.98%), dodecanoic acid (15.74%), terpinen-4-ol (11.61%), and thymol (7.65%) as the main components. In vitro assays determined a minimum inhibitory concentration (MIC) of 30% OEO and a minimal fungicidal concentration (MFC) of 60% OEO. Growth chamber trials demonstrated that preventive sprays maintained 0% foliar damage—similar to Captan^®—while controls reached ≈98%; suspending applications after week 4 resulted in ≈45% damage by week 8. These results confirm that OEO lacks systemic residual activity, acting only as a protectant within preventive integrated pest management (IPM) schemes. Docking to cytochrome b (protein data bank, PDB: 5TL8) indicated strong binding of α-farnesene (−7.638 kcal·mol⁻¹), isoterpinolene (−6.944), and α-terpineol (−6.918), suggesting disruption of mitochondrial respiration via Complex III. OEO represents a promising eco-friendly alternative for managing N. zimbabwana under controlled conditions and reducing reliance on synthetic fungicides. Full article

The olive fruit is recognized for being a significant source of phenolic compounds, including hydroxytyrosol (H-tyr), tyrosol (Tyr), oleuropein (Ole), and verbascoside (Verb). The maturity index (MI) significantly influences the phenolic profile, which is a cultivar-specific trait. A study was conducted to assess the evolution of the phenolic profile in seven olive cultivars during ripening: ‘Galega vulgar’ (Gv), ‘Azeiteira’ (Az), ‘Cobrançosa’ (Cob), ‘Picual’ (Pic), ‘Carrasquenha’ (Car), ‘Redondil’ (Red), and ‘Arbequina’ (Arb). The results indicate a declining trend in total phenolic compounds (TPC) across all cultivars, with Cob and Car exhibiting the highest values, over 60 g GAE kg⁻¹ at T1 and above 30 g GAE kg⁻¹ at T7, respectively. In Ole quantitation, Red demonstrated the highest values, recording 39 g kg⁻¹ in T1 and 15 g kg⁻¹ at T7, with per olive fruit unit measurements ranging from 19.7 mg at T1 to 22.7 mg at T7. These findings underscore olive fruit as an exceptional source of bioactive compounds and their advantageous health-promoting effects, which might be utilized as a functional food source, validating the unique phenolic profiles of each cultivar in relation to ripening. Full article

This study examines the complex relations between corruption, income inequality, and sustainable economic development within the European Union (EU) for the 2003–2023 period. Employing panel data for all 27 EU member states, as well as for the subgroups of Old (OMS) and New Member States (NMS), the analysis applies pooled OLS, random- and fixed-effects models, and panel-corrected standard errors (PCSE) estimations. The results indicate that higher perceived corruption is robustly associated with greater income inequality, while higher tertiary education attainment, greater social protection expenditures, and increased urbanization apparently reduce inequality. Subsample evidence reveals that institutional context conditions the strength of these relationships, with NMS exhibiting a more significant corruption–inequality nexus. These findings highlight that achieving sustainable and inclusive economic growth in the EU depends on institutional integrity and good governance. Strengthening anti-corruption frameworks, investing in human capital, and enhancing social protection are essential policy instruments for supporting the EU’s sustainable development objectives. Full article

Background: Adolescence is a critical developmental stage marked by vulnerability to psychological difficulties. While family relationships, peer bonds, prosocial behaviors, and health-risk factors have been linked to adolescent mental health, few studies have examined their joint effects in clinical pediatric populations. This study assessed demographic, clinical, relational, and behavioral predictors of psychological difficulties in Italian adolescents. Methods: A cross-sectional sample of 177 adolescents (aged 11–14 years) from a pediatric clinic completed the Strengths and Difficulties Questionnaire (SDQ). The Total Difficulties (SDQ TD) score was the main outcome. Associations were tested with ordinary least squares (OLS) and confirmed using robust MM regression. Bootstrap confidence intervals and Benjamini–Hochberg corrections were applied. Sensitivity analyses excluded the Peer Problems subscale to address part–whole overlap. Results: Higher friendship satisfaction was consistently associated with fewer psychological difficulties, confirming its role as a strong protective factor. Prosocial behavior and male sex were also linked to fewer difficulties in initial analyses, though these associations were less stable after correction. Sensitivity analyses further supported the protective value of friendship satisfaction, even when accounting for overlap with peer problems. Despite relatively low overall levels of psychological difficulties, nearly one-quarter of adolescents met the clinical cut-off for eating disorder risk. Conclusions: Friendship satisfaction was the strongest protective factor, while prosocial behavior and sex showed weaker consistency. Findings suggest that distinct aspects of peer relationships jointly shape adolescents’ psychological outcomes. Interventions promoting social functioning may support mental health in clinical youth populations. Full article

This paper proposes a new family of robust estimators of means, depending on the Orthogonalized Gnanadesikan–Kettenring (OGK) covariance matrix. These estimators are computationally feasible and robust replacements of the Minimum Covariance Determinant (MCD) estimator in survey sampling contexts involving auxiliary information. With the growing popularity of outliers in environmental data, as in the case of measuring solar radiation, conventional estimators like the sample mean or the Ordinary Least Squares (OLS) regression-based estimators are both biased and unreliable. The suggested OGK-based exponential-type estimators combine robust measures of location and dispersion and have a considerable advantage in the estimation of the population mean when auxiliary variables such as temperature are highly correlated with the variable of interest. The MSE property of OGK-based estimators is also obtained through a detailed theoretical derivation with the expressions of optimal weights. Performance was further proved using real-world and simulated data on solar radiation, as well as by demonstrating lower MSEs and higher PREs in comparison to MCD-based estimators. These results show that OGK-based estimators are highly efficient and robust in actual and artificially contaminated situations and hence are a good option in robust survey sampling and environmental data analysis. Full article

Volatile organic compounds (VOCs) are critical indicators of the metabolic status of whole-plant maize silage (WPMS). However, the impact of inoculating various strains of fermentation agents on VOC changes has not been systematically explored. This study aimed to determine how inoculation with Lactiplantibacillus plantarum and Lentilactobacillus buchneri modulates the VOC profile and odor of WPMS after 90 days. VOCs were extracted by headspace solid-phase microextraction and analyzed by gas chromatography-mass spectrometry (HS-SPME-GC-MS). Key VOCs were screened using the variable importance in projection (VIP) and substantiated by relative odor activity values (rOAV) and odor descriptions. A total of 82 compounds were identified, including 22 esters, 19 alcohols, 3 acids, 9 aldehydes, 2 ethers, 6 hydrocarbons, 4 ketones, 10 phenols, and 8 terpenoids. L. plantarum enhanced green/fruity odors while strain L. buchneri significantly reduced undesirable phenolic and aldehydic compounds. Six key VOCs influencing the odor of WPMS were selected: 4-ethyl-2-methoxyphenol and benzaldehyde, which contribute smoky, bacon, and bitter almond aromas, and (E)-3-hexen-1-ol, benzyl alcohol, (E, E)-2,4-heptadienal and methyl salicylate, which impart green, fruity, and nutty aromas. These findings highlight the effects and contributions of various strain additives on VOCs in WPMS, providing new theoretical insights for regulating the flavor profile of WPMS. Full article

Functional beverages enhance the nutritional value of their ingredients by increasing the levels of bioactive components, such as probiotics. To achieve consumer acceptance, functional beverages must be both palatable and nutritious. This study investigates the fermentation of quinoa and cherimoya at two temperatures (25 °C and 32 °C) using water kefir grains. The aim was to create a fermented mix that is both balanced and appealing to consumers. The response variables measured were the concentrations of lactic acid bacteria (LAB) and yeasts (CFU mL⁻¹), as well as the overall liking (OL). Ten semi-trained panellists evaluated them using a seven-point hedonic scale. All three developed models for LAB and yeast growth, and OL exhibited R² values exceeding 0.8, indicating a strong model fit and simultaneous optimisation considering the three key responses. At a temperature of 25 °C, the mass fractions of the mixes containing quinoa puree (QP) and cherimoya juice (CJ) were 0.13 and 0.87, respectively. Under optimal conditions, the LAB and yeast increased by 4.2 and 4.4 log units, respectively. Moreover, a significant 62% increase in protein levels and a notable 82% decrease in ascorbic acid were observed after 48 h of fermentation, likely caused by the Maillard reaction. Full article

This study aims to investigate the impact of digital transformation on corporate tax avoidance. In fact, this revolution has pervasively affected firms in different aspects and represents a significant opportunity to modernize their internal processes, bringing alongside a set of challenges that they must overcome. One hypothesis posits that digitalization enhances information transparency and internal control, reducing tax avoidance, while the other one suggests that the increase in digitalization leads to more complex and opaque transactions, leaving avenues for more aggressive tax strategies. This paper uses data of listed firms in the Casablanca Stock Exchange from 2020 to 2024, excluding the financial sector due to its specific tax regulation, leaving a final sample of 56 companies and 272 firm-year observations. It applies an OLS regression to assess the relation between the two variables, controlling for a set of firm and governance characteristics. The aim of the article is to address the scholarly debate by providing insights into an emerging economy where there is little research on the subject. The findings reveal that digital transformation contributes to the decrease in corporate tax avoidance in conjunction with governance variables like the presence of independent directors on the board and the duality of a CEO position, strongly supporting the first hypothesis. Notably, the OLS regression results show that an increase in digitalization by 1 point is associated with a decrease of 40.4755 in the book-tax differences, significant at the 5% level. The results provide high support for firms to invest in technologies in order to optimize their internal processes and improve their data quality; it also calls for tax authorities to strengthen their digital audit capacities and integrate data-driven tools to detect and interpret signals of potential tax-aggressive strategies. Full article

This study evaluated the effects of dietary olive leaf extract (OLE) on Nile tilapia (Oreochromis niloticus) juveniles, focusing on growth parameters, centesimal composition, biochemical responses, and lipid peroxidation. OLE was extracted with 60% ethanol (1:20 w/v). Five diets, containing 34% crude protein and 8% lipids, were tested: a control (0 g/kg) and four with increasing OLE levels (0.25, 0.5, 1, and 2 g/kg). The 46-day trial included 225 fish (0.56 ± 0.11 g) distributed in 15 tanks. Growth performance was not affected, except for a higher condition factor in OLE0.25. This dose also resulted in lower moisture and higher lipid content, while all OLE treatments increased crude protein in fish. Muscle glycogen decreased in all OLE-fed groups, and liver glycogen was reduced in OLE0.25. Plasma triglycerides decreased in OLE0.5 and OLE0.25, while total plasma protein was lower in OLE2.0. Liver triglycerides were lower in OLE0.25 and higher in OLE0.5, whereas glucose showed a glycemic peak in OLE2.0. Hepatic lipid peroxidation was reduced in OLE2.0. Overall, dietary OLE did not compromise the growth performance of Nile tilapia, and 0.25 g/kg promoted beneficial effects on centesimal composition, biochemical parameters, and lipid peroxidation, highlighting its potential as a functional ingredient in aquafeeds. Full article

The aim of this study was to present a comprehensive analysis of honey varieties from different botanical origins, focusing on their phenolic compounds’ composition, volatile profiles, and antioxidant activity. We simultaneously identified and quantified 37 bioactive compounds, including anthocyanins, flavonols, flavones, flavan-3-ols, proanthocyanidins, and phenolic acids, across various honey samples by HPLC-MS/MS. Total phenolic content (TPC), total flavonoid content (TFC), and antioxidant activity (AOA) were determined using UV-Vis spectrophotometric analysis. The content of phenolic compounds quantified by HPLC-MS/MS ranged from 19.56 to 243.94 mg·kg⁻¹, highlighting a high presence of these antioxidant compounds (mainly phenolic acids), confirmed also by the positive correlation between TPC and DPPH values. Among volatiles compounds, analyzed by HS-SPME-GC-MS, benzene acetaldehyde and furfural resulted specific for two types of honey samples (H-7 and H-9), highlighting the possibility of searching for chemical markers to characterize honeys of different specie/origin. This study enhances our understanding of the bioactive potential of honey from different botanical origins and provides a foundation for future research on its health benefits. Full article

Background: Clinician empathy is associated with family satisfaction and reduced anxiety, but quantitative data from the parents’ perspective in pediatric psychiatry are limited. Objective: To assess parent-perceived physician empathy in pediatric psychiatry consultations and explore its associations with clinical and demographic factors. Methods: Cross-sectional, consecutive sample of parents attending an outpatient pediatric psychiatry clinic (n = 163 parents). A 10-item behavioral empathy scale (range 10–40) was used. Analyses included reliability testing, group comparisons, correlations, OLS regression, and exploratory PCA. Results: The mean total empathy score was 34.5 (SD 4.2); most parents rated physicians as highly empathic (65%). Parents of children with ASD reported lower empathy compared to those with anxiety/depression. Empathy increased modestly with child age and was associated with a calmer state at the end of the visit. PCA suggested exploratory evidence of potential subdimensions, including child-centered communication and listening/facilitation. Conclusions: Parent-perceived empathy in this sample was generally high; however, behaviors that directly involve and facilitate the child (listening, encouraging questions) may need strengthening, particularly for children with ASD. Results should be interpreted in light of the single-center design, the absence of a recorded participation rate, parent-proxy reporting, and the exploratory nature of the PCA. Full article

The quantification of volatile compounds in virgin olive oil poses several analytical challenges due to the existence of different concentrations, chemical families, and the possible matrix effect. Accurate quantification, using adequate methodological calibration and statistical procedures, is essential for obtaining reliable results. The aim of this work was to develop and validate an analytical–statistical approach for the quantification of volatile compounds in virgin olive oil. Therefore, several analytical parameters were determined for four calibrations. The ordinary least square (OLS) linear adjustment was selected over the weighted least square due to the homoscedasticity of the variable errors. Additionally, standard addition (AC) and AC with an internal standard (IS) exhibited greater variability, whereas external matrix-matched calibration (EC) was identified as the most reliable approach for quantifying volatile compounds in virgin olive oil. The employment of an IS did not improve the performance of the method in any case. Thus, based on the statistical results, the OLS linear adjustment with EC was selected as the best statistical–analytical approach for quantifying volatiles in olive oil matrices. The volatiles of nine virgin olive oil samples were quantified, applying different methodological calibrations, and no differences were detected, underscoring EC as a superior alternative. Full article

This study investigates the relationship between artificial intelligence (AI) adoption and environmental, social, and governance (ESG) performance among 100 listed Saudi Arabian firms over the period 2015–2024. Drawing on panel data regression techniques, including fixed effects models with Driscoll–Kraay standard errors, pooled OLS with industry and year controls, and dynamic panel estimations using system GMM, the analysis reveals a significant and positive association between AI implementation and overall ESG scores. Disaggregated analysis shows that AI adoption is particularly associated with improvements in the environmental and social dimensions, with a more moderate relationship to governance practices. To address potential issues of cross-sectional dependence and heterogeneity, the study applies the Common Correlated Effects Mean Group (CCEMG) and Mean Group (MG) estimators as robustness checks, which confirm the consistency of the main findings. In addition, the Dumitrescu–Hurlin panel Granger causality test indicates that AI adoption Granger-causes ESG performance—especially in the environmental and social dimensions—while no reverse causality is observed. The results suggest that AI technologies are positively linked to firms’ sustainability strategies and performance, supporting the integration of digital transformation into national and corporate ESG agendas, particularly in emerging markets like Saudi Arabia. Full article

Hypericum perforatum callus and shoot cultures were investigated for biomass production, phenolic compounds and naphthodianthrone biosynthesis, as well antioxidant activities upon elicitation with jasmonic acid (JA). Calli and shoots elicited with 50 and 100 μM JA had comparable or better fresh biomass production, while application of 250 μM JA displayed growth suppression effect. Total phenolics, flavonoids, and flavan-3-ols contents in JA-elicited calli were correlated to increased activities of phenylalanine ammonia lyase (PAL) and chalcone isomerase (CHI). In contrast, PAL and CHI activities in shoots were not significantly related to phenolic compound production, suggesting that JA up-regulated distinct phenylpropanoid/flavonoid pathways. Exogenous application of 250 μM JA was selected as an efficient elicitor dose for enhanced production of hypericin and pseudohypericin in both cultures. Calli and shoots showed an early response to JA elicitation through significant enhancement of non-enzymatic antioxidant properties due to accumulation of phenolic compounds. Concerning antioxidant enzymes, it was shown that up-regulated peroxidase activity in calli and catalase activity in shoots had a pivotal importance in cells’ protection against JA-mediated oxidative stress. Outgoing results indicated that elicitation of H. perforatum callus and shoot cultures with JA represents a promising biotechnological approach for production of bioactive metabolites with medicinal properties. Full article