Search Results (270)

Measurement While Drilling (MWD) systems require high-precision triaxial magnetometers for real-time downhole attitude sensing, yet conventional fluxgates fail to meet the stringent size, noise, bandwidth, and temperature demands of deep reservoirs (>175 °C). To bridge this gap, we present a miniaturized triaxial fluxgate magnetometer (23 × 23 × 21 mm³) leveraging Co-Fe-Si-B amorphous wire cores—a material selected for its near-zero magnetostriction and tunable magnetic anisotropy. The sensor achieves breakthrough performance: a 300 Hz bandwidth combined with noise levels below 200 pT/√Hz at 1 Hz when operating at 175 °C while maintaining full functionality with the probe surviving temperatures exceeding 200 °C. This advancement paves the way for more accurate wellbore positioning and steering in high-temperature hydrocarbon and geothermal reservoirs. Full article

Compared with a traditional distribution transformer with silicon steel sheet as the core material, the no-load loss of an amorphous alloy transformer is greatly reduced due to its core using iron-based amorphous metal material, which has been applied in many countries. However, due to the brittleness of its amorphous strip, an amorphous alloy transformer is prone to debris in the process of production, transportation and work. The charge and migration characteristics of these debris will reduce the insulation strength of the transformer oil and endanger the safe operation of the transformer. In this paper, a charge measurement platform of amorphous alloy debris is set up, and the charging characteristics of amorphous alloy core debris under different flow velocities, particle radius and plate electric field strength are obtained. The results show that with an increase in pipeline flow velocity, the charge-to-mass ratio of the debris increases first and then decreases. With an increase in electric field strength, the charge-to-mass ratio of the debris increases; with an increase in the number of debris, the charge-to-mass ratio of the debris decreases; with an increase in debris size, the charge-to-mass ratio of the debris increases. The debris with different charge-to-mass ratios and types obtained from the above experiments are added to the simulation model of an amorphous alloy transformer. The lattice Boltzmann method (LBM) coupled with the discrete element method (DEM) is used to simulate the migration process of metal particles in an amorphous alloy transformer under the combined action of gravity, buoyancy, electric field force and oil flow resistance under electrothermal excitation boundary. The results show that the trajectory of the debris is related to the initial position, electric field strength and oil flow velocity. The LBM–DEM calculation model and charge measurement platform proposed in this paper can provide a reference for studying the charge mechanism and migration characteristics of amorphous alloy core debris in insulating oil. Full article

The microstructure of polyacrylonitrile (PAN) precursor fibers has a profound influence on the performance of carbon fibers and depends on the spinning processes and processing conditions. This study compared the evolution of the microstructures and performance of PAN fibers between the wet-spinning and dry-jet wet-spinning processes, utilizing scanning electron microscopy, small/wide-angle X-ray scattering, dynamic mechanical analysis, and single-fiber tensile testing. Both spinning processes promoted the oriented alignment of microfibrils and fibrils, improved the crystal arrangement and molecular regularity, and facilitated the transition from a two-phase (crystalline/amorphous) structure to a single-phase structure, thereby gradually improving the fibers’ elastic character and mechanical properties. However, wet-spun fibers exhibited inherent defects (skin-core structure and large voids), which caused surface grooves, radial mechanical heterogeneity, and low breaking elongation during post-spinning. In contrast, dry-jet wet-spun fibers initially had a smooth surface and a homogeneous radial structure, which evolved into well-oriented, radially homogeneous structures during post-spinning. Furthermore, the dry-jet wet-spinning process produced greater increases in crystallinity (46%), crystal size (258%), and orientation index (146%) than the wet-spinning process did. The dry-jet wet-spinning process’s superiority in forming and optimizing the fiber microstructure gives it greater potential for producing high-quality PAN precursor fibers. Full article

Waveguide-integrated electro-optical modulators play a crucial role in the design of new-generation photonic integrated circuits. The target of this paper is to demonstrate the potential offered by the association of graphene (Gr) and hydrogenated amorphous silicon (a-Si:H) in enhancing silicon photonics technology, enabling, in particular, the fabrication of efficient, wide-bandwidth, highly compact active devices. The design of the proposed electro-optic modulator is based on accurate numerical simulations where Gr is explored as the active material, absorbing (or not) the light propagating along the waveguide core, with its absorption coefficient being tunable through the application of an external electric bias. By strategically embedding two Gr monolayers where the propagating optical field is at its maximum, the performance of the modulator is maximized, resulting in a 39.5 GHz 3 dB bandwidth, corresponding to a 0.34 dB/µm modulation depth. The straightforward feasibility of the proposed structure is bolstered by the use of the Plasma-Enhanced Chemical Vapor Deposition technique, which allows for the deposition of a-Si:H on a silicon-on-insulator platform as a post-processing phase, ensuring potential scalability and practical implementation for advanced photonics. Full article

Curcumin, a bioactive polyphenol from turmeric, faces significant challenges in food and pharmaceutical applications due to its poor water solubility, low stability, and limited bioavailability. In this study, curcumin–lecithin complexes (phytosomes) were spray-dried using maltodextrin as the carrier polymer to produce free-flowing powders with improved physicochemical properties. The powders were characterized based on moisture content, particle size, morphology, curcumin loading, thermal behavior, and stability under simulated gastrointestinal and thermal conditions. The lecithin–curcumin complexes exhibited high entrapment efficiency (up to 94%), a predominantly amorphous structure, and improved thermal and digestive stability compared to free curcumin. Particle size and wettability were influenced by carrier and curcumin ratios, with maltodextrin enhancing powder flowability and apparent solubility. Morphological analyses revealed spherical particles with core–shell structures, confirming successful complexation. The complexes protected curcumin from degradation at intestinal pH and elevated temperatures, highlighting their potential for enhanced bioavailability. These findings demonstrate that spray-dried curcumin–lecithin complexes with maltodextrin carriers offer a promising strategy to overcome curcumin’s solubility and stability limitations, supporting their application in functional foods and pharmaceuticals. Full article

Hollow coaxial double-shell submicron fibers were fabricated by combining electrospinning and atomic layer deposition (ALD). Polyvinyl alcohol (PVA) fibers were electrospun to serve as templates for the subsequent atomic layer deposition (ALD) of ZnO doped with transition metals (TM: Ni, Co, and Fe). An inner shell of amorphous Al₂O₃ was first deposited at low-temperature ALD to protect the polymer template. The PVA core was then removed through high-temperature annealing in air. Finally, a top shell of TM-doped ZnO was deposited at an elevated temperature within the ALD window for ZnO. The morphology, microstructure, elemental composition, and crystallinity of these submicron hollow double-shell fibers were thoroughly investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Full article

This study aims to investigate the vibrational, structural, morphological, optical, and magnetic properties of Zn_1−xCo_xO with 0.00 ≤ x ≤ 0.05 prepared by the sol–gel method via an amorphous citrate precursor. FTIR spectroscopy was used to follow the thermal decomposition process of the ZnO precursor, identifying acetate zinc as the intermediate main component. XRD and FTIR-ATR techniques showed only the single wurtzite crystalline phase with the presence of oxygen deficiency and/or vacancies, and secondary phases were not detected. SEM micrographs showed agglomerated particles of irregular shape and size with a high distribution and evidenced particles of nanometric size with a morphology change for x = 0.05. We detected high–spin Co²⁺ ions located in the tetrahedral core and pseudo–octahedral surface sites, substituting Zn²⁺ ions. The energy band gap of the ZnO semiconductor decreased gradually when the Co doping concentration was increased. M vs. H for undoped ZnO nanoparticles exhibited a diamagnetic signal overlapped with a weak ferromagnetic signal at room temperature. Interestingly, temperature-dependent magnetization showed superparamagnetic behavior with a blocked state in the low temperature range. The Co–doped ZnO samples evidenced a weak ferromagnetic signal and a paramagnetic component, which increased with x. The saturation magnetization increased until x = 0.03 and then decreased for x = 0.05, while the coercive field gradually decreased. Full article

Amorphous boron powder, as a high-energy fuel, is widely used in the energy sector. However, its ignition and combustion difficulties have long limited its performance in propellants, explosives, and pyrotechnics. In this study, Mg/Al-coated boron powder with enhanced combustion properties was synthesized using the electrical explosion method. To investigate the effect of Mg/Al coating on the ignition and combustion behavior of boron powder, four samples with different Mg/Al coating contents (4 wt.%, 6 wt.%, 8 wt.%, and 10 wt.%) were prepared. Compared with raw B95 boron powder, the coated powders showed a significant reduction in particle size (from 2.9 μm to 0.2–0.3 μm) and a marked increase in specific surface area (from 10.37 m²/g to over 20 m²/g). The Mg/Al coating formed a uniform layer on the boron surface, which reduced the ignition delay time from 143 ms to 40–50 ms and significantly improved the combustion rate, combustion pressure, and combustion calorific value. These results demonstrate that Mg/Al coating effectively promotes rapid ignition and sustained combustion of boron particles. Furthermore, with the increasing Mg/Al content, the ignition delay time decreased progressively, while the combustion rate, combustion pressure, and heat release increased accordingly, reaching optimal values at 8 wt.% Mg/Al. An analysis of the combustion residues revealed that both Mg and Al reacted with boron oxide to form new multicomponent compounds, which reduced the barrier effect of the oxide layer on oxygen diffusion into the boron core, thereby facilitating continuous combustion and high heat release. This work innovatively employs the electrical explosion method to prepare dual-metal-coated boron powders and, for the first time, reveals the synergistic promotion effect of Mg and Al coatings on the ignition and combustion performance of boron. The results provide both experimental data and theoretical support for the high-energy release and practical application of boron-based fuels. Full article

It is of the utmost importance to accurately solve the transformer temperature field, as it governs the overall performance and operational stability of the transformer. However, the intricate structure of high- and low-voltage windings, insulating materials, and other components presents numerous challenges for modeling. Temperature exerts a significant influence on insulation aging, and elevated temperatures can notably accelerate the degradation process of insulation materials, reducing their service life and increasing the risk of electrical failures. In view of this, this paper proposes an equivalent modeling method of the temperature field of the transformer HLV winding and studies the refined modeling of the winding part. First of all, in order to reduce the difficulty of temperature field modeling, based on the principle of constant thermal resistance, the fine high- and low-voltage windings are equivalent to large conductors, and the equivalent thermal conductivity coefficient of the high- and low-voltage windings is obtained, which improves the calculation accuracy and shortens the calculation time. Secondly, we verify the feasibility of the equivalent model before and after the simulation, analyze the influence of different boundary conditions on the winding temperature field distribution, and predict the local hotspot location and temperature trend. Finally, a 50 kVA amorphous alloy winding-core transformer is tested on different prototypes to verify the effectiveness of the proposed method. Full article

Delivering of hydrophobic drugs by polymeric nanoparticles is an intensively investigated research and development field worldwide due to the insufficient solubility of many existing and potential new drugs in aqueous media. Among polymeric nanoparticles, micelles of biocompatible amphiphilic block copolymers are among the most promising candidates for solubilization, encapsulation, and delivery of hydrophobic drugs to improve the water solubility and thus the bioavailability of such drugs. In this study, amphiphilic ABA triblock copolymers containing biocompatible hydrophilic hyperbranched (dendritic) polyglycerol (HbPG) outer and hydrophobic poly(tetrahydrofuran) (PTHF) inner segments were synthesized using amine-telechelic PTHF as a macroinitiator for glycidol polymerization. These hyperbranched–linear–hyperbranched block copolymers form nanosized micelles with 15–20 nm diameter above the critical micelle concentration. Coagulation experiments proved high colloidal stability of the aqueous micellar solutions of these block copolymers against temperature changes. The applicability of block copolymers as drug delivery systems was investigated using curcumin, a highly hydrophobic, water-insoluble, natural anti-cancer agent. High and efficient drug solubilization up to more than 3 orders of magnitude to that of the water solubility of curcumin (>1500-fold) is achieved with the HbPG-PTHF-HbPG block copolymer nanomicelles, locating the drug in amorphous form in the inner PTHF core. Outstanding stability of and sustained curcumin release from the drug-loaded block copolymer micelles were observed. The in vitro bioactivity of the curcumin-loaded nanomicelles was investigated on U-87 glioblastoma cell line, and an optimal triblock copolymer composition was found, which showed highly effective cellular uptake and no toxicity. These findings indicate that the HbPG-PTHF-HbPG triblock copolymers are promising candidates for advanced drug solubilization and delivery systems. Full article

The harmonic content of transformers used in the field of new energy is significantly higher than that of conventional transformers, leading to an abnormal increase in transformer loss during operation. Therefore, the loss characteristics of amorphous alloy transformers are investigated in this paper. First, a measurement platform for the magnetic property of transformer cores under sinusoidal excitation is developed. The magnetization characteristics, loss characteristics and loss composition of the amorphous alloy core under sinusoidal excitation are measured and analyzed. On this basis, the traditional Steinmetz loss calculation formula is modified, and the loss calculation formula is further refined by improving its coefficients to accommodate various frequencies. Secondly, using a field-circuit coupling method, a 3D model of the transformer core is established by finite element simulation. The magnetic flux distribution and core losses are computed under both sinusoidal excitation and non-sinusoidal excitation. Finally, the impact of core rotation magnetization on the magnetic flux density is considered, and experimental errors are minimized by applying an empirical formula. The numerical model validity and accuracy are verified by comparing the simulation results with experimental data. Full article

Iron core loss (P_cm) is the main source of energy dissipation in motors, primarily affected by the stator material, which necessitates the optimization of soft-magnetic materials. In this work, the magnetic characteristics of FeSiB amorphous alloys and their influence on motors were systematically investigated via both experiment and finite-element simulation. It was found that the P_cm of the FeSiB core initially decreased significantly during heating but subsequently increased with a further temperature rise. In particular, after annealing at 460 °C for 10 min, the FeSiB core exhibited the lowest P_cm of 0.11 W/kg (50 Hz, 1 T) and 5.45 W/kg (1 kHz, 1 T), which correlated well with the changes in the magnetization. With the help of the finite-element analysis, the low P_cm of the motor using the FeSiB core was further demonstrated, and was closely associated with the dominance of the stator loss. Additionally, the magnetic flux density cloud and the related electromagnetic torque of the motor were comparatively analyzed to unveil the potential advantages of the current FeSiB core. This work provides an important theoretical basis for the design and development of amorphous/nanocrystalline motors. Full article

Crystalline–amorphous core–shell-like heterostructures have attracted considerable attention in electrocatalysis due to their unique electronic and structural properties; however, tuning the surface composition of the amorphous shell remains a major challenge. In this work, we report a simple, low-cost, one-pot hydrazine-assisted chemical deposition method for synthesizing a series of Co-doped Ni@Ni(OH)₂ catalysts with a crystalline Ni core and an amorphous Ni(OH)₂ shell. Among the prepared catalysts, the sample containing 10 wt.% cobalt (denoted as b-Co-doped Ni@Ni(OH)₂) exhibited the highest electrocatalytic activity toward both the oxygen evolution reaction (OER) and the urea oxidation reaction (UOR). In 1.0 M KOH, the b-Co-doped Ni@Ni(OH)₂ catalyst achieved a 40 mV lower overpotential at 50 mA·cm⁻² compared to undoped Ni@Ni(OH)₂ for the OER. For the UOR in 0.33 M urea/1.0 M KOH, it delivered approximately twice the anodic current density relative to the undoped sample, along with improved reaction kinetics as evidenced by a Tafel slope of 70.7 mV·dec⁻¹. This performance enhancement is attributed to the optimized core–shell-like architecture, cobalt doping-induced electronic modulation, increased electrochemically active surface area, and improved charge transfer efficiency. Overall, this study demonstrates a promising and scalable strategy for designing advanced Ni-based bifunctional catalysts for sustainable energy conversion and wastewater treatment applications. Full article

The ongoing electrification process also requires improvements in the efficiency of power transmission devices, such as transformers, the main part of which is the magnetic core. Despite great progress in the development of core material, losses and audible noise during their operation is still a critical issue to be solved. Currently, a magnetic material used to produce the transformer core is amorphous steel, which is gaining popularity. Compared to traditionally used grain-oriented silicon electrical steel, a significantly larger number of very thin amorphous ribbons is needed to produce the core, which is due to the fact that they are about an order of magnitude thinner, making mechanical stability a challenge. The presented article describes the preparation of a hybrid binder for amorphous steel based on the two types of silanes, tetraethyl orthosilicate and 1,2-bis(triethoxysilyl)ethane, for which their anticorrosive character and good dielectric properties were confirmed. Using the obtained binders, model toroidal cores were produced and their magnetic and acoustic properties were tested. The obtained results indicate that the applied silane-based hybrid binders improved important functional properties by reducing the magnetic no-load losses and audible noise. Full article

With the global shift in energy structure and the advancement of the “double carbon” strategy, methanol has gained attention as a clean low-carbon fuel in the engine sector. However, the corrosion–wear coupling failure caused by acidic byproducts, such as methanoic acid and formaldehyde, generated during combustion severely limits the durability of methanol engines. In this study, we employed a systematic approach combining the construction of a corrosion liquid concentration gradient experiment with a full-load and full-speed bench test to elucidate the synergistic corrosion–wear mechanism of core friction pairs (cylinder liner, piston, and piston ring) in methanol-fueled engines. The experiment employed corrosion-resistant gray cast iron (CRGCI), high chromium cast iron (HCCI), and nodular cast iron (NCI) cylinder liners, along with F38MnVS steel and ZL109 aluminum alloy pistons. Piston rings with DLC, PVD, and CKS coatings were also tested. Corrosion kinetic analysis was conducted in a formaldehyde/methanoic acid gradient corrosion solution, with a concentration range of 0.5–2.5% for formaldehyde and 0.01–0.10% for methanoic acid, simulating the combustion products of methanol. The results showed that the corrosion depth of CRGCI was the lowest in low-concentration corrosion solutions, measuring 0.042 and 0.055 μm. The presence of microalloyed Cr/Sn/Cu within its pearlite matrix, along with the directional distribution of flake graphite, effectively inhibited the micro-cell effect. In high-concentration corrosion solutions (#3), HCCI reduced the corrosion depth by 60.7%, resulting in a measurement of 0.232 μm, attributed to the dynamic reconstruction of the Cr₂O₃-Fe₂O₃ composite passive film. Conversely, galvanic action between spherical graphite and the surrounding matrix caused significant corrosion in NCI, with a depth reaching 1.241 μm. The DLC piston coating obstructed the permeation pathway of formate ions due to its amorphous carbon structure. In corrosion solution #3, the recorded weight loss was 0.982 mg, which accounted for only 11.7% of the weight loss observed with the CKS piston coating. Following a 1500 h bench test, the combination of the HCCI cylinder liner and DLC-coated piston ring significantly reduced the wear depth. The average wear amounts at the top and bottom dead centers were 5.537 and 1.337 μm, respectively, representing a reduction of 67.7% compared with CRGCI, where the wear amounts were 17.152 and 4.244 μm. This research confirmed that the HCCI ferrite–Cr carbide matrix eliminated electrochemical heterogeneity, while the DLC piston coating inhibited abrasive wear. Together, these components reduced the wear amount at the top dead center on the push side by 80.1%. Furthermore, mismatches between the thermal expansion coefficients of the F38MnVS steel piston (12–14 × 10⁻⁶/°C) and gray cast iron (11 × 10⁻⁶/°C) resulted in a tolerance exceeding 0.105 mm in the cylinder fitting gap after 3500 h of testing. Notably, the combination of a HCCI matrix and DLC coating successfully maintained the gap within the required range of 50–95 μm. Full article