Search Results (4)

In previous work, we investigated thermodynamic processes in systems at the mesoscopic level where traditional thermodynamic descriptions (macroscopic or microscopic) may not be fully adequate. The key result is that entropy in such systems does not change continuously, as in macroscopic systems, but rather in discrete steps characterized by the quantization constant $\beta$. This quantization reflects the underlying discrete nature of the collision process in low-dimensional systems and the essential role played by thermodynamic fluctuations at this scale. Thermodynamic variables conjugate to the forces, along with Glansdorff–Prigogine’s dissipative variable can be discretized, enabling a mesoscopic-scale formulation of canonical commutation rules (CCRs). In this framework, measurements correspond to determining the eigenvalues of operators associated with key thermodynamic quantities. This work investigates the quantization parameter $\beta$ in the CCRs using a nano-gas model analyzed through classical statistical physics. Our findings suggest that $\beta$ is not an unknown fundamental constant. Instead, it emerges as the minimum achievable value derived from optimizing the uncertainty relation within the framework of our model. The expression for $\beta$ is determined in terms of the ratio $\chi$, which provides a dimensionless number that reflects the relative scales of volume and mass between entities at the Bohr (atomic level) and the molecular scales. This latter parameter quantifies the relative influence of quantum effects versus classical dynamics in a given scattering process. Full article

In this paper, we discuss some well-known experimental observations on self-organization in dissipative systems. The examples range from pure fluid flow, pattern selection in fluid–solid systems to chemical-reaction-induced flocking and aggregation in fluid systems. In each case, self-organization can be seen to be a function of a persistent internal gradient. One goal of this article is to hint at a common theory to explain such phenomena, which often takes the form of the extremum of some thermodynamic quantity, for instance the rate of entropy production. Such variational theories are not new; they have been in existence for decades and gained popularity through the Nobel Prize-winning work of theorists such as Lars Onsager and Ilya Prigogine. The arguments have evolved since then to include systems of higher complexity and for nonlinear systems, though a comprehensive theory remains elusive. The overall attempt is to bring out examples from physics, chemistry, engineering, and biology that reveal deep connections between variational principles in physics and biological, or living systems. There is sufficient evidence to at least raise suspicion that there exists an organization principle common to both living and non-living systems, which deserves deep attention. Full article

There is little doubt that life’s origin followed from the known physical and chemical laws of Nature. The most general scientific framework incorporating the laws of Nature and applicable to most known processes to good approximation, is that of thermodynamics and its extensions to treat out-of-equilibrium phenomena. The event of the origin of life should therefore also be amenable to such an analysis. In this review paper, I describe the non-equilibrium thermodynamic foundations of the origin of life for the non-expert from the perspective of the “Thermodynamic Dissipation Theory for the Origin of Life” which is founded on Classical Irreversible Thermodynamic theory developed by Lars Onsager, Ilya Prigogine, and coworkers. A Glossary of Thermodynamic Terms can be found at the end of the article to aid the reader. Full article

It has been conjectured that the origin of the fundamental molecules of life, their proliferation over the surface of Earth, and their complexation through time, are examples of photochemical dissipative structuring, dissipative proliferation, and dissipative selection, respectively, arising out of the nonequilibrium conditions created on Earth’s surface by the solar photon spectrum. Here I describe the nonequilibrium thermodynamics and the photochemical mechanisms involved in the synthesis and evolution of the fundamental molecules of life from simpler more common precursor molecules under the long wavelength UVC and UVB solar photons prevailing at Earth’s surface during the Archean. Dissipative structuring through photochemical mechanisms leads to carbon based UVC pigments with peaked conical intersections which endow them with a large photon disipative capacity (broad wavelength absorption and rapid radiationless dexcitation). Dissipative proliferation occurs when the photochemical dissipative structuring becomes autocatalytic. Dissipative selection arises when fluctuations lead the system to new stationary states (corresponding to different molecular concentration profiles) of greater dissipative capacity as predicted by the universal evolution criterion of Classical Irreversible Thermodynamic theory established by Onsager, Glansdorff, and Prigogine. An example of the UV photochemical dissipative structuring, proliferation, and selection of the nucleobase adenine from an aqueous solution of HCN under UVC light is given. Full article