Search Results (92)

Atmospheric water harvesting, as an emerging water collection technology, is expected to mitigate water resource crises. Adsorption-based atmospheric water harvesting technology offers distinct advantages, including geographical independence and reduced reliance on ambient humidity levels. Herein, a thermoresponsive gel (PNIPAM/TO-CNF) integrated with lithium chloride was constructed to achieve accelerated moisture sorption and rapid desorption capabilities. In the designated PNIPAM/TO-CNF/LiCl gel, PNIPAM provided a temperature-responsive hydrophilic–hydrophobic transition network; the hydrophilicity and structural strength were enhanced by TO-CNF, the moisture absorption capacity was dramatically elevated by hygroscopic salt LiCl, and pore-forming agent polyethylene glycol created a favorable porous structure. This synergistic design endows the gel with an optimized hydrophilic network, temperature-responsive behavior, and a porous architecture conducive to water vapor transportation, thereby achieving rapid moisture absorption and desorption. Under 60% relative humidity, the gel exhibited a water vapor adsorption capacity of 144% within 1 h, reaching its maximum absorption capacity of 178% after 140 min. The gel exhibited an even more superior desorption performance: when heated to 70 °C, its moisture content rapidly decreased to 16% of its initial weight within 1 h, corresponding to the desorption of 91% of the total absorbed water. A simplified pore-forming methodology that enables the integration of temperature-responsive properties with efficient moisture transfer channels was reported in this paper, providing a viable design pathway for achieving accelerated adsorption–desorption cycles in atmospheric water harvesting. Full article

We evaluated the impact of environmental variability on lobster Panulirus argus and Panulirus laevicauda resources in the waters off Brazil and southern Cuba. This study also covered aspects of larval recruitment associated with the availability of fishing resources in the Southern and Northern Hemispheres. Satellite-generated environmental data were sampled from 18 stations, 6 of which were in the sea off southern Cuba, 6 of which were in the coastal region of Brazil, and 6 of which were offshore near Brazil, covering important lobster fishing grounds and phyllosoma-rich areas of ocean surface circulation along the offshore boundary. The Southern Oscillation Index (SOI) was used to quantify the global ocean–atmosphere variability. Other environmental parameters included in the analysis were the monthly coastal sea levels, surface temperature (SST), salinity, wind/current speed, chlorophyll-a (Chl-a) concentrations, rainfall (RF), and Amazon River discharge (ARD). Variations in the level of puerulus settlement, juveniles, and population harvest in the coastal region of Brazil and Cuba were used to better understand the impact of environmental variability on organisms in their larval stages and their subsequent recruitment to fisheries. The surface temperature, chlorophyll-a concentration, and wind/current patterns were significantly associated with the variability in puerulus settlement. Larger-scale processes (as proxied by the SOI) affected RF, ARD, and sea levels, which reached a maximum during La Niña. As for Brazil, the full-year landings prediction model included Chl-a concentration, SST, RF, and ARD and their association with lobster landings (LLs). The landing predictions for Cuba were based on fluctuations in the Chl-a concentration and SST. Full article

The global scarcity of freshwater, driven by population growth and the unequal distribution of water resources, has intensified the need for alternative water supply technologies. Among the most promising solutions, adsorption-based atmospheric water harvesting (AWH) systems offer the ability to extract water vapor directly from ambient air, even under low-humidity conditions. This review presents a comprehensive overview of the thermodynamic principles and material characteristics governing these systems, with particular emphasis on adsorption isotherms and their role in predicting and optimizing system performance. A generalized theoretical framework is proposed to assess the energy efficiency of thermally driven AWH devices, based on key material parameters. Recent developments in sorbent materials, especially metal–organic frameworks (MOFs) and advanced zeolites, are examined for their high-water uptake, regeneration efficiency, and potential for operation under real climatic conditions. The Dubinin–Astakhov and modified Langmuir isotherm models are reviewed for their effectiveness in describing nonlinear sorption behaviors critical to performance modeling. In addition, component-level design strategies for adsorption-based AWH systems are discussed. The integration of solar energy is also discussed, highlighting recent prototypes and design strategies that have achieved water yields ranging from 0.1 to 2.5 L m⁻²/day and specific productivities up to 2.8 L kg⁻¹ using MOF-801 at 20% RH. Despite notable progress, challenges remain, including limited productivity in non-optimized setups, thermal losses, long-term material stability, and scalability. This review concludes by identifying future directions for material development, system integration, and modeling approaches to advance the practical deployment of efficient and scalable AWH technologies. Full article

This study investigated the integration of advanced Atmospheric Water Generators (AWGs) within the design process of building energy systems, focusing on the water–energy nexus in the context of a real-life hospital building. It is based on a simulation approach, recognised as a viable means to analyse and enhance AWG potentialities. However, the current state of research does not address the issue of AWG integration within building plant systems. This study contributes to fill such a research gap by building upon an authors’ previous work and proposing an enhanced methodology. The methodology describes how to incorporate a multipurpose AWG system into the energy simulation environment of DesignBuilder (DB), version 7.0.0116, through its coupling with AWGSim, version 1.20d, a simulation tool specifically developed for atmospheric water generators. The chosen case study is a wing of the Mondino Hospital in Pavia, Italy, selected for its complex geometry and HVAC requirements. By integrating AWG outputs—covering water production, heating, and cooling—into DB, this study compared two configurations: the existing HVAC system and an enhanced version that includes the AWG as plant support. The simulation results demonstrated a 16.3% reduction in primary energy consumption (from 231.3 MWh to 193.6 MWh), with the elimination of methane consumption and additional benefits in water production (257 m³). This water can be employed for photovoltaic panel cleaning, further reducing the primary energy consumption to 101.9 MWh (55.9% less than the existing plant), and for human consumption or other technical needs. Moreover, this study highlights the potential of using AWG technology to supply purified water, which can be a pivotal solution for hospitals located in areas affected by water crises. This research contributes to the atmospheric water field by addressing the important issue of simulating AWG systems within building energy design tools, enabling informed decisions regarding water–energy integration at the project stage and supporting a more resilient and sustainable approach to building infrastructure. Full article

The consumption of fresh fruit and vegetables is essential for a healthy diet as they contain a diverse composition of vitamins, minerals, fibre, and bioactive compounds. However, cross-contamination during harvest and post-harvest poses a high risk of microbial contamination. Therefore, handling fruit and vegetables during processing and contact with wet equipment and utensil surfaces is an ideal environment for microbial contamination and foodborne illness. Nevertheless, less attention has been paid to some emerging pathogens that are now increasingly recognised as transmissible to humans through contaminated fruit and vegetables, such as Arcobacter and Cronobacter species in various products, which are the main risk in fruit and vegetables. Cronobacter and Arcobacter spp. are recognised food-safety hazards because they pose a risk of foodborne disease, especially in vulnerable groups such as newborns and immunocompromised individuals. Cronobacter spp. have been linked to severe infant conditions—notably meningitis and sepsis—most often traced to contaminated powdered infant formula. Although Arcobacter spp. have been less extensively studied, they have also been associated with foodborne disease, chiefly from dairy products and meat. With this in mind, this review provides an overview of the main chemical and physical sanitisation methods in terms of their ability to reduce the contamination of fresh fruit and vegetable products caused by two emerging pathogens: Arcobacter and Cronobacter. Emerging chemical (organic acid compounds, extracts, and essential oils) and physical methods (combination of UV-C with electrolysed water, ultrasound, and cold atmospheric plasma) offer innovative and environmentally friendly alternatives to traditional approaches. These methods often utilise natural materials, less toxic solvents, and novel techniques, resulting in more sustainable processes compared with traditional methods that may use harsh chemicals and environmentally harmful processes. This review provides the fruit and vegetable industry with a general overview of possible decontamination alternatives to develop optimal and efficient processes that ensure food safety. Full article

This study employs Density Functional Theory (DFT) and Molecular Dynamics (MD) simulations to investigate interactions between water molecules and Poly(N-isopropylacrylamide) (PNIPAM). DFT reveals preferential water binding sites, with enhanced binding energy observed in the linker zone. Quantum Theory of Atoms in Molecules (QTAIM) and electron localization function (ELF) analyses highlight the roles of hydrogen bonding and steric hindrance. MD simulations unveil temperature-dependent hydration dynamics, with structural transitions marked by changes in the radius of gyration (Rg) and the radial distribution function (RDF), aligning with DFT findings. Our work goes beyond prior studies by combining a DFT, QTAIM and MD simulations approach across different PNIPAM monomer-to-30mer structures. It introduces a systematic quantification of pseudo-saturation thresholds and explores water clustering dynamics with structural specificity, which have not been previously reported in the literature. These novel insights establish a more complete molecular-level picture of PNIPAM hydration behavior and temperature responsiveness, emphasizing the importance of amide hydrogen and carbonyl oxygen sites in hydrogen bonding, which weakens above the lower critical solution temperature (LCST), resulting in increased hydrophobicity and paving the way for understanding water sorption mechanisms, offering guidance for future applications such as dehumidification and atmospheric water harvesting. Full article

Background/Objectives: Strawberries (Fragaria × ananassa) are among the most commonly consumed fruits due to their taste and nutritional benefits. However, their high rate of spoilage poses a major problem during the period from harvest and transport to further processing or marketing. The aim of this study was, therefore, to investigate the effects of passive modified atmosphere packaging on the metabolome and shelf life of strawberries as a more sustainable alternative compared to standard market storage conditions. Methods: A total of 99 strawberry samples were analyzed for microbial viable counts, water content, and metabolomic changes using non-targeted low-resolution near-infrared spectroscopy, high-resolution mass spectrometry, and microbial culture-based methods. Results: Using near-infrared spectroscopy as a rapid screening method, the linear regression model indicated that strawberries stored under modified atmosphere packaging conditions had a longer shelf life. Furthermore, lipidomic analysis using mass spectrometry showed that the levels of spoilage biomarkers, such as oxidized phosphatidylcholines and lysophosphatidylcholines, were increased under common market storage conditions without a controlled atmosphere. In contrast, the levels of these metabolites were reduced when strawberries were stored in modified atmosphere packaging. Moreover, the strawberries stored under modified atmosphere packaging had a lower number of bacteria, yeasts, and molds as well as a lower water loss throughout the entire storage period. Conclusions: Overall, the study highlights the potential of passive modified atmosphere packaging films to extend the shelf life and thus maintain the edibility of strawberries over a longer period. Full article

Freshwater scarcity demands innovative solutions, and Atmospheric Water Generation (AWG) technology offers a promising approach. This study applies a data-driven optimization methodology to enhance AWG efficiency by improving condensation surface design using Triply Periodic Minimal Surface (TPMS) structures. Five TPMS types (Gyroid, Diamond, Lidinoid, SplitP, and Schwartz) were evaluated using thermal simulations in nTop, and a regression-based predictive model was developed to assess the impact of lattice thickness and cell size on surface area to volume ratio (SA/V_S) and temperature difference (ΔT). A multi-objective optimization approach, incorporating sensitivity-weighted desirability analysis, identified optimal design parameters under varying performance priorities. Results show Schwartz exhibits the highest tunability, with both factors significantly influencing its performance, while other TPMS types are primarily governed by lattice thickness. By integrating regression modeling, multi-objective optimization, and sensitivity analysis, this study provides a systematic framework for AWG surface design, offering scalable insights for thermal management and moisture collection efficiency in sustainable water harvesting applications. Full article

Atmospheric water harvesting (AWH) is a promising alternative to address immediate water needs. Desiccant-based AWH could compete effectively with other commercially available AWH technologies. One of the primary challenges facing desiccant-based AWH is the energy required to desorb the captured water vapor from the desiccant. This work presents a multi-faceted approach targeted explicitly at low-humidity and arid regions, aiming to overcome the limitations of the refrigerant-based AWH system. It includes assessing common desiccants (zeolite, activated alumina, and silica gel) and their forms (beads, powdered, or coated on a substrate). A bench-scale test rig was designed to evaluate different types and forms of desiccants for adsorption and desorption cycles and overall adsorption capacity (g/g), kinetic profiles, and rates. Experimental results indicate that beaded desiccants possess the highest adsorption capacity compared to powdered or coated forms. Furthermore, coated desiccants double the water uptake (1.12 vs. 0.56 g water/g desiccant) and improve adsorption/desorption cycling by 52% compared to beaded forms under the same conditions. Additionally, Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), and dynamic vapor sorption (DVS) analysis show the pore geometry, morphology, and sorption capacity. The goal is to integrate these performance improvements and propose a more effective, energy-efficient desiccant-based AWH system. Full article

This paper presents the first results of a broader study aimed at considering atmospheric water generation as a viable option within sustainable building design strategies. In particular, the focus is on integrated systems in which atmospheric water generator (AWG) machines, in addition to producing water, support HVAC systems. The research focuses on the combined use of two different simulation tools: a commercial tool designed to study the energy balance of buildings and a custom-developed software for AWG modelling. This is the first step of a more complex procedure of software integration that is aimed to provide designers with a method to implement AWGs in the design process of buildings, both residential or industrial. This preliminary procedure is applied to a case study concerning the link between an advanced integrated AWG and a building housing inverters and transformers that belong to a photovoltaic field. The scope of the integration consists in enhancing the energy sustainability of atmospheric water intended for hydrogen production and panel washing by means of the dry and cold air flux that comes from the cycle of vapour condensation. The results highlight the potentialities of the integrated design, which includes AWGs, to enhance the final efficiency of sustainable housing. In particular, the joint action of the simulation tools used in this study provides insights about the possibility to reduce the size of traditional chiller that serve the building by an order of magnitude, and to achieve an energy saving of 29.8 MWh a year. Full article

Freshwater resources that humans can use directly account for 2.5 percent. Fog collection from the atmosphere is an eco-friendly and potential solution to the water shortage crisis. This study presents a biomimetic approach to fog collection inspired by the Namib Desert beetle and cacti. Using fused deposition modeling (FDM) 3D printing and atmospheric pressure plasma (APP) treatment, we fabricated hybrid wettability surfaces combining hydrophobic polypropylene (PP) and super hydrophilic polycarbonate (PC). These surfaces significantly improved fog collection efficiency, achieving 366.2 g/m²/h rates by leveraging the Laplace pressure gradient and hybrid wettability gradient. This work provides an efficient and effective methodology to fabricate hybrid wetting surfaces and can be potentially applied to fog harvesting and microfluidic devices. Full article

Agricultural runoff ranks second only to atmospheric deposition as a source of nitrogen pollution to streams in the southeastern United States. Climate-smart practices such as irrigation have the potential to reduce these impacts and provide resilience in the face of climate change. The purpose of this study is to evaluate the impact of irrigation amounts and fertilizer application strategies on surface nitrate export to surrounding steams. Data from an existing experiment on corn nitrogen fertilization in the Southeastern US was utilized and a crop simulation model was employed to simulate the water and nitrogen dynamics within the soil with particular emphases on nutrient uptake and residual nutrients. left in the soil after harvest under varying fertilization scenarios. A hydrologic and nutrient export model was developed to run in conjunction with the crop model to simulate lateral export from the fields. The results of this study indicate that climate and nutrient management are the dominant factors in determining surface nutrient transport under both rain fed and irrigated conditions, confirming previous studies. The overall results show that irrigation, on average, reduced nutrient export from the surface, especially in dry years. The effect is even greater if the nutrients are applied later in the year while irrigation is on-going. While this present study provides an initial look at the potential impacts of irrigation on nutrient export in humid areas, the available on-farm observational data is limited in its content. However, the results obtained support existing literature and provide further evidence on the impact of irrigation as a climate resilient practice and will help direct future studies in the region. Full article

Climate change continues to exacerbate water scarcity by altering global weather patterns and intensifying extreme climatic events. This review examines the potential of atmospheric water generation technologies to mitigate water scarcity under such conditions. By leveraging a multidisciplinary approach, we review advancements in fog harvesting, sorption-based systems, membrane technologies, radiative sky cooling, and cloud seeding. A special emphasis is placed on passive systems utilizing renewable energy to address challenges of high energy demands. Predictive tools such as machine learning, climate models, and geographic information systems are explored to optimize atmospheric water generation deployment under shifting climatic conditions. This review article outlines critical innovations in materials, economic considerations, and policy frameworks required for atmospheric water generation to transition from niche to mainstream water solutions. These findings aim to inform sustainable strategies for tackling water scarcity in the context of global climate challenges. Full article

The fibrous hybrid material was synthesized by suspension radical styrene polymerization on the surface of cellulose microfibers. The resulting material was used to prepare a thermally stable and mechanically strong porous composite matrix that was employed as a carrier for further precipitation of the hygroscopic agents: CaCl₂ and 1-butyl-3-methylimidazolium chloride. The obtained composite materials were used to capture atmospheric water at different relative humidity levels and extract fresh water. A composite material containing an ionic liquid (1-butyl-3-methylimidazolium chloride) as a hygroscopic agent demonstrated the best water absorption efficiency and reusability potential. Full article

Extracting water directly from the atmosphere seems to be a perfect way to solve the water scarcity facing 2 billion people; however, traditional Atmospheric Water Harvesting (AWH) lacks the ability to adsorb water molecules in an arid climate. Porous materials are capable of assisting water adsorption; however, currently, only certain customizable Metal–Organic Frameworks (MOFs) are able to meet the standard of adsorbing water molecules at low humidity and releasing water at low temperatures at certain times that can realize assisted AWH’s practical and energy-efficient use (Energy consumption < 5kWh/L-water). From this perspective, we offer a concise review of the advancements in enhanced AWH technologies, delve into the attributes of appropriate MOFs, and offer insights into the potential and future directions of MOFs–AWH. In conclusion, we underscore that that the development of designable MOFs holds the key to the widespread practical implementation of AWH, promising the availability of affordable clean water anywhere in the world. Full article