Search Results (26)

The application of ceramic membranes in hemodialysis modules remains underexplored, as prior investigations have primarily concentrated on flat-sheet samples or small-scale assessments. This study advances the field by fabricating Al₂O₃ hollow fiber membranes, integrating them into a lab-scale module, and systematically evaluating the influence of sintering temperature on their structural characteristics, hemocompatibility, and dialysis performance. Al₂O₃ hollow fiber membranes were prepared using a phase inversion method and then sintered at three different temperatures. All membranes exhibited superior protein adsorption behavior compared to conventional polymer-based membranes, which indicates higher biocompatibility. Furthermore, the amount of adsorbed protein decreased with increasing sintering temperature. This suggests that the amount of protein adsorption can be controlled by adjusting the heat treatment conditions. The lab-scale hemodialyzer integrated with a membrane sintered at 1200 °C achieved the fastest urea removal rate of approximately 90% in 2 h and reached a Kt/V value of 1.1 after 60 min, which is comparable to the performance of commercial polymer-based hemodialyzers. Full article

In this study, high-yield biopolymer/ceramic hollow fibers were fabricated via a facile, modified polyol process in a spinneret setup, enabling the controlled adsorption of Cu²⁺ ions. Post sintering transformed these into catalytic copper-decorated carbon/ceramic (alumina) composite hollow fibers, with alginate serving as both a metal ion binder and a copper nanoparticle stabilizer. The resulting hollow fibers featured porous walls with a high surface area and were densely decorated with copper nanoparticles. Their structural and morphological characteristics were analyzed, and their NO reduction performance was assessed in a continuous flow configuration, where the gas stream passed through both the shell and lumen sides of a fiber bundle in a tangential flow mode. This study also examined the stability, longevity and regeneration potential of the catalytic fibers, including the mechanisms of deactivation and reactivation. Carbon content was found to be decisive for catalytic performance. High-carbon fibers exhibited a light-off temperature of 250 °C, maintained about 90% N₂ selectivity and sustained a consistently high NO reduction efficiency for over 300 h, even without reducing gases like CO. In contrast, low-carbon fibers displayed a higher light-off temperature of 350 °C and a reduced catalytic efficiency. The results indicate that carbon enhances both activity and selectivity, counterbalancing deactivation effects. Owing to their scalability, durability and effectiveness, these catalytic fibers and their corresponding bundle-type reactor configuration represent a promising technology for advanced NO abatement. Full article

This study aims to compare the carbon footprints associated with the fabrication of two types of alumina-based tubular ceramic membranes used in microfiltration (MF): a multichannel membrane produced by extrusion and dip-coating, and an asymmetric hollow fiber membrane fabricated via phase inversion. The multichannel process involves two sintering steps but uses no organic solvents, whereas the phase-inversion method simplifies production through single-step shaping and sintering but requires organic solvents that increase environmental burdens. Using a functional unit of 1 m² effective membrane area, carbon emissions were quantified from raw material extraction to waste disposal. The results showed total emissions of 8.57 kg CO₂-eq/m² for the multichannel membrane and 10.67 kg CO₂-eq/m² for the hollow fiber membrane. Although the hollow fiber process consumed less energy, its extensive use of solvents, particularly NMP, led to significantly higher emissions. This study provides the first quantitative comparison of these two common ceramic membrane fabrication routes and underscores the importance of considering both energy use and solvent impacts when evaluating the environmental sustainability of membrane production. A sensitivity analysis further evaluated the influence of key parameters, including alumina emission factor, regional electricity carbon intensity, alumina recycling, and solvent substitution or NMP recycling. The analysis demonstrated that each factor could significantly influence the total carbon footprint and, under favorable conditions, narrow or even reverse the gap between the two fabrication routes. This study provides the first quantitative comparison of these two common ceramic membrane fabrication methods and highlights the importance of considering energy use, solvent impacts, and potential mitigation strategies when assessing the environmental sustainability of ceramic membrane production. Full article

This study investigates the application of spinel (MgAl₂O₄) hollow fiber membranes for clarification of clove basil (Ocimum gratissimum L.) aqueous extract, a rich source of bioactive compounds. The membranes were produced using a phase-inversion and sintering method at 1350 °C, combining alumina and dolomite as raw materials. The calcination of the powder materials at 1350 °C resulted in the spinel phase formation, as indicated by the XRD analyses. The spinel hollow fiber membrane presented a hydrophilic surface (water contact angle of 74°), moderate roughness (144.31 ± 12.93 nm), and suitable mechanical strength. The ceramic membrane demonstrated a water permeability of 35.28 ± 2.46 L h⁻¹ m⁻² bar⁻¹ and a final permeate flux of 9.22 ± 1.64 L h⁻¹ m⁻² for filtration of clove basil extract at 1.0 bar. Fouling analysis identified cake formation as the dominant mechanism for flux decline. The membrane retained 44% of the total phenolic compounds and reduced turbidity by 60%, while preserving significant antioxidant capacity in the permeate. The results highlight the potential of spinel-based hollow fiber membranes as a cost-effective and efficient solution for clarifying bioactive plant extracts, offering enhanced mechanical properties and lower sintering temperatures compared to conventional alumina membranes. Full article

This work focuses on the production of ceramic nanofibers from waste materials, which represents a significant contribution to the sustainable use of resources and innovative solutions in the field of nanotechnology. The research builds on existing knowledge of nanofiber production, with a specific focus on the use of zinc galvanizing flue dust. The main objective of the study is to explore the possibilities of converting zinc-containing waste materials into ceramic nanofibers, introducing a new direction in nanotechnology. Laboratory experiments involved leaching processes and electrostatic spinning processes of zinc solutions. From the obtained results, it can be concluded that ZnO ceramic nanofibers produced from both synthetic and real solutions exhibit similar fiber structures. Therefore, it can be stated that both acids (HCl and H₂SO₄) are suitable for preparation. Among them, 0.5 M HCl is the most ideal, resulting in oval fibers with a rough and coarse surface, while 0.5 M H₂SO₄ produces fibers with a different morphology in the form of hollow ribbons, which are presumed to have a higher specific surface area. Thus, it can be concluded that the production of ceramic nanofibers from zinc galvanizing flue dust is feasible and effective, with electrostatic spinning proving to be a low-waste technology. The study also examines the influence of contaminants from real waste solutions on the production of ceramic nanofibers and compares their properties with nanofibers obtained from synthetic solutions. Experimental results suggest that contaminants in real solutions did not have a negative impact on the morphology of the prepared ZnO nanofibers. In conclusion, the production of ZnO ceramic nanofibers from waste offers a promising approach for the future development of nanotechnology, combining innovation with sustainability and efficient resource utilization. Full article

In this numerical study, the performance of ceramic-based mullite hollow fiber (HF) membranes in a direct contact membrane distillation (DCMD) process was evaluated. Three types of membranes were tested: (i) hydrophobic membrane C8-HFM, (ii) rod-like omniphobic membrane (C8-RL/TiO₂), and (iii) flower-like omniphobic membrane (C8-FL/TiO₂). The CFD model was developed and validated with experimental results, which were performed over a 500 min period. The initial mass flux of C8-HFM was 30% and 9% higher than that of C8-FL/TiO₂ and C8-RL/TiO₂, respectively. However, the flower-like omniphobic membrane C8-FL/TiO₂ had the lowest drop in flux, around 11%, while the rod-like omniphobic membrane C8-RL/TiO₂ had a 15% reduction, both better than the 23% reduction in the hydrophobic membrane C8-HFM over the 500 min. The study also analyzed the impact of fouling by examining the variation in mass transfer coefficient (MTC) over time. The results indicated that the ceramic-based mullite HF membranes with TiO₂ flowers and rods demonstrated a high resistance to fouling compared to C8-HFM. The modified membranes could find applications in the desalination and handling of seawater samples containing organic contaminants. The CFD model’s versatility can be utilized beyond the current investigation’s scope, offering a valuable tool for efficient membrane development solutions, particularly for challenges such as the presence of organic contaminants in seawater. Full article

Partial oxidation of methane (POM) is a prominent pathway for syngas production, wherein the hydrogen in syngas product can be recovered directly from the reaction system using a hydrogen (H₂)-permeable membrane. Enhancing the efficiency of this H₂ separation process is a current major challenge. In this study, Ce_0.8Y_0.2O_2-δ-BaCe_0.8Y_0.2O_3-δ (YDC-BCY) hollow fiber (HF) membranes were developed and characterized for their H₂ permeation fluxes. Firstly, YDC and BCY ceramic powders were synthesized using the sol-gel method, followed by the fabrication of YDC-BCY dual-phase ceramic HF membranes using a combined phase inversion–sintering process. Characterization using SEM, powder XRD, EDS, and electrical conductivity tests confirmed the phases of the prepared powders and HF membranes. Well-structured YDC and BCY powders with uniform particle sizes were obtained after calcination at 900 °C. With the addition of 1 wt.% Co₂O₃ as a sintering aid, the YDC-BCY dual-phase HF membrane achieved densification after sintering at 1500 °C. Subsequently, the influences of sweep gas composition and temperature on the hydrogen permeation of the YDC-BCY HF membranes with YDC/BCY molar ratios of 2:1, 3:1, and 4:1 were investigated. At 1000 °C and a sweep-gas flow rate of 120 mL·min⁻¹, the YDC-BCY HF membrane with a YDC/BCY molar ratio of 4:1 exhibited a peak hydrogen flux of 0.30 mL·min⁻¹ cm⁻². There is significant potential for improving the hydrogen permeation of dual-phase ceramic membranes, with future efforts aimed at reducing dense layer thickness and enhancing the membrane material’s electronic and proton conductivities. Full article

This report presents the results of long-term tests on concrete beams reinforced with steel cord. In this study, natural aggregate was wholly replaced with waste sand or with wastes from the production of ceramic products and ceramic hollow bricks. The amounts of individual fractions used were determined in accordance with guidelines for reference concrete. A total of eight mixtures were tested; these differed in terms of the type of waste aggregate used. Elements with various fiber-reinforcement ratios were made for each mixture. Steel fibers and waste fibers were used in amounts of 0.0%, 0.5%, and 1.0%. Compressive strength and modulus of elasticity were determined experimentally for each mixture. The main test was a four-point beam bending test. Beams with dimensions of 100 mm × 200 mm × 2900 mm were tested on a stand, which was specially prepared so that three beams could be tested simultaneously. Fiber-reinforcement ratios were 0.5% and 1.0%. Long-term studies were conducted for 1000 days. During the testing period, beam deflections and cracks were measured. The obtained results were compared with values calculated using several methods, considering the influence of dispersed reinforcement. The results enabled the best methods for calculating individual values for mixtures with different types of waste materials to be determined. Full article

The absorption efficiencies of CO₂ in ceramic hollow-fiber membrane contactors using monoethanolamine (MEA) absorbent under both cocurrent- and countercurrent-flow operations were investigated theoretically and experimentally; various MEA absorbent flow rates, CO₂ feed flow rates, and inlet CO₂ concentrations were used as parameters. Theoretical predictions of the CO₂ absorption flux were analyzed by developing the mathematical formulations based on Happel’s free surface model in terms of mass transfer resistances in series. The experiments of the CO₂ absorption were conducted by using alumina (Al₂O₃) hollow-fiber membranes to confirm the accuracy of the theoretical predictions. The simplified expression of the Sherwood number was formulated to calculate the mass transfer coefficient of the CO₂ absorption incorporating experimental data. The data were obtained numerically using the fourth-order Runge–Kutta method to predict the concentration distribution and absorption rate enhancement under various fiber packing configurations accomplished by the CO₂/N₂ stream passing through the fiber cells. The operations of the hollow-fiber membrane contactor encapsulating N = 7 fiber cells and N = 19 fiber cells of different packing densities were fabricated in this work to examine the device performance. The accuracy derivation between experimental results and theoretical predictions for cocurrent- and countercurrent-flow operations were $1.31\times {10}^{-2}\le E\le 4.35\times {10}^{-2}$ and $3.90\times {10}^{-3}\le E\le 2.43\times {10}^{-2}$, respectively. A maximum of 965.5% CO₂ absorption rate enhancement was found in the module with embedding multiple fiber cells compared with that in the device with inserting single-fiber cell. Implementing more fiber cells offers an inexpensive method of improving the absorption efficiency, and thus the operations of the ceramic hollow-fiber membrane contactor with implementing more fiber cells propose a low-priced design to improve the absorption rate enhancement. The higher overall CO₂ absorption rate was achieved in countercurrent-flow operations than that in cocurrent-flow operations. Full article

Due to its greater physical–chemical stability, ceramic nanofiltration (NF) membranes were used in a number of industrial applications. In this study, a novel NF membrane was prepared by co-depositing a titanium dioxide (TiO₂) and graphene oxide (GO) composite layer directly onto a porous α-Al₂O₃ hollow fiber (HF) support. An 8 µm-thick TiO₂/GO layer was deposited to the surface of α-Al2O3 HF support by vacuum deposition method to produce advanced TiO₂/GO-Al₂O₃ HF NF membrane. Scanning electron microscope (SEM) micrographs, energy dispersive spectrometer (EDS), X-ray powder diffraction (XRD), thermogravimetric analyzer (TGA), porosity, 3-point bending strength, zeta potential analysis, and hydrophilic properties by water contact angle are used for TiO₂/GO-Al₂O₃ HF NF membrane characterization. The results show that the developed membrane’s MWCO ranged from 600 to 800 Da. The water flux, rejection of lignin, and sodium ions were 5.6 L/m² h·bar, ~92.1%, and ~5.5%, respectively. In a five-day NF process, the TiO₂/GO-Al₂O₃ HF NF membrane exhibits good lignin permeation stability of about 14.5 L/m² h. Full article

This article describes the recycling of coarse and fine fractions and powder from construction and demolition waste (CDW) using alkaline activation technology (geopolymerization). The CDW sample used corresponds to a mixture (mixed waste) of concrete (Co), ceramics (Ce) and masonry (M). Co, Ce and M (CDW-Mixed) powders were used as geopolymer precursors. As an alkaline activator, a mixture of sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) was used. From CDW-Mixed, a hybrid cement added with 10% ordinary Portland cement (OPC) was synthesized to promote curing at room temperature (25 °C). From the alkali-activated hybrid cement and the incorporation of mixed recycled aggregates (gravel and sand), applications of mortars, concretes, fiber-reinforced materials and prefabricated units, such as solid blocks, perforated (hollow) blocks and pavers, were produced. The results of the physical–mechanical characterization validate the application potential of these CDW-based materials in the construction sector. Compressive strengths of up to 40.5 MPa for mortar and 36.9 MPa for concrete were obtained after 90 days of curing at room temperature ≈ 25 °C. Similarly, a life cycle analysis (LCA) associated with raw materials demonstrated the environmental sustainability (44% lower carbon footprint) of mixed alkali-activated CDWs compared to conventional materials based on OPC. Full article

Membrane processes can be integrated with fermentation for the selective separation of the products from the fermentation broth. Sterilization with saturated steam under pressure is the most widely used method; however, data concerning heat sterilization applicability to polymeric ultrafiltration (UF) membranes are scarcely available. In this study, the effect of the sterilization process on the filtration performance of a commercial polyvinylidene difluoride (PVDF) hollow fiber UF membrane was evaluated. Membrane modules were constructed and sterilized several times in an autoclave. Pure water flux tests were performed, to assess the effect of heat sterilization on the membrane’s pure water permeance. Dextran rejection tests were performed for the characterization of membrane typical pore size and its fouling propensity. Filtration performance was also assessed by conducting filtration tests with real fermentation broth. After repeated sterilization cycles, pure water permeance remained quite constant, varying between approx. 830 and 990 L·m⁻²·h⁻¹·bar⁻¹, while the molecular weight cut-off (MWCO) was estimated to be in the range of 31.5–98.0 kDa. Regarding fouling behavior, the trans-membrane pressure increase rate was stable and quite low (between 0.5 and 7.0 mbar/min). The results suggest that commercial PVDF UF membranes are a viable alternative to high-cost ceramic UF membranes for fermentation processes that require heat sterilization. Full article

This research aimed to investigate the ultrafiltration of water from emulsified oily wastewater through the application of surface-functionalized ceramic membrane to enhance its water permeability based on optimized parameters using a cross-flow filtration system. The interactive effects of feed concentration (10–1000 ppm), pH (4–10), and pressure (0–3 bar) on the water flux and oil rejection were investigated. Central composite design (CCD) from response surface methodology (RSM) was employed for statistical analysis, modeling, and optimization of operating conditions. The analysis of variance (ANOVA) results showed that the oil rejection and water flux models were significant with p-values of 0.0001 and 0.0075, respectively. In addition, good correlation coefficients of 0.997 and 0.863 were obtained for the oil rejection and water flux models, respectively. The optimum conditions for pressure, pH, and feed concentration were found to be 1.5 bar, pH 8.97, and 10 ppm, respectively with water flux and oil rejection maintained at 152 L/m²·h and 98.72%, respectively. Hence, the functionalized ultrafiltration ceramic membrane enables the separation efficiency of the emulsified oil in water to be achieved. Full article

A compact microfluidic Raman detection system based on a single-ring negative-curvature hollow-core fiber is presented. The system can be used for in-line qualitative and quantitative analysis of biochemicals. Both efficient light coupling and continuous liquid injection into the hollow-core fiber were achieved by creating a small gap between a solid-core fiber and the hollow-core fiber, which were fixed within a low-cost ceramic ferrule. A coupling efficiency of over 50% from free-space excitation laser to the hollow core fiber was obtained through a 350 μm-long solid-core fiber. For proof-of-concept demonstration of bioprocessing monitoring, a series of ethanol and glucose aqueous solutions at different concentrations were used. The limit of detection achieved for the ethanol solutions with our system was ~0.04 vol.% (0.32 g/L). Such an all-fiber microfluidic device is robust, provides Raman measurements with high repeatability and reusability, and is particularly suitable for the in-line monitoring of bioprocesses. Full article

A numerical study on the oxidation removal of nitric oxide in a ceramic hollow fiber membrane contactor was performed. To represent the transport and absorption process, the model was created by combining multiphase, species, reaction, and porous models. The numerical results were verified by comparing them with experimental data. The tube and lumen sides both have laminar parabolic velocity distributions. The nitric oxide concentration decreases gradually from the membrane wall to axis at the cross-section except on the inner and outer sides of the membrane tube. The equivalent diffusion length was proved useful for evaluating the entrance effect. At low concentrations, the reduction efficiency was proportional to the absorbent concentration, and at large concentrations, it neared a maximum value. The reduction efficiency was positively affected by elevated operating temperature and pressure. With a gas channel width of 13 mm, the reduction flow rate achieves its maximum. The efficiency of NO reduction per area decreases as the effective membrane length increases. Increasing the operating temperature and membrane length are recommended as design priorities due to high relative enhancements. It is not recommended to improve reduction efficiency by increasing membrane tube diameter and operating pressure in design. Changing the gas flow rate, absorbent concentration and gas channel width are moderate recommended as well. Full article