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Keywords = cement materials

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23 pages, 5091 KB  
Article
Erosion, Mechanical and Microstructural Evolution of Cement Stabilized Coarse Soil for Embankments
by Adel Belmana, Victor Cavaleiro, Mekki Mellas, Luis Andrade Pais, Hugo A. S. Pinto, Vanessa Gonçalves, Maria Vitoria Morais, André Studart and Leonardo Marchiori
Geotechnics 2025, 5(3), 62; https://doi.org/10.3390/geotechnics5030062 (registering DOI) - 4 Sep 2025
Abstract
Internal erosion is a significant issue caused by water flow within soils, resulting in structural collapse of hydraulic structures, particularly in coarse soils located near rivers. These soils typically exhibit granulometric instability due to low clay content, resulting in poor hydraulic and mechanical [...] Read more.
Internal erosion is a significant issue caused by water flow within soils, resulting in structural collapse of hydraulic structures, particularly in coarse soils located near rivers. These soils typically exhibit granulometric instability due to low clay content, resulting in poor hydraulic and mechanical properties. To mitigate this problem, cement treatment is applied as an alternative to soil removal, reducing transportation and storage costs. The hole erosion test (HET) and Crumbs tests, shearing behaviour through consolidated undrained (CU) triaxial, and microstructure analyses regarding scanning electron microscopy (SEM), mercury intrusion porosimeter (MIP) and thermogravimetric analysis (TGA) were conducted for untreated and treated coarse soil specimens with varying cement contents (1%, 2%, and 3%) and curing durations (1, 7, and 28 days). The findings indicate a reduction in the loss of eroded particles and overall stability of treated soils, along with an improvement in mechanical properties. SEM observations reveal the development of hydration gel after treatment, which enhances cohesion within the soil matrix, corroborated by TGA analyses. MIP reveals the formation of a new class of pores, accompanied by a reduction in dry density. This study demonstrates that low cement addition can transform locally unsuitable soils into durable construction materials, reducing environmental impact and supporting sustainable development. Full article
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21 pages, 10515 KB  
Article
Comprehensive Study on Mechanical Properties of Rubberized Geopolymer Concrete Reinforced with Steel Fibers
by Xiaoping Wang, Feng Liu, Lei Luo, Baifa Zhang and Lijuan Li
Buildings 2025, 15(17), 3175; https://doi.org/10.3390/buildings15173175 - 4 Sep 2025
Abstract
To address challenges posed by waste tires and greenhouse gas emissions associated with ordinary Portland cement, exploring eco-friendly construction materials is critical for sustainability. This study examines the workability and mechanical properties of straight steel fiber-reinforced rubberized geopolymer concrete (SFRRGC), where rubber powder [...] Read more.
To address challenges posed by waste tires and greenhouse gas emissions associated with ordinary Portland cement, exploring eco-friendly construction materials is critical for sustainability. This study examines the workability and mechanical properties of straight steel fiber-reinforced rubberized geopolymer concrete (SFRRGC), where rubber powder is derived from recycled waste tires. The experimental variables included rubber powder (RP) content (0%, 6%, 12%, and 20% by volume of fine aggregate) and steel fiber (SF) content (0%, 0.5%, 1.0%, and 1.5% by volume). The results show that incorporating RP and SFs reduced the workability of SFRRGC but increased its peak strain. Specifically, RP addition decreased the elastic modulus, compressive strength, and toughness; increasing the SF content enhanced energy dissipation, while the effects of SF and RP contents on Poisson’s ratio were negligible. The specimens showed that a higher RP content would weaken the crack-bridging effect of SF. For example, specimens with 1.0% SF and 6% RP achieved 49.56 MPa compressive strength and 4.04 × 10−3 maximum peak strain; those with 0.5% SF and 20% RP had 118.40 J compressive toughness, which was 5.53% lower than that of the reference specimens (125.33 J). Furthermore, a constitutive model for SFRRGC was proposed, and its theoretical curves aligned well with the experimental results. This proposed model can reliably predict the stress–strain curves of geopolymer concrete with different SF and RP mixture proportions. Full article
(This article belongs to the Special Issue Next-Gen Cementitious Composites for Sustainable Construction)
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27 pages, 4462 KB  
Review
Unlocking Alternative Cement Solutions: Utilizing Wastes and By-Products for Magnesium Phosphate Cement Development
by Anna Alfocea-Roig, Jessica Giro-Paloma, Sergio Huete-Hernández and Joan Formosa
Urban Sci. 2025, 9(9), 352; https://doi.org/10.3390/urbansci9090352 - 3 Sep 2025
Abstract
Concrete is the most used material worldwide, with cement as its essential component. Cement production, however, has a considerable environmental footprint contributing nearly 8% of global CO2 emissions, largely from clinker calcination. This review aims to examine strategies for reducing these emissions, [...] Read more.
Concrete is the most used material worldwide, with cement as its essential component. Cement production, however, has a considerable environmental footprint contributing nearly 8% of global CO2 emissions, largely from clinker calcination. This review aims to examine strategies for reducing these emissions, with a particular focus on alternative materials for producing magnesium phosphate cements (MPCs). Specifically, the objectives are first to summarize mitigation pathways, such as CO2 capture, energy efficiency, and alternative raw materials, and second evaluate the feasibility of using industrial wastes and by-products, including low-grade MgO, tundish deskulling waste (TUN), boron-MgO (B-MgO), and magnesia refractory brick waste (MRB), as MgO sources for MPC. The review highlights that these materials represent a promising route to reduce the environmental impact of cement production and support the transition toward carbon neutrality by 2050. Full article
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20 pages, 5622 KB  
Article
Thermal Performance of Concrete Containing Graphite at High Temperatures for the Application in a TES
by Seung-Tae Jeong, Ji-Hun Park, Tuan-Kiet Tran and In-Hwan Yang
Energies 2025, 18(17), 4685; https://doi.org/10.3390/en18174685 - 3 Sep 2025
Abstract
Thermal energy storage (TES) technology is pivotal for storing thermal energy and has numerous applications in buildings and industrial processes. Graphite is a potential additive for improving TES materials because of its high-temperature resistance and thermal conductivity. This study presents an examination of [...] Read more.
Thermal energy storage (TES) technology is pivotal for storing thermal energy and has numerous applications in buildings and industrial processes. Graphite is a potential additive for improving TES materials because of its high-temperature resistance and thermal conductivity. This study presents an examination of TES concrete with 5%, 10%, and 15% (by volume of binder) compared to concrete that contains only ordinary Portland cement (OPC). Notably, increasing graphite content reduced the unit weight by 0.3%, 2.0%, and 2.6%. Additionally, the graphite mixture exhibited less strength loss than the OPC mixture. Specifically, the G15 mixture achieved a 38.3% cut in compressive strength compared to 51.9% for OPC and a 51.8% cut in splitting tensile strength compared to 56.1% for OPC. Additionally, the thermal conductivity of graphite mixtures was greater than that of the OPC concrete under high-temperature conditions. Microstructural analysis through scanning electron microscopy (SEM) and X-ray diffraction (XRD) revealed reduced portlandite content and fewer voids in graphite-integrated samples, suggesting increased thermal stability and matrix densification. Thermogravimetric analysis (TGA) further confirmed the effect of graphite on thermal behavior, revealing distinct mass loss patterns at increased temperatures. Based on the findings, numerical simulations were conducted. The results confirm trends in thermal conductivity and heat propagation in the experiment, revealing the potential of graphite concrete in TES design by obtaining temperature distributions under thermal cycling. Overall, this study confirms the feasibility and efficiency of using graphite to improve the thermal properties of concrete for TES applications. Full article
(This article belongs to the Special Issue Advanced Technologies and Materials for Thermal Energy Storage)
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20 pages, 3317 KB  
Article
Antagonistic Effects of Hydrated Lime and Calcium Formate on Early-Age Strength in High Volume Fly Ash Composites: Mechanisms and Engineering Implications
by Zhiyuan Zhou, Massoud Sofi, Jinghan Lu, Zipeng Zhang, Pooria Pasbakhsh and Priyan Mendis
J. Compos. Sci. 2025, 9(9), 476; https://doi.org/10.3390/jcs9090476 - 3 Sep 2025
Abstract
The utilization of high-volume fly ash (HVFA, ≥50% cement replacement) in concrete is pivotal for sustainable construction but hindered by low early-age strength. This study investigates the individual and combined effects of hydrated lime (HL) and calcium formate (CF) on the strength development, [...] Read more.
The utilization of high-volume fly ash (HVFA, ≥50% cement replacement) in concrete is pivotal for sustainable construction but hindered by low early-age strength. This study investigates the individual and combined effects of hydrated lime (HL) and calcium formate (CF) on the strength development, hydration kinetics, and microstructure of HVFA pastes (60% and 70% FA). Individual additions of 11% HL (HVFA60) or 14% HL (HVFA70) raised 28-day compressive strength by 18% and 22%, respectively, and shortened final setting from 10.0 h to 3.8 h. Similarly, 3% CF increased 28-day strength by 15% (HVFA60) and 12% (HVFA70) while cutting final setting to 2.1 h and 3.3 h. In contrast, combining HL and CF suppressed strength by 15–22% despite accelerating final setting to less than 1 h. Isothermal calorimetry showed a 40% reduction in cumulative heat release at 44 h for the combined system. XRD, TGA and SEM confirmed 20–30% lower C-S-H content, 25% less CH, and a rise in porosity when HL and CF were used together. These findings demonstrate that HL and CF act as competing accelerators, where rapid heat release compromises microstructural integrity. For practical applications using HVFA materials, individual use of HL or CF is recommended to enhance early-age performance, while combined application should be avoided to prevent strength reduction. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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28 pages, 3081 KB  
Review
Low-Carbon and Recycled Mineral Composite Materials for Sustainable Infrastructure: A Comprehensive Review
by Rong Zhang, Yihe Zhang, Guoxing Sun and Hongqiang Wei
Sustainability 2025, 17(17), 7908; https://doi.org/10.3390/su17177908 - 2 Sep 2025
Abstract
Infrastructure construction is a major contributor to carbon emissions, primarily due to the extensive use of mineral materials such as cement and aggregates, which release significant amounts of carbon dioxide during production and use. While existing research has predominantly centered on the applications [...] Read more.
Infrastructure construction is a major contributor to carbon emissions, primarily due to the extensive use of mineral materials such as cement and aggregates, which release significant amounts of carbon dioxide during production and use. While existing research has predominantly centered on the applications of concrete, the present study extends the investigation to encompass inorganic–organic composites, alloy materials, and wastewater treatment systems, with particular attention to bridging the gap between theoretical potential and practical implementation. This study identifies China, the USA, and India as leaders in this field, attributing their progress to abundant material resources and sustained policy support. Key findings reveal that while geopolymers can fully replace cement, substitution rates of less than 50% are optimal for high-performance concrete to maintain structural integrity and decarbonization benefits. Aggregate replacements using materials such as air-cooled blast furnace slag show 50–100% feasibility. This review further highlights the multifunctional potential of red mud, rice husk ash, fly ash, and blast furnace slag as cement replacements, aggregates, reinforcers, catalysts, adsorbents, and composite fillers. However, challenges such as unstable raw material supply, lack of standardization, and insufficient international collaboration persist; these issues have often been overlooked in prior research and viable solutions have not been proposed. To address these barriers, a triple-objective framework is introduced in this study, integrating sustainable infrastructure, resource recycling, and environmental remediation, supported by optimized production processes and policy models from leading nations. Future research directions emphasize comprehensive life cycle assessments and enhanced global cooperation to bridge the divide between resource-rich and resource-scarce regions. By synthesizing cross-disciplinary applications and actionable solutions, this work advances the transition toward sustainable infrastructure systems. Full article
(This article belongs to the Section Waste and Recycling)
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14 pages, 768 KB  
Article
Microtensile Bond Strength of Composite Restorations: Direct vs. Indirect Techniques Using Cohesive Zone Models
by Maria A. Neto, Ricardo Branco, Ana M. Amaro and Ana Messias
J. Compos. Sci. 2025, 9(9), 475; https://doi.org/10.3390/jcs9090475 - 2 Sep 2025
Abstract
The purpose of this in silico study was to evaluate the main difference of the adhesion strength of direct and semi-direct composite resin restorations in dentin using micro-tensile testing (μTBS) and finite element analysis (FEA). This in silico study employed cohesive zone traction [...] Read more.
The purpose of this in silico study was to evaluate the main difference of the adhesion strength of direct and semi-direct composite resin restorations in dentin using micro-tensile testing (μTBS) and finite element analysis (FEA). This in silico study employed cohesive zone traction and shear laws to investigate interfacial damage in both restoration groups. Tridimensional finite element models of both restoration specimens were created. A 20 μm thick resin cement layer was created for the semi-direct case. The Clearfil SE Bond 2 adhesive system and the restorative material, Ceram X Spectra ST HV composite resin, were used on both restorations. The numerical bond strength of both restoration techniques was evaluated using two different analysis assumptions. In the first assumption, the numerical analysis procedure included only the non-linear behavior of dentin and the von Mises damage criterion, whereas cohesive zone models were included in the second analysis assumption. The influence of dentin-adhesive cohesive mechanical properties was studied using values reported in the literature, and a sensitivity study helped improve the correlation between experimental and numerical results. The mechanical properties of the composite cohesive zone were defined assuming that the interface strength of dentin and composite follows the values reported by the manufacturer of Spectra ST. Damage initiation and progression were analyzed, and strains and stresses of the cohesive zone models (CZM) were compared with the corresponding perfect bonded models. The experimental µTBS results for the direct restoration strategy showed an adhesive strength of 38.156 ± 10.750 MPa, while the CZM predicted a slightly higher value of 40.4 ± 10.8 MPa. For the indirect restoration strategy, the experimental adhesive strength was 25.449 ± 10.193 MPa, compared to a numerically predicted strength of 28.1 ± 9.3 MPa. Overall, the CZM tends to overestimate the adhesive strength relative to experimental values. The statistical analysis of dentin extension strains for direct (DR) and semi-direct (SR) group models reveals that the SR configuration yields higher strain levels. Hence, these results suggest that, assuming identical dentin properties across both restoration groups, the material configuration in the direct restoration offers better mechanical protection to the dentin. These findings highlight the critical role of incorporating damage mechanics to more accurately characterize stress distribution during tooth rehabilitation. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
26 pages, 4718 KB  
Article
Optimum Mix Design and Correlation Analysis of Pervious Concrete
by Fenting Lu, Li Yang and Yaqing Jiang
Materials 2025, 18(17), 4129; https://doi.org/10.3390/ma18174129 - 2 Sep 2025
Abstract
Pervious concrete is challenged by the inherent trade-off between permeability and mechanical strength. This study presents a systematic optimization of its mix design to achieve a balance between these properties. Single-factor experiments and an L9(33) orthogonal array test were [...] Read more.
Pervious concrete is challenged by the inherent trade-off between permeability and mechanical strength. This study presents a systematic optimization of its mix design to achieve a balance between these properties. Single-factor experiments and an L9(33) orthogonal array test were employed to evaluate the effects of target porosity (14–26%), water–cement ratio (0.26–0.34), sand rate (0–10%), and VMA dosage (0–0.02%). Additionally, Spearman rank correlation analysis and nonlinear regression fitting were utilized to develop quantitative relationships correlating the measured porosity to material performance. The results revealed that increasing target porosity enhances permeability but reduces compressive and splitting tensile strengths. The optimal water-to-cement ratio (w/c) was found to be 0.32, balancing both permeability and strength. An appropriate sand content of 6% improved mechanical properties, while a VMA dosage of 0.01% effectively enhanced bonding strength and workability. The orthogonal experiment identified the optimal mix ratio as a w/c ratio of 0.3, VMA dosage of 0.12%, target porosity of 14%, and sand content of 7%, achieving a compressive strength at 28-days of 43.5 MPa and a permeability coefficient of 2.57 mm·s−1. Empirical relationships for the permeability coefficient and mechanical properties as functions of the measured porosity were derived, demonstrating a positive exponential correlation between the measured porosity and the permeability coefficient, and a negative correlation with compressive and splitting tensile strengths. This research provides a systematic framework for designing high-performance pervious concrete with balanced permeability and mechanical properties, offering valuable insights for its development and application in green infrastructure projects. Full article
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23 pages, 2813 KB  
Article
Development and Validation of a Low-Cost Arduino-Based Lee Disc System for Thermal Conductivity Analysis of Sustainable Roofing Materials
by Waldemiro José Assis Gomes Negreiros, Jean da Silva Rodrigues, Maurício Maia Ribeiro, Douglas Santos Silva, Raí Felipe Pereira Junio, Marcos Cesar da Rocha Seruffo, Sergio Neves Monteiro and Alessandro de Castro Corrêa
Sensors 2025, 25(17), 5447; https://doi.org/10.3390/s25175447 - 2 Sep 2025
Abstract
The optimization of thermal performance in buildings is essential for sustainable urban development, yet the high cost and complexity of traditional thermal conductivity measurement methods limit broader research and educational applications. This study developed and validated a low-cost, replicable prototype that determines the [...] Read more.
The optimization of thermal performance in buildings is essential for sustainable urban development, yet the high cost and complexity of traditional thermal conductivity measurement methods limit broader research and educational applications. This study developed and validated a low-cost, replicable prototype that determines the thermal conductivity of roof tiles and composites using the Lee Disc method automated with Arduino-based acquisition. Standardized samples of ceramic, fiber–cement, galvanized steel, and steel coated with a castor oil-based polyurethane composite reinforced with miriti fiber (Mauritia flexuosa) were analyzed. The experimental setup incorporated integrated digital thermocouples and strict thermal insulation procedures to ensure measurement precision and reproducibility. Results showed that applying the biocompatible composite layer to metal tiles reduced thermal conductivity by up to 53%, reaching values as low as 0.2004 W·m−1·K−1—well below those of ceramic (0.4290 W·m−1·K−1) and fiber–cement (0.3095 W·m−1·K−1) tiles. The system demonstrated high accuracy (coefficient of variation < 5%) and operational stability across all replicates. These findings confirm the feasibility of open-source, low-cost instrumentation for advanced thermal characterization of building materials. The approach expands access to experimental research, promotes sustainable insulation technologies, and offers practical applications for both scientific studies and engineering education in resource-limited environments. Full article
(This article belongs to the Section Sensor Materials)
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21 pages, 1368 KB  
Article
Laterite-Based Low-Carbon Binder Supporting the Circular Economy in Yaoundé, Cameroon
by Louise Mazzoni Leduc, Bernadin Kenne Diffo, Jean Ambroise and Abdelkrim Bennani
Buildings 2025, 15(17), 3154; https://doi.org/10.3390/buildings15173154 - 2 Sep 2025
Abstract
This study formulates an efficient, affordable, and low-carbon binder based on locally excavated earth from Yaoundé, offering sufficient mechanical strength and water resistance for rendering applications. Through material characterization, a binary binder composed of Portland cement (PC) and calcined laterite (CL) was developed, [...] Read more.
This study formulates an efficient, affordable, and low-carbon binder based on locally excavated earth from Yaoundé, offering sufficient mechanical strength and water resistance for rendering applications. Through material characterization, a binary binder composed of Portland cement (PC) and calcined laterite (CL) was developed, reducing the PC content by up to 30%. The mortar used laterite sand with varying fine particle contents in place of river sand, and its mechanical strength and water absorption via capillarity action were evaluated. Due to the porosity of the laterite fines, all mixes were prepared at equivalent workability. The mechanical strength was the same as if the binder solely consisted of PC and reached 11 MPa when the laterite sand contained no fine particles. As the fine particle content increased, the mechanical strength decreased to a minimum value of 4 MPa when raw laterite was used, and the coefficient of water absorption via capillarity action decreased. Overall, the formulated class Wc2 mortar is suitable for rendering applications. The valorization potential of fine particles and coarse aggregates of the crushed mortar was assessed: the crushed mortar fines had pozzolanic properties and could serve as supplementary cementitious materials; the largest particles are suitable for lime stabilization. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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18 pages, 2760 KB  
Article
Behavioral Analysis of Rigid Pavements Utilizing Recycled Base Layers
by Elaheh TaghaviGhalehsari, Hassan Kardgar and Ali Hasanzadeh
J 2025, 8(3), 34; https://doi.org/10.3390/j8030034 - 2 Sep 2025
Abstract
Sustainable pavement design requires a balanced consideration of economic, environmental, and social impacts. In line with Federal Highway Administration (FHWA) guidelines for sustainable roadway infrastructure, incorporating recycled materials such as reclaimed asphalt pavement (RAP), recycled pavement material (RPM), recycled asphalt shingles (RASs), and [...] Read more.
Sustainable pavement design requires a balanced consideration of economic, environmental, and social impacts. In line with Federal Highway Administration (FHWA) guidelines for sustainable roadway infrastructure, incorporating recycled materials such as reclaimed asphalt pavement (RAP), recycled pavement material (RPM), recycled asphalt shingles (RASs), and warm-mix asphalt (WMA) has been shown to reduce natural resource depletion while promoting circular construction practices. This study investigates the structural performance of Portland cement concrete (PCC) pavements constructed on RAP and RPM base layers. A series of design scenarios was modeled using site-specific laboratory and field data—particularly subgrade soil properties and climatic conditions—from El Paso and San Antonio, Texas. The analysis incorporates unsaturated soil parameters and follows the performance thresholds set by the Mechanistic-Empirical Pavement Design Guide (MEPDG). Findings indicate that concrete mixture design, pavement structure, and local weather conditions are the primary drivers of distress in jointed plain concrete pavements (JPCPs). However, subsoil characteristics have a significant impact on joint faulting in JPCP and punchout occurrences in continuously reinforced concrete pavements (CRCPs), especially in thinner sections. Notably, the use of up to 50% recycled material in the base layer had minimal adverse effects on pavement performance, underscoring its viability as a sustainable design strategy for rigid pavements. Full article
(This article belongs to the Section Engineering)
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23 pages, 15804 KB  
Article
Experimental Study on the Strengthening Mechanism of Modified Coal Gangue Concrete and Mechanical Properties of Hollow Block Masonry
by Qing Qin, Yuchen Wang, Chenghua Zhang, Zhigang Gao, Sha Ding, Xueming Cao and Xinqi Zhang
Buildings 2025, 15(17), 3141; https://doi.org/10.3390/buildings15173141 - 2 Sep 2025
Viewed by 165
Abstract
To enhance the utilization efficiency of coal gangue aggregate, coarse aggregates are chemically modified with 5% sodium silicate solution. The effects of this modification on the compressive strength and microstructural characteristics of concrete are systematically investigated through integrated macro-testing and micro-characterization. By evaluating [...] Read more.
To enhance the utilization efficiency of coal gangue aggregate, coarse aggregates are chemically modified with 5% sodium silicate solution. The effects of this modification on the compressive strength and microstructural characteristics of concrete are systematically investigated through integrated macro-testing and micro-characterization. By evaluating the compressive performance of modified coal gangue concrete blocks, the optimal mix ratio of each strength grade of blocks is determined. Experimental results indicate that the apparent density, water absorption, and crushing index of the modified coal gangue coarse aggregate exhibit better mechanical properties than the control group. The modified coal gangue coarse aggregate demonstrates improved mechanical performance, with the compressive strength of 28-day concrete showing a 15.3% increase relative to the control group. Furthermore, using a sodium silicate solution effectively enhances the interface transition zone’s performance between coal gangue coarse aggregate and cement mortar, improving the compactness of this interface. The modified coal gangue concrete blocks exhibit higher compressive strength than the original material. When the substitution rate remains constant, the compressive strength of modified coal gangue concrete decreases with increasing water–cement ratio. Similarly, at a constant water–binder ratio, compressive strength decreases with higher modified gangue aggregate replacement. Finally, compressive tests are conducted on masonry constructed with hollow blocks of strength grades MU7.5, MU10, and MU15. Then, a calculation model for the average compressive strength of modified coal gangue concrete hollow block masonry is proposed, providing theoretical support for its engineering application. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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21 pages, 6894 KB  
Article
Study on the Influence and Performance of Nano SiO2 on Solid Waste Grouting Material
by Huifang Zhang, Lei Wang, Jie Chen, Haiyang Chen, Wei Wu, Jinzhu Li, Henan Lu, Dongxiao Hu and Hongliang Huang
Materials 2025, 18(17), 4110; https://doi.org/10.3390/ma18174110 - 1 Sep 2025
Viewed by 85
Abstract
As a key connection technology in prefabricated buildings, offshore wind power, and bridge engineering, the performance and environmental sustainability of grouted sleeve connections are essential for the long-term development of civil infrastructure. To address the environmental burden of conventional high-strength cement-based grouts, an [...] Read more.
As a key connection technology in prefabricated buildings, offshore wind power, and bridge engineering, the performance and environmental sustainability of grouted sleeve connections are essential for the long-term development of civil infrastructure. To address the environmental burden of conventional high-strength cement-based grouts, an eco-friendly sleeve grouting material incorporating industrial solid waste was developed. In this study, silica fume (15%) and fly ash (5%) were employed as supplementary cementitious materials, while nanosilica (NS) was introduced to enhance the material properties. Mechanical testing, microstructural characterization, and half-grouted sleeve uniaxial tensile tests were conducted to systematically evaluate the effect of NS content on grout performance. Results indicate that the incorporation of NS significantly accelerates the hydration of silica fume and fly ash. At an optimal dosage of 0.4%, the 28-day compressive strength reached 105.5 MPa, representing a 37.9% increase compared with the control group without NS. In sleeve tensile tests, specimens with NS exhibited reinforcement necking failure, and the load–displacement response closely aligned with the stress–strain behavior of the reinforcement. A linear relationship was observed between sleeve wall strain and reinforcement stress, confirming the cooperative load-bearing behavior between the grout and the sleeve. These findings provide theoretical guidance and technical support for developing high-strength, low-impact grouting materials suitable for sustainable engineering applications. Full article
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14 pages, 2674 KB  
Article
Thermal and Electrical Properties of Cement-Based Materials Reinforced with Nano-Inclusions
by Spyridoula G. Farmaki, Panagiota T. Dalla, Dimitrios A. Exarchos, Konstantinos G. Dassios and Theodore E. Matikas
Nanomanufacturing 2025, 5(3), 13; https://doi.org/10.3390/nanomanufacturing5030013 - 1 Sep 2025
Viewed by 66
Abstract
This study explores the influence of various nano-inclusions on the electrical and thermal properties of cement-based materials. Specifically, it investigates the incorporation of Multi-Walled Carbon Nanotubes (MWCNTs) and Graphene Nanoplatelets (GNPs) as reinforcement materials in cement composites. These advanced nanomaterials enhance the mechanical [...] Read more.
This study explores the influence of various nano-inclusions on the electrical and thermal properties of cement-based materials. Specifically, it investigates the incorporation of Multi-Walled Carbon Nanotubes (MWCNTs) and Graphene Nanoplatelets (GNPs) as reinforcement materials in cement composites. These advanced nanomaterials enhance the mechanical strength, durability, and functional properties of cementitious matrices. A series of experimental tests was conducted to evaluate the thermal and electrical behavior of nano-reinforced concrete, employing nondestructive evaluation techniques, such as Infrared Thermography (IRT) and Electrical Resistivity measurements. The results indicate that increasing the concentration of nanomaterials significantly improves both the thermal and electrical conductivity of the composites. Optimum performance was observed at a CNT dosage of 0.6% and a GNP dosage of 1.2% by weight of cement in cement paste, while in concrete, both nanomaterials showed a significant decrease in resistivity beginning at 1.0%, with optimal performance at 1.2%. The study also emphasizes the critical role of proper dispersion techniques, such as ultrasonication, in achieving a homogeneous distribution of nanomaterials within the cement matrix. These findings highlight the potential of carbon nanotubes (CNTs) and GNPs to enhance the multifunctional properties of cement-based materials, paving the way for their application in smart and energy-efficient construction applications. Full article
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16 pages, 2351 KB  
Article
Use of Expansive Agents to Increase the Sustainability and Performance of Heat-Cured Concretes
by José Luis García Calvo and Pedro Carballosa
Buildings 2025, 15(17), 3128; https://doi.org/10.3390/buildings15173128 - 1 Sep 2025
Viewed by 131
Abstract
Heat-curing processes are often used to ensure the production rate of precast concrete elements, as this process increases the early strength of the material. However, the increase in curing temperature can negatively affect the final mechanical properties since cracking, and especially high porosity, [...] Read more.
Heat-curing processes are often used to ensure the production rate of precast concrete elements, as this process increases the early strength of the material. However, the increase in curing temperature can negatively affect the final mechanical properties since cracking, and especially high porosity, may occur under these conditions. In order to compensate for the expected loss in mechanical and durability-related properties, the cement content is typically increased. This solution raises the cost of the final product and reduces its sustainability. Thus, in this study, the development of expansive self-compacting concretes (SCCs) is proposed to achieve higher final mechanical properties without increasing cement contents. The mechanical properties, expansive performance, and porous microstructure have been evaluated under different curing regimes. The obtained results show that it is possible to obtain similar or even better mechanical performance in expansive concretes cured at high temperatures than in those cured in standard conditions, particularly when using ettringite-based expansive agents (EAs). Moreover, the use of limestone filler (LF) proved to be more suitable than the use of fly ashes in the working conditions evaluated in the present study. In this sense, the compressive strength at 28 days of SCC with LF and ettringite-based EAs is 4.3% higher than the one obtained under standard curing; moreover, the total porosity is reduced (5%), and the drying shrinkage is also limited. These aspects have not been previously reported in non-expansive heat-cured concretes and represent a unique opportunity to reduce the cement content and, therefore, the carbon footprint of precast concretes without reducing their mechanical properties. When using CaO-based EAs, the results are also better than those of non-expansive SCC, although the improvement is less pronounced than in the previous case. Full article
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