Search Results (784)

Chronic stress is a key risk factor for depression and metabolic dysfunction, widely mediated through oxidative stress and inflammatory pathways. Natural products such as honey are increasingly investigated for their potential to attenuate stress-induced pathophysiological changes. This study evaluated the protective effects of Malaysian Acacia honey (AH) on glucose regulation, oxidative damage, histopathological alterations, and pro-inflammatory cytokine expression in stress-induced rats. Male Sprague–Dawley rats (n = 42) were subjected to chronic unpredictable mild stress and supplemented with AH, amitriptyline (AMT), or their combination for 28 days. Blood glucose levels, erythrocyte hemolysis, histological changes in liver and kidney, and expression of IL-1β and TGF-β1 in ileum, caecum, and hypothalamus were assessed. Data were reported as mean and standard error of mean (SEM) after three or more independent experiments had been conducted. The data were analyzed using a paired-t-test or a one-way or two-way analysis of variance (ANOVA) and considered significant if p < 0.05. Stress markedly elevated glucose levels (7.97 ± 0.20 mmol/L), increased hemolysis (14.30% ± 2.96), and induced hepatic (cytoplasmic vacuolation, 1.40 ± 0.25; cell lining absent, 1.20 ± 0.37) and renal lesions (dilated intertubular capillaries, 1.40 ± 0.51; inflammation, 2.20 ± 0.20), accompanied by upregulation of IL-1β (1.27-fold ± 0.20) and TGF-β1 (1.00-fold ± 0.08). Supplementation with AH significantly reduced hyperglycemia, inhibited hemolysis, ameliorated tissue damage, and downregulated pro-inflammatory cytokines. Combination therapy with AH and AMT produced the most significant improvements near to normal level, suggesting synergistic benefits. These findings highlight the therapeutic potential of AH as a natural adjunct in managing stress-related metabolic and inflammatory disturbances. Full article

Chromophore domains were proposed in a previous work as the mediators of self-healing of optical properties in dye-doped polymers. A statistical mechanical model based on domains matches all observed self-healing dynamics as a function of dye concentration, temperature and light intensity. This suggests that domains are responsible. However, there is no direct observation of domains, nor has their physical morphology been determined. This work reports the first observation of domains in a self-healing polymer using Resonant Soft X-ray Scattering (RSoXS), which gives a domain size in the range of 39.3 Å to 62.8 Å. This range includes the domain model’s prediction of an average domain size of roughly 30 molecules, which is about 56 Å, if the molecules form a loosely packed ball. X-ray scattering of samples of concentration spanning from neat polymer to the saturation limit of Disperse Orange 11 (DO11) dye in poly (methyl methacrylate) (PMMA) polymer shows domains in the expected size scales, with the mode of the effective scattering width varying little with concentration. However, for constant domain shape, the mode peak would decrease in q with increasing concentration, according to the domain model. This work suggests that the domain shape might change with concentration, which warrants further investigations of domain topology and geometry. The important evidence presented in this work is the direct experimental observation of domains, which is central to self-healing models. Full article

Understory vegetation diversity is the key indicator of ecological outcomes in the close-to-nature transformation of plantations, with its composition revealing successional dynamics and ecosystem functionality. In response to China’s “Green and Beautiful Guangdong” Initiative, enhancing the ecological quality of plantations has been established as a critical objective for sustainable forest management. This study assessed the understory vegetation in four representative transformed plantations in Guangdong Province, China, using Multi-Response Permutation Procedure (MRPP), Indicator Species Analysis (ISA), Detrended Correspondence Analysis (DCA), and Redundancy Analysis (RDA). The results showed that: (1) Species richness was highest in the Eucalyptus L’Hér plantation (102 species), followed by Pinus massoniana Lamb (94), Acacia mangium Willd (92), and Litchi chinensis Soon plantations (85). (2) MRPP analysis revealed significant differences in species composition among plantation types (A = 0.149, p < 0.001). ISA identified 5, 7, 3, and 5 indicator species for each type, respectively, predominantly light-demanding pioneers such as Dicranopteris dichotoma (Thunb.) Bernh and Microstegium vagans (Nees ex Steud.) A. Camus. (3) DCA ordination showed clear compositional segregation among the understory communities of Eucalyptus, Pinus massoniana, and Acacia mangium plantations, whereas the Litchi chinensis plantation exhibited substantial overlap with others. RDA further demonstrated a significant negative correlation between mean diameter at breast height (DBH) and understory diversity (p < 0.01) across all plantations except Litchi chinensis. These findings offer a quantitative basis for tailored management strategies. We recommend structural adjustments through target-tree thinning to optimize light availability by regulating DBH, combined with interplanting native understory species. This integrated approach can enhance structural heterogeneity and promote more effective and sustainable plantation restoration. Full article

Organic acids shape the organoleptic properties of honey and are linked to its health-beneficial properties. Their composition is affected by botanical and geographical origin, and some acids have even been proposed as markers for authentication of varietal honeys. Organic-acid composition was determined using high-performance liquid chromatography with photodiode-array detection (HPLC-DAD) in 152 samples of monofloral (willow, acacia, rape, phacelia, linden, heather, buckwheat and goldenrod) and honeydew (deciduous and coniferous) honeys from Poland. The deciduous and coniferous honeydew honeys were distinguished by high content of L-(+)-lactic acid and the presence of succinic acid as well as high total content of acids. Buckwheat honey was the only variety for which the presence of D-(−)-tartaric acid was quantified. These three honey varieties were clearly separated from the others using principal component analysis (PCA). Samples from the other varieties formed one cluster. We conclude that while some promising results were obtained for distinguishing honeydew and buckwheat honeys from other varieties, further investigation is needed, including analysis of additional acids and possibly other physicochemical parameters. Full article

Polychrome paintings on wooden artifacts are vital elements of cultural heritage, where plant-derived binders play a crucial role in color formation and durability. This study aims to systematically compare the chemical, optical, and surface characteristics of two traditional natural adhesives—acacia gum (AG) and tragacanth gum (TG)—to better understand their influence on the preservation and reproduction of wood-supported polychrome coatings. Fourier-transform infrared spectroscopy (FTIR) confirmed their polysaccharide-rich structures, with distinct ester and glycosidic linkages, while rheological tests demonstrated that TG exhibited higher viscosity at 1–3% concentrations, whereas AG showed a sharper increase at 5%, reflecting different molecular architectures. Colorimetric analysis combined with two-way ANOVA revealed that gum type significantly influenced color development in blue and red coatings (p < 0.001), while yellow and green coatings remained largely unaffected. Gum concentration (1–5%) generally showed no significant effect on color. All coatings exhibited a matte appearance (<3 GU), with statistical analysis indicating that gloss was mainly determined by pigment particle distribution rather than adhesive type. Surface roughness increased notably with gum concentration (p < 0.001), demonstrating that binder content strongly affects coating microtexture. Overall, pigment type was the dominant factor for color, whereas gum concentration critically influenced surface morphology. These findings provide practical guidance for optimizing natural adhesives in the conservation of traditional polychrome artifacts. Full article

This exploratory study assessed the influence of botanical origin and acquisition source on the phenolic profile and antioxidant properties of selected Romanian monofloral honeys. Eight samples were analyzed, representing five floral types: acacia, linden, rapeseed, lavender, and thyme. For acacia, linden, and rapeseed, both commercial and locally sourced honeys were included. Analytical techniques included total phenolic content (TPC, Folin–Ciocalteu), antioxidant assays (DPPH, ABTS, FRAP), color intensity (ABS₄₅₀), and phenolic compound profiling via HPLC-DAD-ESI⁺. TPC ranged from 179.26 ± 23.57 to 586.67 ± 18.33 mg GAE/100 g, with thyme and linden honeys presenting the highest values. Seventeen phenolic compounds were tentatively identified; gallic acid was predominant in thyme honey (127 mg/100 g), and linden honey contained high levels of rutin (70 mg/100 g) and galangin-glucoside. Antioxidant capacity varied notably by floral origin, with thyme and linden outperforming acacia samples. Significant correlations were found between total phenolics and ABTS (r = 0.86), and between ABS₄₅₀ and FRAP (r = 0.86). DPPH kinetics followed zero-order behavior (R² > 0.98). Principal component analysis (PC1 + PC2 = 88%) enabled preliminary separation by botanical origin. While based on a limited sample set, findings support the relevance of combining chromatographic, kinetic, and multivariate tools for exploratory honey characterization. Full article

The increasing emphasis on environmental sustainability has placed biomass as a versatile and renewable resource, while the management and disposal of forest byproducts remain a significant challenge. This study explores the valorization of forest biomass residues derived from Pinus pinaster, Pinus pinea, and the invasive species Acacia dealbata, with a focus on their potential application as bioadsorbents. A comprehensive physicochemical characterization was conducted for different biomass fractions (leaves, needles, and branches of varying diameters). Leaves and needles contained higher amounts of extractives (from 7.7% in acacia leaves to 18.8% in maritime pine needles) and ash (3.4 and 4.2% in acacia leaves and stone pine needles, respectively), whereas branches contained more holocellulose (from 59.6% in P. pinea small branches to 79.2% in P. pinaster large branches). ATR-FTIR and pHpzc analyses indicated compositional and surface charge differences, with higher pHpzc values in A. dealbata relative to Pinus. TG analysis showed that acacia large branches degraded at a lower temperature (320 °C) compared to Pinus species (440–450 °C). Overall, the findings highlight the suitability of these underutilized forest byproducts as bioadsorbents, contributing to the advancement of circular economy practices. Full article

Malagousia represents one of the most promising white native Greek grapevine varieties, producing wines of excellent quality. This study aimed to explore the quality characteristics of Malagousia wines from Northern Greece (Macedonia and Thessaly regions) and evaluate the impact of location and processing. We hypothesized that processing can exceed the terroir effect on most compositional traits. To verify this hypothesis, 28 commercial single-varietal Malagousia wines were chosen, varying in location, processing, and vintage. Wines were examined for alcohol content, pH, color, phenolic content, antioxidant activity, elemental composition, and sensory attributes. There was a significant variation in the parameters measured among the wine samples depending on the processing applied, such as skin contact, lees aging, and barrel maturation. While aging on lees affected antioxidant activity and aroma complexity, wines aged in oak or acacia barrels displayed higher phenolic content. Common sensory descriptors included citrus (such as lemon and lime), chamomile, and peach, with some wines exhibiting unique notes like caramel or peppermint. Cluster and Principal Component analyses showed distinct clusters based on winemaking methods and, to a lesser degree, place of origin. The results highlight Malagousia’s varietal potential and the significance of carefully managed processing in expressing stylistic and terroir-driven complexity. Full article

In Africa, the folkloric practices involving plant-based remedies play a crucial role in livestock farming, often attributed to the limited access to modern veterinary services. The use of Acacia species (including those reclassified as Vachellia species) in ethnoveterinary medicine has garnered increasing interest due to their high protein content and medicinal (including anti-parasitic) properties, offering a sustainable source of fodder particularly in arid and semi-arid regions. However, scientific assessment of their efficacy and safety remains limited. This systematic review examines the ethnoveterinary uses, biological efficacy and safety of Acacia species across Africa. A literature search was conducted using PubMed, Google Scholar and Scopus, yielding 519 relevant studies published between 2001 and 2024. After applying the inclusion and exclusion criteria, 43 eligible studies were analyzed based on their relevance, geographical location and livestock disease applications. Plants of the World online database was used to validate the names of the species and authority. Ethiopia had the highest usage of Acacia species (25%), then Nigeria (20%) followed by both South Africa (15%) and Namibia (15%). Vachellia nilotica (Acacia nilotica) was the most frequently cited species (26.3%), followed by Vachellia karroo (Acacia karroo) (15.8%). Ethnobotanical records indicate that the different Acacia species have been traditionally used to treat conditions such as diarrhea, wound infections and complications such as retained placenta. Pharmacological studies corroborate the therapeutic benefits of Acacia species with evidence of their antimicrobial, anti-inflammatory, antioxidant and anthelmintic effects, though some toxicity concerns exist at high dosages. The systematic review revealed the efficacy and safety (to some extent) of Acacia species in livestock disease management, emphasizing their potential integration into veterinary medicine. However, the dearth of in vivo studies underscores the need for pre-clinical and clinical trials to establish safe and effective dosages for use in livestock. Full article

Livestock production raises significant environmental concerns, necessitating the development of sustainable feeding strategies based on non-conventional forages, such as locally available vegetation. This study evaluated the effects of a pelleted concentrate containing 10% Acacia farnesiana leaves as a dietary supplement on in vitro ruminal fermentation. Four experimental diets were formulated with increasing levels of the concentrate (0%, 25%, 50%, and 75%). Analyses were performed in triplicate and included chemical composition, in vitro gas and methane production, fermentation kinetics, ammonia nitrogen concentration (N–NH₃), in vitro dry matter digestibility (IVDMD), and metabolizable energy (ME) estimation. The results revealed no significant differences (p > 0.05) in most gas production kinetic parameters, overall fermentation patterns, or metabolizable energy. In contrast, a significant increase (p < 0.05) in secondary metabolite concentrations was detected. While methane production remained unaltered (p > 0.05), a significant linear reduction was observed for IVDMD, the lag phase (L), and N–NH₃ concentration (p = 0.0064, p = 0.0036, and p < 0.0001, respectively). These findings suggest that A. farnesiana can be incorporated into ruminant concentrates without increasing methane emissions. However, in vivo trials and mechanistic studies are required to validate and further elucidate these results. Full article

Using renewable D-gluconic acid δ-lactone as the starting material, two novel glucosamide-based organosilicon quaternary ammonium surfactants (2/3SiDDGPBH) were synthesized through an environmentally friendly three-step process involving amidation, hydrophobic modification, and quaternization. Comprehensive characterization demonstrated their exceptional performance: surface tension reduction to 33.4 mN/m (2SiDDGPBH) and 33.64 mN/m (3SiDDGPBH), uniform spherical micelles (1–10 nm and 30–100 nm) were formed, and outstanding foam properties with 3SiDDGPBH developed, showing superior foamability and stability. Material modification tests on polymethyl methacrylate (PMMA) plates, mature acacia leaves, oilpaper, vegetable-tanned top-grain leather, and melamine-formaldehyde resin (MFR) faced with plywood revealed excellent spreading performance and durability, particularly for 3SiDDGPBH-treated MFR plywood, which maintained excellent spreading performance even after 80 washing cycles. Scanning electron microscopy (SEM) analysis confirmed that the Si wt% of MFR plywood treated with 2/3SiDDGPBH and scrubbed MFR plywood both exhibited a significant increase, and the 3SiDDGPBH-treated MFR plywood demonstrated superior bonding properties. These surfactants combine low surface tension, excellent foaming properties, and outstanding spreading performance, demonstrating broad application prospects in fields such as pesticide adjuvants, industrial and household cleaning agents, cosmetics, oilfield extraction, textile printing and dyeing, and functional coatings. Full article

This study elucidates the mechanisms through which hydrocolloids inhibit oil penetration and improve the sensory quality of batter-coated fried fish cubes. Specifically, guar gum (GuG), linseed gum (LG), acacia senegal gum (AS), and gellan gum (GeG) were individually incorporated into the batter coating system at an addition level of 0.1%. The results indicated that the 0.1% LG-supplemented group significantly increased batter viscosity by 74.9% compared to the control, which in turn improved batter pickup by 26.1% and frying yield by 8.1%. Rheological analysis revealed that hydrocolloid-incorporated batters exhibited markedly higher storage modulus and loss modulus compared to the control group, with a lower loss tangent. Experimental results indicated that hydrocolloids effectively reduced oil absorption and mitigated the rate of lipid oxidation in fried fish cubes while promoting the release of key flavor compounds. Notably, fried fish cubes coated with GuG, when fried at 170 °C, not only reduced oil absorption but also facilitated the formation of critical flavor compounds. These findings provide a theoretical foundation for optimizing fried food processing and flavor control. Full article

Excessive release of ammonium (NH₄⁺) into aquatic ecosystems can promote eutrophication. In this study, the natural adsorbents, coal (C) prepared from Hawthorn (Acacia caven) and coal fly ash obtained from C, were used to remove NH₄⁺ from aqueous systems through batch adsorption–desorption studies. Both adsorbents were physically and chemically characterized, while Fourier-transform infrared spectroscopy and zeta potential were used to understand the surface functional groups and surface charge characteristics. CFA showed a higher pH, BET specific surface area, electrical conductivity and higher % values for CaO and MgO than C. Kinetic studies of NH₄⁺ adsorption at pH = 4.5 for both materials fitted the pseudo-second-order model giving the r² of 0.970–0.983 and the χ² of 0.008–0.005 and at pH = 6.5 only for C with the r² of 0.986 and the χ² of 0.013. Meanwhile, the adsorption isotherm data at pH = 4.5 for both materials and 6.5 for CFA complied with the Freundlich model (r² > 0.965 and χ² < 0.012), suggesting that NH₄⁺ adsorption onto both adsorbents at those pH values occurred through the formation of a multilayer adsorption on heterogeneous surfaces. This indicates that the dominant adsorption of both adsorbents was physisorption with no site-specific interaction. Based on these results, CFA is proposed as a promising and economical material for the removal of NH₄⁺ from aqueous systems. Full article

In tropical regions, the establishment of large-scale exotic plantations has addressed the demand for timber resources but has also disrupted the structural stability of native vegetation and altered soil nutrient cycling, thereby impairing ecosystem functions. Identifying effective restoration strategies for these plantations is crucial for sustainable forest management and ecological security. This study examined Acacia mangium Willd., Cunninghamia lanceolata (Lamb.) Hook., and Pinus caribaea Morelet. plantations in Hainan Tropical Rainforest National Park under three treatments: plantation control, girdling, and natural secondary forest. Vegetation surveys and soil analyses were conducted to explore the relationships between community structure, soil physicochemical properties, and enzyme activities. Diversity indices, Pearson correlations, and redundancy analysis were used to assess plant–soil relationships. The results showed that girdling significantly accelerated succession in C. lanceolata and P. caribaea plantations, increased species diversity, and enhanced the dominance of native species. Shrub-layer diversity indices (H_shrub, D_shrub, E_shrub) were the main drivers of soil properties and enzyme activities, while tree-layer effects were weaker. Girdling regulated soil nutrients and biological activity primarily via changes in community structure. These findings highlight the importance of optimizing shrub-layer structure and enhancing diversity for tropical plantation restoration. Combining forest type conversion with moderate interventions can promote coordinated plant–soil development over time. Full article

Potential fire behavior varied significantly among tree species, directly influencing forest fire intensity and spread. To quantify these differences and evaluate species-specific fuel traits for fire management applications, this study conducted field surveys and sample collection in the Jin Dian Yuanbaoshan Forest Area, Kunming, Yunnan Province. Using a combustion bed experiment, we simulated the burning behavior of Acacia dealbata, Alnus nepalensis, and Pinus armandii under windless conditions, recording ignition time, extinction time, flame height, spread rate, and calculating fire intensity. Comparative analysis revealed: (1) Fire intensity ranking: P. armandii needles > A. dealbata leaves > P. armandii branches > A. nepalensis leaves > P. armandii bark > A. dealbata branches > A. nepalensis branches > A. dealbata bark > A. nepalensis bark; (2) The biological firebreaks composed of A. nepalensis and A. dealbata in Yuanbaoshan exhibited effective flame-retardant performance; (3) Coarse woody fuels negatively affected prescribed burning intensity and effectiveness. By quantifying fire behavior differences among these species, this study provides scientific support for fuel management and fire-resistant species selection in central Yunnan, while offering practical guidance for prescribed burning strategies in the Jin Dian Yuanbaoshan Forest Area. Full article