Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (1)

Search Parameters:
Keywords = bromoferrocenes

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
9 pages, 2418 KiB  
Short Note
1,1′-Dibromo-2,2′,5,5′-tetrakis(methylthio)ferrocene
by Tobias Blockhaus, Fabian Zott and Karlheinz Sünkel
Molbank 2023, 2023(1), M1542; https://doi.org/10.3390/M1542 - 9 Jan 2023
Viewed by 1933
Abstract
The reaction of 1,1′-dibromoferrocene with three equivalents of LiTMP and Me2S2 produces a product mixture, from which 1,1′-dibromo-2,2′-bis(methylthio)ferrocene (4) can be isolated in moderate yield. Further treatment of the isolated compound 4 with two equivalents of LiTMP and [...] Read more.
The reaction of 1,1′-dibromoferrocene with three equivalents of LiTMP and Me2S2 produces a product mixture, from which 1,1′-dibromo-2,2′-bis(methylthio)ferrocene (4) can be isolated in moderate yield. Further treatment of the isolated compound 4 with two equivalents of LiTMP and Me2S2 also produced a mixture, from which the title compound 7 could be isolated. A crystal structure determination of 7 shows that the two cyclopentadienyl rings are oriented in such a way that a maximum number of S…Br contacts results. Intermolecular S…Br contacts, supported by S…S contacts, lead to a 1D-chain polymer in [1 0 0] direction. Full article
Show Figures

Figure 1

Back to TopTop