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Search Results (167)

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31 pages, 6688 KB  
Article
Seismic Behavior of Steel Frames with Geopolymer and Conventional Mortars Under Rigid and Flexible Joint Conditions
by Oğuzhan Çelebi and Muhammet Mücahit Demir
Buildings 2026, 16(5), 1055; https://doi.org/10.3390/buildings16051055 - 6 Mar 2026
Viewed by 246
Abstract
This work experimentally examines the seismic performance of steel frames with masonry infill walls produced with geopolymer and traditional mortars under both rigid and flexible joint configurations. Four single-span specimens were evaluated on a uniaxial shake table utilizing eleven scaled earthquake records that [...] Read more.
This work experimentally examines the seismic performance of steel frames with masonry infill walls produced with geopolymer and traditional mortars under both rigid and flexible joint configurations. Four single-span specimens were evaluated on a uniaxial shake table utilizing eleven scaled earthquake records that represent both in-plane and out-of-plane excitations. Flexible joints markedly diminished acceleration requirements and enhanced deformation capacity in comparison to stiff systems. Rigid frames attained maximum accelerations of 1.82 ± 0.21 g, whilst flexible-joint specimens measured 1.15 ± 0.18 g; the associated lateral displacements were 6.8 ± 0.9 mm and 10.5 ± 1.1 mm, respectively. Geopolymer mortar improved interface adhesion and rigidity, elevating dominant frequencies in rigid systems by around 40% and fostering more ductile behavior in flexible structures. Frequency-domain analysis indicated that decreases in dominant frequency correlated with stiffness deterioration. Geopolymer–flexible systems yielded the minimal acceleration responses and displayed only negligible cracking, indicating enhanced seismic performance. Full article
(This article belongs to the Collection Structural Analysis for Earthquake-Resistant Design of Buildings)
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31 pages, 17275 KB  
Article
Shear Performance of Reinforced 3DPM-NM Specimens with Different Interface Locking Designs
by Chang Sun, Zhipeng Chu, Yijing Luo, Long Li, Qiong Liu and Amardeep Singh
Buildings 2026, 16(3), 626; https://doi.org/10.3390/buildings16030626 - 2 Feb 2026
Viewed by 376
Abstract
As 3D printing emerges as a transformative technology in construction, the structural performance of 3D-printed mortar (3DPM) has become a key research focus. This study conducted shear tests on reinforced specimens combining 3D-printed mortar (3DPM) and normal mortar (NM). Four different shapes of [...] Read more.
As 3D printing emerges as a transformative technology in construction, the structural performance of 3D-printed mortar (3DPM) has become a key research focus. This study conducted shear tests on reinforced specimens combining 3D-printed mortar (3DPM) and normal mortar (NM). Four different shapes of interfacial locking design (I-shaped, K-shaped, C-shaped, S-shaped) were examined, comparing reinforced (CR) and non-reinforced (NR) specimens. The investigation analyzed failure modes, crack propagation patterns, and shear transfer mechanisms at CR series specimens under direct shear loading. CR-S specimens exhibited a shear peak load value 14.0% higher than CR-K specimens, 33.2% higher than CR-C specimens, and 42.9% higher than CR-I specimens. CR-I specimens exhibited pure adhesive failure. CR-K, CR-C, and CR-S specimens showed composite failure patterns combining adhesive and shear failure mechanisms. Strain analysis revealed the maximum horizontal strain εxx across all specimen shapes. CR-C and CR-S specimens recorded strain values exceeding CR-I and CR-K specimens by over 50%. Reinforcement produced pronounced increases in ultimate bearing capacity for I-shaped and C-shaped specimens, achieving gains of 51.9% and 60.4%, respectively. Reinforcement substantially enhanced energy dissipation capacity. Compared with NR series specimens, the performance improvements ranked as follows: CR-C (+164.67%) > CR-S (+70.70%) > CR-I (+52.05%) > CR-K (+9.42%). Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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26 pages, 4742 KB  
Article
Research on Plate–Umbrella Composite Recyclable Rock Anchor Used in Electrical Wire Tensioning and Its Ultimate Bearing Capacity
by Yimin Zheng, Peng Zhang, Wangwang Zhang, Deyong Wu and Yang Xu
Appl. Sci. 2026, 16(3), 1434; https://doi.org/10.3390/app16031434 - 30 Jan 2026
Viewed by 336
Abstract
Temporary ground anchors are widely used to provide anchorage for winches, tensioners, and guy wires during power transmission construction. In mountainous terrain, the drilling efficiency is limited, and conventional cement-grouted rock anchors are typically abandoned after use, causing resource waste and local environmental [...] Read more.
Temporary ground anchors are widely used to provide anchorage for winches, tensioners, and guy wires during power transmission construction. In mountainous terrain, the drilling efficiency is limited, and conventional cement-grouted rock anchors are typically abandoned after use, causing resource waste and local environmental disturbances. This study proposes a plate–umbrella composite recyclable rock anchor in which a hinged umbrella head can unfold and retract within an end-plate sleeve to mobilize slab-bearing resistance under pull-out. A composite grouting scheme (epoxy mortar plus hot-melt adhesive) combined with resistive heating enables component recovery after service. Field pull-out/recovery trials and ABAQUS simulations were conducted to evaluate load–displacement behavior, recovery feasibility, and key influencing factors (embedment length and drilling/tension angle combinations). Compared with a conventional end-plate anchor of the same short embedment length (1 m), the proposed anchor achieved a markedly higher ultimate capacity and smaller displacement. Angle mismatch between the drilling and tension directions caused substantial capacity loss, highlighting the need for alignment control in practice. Parametric simulations further indicate stable performance across representative weathered granite conditions. The proposed system provides a promising approach for efficient and reusable temporary anchorage in mountainous transmission projects. Full article
(This article belongs to the Special Issue Tunnel Construction and Underground Engineering)
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16 pages, 2278 KB  
Article
Fine-Fraction Brazilian Residual Kaolin-Filled Coating Mortars
by Thamires Alves da Silveira, Mirian Dosolina Fusinato, Gustavo Luis Calegaro, Cristian da Conceição Gomes and Rafael de Avila Delucis
Waste 2026, 4(1), 3; https://doi.org/10.3390/waste4010003 - 13 Jan 2026
Viewed by 436
Abstract
This study investigates the use of the fine fraction of Brazilian residual kaolin, a material with no pozzolanic activity according to the modified Chapelle test, as a partial cement replacement in rendering mortars. The kaolin was classified into three granulometric fractions (coarse: 150–300 [...] Read more.
This study investigates the use of the fine fraction of Brazilian residual kaolin, a material with no pozzolanic activity according to the modified Chapelle test, as a partial cement replacement in rendering mortars. The kaolin was classified into three granulometric fractions (coarse: 150–300 µm, intermediate: 75–150 µm, and fine: <75 µm) and incorporated at two filler contents (10% and 20% by weight). Mineralogical and chemical analyses revealed that the fine fractions contained higher proportions of kaolinite and accessory oxides, while medium and coarse fractions were dominated by quartz. Intensity ratios from XRD confirmed greater structural disorder in the fine fraction, which was associated with higher water demand but also improved particle packing and pore refinement. Fresh state tests showed that mortars with fine kaolin maintained higher density and exhibited moderate increases in air content, whereas medium and coarse fractions promoted greater entrainment. In the hardened state, fine kaolin reduced water absorption by immersion and capillary rise, while medium and coarse fractions led to higher porosity. Mechanical tests confirmed these trends: although compressive and flexural strengths decreased with increasing substitution, mortars containing the fine kaolin fraction consistently exhibited more moderate strength losses than those with medium or coarse fractions, reflecting their enhanced packing efficiency and pore refinement. Tensile bond strength results further highlighted the positive contribution of the kaolin additions, as the mixtures with 10% coarse kaolin and 20% fine kaolin achieved adhesion values only about 7% and 4% lower, respectively, than the control mortar after 28 days. All mixtures surpassed the performance requirements of NBR 13281, demonstrating that the incorporation of residual kaolin—even at higher substitution levels—does not compromise adhesion and remains compatible with favorable cohesive failure modes in the mortar layer. Despite the lack of pozzolanic activity, residual kaolin was used due to its filler effect and capacity to enhance particle packing and pore refinement in rendering mortars. A life cycle assessment indicated that the partial substitution of cement with residual kaolin effectively reduces the environmental impacts of mortar production, particularly the global warming potential, when the residue is modeled as a by-product with a negligible environmental burden. This highlights the critical role of methodological choices in assessing the sustainability of industrial waste utilization. Full article
(This article belongs to the Special Issue Use of Waste Materials in Construction Industry)
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19 pages, 5149 KB  
Article
Comprehensive Analysis of Gypsum Mortar with Glass Waste Aggregates as a Substitute for Sand
by Mohamed Amine Ouared, Abdelkader Bougara, Ismail Yurtdas, Rodica-Mariana Ion, Said Beldjilali and Nordine Leklou
Processes 2026, 14(2), 209; https://doi.org/10.3390/pr14020209 - 7 Jan 2026
Viewed by 679
Abstract
Gypsum has been used as a building material for a long time due to its environmental friendliness, exceptional fire performance, and ease of use. However, it is also known to have poor moisture resistance and lower mechanical performance. Construction and demolition wastes, which [...] Read more.
Gypsum has been used as a building material for a long time due to its environmental friendliness, exceptional fire performance, and ease of use. However, it is also known to have poor moisture resistance and lower mechanical performance. Construction and demolition wastes, which can cause many environmental issues if not properly managed, are increasingly recycled as reinforcement materials in gypsum mortar. This study aims to assess the effect of incorporating fine glass waste aggregates into gypsum mortars on their physical, mechanical, and adhesive properties. The effect of replacing sand from 0% to 100% by glass waste in gypsum mortar was investigated using various tests and analyses including scanning electron microscopy (SEM), X-ray diffraction (XRD), thermal analysis (DTA and TGA), setting time, flexural and compressive strengths, adhesive, surface hardness, water absorption, thermal conductivity, and ultrasonic pulse velocity. The results obtained emphasize that glass waste can substitute sand in gypsum mortar, even when used at high replacement levels. Replacing all the sand in mortar with glass waste results in a 11% increase in porosity, a 9% decrease in density, and a 53% decrease in thermal conductivity, while still maintaining acceptable mechanical performances. The adhesive strength shows a great dependence on the nature of the substrate. Full article
(This article belongs to the Special Issue Preparation and Application of Functional Fiber Materials)
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20 pages, 3143 KB  
Article
Young’s Modulus Variation of the Deformable Cement Adhesives Under Thermal Action in LRHS
by Jacek Karpiesiuk and Tadeusz Chyzy
Materials 2025, 18(23), 5341; https://doi.org/10.3390/ma18235341 - 27 Nov 2025
Viewed by 520
Abstract
Young’s modulus (E), one of the many material properties, changes in response to thermal actions. The magnitude of these changes also depends on the material used. This is particularly important when the materials used are components of lightweight radiant heating systems [...] Read more.
Young’s modulus (E), one of the many material properties, changes in response to thermal actions. The magnitude of these changes also depends on the material used. This is particularly important when the materials used are components of lightweight radiant heating systems (LRHSs) without screeds. Adhesives or adhesive composites take over the role of the screed in LRHSs. The adhesives, which directly connect the thermal insulation layer and the floor, are responsible for the proper functioning of the heated floor. Therefore, changes in their Young’s modulus cause a loss of layer integrity and ultimately delamination of the floor. Thus, research was conducted on the variation of the Young’s modulus of deformable cement adhesive mortars, specifically types C2S1 and C2S2, used in LRHSs under thermal actions. The deformation values of adhesive mortar samples were measured in a thermal chamber, subjected to compressive strength tests, at temperatures from 30 °C to 50 °C. Deformation measurements of heated samples were performed using the extensometer technique. The measurement results were subjected to mathematical analysis using polynomial regression based on the least squares method and the “Madrid parabola” formulas. After analysis, it was assumed that the Young’s modulus E for the deformable C2S1 cement adhesive, depending on the thermal action taken in the study, falls within the range of 4600 MPa to 5800 MPa when the temperature is varied from 30 °C to 50 °C. Simultaneously, the Young’s modulus E remains constant over these temperatures, at 2300 MPa for the C2S2 adhesive. Knowledge of the Young’s modulus and other strength parameters of adhesive mortars connecting layers of lightweight heated floors or other partitions, subjected to temperature can directly impact their durability. This data can be used to analyse the performance of LRHSs and numerical calculation techniques for various building partitions, such as stairs, balconies, and terraces. Full article
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23 pages, 6706 KB  
Article
Mechanical and Microstructural Evaluation of Compacted Mixtures of Tropical Soils with Expanded Polystyrene (EPS) Waste for Sustainable Construction Applications
by Gian Fonseca dos Santos, Heraldo Nunes Pitanga, Klaus Henrique de Paula Rodrigues, Gustavo Henrique Nalon and Taciano Oliveira da Silva
Buildings 2025, 15(22), 4037; https://doi.org/10.3390/buildings15224037 - 9 Nov 2025
Viewed by 598
Abstract
Expanded polystyrene (EPS), a lightweight thermoplastic polymer widely used in packaging and insulation, has become a growing environmental concern due to its non-biodegradable nature and escalating global consumption. Although EPS waste shows potential in construction applications, previous studies have primarily incorporated it into [...] Read more.
Expanded polystyrene (EPS), a lightweight thermoplastic polymer widely used in packaging and insulation, has become a growing environmental concern due to its non-biodegradable nature and escalating global consumption. Although EPS waste shows potential in construction applications, previous studies have primarily incorporated it into mortars, concrete, or soil–cement mixtures, often relying on the addition of cement to improve its mechanical performance. This approach compromises sustainability and has generally overlooked the role of microstructural interactions in the behavior of soil–EPS waste mixes without cement. This study differs from prior works by exploring the mechanical and microstructural properties of soil–EPS waste mixtures without cementitious binders under different compaction energies. Experimental tests were carried out for the technical characterization of soils, ground EPS waste, and mixtures of soil and different contents of EPS waste (0%, 20%, 30%, and 40% of the total apparent volume of the composite), using different compaction energies (Intermediate and Modified Proctor). The mixtures were subjected to Unconfined Compressive Strength (UCS), California Bearing Ratio (CBR), and direct shear strength tests, in addition to physical and microstructural characterization. The results indicated that both soil type and compaction energy influenced the engineering behavior of the mixtures. The clayey soil exhibited superior mechanical performance, while the sandy soil showed reductions in all mechanical properties. The UCS values of the clayey soil with the addition of EPS did not change significantly (297 kPa to 286 kPa at intermediate energy and 514 kPa to 505 kPa at modified energy), while for the sandy soil, there was a decrease in values (from 167 kPa to 46 kPa at intermediate energy and from 291 kPa to 104 kPa at modified energy). In the CBR tests, only the 20% and 30% addition of EPS to the clayey soil, using the Modified Proctor energy, showed an increase (from 18% to 20% for both percentages). This behavior was primarily attributed to adhesion mechanisms at the soil–EPS waste interface, with friction playing a secondary role, thereby suggesting that clayey soils may offer better mechanical response. The lower dry density of these mixtures compared to compacted natural soils presents a technical benefit for use as backfill in areas with low bearing capacity, where minimizing the load from the fill material is critical. Full article
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31 pages, 17858 KB  
Article
Bond Strength of Adhesive Mortars to Substrates in ETICS—Comparison of Testing Methods
by Paweł Gaciek, Mariusz Gaczek and Paweł Krause
Materials 2025, 18(21), 4977; https://doi.org/10.3390/ma18214977 - 31 Oct 2025
Viewed by 1368
Abstract
This study investigates the bond strength of fifteen cement-based adhesive mortars used for expanded polystyrene (EPS) in External Thermal Insulation Composite Systems (ETICS). Field surveys and contractor interviews (170 questionnaires) found that adhesive layer thicknesses in real applications typically range from 15–20 mm [...] Read more.
This study investigates the bond strength of fifteen cement-based adhesive mortars used for expanded polystyrene (EPS) in External Thermal Insulation Composite Systems (ETICS). Field surveys and contractor interviews (170 questionnaires) found that adhesive layer thicknesses in real applications typically range from 15–20 mm and frequently exceed 20 mm, in contrast to the smaller values most often recommended by guidelines and technical instructions. Laboratory testing was conducted using two approaches: the standardized pull-off procedure according to EAD 040083-00-0404 (EAD and EAD′ variants) and an in-house pull-off procedure designed to reflect practical conditions of substrate type (concrete slab, silicate block), substrate orientation (horizontal, vertical), and adhesive layer thickness (10 and 20 mm). The results showed that adhesive bond strength is strongly influenced by adhesive layer thickness, substrate type, and substrate orientation. Increasing thickness from 10 mm to 20 mm on concrete substrates typically reduced bond strength by about 65–75%, while vertical orientation lowered adhesion to about half of that obtained in horizontal placement. Silicate substrates exhibited generally lower bond strength but higher variability, occasionally with ratios above unity due to their greater porosity. In some configurations, detachment occurred already during specimen preparation, underlining the variability of performance. The combined effect of increased thickness and vertical orientation on concrete substrates reduced adhesion by about 85% compared to the 10 mm horizontal baseline, highlighting the severity of unfavorable application conditions, whereas on silicate blocks, the effect was weaker but accompanied by large variability. The findings indicate that adhesive layer thickness has a stronger impact on bond strength than orientation and that substrate properties play an important role. The study provides a comparative perspective on current and alternative testing approaches, revealing significant differences in the results. The author’s testing method makes it possible to account for, in laboratory conditions, primarily the geometric shape and orientation of samples that are close to the actual form of adhesive mortar application in real insulation installations. This allows for the assessment of the properties of mortars and substrates that were not exposed under the conditions of current testing methods. The above provides a basis for further discussion on the inclusion of realistic application conditions in the evaluation of adhesive mortars used for bonding thermal insulation in ETICS, and for the validation assessment of an additional testing method, which is currently of an experimental nature. Full article
(This article belongs to the Section Construction and Building Materials)
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32 pages, 8357 KB  
Article
Multiscale Damage and Failure Behavior of Drainage Asphalt Mixture Under Multifactor
by Xiong Tao, Tao Bai, Jianwei Fan, Haiwei Shen and Hao Cheng
Materials 2025, 18(21), 4924; https://doi.org/10.3390/ma18214924 - 28 Oct 2025
Viewed by 590
Abstract
Macroscopic fatigue tests, mesoscopic finite element simulations, and microscopic molecular dynamics simulations were composed to study the damage and failure of drainage asphalt mixtures in multiscale. The applicability of the fatigue models fit by strain, stress, and the linear fitting slope of the [...] Read more.
Macroscopic fatigue tests, mesoscopic finite element simulations, and microscopic molecular dynamics simulations were composed to study the damage and failure of drainage asphalt mixtures in multiscale. The applicability of the fatigue models fit by strain, stress, and the linear fitting slope of the indirect tensile modulus curves were compared. The mesoscopic damage and failure distribution and evolution characteristics were studied, considering the single or coupling effect of traffic loading, hydrodynamic pressure, mortar aging, and interfacial attenuation. The microscopic molecular mechanism of the interface adhesion failure between the aggregate and mortar under water-containing conditions was analyzed. Results show that the fatigue model based on the linear fitting slopes of the indirect tensile modulus curves has significant applicability for drainage asphalt mixtures with different void rates and gradations. The damage and failure have an obvious leap development when traffic loading increases from 0.7 MPa to 0.8 MPa. The hydrodynamic pressure significantly increases the stress of the mortar around the voids and close to the aggregate, promoting damage development and crack extension, especially when it is greater than 0.3 MPa. With the aging deepening of the mortar, the increase rate of the damage degree gradually decreases from the top to the bottom of the mixture. With the development of interfacial attenuation, the damage and failure of interfaces continue increasing, while that of the mortar increases first and then decreases, which is related to the loading concentration in the interface and the stress decrease in the mortar. Under the coupling effects, whether the cracks mainly generate in the mortar or interface depends on their damage degrees, thus causing the stripping of the aggregate wrapped or not wrapped by the mortar, respectively. The van del Waals force is the main molecular effect of interface adhesion, and both acidic and alkaline aggregate components significantly tend to form hydrogen bonds with water rather than asphalt, thus attenuating the interface adhesion. Full article
(This article belongs to the Section Construction and Building Materials)
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18 pages, 13010 KB  
Article
Multiscale Analysis of Styrene–Butadiene Latex Modified Rubber Concrete
by Weiming Wang, Yong Feng and Jingjie Feng
Buildings 2025, 15(21), 3881; https://doi.org/10.3390/buildings15213881 - 27 Oct 2025
Viewed by 700
Abstract
Rubberized concrete is a novel green building material that enhances many features when rubber particles are incorporated into cement mortar, simultaneously yielding economic benefits through the recycling of waste tires. This study applies styrene–butadiene latex (SBL) for toughening treatment. The investigation delves into [...] Read more.
Rubberized concrete is a novel green building material that enhances many features when rubber particles are incorporated into cement mortar, simultaneously yielding economic benefits through the recycling of waste tires. This study applies styrene–butadiene latex (SBL) for toughening treatment. The investigation delves into the mechanism by which SBL improves the interface between rubber and cement, encompassing macroscopic mechanical properties, microscopic structural characteristics, and nano-scale interfacial interactions. Macroscopic mechanical tests reveal a significant increase in flexural strength, shear strength, and compressive strength of the composite concrete upon the introduction of SBL and rubber. Specifically, the compressive strength improved by 8.8%, shear strength by 13.7%, and flexural strength by 18.9% at 28 days. Through electron microscopy observation of corresponding polymer cement concrete sections, observations reveal that SBL reinforces both interfaces and elucidates its bonding impact at the micro-level interface. Molecular dynamics (MD) modeling of SBL/rubber/CSH is employed at the nanoscale to compute and examine the local structure, dynamic behavior, and binding energy of the interface. The findings indicate that SBL mitigates interface impacts, enhances interface hydrogen bonds, van der Waals interactions, CaH coordination bonds, and stability, consequently improving interfacial adhesion and fortifying the feeble interface bonding between organic polymers (rubber) and inorganic silicates (CSH). Full article
(This article belongs to the Topic Sustainable Building Materials)
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22 pages, 3648 KB  
Article
Hybrid Mortar Composites Incorporating Oyster Shell Filler and Recycled Fibers from Disposable Masks
by René Sebastián Mora-Ortiz, Sergio Alberto Díaz Alvarado, Ebelia Del Angel-Meraz, Francisco Magaña-Hernández, Mayra Agustina Pantoja Castro and Emmanuel Munguía-Balvanera
Materials 2025, 18(21), 4854; https://doi.org/10.3390/ma18214854 - 23 Oct 2025
Viewed by 897
Abstract
This study presents the development of hybrid masonry mortars by incorporating two waste materials: recycled plastic strips from disposable face masks (FM) as mechanical reinforcement and calcined oyster shell powder (OSP) as a filler. The objective was to evaluate the combined effect of [...] Read more.
This study presents the development of hybrid masonry mortars by incorporating two waste materials: recycled plastic strips from disposable face masks (FM) as mechanical reinforcement and calcined oyster shell powder (OSP) as a filler. The objective was to evaluate the combined effect of FM and OSP on the mechanical behavior of mortars. Three types of mixes were prepared: a reference mix, a mix with 5% OSP (by cement weight), and mixes with 5% OSP reinforced with FM strips. FM strips were incorporated at three different lengths, dividing the FM-reinforced group into three subgroups (0.1%, 0.2%, 0.5%, and 0.8%). The results showed an approximately 10% increase in compressive strength with the addition of 5% OSP compared to the control mortar, as well as an improvement in bond strength of about 21%. Furthermore, an optimum content of 0.2% of 6 mm strips allowed for adequate dispersion and maintained indirect tensile strengths similar to the control + OSP. OSP acted as a reactive filler, increasing compressive strength and improving both density and adhesion. However, higher FM contents or longer strips increased porosity and water absorption, while reducing strength. This combination represents an innovative strategy for valorizing post-pandemic and marine waste. Full article
(This article belongs to the Special Issue Advances in Sustainable Construction Materials, Third Edition)
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16 pages, 4308 KB  
Article
Influence of HPMC and VAE on the Properties of Geopolymer Mortar
by Wenjun Ji, Pengfei Chen, Ying Lu, Zeyang Zhang, Baolong Shan, Sha Li, Mengyan Chi and Haifeng Yu
Buildings 2025, 15(19), 3621; https://doi.org/10.3390/buildings15193621 - 9 Oct 2025
Viewed by 818
Abstract
The delamination of building facades creates a critical demand for inorganic adhesive mortars with high long-term adhesion. Geopolymer (GP) represents an eco-friendly alternative to Portland cement (PC). However, the effect of polymer additives, commonly used in cement-based adhesive mortars, on GP mortar remains [...] Read more.
The delamination of building facades creates a critical demand for inorganic adhesive mortars with high long-term adhesion. Geopolymer (GP) represents an eco-friendly alternative to Portland cement (PC). However, the effect of polymer additives, commonly used in cement-based adhesive mortars, on GP mortar remains insufficiently studied. This study examines the effects of hydroxypropyl methylcellulose (HPMC) and vinyl acetate-ethylene (VAE) polymer on the workability, mechanical properties, durability, and microstructure of GP mortar. Results show that an optimal HPMC content (0.4 wt%) improves the fluidity, compressive strength, and adhesive strength of GP mortar, approximately 6%, 16%, and 20%, respectively. These enhancements are attributed to the incorporation of uniformly distributed microbubbles in the mortar matrix. Beyond this optimal content, however, HPMC impairs flowability and adhesion due to its thickening effect. In contrast, VAE addition significantly enhanced adhesive strength by approximately 28%, albeit at the cost of a 17% reduction in compressive strength, resulting from the retardation of the alkali activation process. This gain in adhesion is associated with the formation of a continuous polymer film that establishes both physical interlocking and chemical bonding with the GP matrix. Furthermore, HPMC improved the durability of the GP mortar, while VAE did not contribute to this aspect. These insights offer valuable guidance for designing high-performance GP-based adhesive mortars suitable for building applications. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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22 pages, 8131 KB  
Article
Study on Graphene-Reinforced Epoxy Solvent-Borne High-Temperature-Resistant Adhesives for Bonding C/C Composites Under Extreme Temperatures
by Yue Wang, Yuqing Zhang, Zhanming Hu, Jingjing Li, Zhuo Gao, Mingchao Wang and Haijun Zhang
Materials 2025, 18(17), 4213; https://doi.org/10.3390/ma18174213 - 8 Sep 2025
Cited by 2 | Viewed by 1153
Abstract
Drawing inspiration from the bionic nacre structure, graphene was incorporated into the epoxy solvent-borne adhesive to construct a laminated architecture. At the same time, ferrocene was employed as a catalyst to induce the in situ growth of carbon nanotubes (CNTs) under high-temperature conditions. [...] Read more.
Drawing inspiration from the bionic nacre structure, graphene was incorporated into the epoxy solvent-borne adhesive to construct a laminated architecture. At the same time, ferrocene was employed as a catalyst to induce the in situ growth of carbon nanotubes (CNTs) under high-temperature conditions. This modification endowed the epoxy solvent-borne adhesive with not only high strength in atmospheric environments but also the capability to retain considerable mechanical performance at elevated temperatures. Experimental results demonstrated that when the graphene content in the epoxy solution fell within the range of 3.2–4%, the bonding strength exceeded 3 MPa within the temperature range of 1000–1300 °C. In particular, the adhesive exhibited excellent thermal shock resistance, with no degradation in strength observed after 15 thermal shock cycles at 1300 °C. Such exceptional performance was attributed to the formation of interlaminar CNTs generated after high-temperature treatment. Scanning electron microscopy (SEM) observations clearly revealed the laminated graphene sheets and in situ grown CNTs, confirming the feasibility of the strategy to enhance bonding efficacy by mimicking the nacre structure. This approach represented an innovative breakthrough for further research on the application of the “brick-and-mortar” structure in the bonding layer and the in situ growth of CNTs among lamellar graphene, while also providing detailed supporting data. Full article
(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
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20 pages, 7919 KB  
Article
Application and Mechanism Study on Optimal Design of Cement-Based Building Materials Based on Polymer Binder
by Lei Yu, Qichang Fan, Dan Meng, Xue Meng and Binghua Xu
Buildings 2025, 15(17), 3192; https://doi.org/10.3390/buildings15173192 - 4 Sep 2025
Cited by 2 | Viewed by 949
Abstract
This study examines the effects of three polymer binders—polyvinyl alcohol (PVA), polyethylene glycol (PEG), and polyacrylic acid (PAA) on the mechanical properties and dry–wet cycle corrosion resistance of cement mortar at different dosages (1–4%). Mechanical testing combined with scanning electron microscopy (SEM) and [...] Read more.
This study examines the effects of three polymer binders—polyvinyl alcohol (PVA), polyethylene glycol (PEG), and polyacrylic acid (PAA) on the mechanical properties and dry–wet cycle corrosion resistance of cement mortar at different dosages (1–4%). Mechanical testing combined with scanning electron microscopy (SEM) and molecular dynamics (MD) simulations was conducted to validate the experimental findings and reveal the underlying mechanisms. Results show that polymers reduce early-age strength but improve flexural performance, and at low dosage, enhance compressive strength. PVA and PAA exhibited a pronounced improvement in mechanical strength while PVA and PEG showed a significant improvement in wet cycle corrosion resistance. SEM observations indicated that polymers encapsulate cement particles, enhancing interfacial bonding while partially inhibiting hydration. MD simulations revealed that PVA and PAA interact with Ca2+ via Ca-O coordination, while PEG primarily forms hydrogen bonds, resulting in distinct water-binding capacities (PEG > PVA > PAA). These interactions explain the enhanced mechanism of mechanical and dry–wet cycle resistance properties. This work combined experimental and molecular-level validation to clarify how polymer–matrix and polymer–water interactions govern mechanical and durability, respectively. The findings provide theoretical and practical guidance for designing advanced polymer binders with tailored interfacial adhesion and water absorption properties to improve cementitious materials. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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34 pages, 6753 KB  
Article
Factors Influencing Adhesive Bonding Efficiency in ETICS Application
by Paweł Gaciek, Mariusz Gaczek and Paweł Krause
Materials 2025, 18(17), 4043; https://doi.org/10.3390/ma18174043 - 29 Aug 2025
Cited by 2 | Viewed by 3020
Abstract
In this study, physical factors influencing the efficiency of adhesive bonding in External Thermal Insulation Composite Systems (ETICS) using the ribbon-and-dab bonding method were analyzed. Tests were carried out to show the distribution of pressure transmitted through thermal insulation to adhesive mortar and [...] Read more.
In this study, physical factors influencing the efficiency of adhesive bonding in External Thermal Insulation Composite Systems (ETICS) using the ribbon-and-dab bonding method were analyzed. Tests were carried out to show the distribution of pressure transmitted through thermal insulation to adhesive mortar and substrate during bonding, and to demonstrate the relationship between pressure, adhesive layer thickness, and bond strength of mortar to concrete substrate. The analysis was also based on in situ observations, laboratory experiments, and numerical modeling, with particular attention paid to contact pressure and adhesive strength depending on cement-based mortar layer thickness. Example pull-off tests (CAST, DAST) performed on dabs showed that increasing thickness from 10 mm to 20 mm caused a decrease in bond strength in the central area by about 86% for tested adhesive mortars and substrate—values dropped from 1.8 MPa to below 0.25 MPa, while edge zones often showed no adhesion. Pressure-mapping tests (PMAST) revealed distinct pressure zones within dabs and perimeter ribbons. The analysis showed that average normalized pressures in adhesive dabs reached about 52% of the maximum value, while the [0.9; 1.0] pressure interval covered about 12% of the contact area. Based on empirical data, a decay function was developed to build a model of radial pressure attenuation. Monte Carlo simulations defined ranges of random model parameters and variability of average pressures in a 10 mm adhesive dab. The model allowed inclusion of a peripheral zero-pressure ring and enabled simulation for a 20 mm layer, confirming that increased thickness led to reduced contact pressure and explained the decrease in bonding performance. Full article
(This article belongs to the Section Construction and Building Materials)
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