Search Results (2,701)

Accurate measurement of low-level radon concentrations in the environment is increasingly important for climate research, radon priority area delineation, and atmospheric studies. Adsorbent-based radon detectors offer high sensitivity but suffer from strong temperature dependence of radon adsorption and rapid degradation under humid conditions, limiting their applicability in long-term environmental monitoring. This work presents a universal design methodology for temperature- and moisture-compensated radon detectors based on hermetically packaged adsorbents enclosed by radon-permeable polymer foils. Analytical models describing the opposing temperature dependences of radon adsorption in adsorbents and radon permeability in polymers are combined to derive a general optimization criterion that minimizes temperature-induced response variations over a defined temperature range. The method is applicable to arbitrary combinations of adsorbent materials and polymer foils, provided their radon adsorption and permeability characteristics are known. The approach is demonstrated using activated carbon fabrics and common polymers (LDPE, HDPE, and polypropylene), for which optimal design parameters are identified. In addition, water vapor permeation through polymer foils is modeled to estimate moisture protection and permissible exposure durations under high humidity. The results demonstrate that appropriately designed compensation modules can significantly reduce temperature sensitivity while extending operational stability in humid environments, enabling next-generation high-sensitivity radon detectors suitable for environmental applications. Full article

This study investigates the formation mechanism of lactic-acid-derived coatings produced by open-air atmospheric-pressure plasma polymerization. A comparison of nebulization and bubbling precursor-delivery methods using FT-IR and XPS showed that the bubbling method facilitated plasma-assisted chemical bonding, including the possible formation of copper(II) lactate-like interfacial species and the retention of carbonyl-containing functional groups. However, the present dataset does not provide direct, discriminating evidence for a specific metal-lactate interfacial species, and alternative interpretations such as adsorption, oxidation, hydroxylation, or generic oxygenated carbon deposition cannot be excluded. Time-dependent analysis revealed a transition from oxygen-rich functional layers at short plasma exposure to carbon-rich overlayers at longer exposure, suggesting a fragmentation-recombination mechanism that is consistent with the formation of a metal-lactate-like interfacial region and a carbon-rich overlayer, while alternative interpretations related to signal attenuation and non-uniform coverage remain possible. Antibacterial testing revealed that the observed bacterial responses were not attributable to an intrinsic antibacterial property of the deposited films, but were instead strongly dependent on the underlying substrate chemistry and exposure time. C1100 retained the inherent antibacterial activity of copper, SUS430 showed no activity due to the absence of film formation, and SPCC exhibited only a transient effect attributed to lactic-acid-induced local acidification. Overall, the study elucidates the plasma-assisted deposition mechanism of lactic-acid-derived coatings under open-air conditions and highlights the critical role of interface chemistry in achieving stable and substrate-independent functional properties. Full article

6PPD-Quinone (6PPD-Q) is a tire derivative formed by the oxidation of N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine (6PPD), a commonly used antioxidant and ozone stabilizer in rubber products, and has emerged as a significant environmental concern in recent years. It is widely present in the atmosphere, surface lakes, and soil. The primary routes of exposure to 6PPD-Q are the digestive tract and respiratory tract. Studies indicate that it is a major factor causing acute mortality in coastal coho salmon (Oncorhynchus kisutch). Reports indicate that 6PPD-Q exhibits greater chemical stability and stronger biological toxicity than 6PPD, demonstrating toxic effects across multiple species. 6PPD-Q has been detected in human urine samples, indicating a need for heightened attention to its potential health risks. 6PPD-Q exhibits multi-organ toxicity in organisms, including intestinal, hepatic, neurotoxic, and reproductive toxicity. Its potential toxic mechanisms are associated with oxidative stress and inflammatory responses, and it can disrupt amino acid metabolism, carbohydrate metabolism, and lipid metabolism while interfering with signal transduction pathways by binding to specific receptors. This paper reviews the environmental contamination of 6PPD-Q, explores its potential toxic effects on organisms and underlying mechanisms, analyzes gaps in the current research and future trends, and contributes to a better understanding of its environmental occurrence and biological hazards. Full article

Soil CO₂ emissions are critical for predicting terrestrial ecosystem feedbacks to climate change, yet significant knowledge gaps persist regarding carbon flux dynamics within the deep vadose zone and during freeze–thaw processes. In this study, the Mu Us Sandy Land, a representative seasonally frozen and semi-arid region in Northwestern China, was selected as the research site. Based on in situ observation data and the XGBoost algorithm, the spatiotemporal variations of soil carbon flux and its environmental drivers were investigated. Results revealed distinct depth-dependent patterns, where carbon release reached its maximum flux in the 100–200 cm layer and carbon sequestration dominated the soil layers below 200 cm. Soil temperature and moisture were the primary controlling factors, but their impacts exhibited significant depth and seasonal heterogeneity. Notably, in the 20–50 cm soil layer, soil water content provided the highest explanatory power, reaching 55.3% and 47.8% in winter and summer, respectively. Furthermore, carbon fluxes exhibited distinct response thresholds to environmental factors, and their spatiotemporal variations were fundamentally regulated by an atmosphere-driven coupled water–vapor–heat–carbon process. These findings elucidate the complex relationship between soil carbon fluxes and the environment at different depths, providing theoretical support for deepening the understanding of regional carbon cycling. Full article

Spring and autumn phenology jointly regulate terrestrial carbon, water, and energy exchanges, yet the mechanisms linking seasonal transitions remain debated under increasing hydroclimatic stress. Here, we integrate satellite-derived phenology with reanalysis-based indicators of land–atmosphere coupling to examine how spring onset interacts with growing season controlling factors and how these interactions shape autumn senescence at the global scale. Globally, start-of-season (SOS) and end-of-season (EOS) timings are positively coupled, with later SOS generally followed by later EOS, and this relationship becomes stronger when only later-SOS years are considered. However, SOS does not induce coherent global shifts in growing season climate limitation. Piecewise structural equation modeling reveals that SOS influences EOS primarily through a direct phenological pathway, with a mean path coefficient of ~0.4 day·day⁻¹ explaining approximately 26% of global EOS variability. In contrast, energy and water-mediated pathways contribute smaller but spatially heterogeneous effects, together accounting for ~5% of explained variance on average. SOS–EOS coupling is strongest in water-limited regimes, particularly in grasslands and shrublands. Managed croplands exhibit distinct and more heterogeneous responses, reflecting partial decoupling of phenology from natural hydroclimatic constraints. Collectively, our results indicate that spring phenology exerts a robust but spatially variable influence on autumn timing, dominated by direct effects rather than indirect mediation through growing season climate limitations, with regional modulation imposed by background hydroclimatic conditions. Full article

Large-scale photovoltaic (PV) deployment in arid deserts may alter land–atmosphere interactions and influence groundwater systems, yet such impacts remain poorly quantified due to limited high-resolution observations. To overcome the coarse spatial resolution of GRACE data, this study develops a CNN-LSTM-Attention deep learning framework to downscale terrestrial water storage anomalies (TWSA) from 0.25° × 0.25° to 0.1° × 0.1° over the Huadian PV base in the Tengger Desert, China, during 2004–2024. Groundwater storage anomalies (GWSA) were derived using a water-balance approach, and piecewise linear regression was applied to detect trend shifts associated with PV development. Results show a persistent decline in TWSA and GWSA before 2022, followed by short-term recovery signals afterward. Groundwater responses exhibit greater magnitude and delayed behavior relative to soil moisture. Spatial analysis reveals stronger variability and more frequent deficits in the western subregion, indicating intra-base heterogeneity. A seasonal phase analysis identifies an approximately six-month lag between soil moisture and groundwater, highlighting constraints from deep vadose-zone processes. The findings suggest that groundwater dynamics reflect the combined effects of climate variability, infiltration lag, and PV-related land surface modification rather than a single driver. This study demonstrates the potential of deep-learning-based GRACE downscaling for groundwater monitoring in human-modified arid regions and provides insights for sustainable water management under renewable energy development. Full article

Lago Argentino and Lago Viedma are large lakes fed by glaciers in Southern Patagonia, characterized by extraordinarily strong, persistent westerly winds and sharp gradients in regional relief, climate, and gravity field. We present operational models of spatio-temporal lake-level variations that represent instantaneous ellipsoidal lake-surface height as the superposition of three components: (i) a time-averaged lake-level topography derived from geoid modeling and ICESat-2 residuals, (ii) temporally varying water-volume changes in the lake estimated from tide gauge time series corrected for atmospherically driven perturbations, and (iii) a static hydrodynamic response to wind stress and air-pressure forcing. The atmospheric response is parametrized through empirically derived transfer functions obtained by regressing instantaneous lake-level anomalies against ERA5 wind and pressure fields, capturing wind-driven tilting. Standard deviations of ICESat-2 ATL13 elevations amount to 106 cm and 70 cm over Lago Argentino and Lago Viedma, respectively. The subtraction of our models reduces these standard deviations to 8 cm (Argentino) and 14 cm (Viedma). Surface waves incompletely averaged out within ICESat-2’s narrow footprint are identified as a principal source for the residual variability. A standard deviation of ATL13 elevations below 2 cm on calm days demonstrates ICESat-2’s unprecedented capability of monitoring water resources from space in a region of sparse hydrological infrastructure. Full article

In situ hydrogen generation can extend in situ combustion (ISC) by converting part of the heavy oil in place into H₂-containing gas while allowing part of the carbonaceous products to remain in the reservoir. To clarify how operating conditions affect hydrogen behavior, this study recalibrated key Arrhenius parameters in a pseudo-component kinetic network through least-squares-guided manual history matching against high-temperature/high-pressure (HTHP) reactor data obtained under three gas atmospheres (air, N₂, and CO₂). Model performance was evaluated through a direct comparison between raw simulator predictions and measured gas compositions using parity plots with a 1:1 reference line and residual-based statistics calculated from the simulated values rather than from regression-fitted values. The calibrated model was then used to compare hydrogen responses over 150–425 °C, 4–8 MPa, and 0.25–10 days. Within the tested range, three temperature regimes were identified: initiation (150–250 °C), pyrolysis-controlled (250–325 °C), and high-yield (325–425 °C). Oxygen and CO₂ generally reduced net hydrogen accumulation through competing pathways, whereas an inert N₂ background produced the highest H₂ fraction, reaching 28.6 vol% at 425 °C and 6 MPa after 10 days. These results provide a reactor-scale basis for selecting favorable operating windows and for subsequent reservoir-scale evaluation of in situ hydrogen generation under ISC conditions. Full article

(1) Research Highlights: This study provides the first integrated assessment of Scots pine (Pinus sylvestris L.) growing in the urban forests of Karaganda, Kazakhstan, a city consistently ranked among the most air-polluted cities globally. We examined the adaptive phyto-chemical response of needles to extreme technogenic stress and evaluated their dual potential as biological filters and renewable sources of bioactive compounds. (2) Background and Objectives: Urban forests are critical for mitigating air pollution; however, the biochemical responses of trees in heavily industrialized environments remain poorly understood. Karaganda faces severe atmospheric pollution from mining, metallurgy, and energy sectors, with particulate matter (PM) levels exceeding permissible limits by up to 20-fold. This study aimed to evaluate the state of Pinus sylvestris, a key component of local protective plantations, by studying heavy metal accumulation, anatomical localization of secondary metabolites, and the phytochemical profile and biological activity of needle extracts obtained using different extraction techniques. (3) Materials and Methods: Needles were collected from 15 trees across three sites in Karaganda’s industrial green zones. Heavy metal content (Pb, Cd, As, and Hg) was determined using atomic absorption spectroscopy and voltammetry. Anatomical–histochemical analysis localizes major metabolite classes. Liquid extracts were prepared using four methods, percolation (PER), vortex-assisted (VAE), microwave-assisted (MAE), and ultrasound-assisted (UAE) extraction, and analyzed by GC-MS. Antimicrobial activity was tested against S. aureus, B. subtilis, E. coli, and C. albicans using the disk diffusion method. The antioxidant capacity (water- and fat-soluble) was measured amperometrically. Statistical analysis was performed using one-way ANOVA with Tukey’s HSD test (p < 0.05). Results: Despite extreme ambient pollution, heavy metal concentrations remained below pharmacopoeial limits (Pb < 0.1, Cd < 0.05, As < 0.01, Hg < 0.001 mg/kg), indicating effective biofiltration without toxic accumulation. Histochemistry confirmed the active synthesis of protective phenolics, flavonoids, and essential oils in the mesophyll, epidermis, and schizogenic cavities. GC-MS identified 72 compounds in the PER extract, 70 (the VAE), 72 in (MAE), and 46 in (UAE). The PER extract exhibited the highest relative abundance of bioactive terpenoids: α-cadinol (5.24%), α-muurolene (4.32%), and caryo-phyllene (2.20%). UAE extracts exhibited elevated 5-hydroxymethylfurfural (6.90%), indicating degradation. Antimicrobial testing revealed that PER produced the largest inhibition zone against S. aureus (15.0 ± 1.0 mm), significantly exceeding that of the other methods (p < 0.001). PER extract also demonstrated the highest water-soluble antioxidant capacity (3600 ± 0.40 mg quercetin equiv./dm³) and substantial fat-soluble activity (1633 ± 0.23 mg gallic acid equiv./dm³). (4) Conclusions: Pinus sylvestris in Karaganda exhibits remarkable adaptive resilience, maintaining safe heavy metal levels while accumulating a rich repertoire of stress-induced secondary metabolites. Classical percolation optimally preserves this native phytocomplex, yielding extracts with superior antimicrobial and antioxidant properties. These findings support a dual-use model wherein urban pine plantations simultaneously serve as living biofilters and renewable sources of standardized bioactive extracts, a concept with direct implications for circular bioeconomy strategies in industrial regions worldwide. This supports the strategic importance of coniferous plantations for bioremediation and sustainable resource use in industrial regions. Full article

The transition from passive containment to active, responsive management is defining the next generation of intelligent packaging. This evolution creates a critical demand for materials that can be precisely engineered to monitor, regulate, and protect. Hydrogen-bonded organic frameworks (HOFs) have emerged as a uniquely versatile platform in this regard, owing to their synthetically tunable porosity, inherent biocompatibility, and exceptional solution processability derived from reversible supramolecular assembly. This review moves beyond cataloging applications to dissect the fundamental mechanisms by which HOFs enable smart packaging functions, including the following: (i) selective gas capture and atmosphere tailoring via molecular recognition within designed pores; (ii) high-sensitivity optical and electrochemical sensing for real-time quality and safety signaling; and (iii) stimuli-responsive release of active agents (e.g., antimicrobials). We further explore the frontier of integrating HOFs as functional fillers or coatings within polymeric matrices, a key step toward practical devices. Despite challenges such as structural stability and maintaining permanent porosity due to relatively weak hydrogen bonds, this work aims to provide a design blueprint for advancing HOFs from laboratory curiosities to core components of sustainable, multifunctional packaging systems. Full article

To address global carbon reduction demands, oxy-fuel combustion in circulating fluidized beds (oxy-CFB) has emerged as a highly promising carbon capture technology, offering extensive fuel flexibility and facilitating bioenergy with carbon capture and storage (BECCS). However, its commercialization is hindered by significant energy penalties and complex scale-up challenges. This review comprehensively analyzes the fundamental multiphase mechanisms, heat transfer behaviors, and multi-pollutant emission characteristics of oxy-CFB systems, drawing upon multiscale modeling advancements and operational data from pilot to 30 MW_th industrial demonstrations. Replacing air with an O₂/CO₂/H₂O mixture fundamentally alters gas–solid hydrodynamics and char conversion pathways, necessitating active fluidization state re-specification. Despite shifting optimal desulfurization temperatures and introducing recarbonation risks, the technology demonstrates inherent advantages in synergistic pollutant control, including the complete elimination of thermal NO_x. While atmospheric oxy-CFB is technically viable, transitioning to pressurized operation is critical to minimizing system efficiency penalties. Furthermore, integrating oxygen carrier-aided combustion (OCAC) and developing advanced predictive control strategies are essential to managing multi-module thermal inertia and enabling rapid dynamic responsiveness for modern power grids. Full article

Global agricultural drought is evolving into a compound crisis threatening food security and ecological stability that is characterized by increased frequency, intensity, duration, and spatial extent. Since 2000, the global number of drought events has increased by 29% compared with the previous two decades, and 82% of drought-related losses in developing countries are concentrated in agriculture. The UNCCD (2022) projects that drought may affect up to three quarters of the world’s population by 2050. Climate change and human activities jointly drive this escalation through higher atmospheric evaporative demand, altered precipitation regimes, land use change, groundwater overexploitation, and pollution emissions. Their interaction forms amplifying feedback loops across ecology-agriculture and climate–agriculture systems, resulting in ecosystem degradation, crop yield loss, and rising socioeconomic inequality. Addressing this crisis requires a three-dimensional framework integrating mitigation, adaptation, and collaborative governance. This review synthesizes coupled driving mechanisms, cross-system impacts, and response pathways, and it also highlights priorities in compound-drought attribution, region-specific technology scaling, cross-scale governance, and resilience building in vulnerable regions. Full article

Wintertime extratropical cyclones frequently traverse the Kuroshio–Oyashio Extension frontal system. However, their net impacts on synoptic sea-surface temperature (SST) variability and mixed-layer structure remain uncertain in the presence of strong fronts and intrinsic ocean variability. Using reanalysis data, we classify extreme events into cyclone cold-sector and warm-sector types based on synoptic air–sea flux anomalies. With ensembles of single-column model experiments, we decompose the upper-ocean response into surface heat-flux forcing, wind-driven mechanical mixing, Ekman temperature advection, wave-breaking mixing, and freshwater effects. Cold-sector events amplify synoptic SST variability and deepen the mixed layer, whereas warm-sector events suppress SST variability and shoal the mixed layer. Surface heat flux is the primary driver of both responses. Ekman advection provides crucial modulation within the frontal zone. Wave-breaking mixing generally damps temperature perturbations. Freshwater forcing exerts a pronounced regional influence southeast of the subarctic front. The combined effects yield an asymmetric spatial fingerprint on SST variability and mixed-layer depth across the frontal system. Comparison between forced variability and total reanalysis variability indicates that within the frontal zone, atmospheric impacts can be redistributed or partly offset by intrinsic ocean processes, while outside the frontal zone, the behavior is closer to an externally forced response. Full article

In this work, we present a novel online acoustic sulfur hexafluoride (SF₆) monitoring system utilizing a miniaturized lithium niobate tuning fork (LNTF) sensor. The proposed system demonstrates enhanced stability and a broadband vibration–frequency response. The LNTF exhibits a fundamental resonance frequency of 32,901 Hz, and its quality factor (Q-factor) decreases from 19,700 to 18,300 as the SF₆ concentration increases at atmospheric pressure. Verification experiments at room temperature reveal a quantifiable correlation between the SF₆/N₂ mixture concentration ratio and the sensor’s mechanical impedance. Specifically, an impedance shift of 100 Ω corresponds to a concentration change of 0.0145 g/L. In air, with a signal integration time of 80 s, the measured noise voltage and current are 0.13 µV and 0.18 pA, respectively. These results underscore the potential of the LNTF as a compact, high-stability sensing platform for greenhouse gas monitoring in electrical infrastructure and industrial environments. Full article

Benzothiophene polymers, as a class of novel organic semiconductor materials, exhibit significant potential in the field of photocatalysis due to their broad light-responsive range and tunable energy level structures. In this study, a benzothiophene-based polymer organic semiconductor (denoted as P42) was integrated with titanium dioxide (TiO₂) via a simple sol–gel method, yielding an organic–inorganic hybrid material. This composite facilitates the modulation of energy level potentials and promotes the effective separation of photogenerated charges, thereby demonstrating remarkable synergistic catalytic performance in the photocatalytic oxidative coupling of benzylamines. By optimizing the ratio of organic to inorganic components and various photocatalytic reaction conditions, the hybrid material 1.7%P42-TiO₂, containing 1.7 wt% of the dithiophene polymer without any metal cocatalysts, exhibited outstanding performance under an air atmosphere and visible light irradiation after 12 h. It achieved a yield of over 88.7% and a selectivity exceeding 89.8% in the synthesis of N-benzoylaniline, significantly surpassing the performance of pure TiO₂ (52.9% yield, 54.9% selectivity) and P42 (54.4% yield, 54.9% selectivity). Structural and photophysical characterizations, including UV–Vis DRS, XRD, SEM, TEM, and EPR, reveal that the enhanced photocatalytic activity originates from broad visible-light absorption, improved charge separation, and well-matched energy levels. Mechanistic investigations suggest a synergistic pathway involving photoinduced hole oxidation and radical-mediated coupling. This work provides valuable insights and a reference for the solar-driven photocatalytic synthesis of nitrogen-containing platform molecules under mild conditions. Full article