Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (1)

Search Parameters:
Keywords = acremolide

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
15 pages, 1233 KB  
Article
Total Syntheses and Stereochemical Assignment of Acremolides A and B
by Yi Xiao, Junyang Liu, Yangyang Jiang, Yian Guo and Tao Ye
Molecules 2024, 29(15), 3599; https://doi.org/10.3390/molecules29153599 - 30 Jul 2024
Cited by 1 | Viewed by 2107
Abstract
The absolute stereochemical configurations of acremolides A and B were predicted by a biochemistry-based rule and unambiguously confirmed through their total syntheses. The features of the total syntheses include sequential Krische’s Ir-catalyzed crotylation, Brown’s borane-mediated crotylation, Mitsunobu esterification reaction, and cross-metathesis reaction. The [...] Read more.
The absolute stereochemical configurations of acremolides A and B were predicted by a biochemistry-based rule and unambiguously confirmed through their total syntheses. The features of the total syntheses include sequential Krische’s Ir-catalyzed crotylation, Brown’s borane-mediated crotylation, Mitsunobu esterification reaction, and cross-metathesis reaction. The efficient total synthesis enabled clear validation of the predicted stereochemistry for acremolides A and B. Full article
(This article belongs to the Special Issue Bioactive Molecules: Isolation, Synthesis, Analysis, and Application)
Show Figures

Figure 1

Back to TopTop